Yusmaniar
Program Studi Kimia, Fakultas Matematika Dan Ilmu Pengetahuan Alam, Universitas Negeri Jakarta, Gedung KH. Asj’arie, Jl. Rawamangun Muka, 13220, Jakarta, Indonesia

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Pengaruh Integrasi Laboratorium Virtual dalam Model Pembelajaran Problem Solving Terhadap Kemampuan Berpikir Kritis Peserta Didik pada Materi Elektrolit dan Non elektrolit Dwi Afni Musyaillah; Sukro Muhab; Yusmaniar
Jurnal Riset Pendidikan Kimia (JRPK) Vol 10 No 1 (2020): Jurnal Riset Pendidikan Kimia (JRPK), Volume 10 Nomor 1 (2020)
Publisher : LPPM Universitas Negeri Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21009/JRPK.101.07

Abstract

The purpose of this study was to determine the positive effect of virtual laboratory integration in Problem Solving learning models on students' critical thinking skills in the electrolyte and non-electrolyte solution materials. This research was conducted in December 2018 - May 2019. The quantitative research method used was a quasi-experiment with Posttest Only Control Group Design. This research consisted of experimental class and control class, with 36 students in each class. The experimental class applies virtual laboratory integration learning in the Problem Solving learning model, while the control class applies 5M learning. The results showed that the average posttest value of the experimental class was 72.8 and the control class was 63.7. The results of the testing of the hypothesis were obtained by the value of t count (4.942)> t table (1,667) with a value with a significant level of 0.05, indicating that the positive influence of virtual laboratory integration in the Problem Solving learning model on students' critical thinking abilities in electrolyte solution material and nonelectrolytes. KeywordsVirtual Laboratory, Problem Solving, Critical Thinking Ability, Electrolyte and nonelectrolyte
SINTESIS DAN UJI ADSORPSI SILIKA TERMODIFIKASI 3-Aminopropiltrietoksisilan (APTS) PADA LOGAM Cu (II) DALAM LARUTAN Yusmaniar Yusmaniar; Maria Paristiowati; Nathasya Jofita
Jurnal Riset Sains dan Kimia Terapan Vol 4 No 2 (2014): JRSKT - Jurnal Riset Sains dan Kimia Terapan, Volume 4 Nomor 2 Desember 2014
Publisher : Program Studi Kimia Universitas Negeri Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (935.472 KB) | DOI: 10.21009/JRSKT.042.02

Abstract

Pada penelitian ini dibuat adsorben silika termodifikasi APTS yang disintesis menggunakan bahan dasar sekam padi. Abu sekam padi ini diolah sedemikian rupa menjadi larutan natrium silikat hingga menghasilkan produk silika gel. Silika gel kemudian dimodifikasi secara kimia dengan reagen 3-aminopropiltrietoksisilan (APTS) sehingga menghasilkan silika termodifikasi APTS. Hasil FTIR menunjukkan bahwa silika termodifikasi APTS mengandung serapan gugus fungsi amino (-NH2), silanol (Si-OH), siloksana (Si-O-Si), dan rantai alifatik (-CH2-). Kandungan dari silika termodifikasi APTS yang ditunjukkan melalui hasil analisis EDX juga menunjukkan bahwa produk memiliki persentase massa masing-masing atom 35.26% silika, 48.47% oksigen, dan 16.27% nitrogen. Hasil penelitian menunjukkan bahwa pH optimum yang diperlukan untuk adsorpsi ion Cu(II) dengan silika termodifikasi APTS adalah 4.0 dan konsentrasi optimum sebesar 100 mg/L. Adsorpsi ion Cu(II) oleh silika termodifikasi APTS mengikuti isoterma adsorpsi Langmuir dengan nilai qmaks sebesar 48.36 mg/g. Dengan demikian adsorpsi terjadi secara kimia dengan membentuk lapisan monolayer. APTS modified silica adsorbent which has been synthesized, using rice hull ash as a raw material. This rice hull ash was carried out to sodium silicate which will be produced to silica gel product. Silica gel was modified with 3-Aminopropyltriethoxysilane (3-APTS) so that produced APTS modified silica. FTIR data indicated APTS modified silica showed the presence of amine (-NH2), silanol (Si-OH), siloxane (Si-O-Si) groups, and aliphatic chains (-CH2-). Contents of APTS modified silica were determined by EDX which had 35.26% silica, 48.47% oxygen, and 16.27% nitrogen. Research results showed that a pH value is 4.0 which is favorable for copper adsorption and optimum concentration value is 100 mg/L Cu(II). Adsorption process of Copper(II) ion by APTS modified silica followed Langmuir isotherm with qmaks 48.36 mg/g. Therefore adsorption happened chemically with monolayer.Key words: APTS modified silica, sol-gel, rice hull ash, adsorption, copper.
PENGARUH WAKTU REAKSI DALAM SINTESIS BESI BERVALENSI NOL (ZVI) DARI FeSO4 DENGAN EKSTRAK POLIFENOL KULIT PISANG KEPOK Gilang Arif Pribadi; Setia Budi; Yusmaniar Yusmaniar
Jurnal Riset Sains dan Kimia Terapan Vol 4 No 2 (2014): JRSKT - Jurnal Riset Sains dan Kimia Terapan, Volume 4 Nomor 2 Desember 2014
Publisher : Program Studi Kimia Universitas Negeri Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (722.45 KB) | DOI: 10.21009/JRSKT.042.04

Abstract

Besi bervalensi nol (ZVI) telah berhasil disintesis menggunakan ekstrak kulit pisang kepok sebagai reduktor alami. Analisis terhadap karakteristik ZVI hasil sintesis berupa ukuran, kristalinitas dan morfologi telah dilakukan dengan menggunakan spektrofotometer UV-Vis, particle size analyzer (PSA), X-ray difractometer (XRD), scanning electron microscope (SEM), dan fourier transform infra-red (FT-IR). Pengukuran konsentrasi Fe2+ yang bereaksi dengan ekstrak yang digunakan divariasikan terhadap waktu, yaitu: 0 jam, 3 jam, 24 jam, 48 jam dan 144 jam. Konsentrasi Fe2+ yang bereaksi dengan polifenol terbesar terjadi ketika waktu reaksi 3 jam, yaitu 110.465,22 ppm. Waktu reaksi 1 jam menghasilkan distribusi ukuran partikel yang paling rendah, yaitu Dv 10 = 383,93 nm; Dv 50 = 537,17 nm; dan Dv 90 = 851,36 nm dengan polydispersity Index (PDI) sebesar 0,1240. Difrasi sinar-X menunjukkan ZVI hasil sintesis merupakan amorf yang terdiri dari fasa iron dan magnetite dengan presentase masing-masing berturut-turut 17,5 % dan 82,5%.Kata Kunci: Besi Bervalensi Nol (ZVI), Reduksi Garam Besi, Polifenol, Waktu Reaksi, Dv, PDI, Aglomerasi. Zero valent iron (ZVI) has been synthesized using banana peel extracts. Characterization of the obtained ZVI was carried out using UV-Vis spectrophotometer, particle size analyzer (PSA), X-ray difractometer (XRD), scanning electron microscope (SEM), and fourier transform infra-red (FT-IR). Measurement of the concentration of Fe2+ reacted with the used extracts varied with respect to time, namely 0 hours, 3 hours, 24 hours, 48 hours and 144 hours. The concentration of Fe2+ which reacts with the largest polyphenols occur when reaction time of 3 hours, ie 110,465.22 ppm. Reaction time of 1 hour to produce a particle size distribution of the lowest, ie Dv 10 = 383.93 nm; Dv 50 = 537.17 nm; and Dv 90 = 851.36 nm with a polydispersity index (PDI) of 0.1240. X-ray diffraction showed that synthesized ZVI is an amorphous phase consisting of iron and magnetite with the percentage of each respectively 17.5% and 82.5%.Keywords: Zero Valent Iron (ZVI), Reduction of Iron Salt, Polyphenols, Time Reaction, Dv, PDI, Agglomeration
PENGARUH PENAMBAHAN SILIKA TERHADAP MEMBRAN SULFONASI POLIETER ETER KETON – AKRILONITRILBUTADIENA STIRENA Eka Fitrianingsih; Yusmaniar Yusmaniar; Afrizal Afrizal
Jurnal Riset Sains dan Kimia Terapan Vol 3 No 1 (2013): JRSKT - Jurnal Riset Sains dan Kimia Terapan, Volume 3 Nomor 1 Juli 2013
Publisher : Program Studi Kimia Universitas Negeri Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (902.702 KB)

Abstract

Telah dilakukan penelitian mengenai pengaruh penambahan silika pada membran Sulfonasi Polieter Eter Keton-Akrilonitril Butadiena Stirena untuk aplikasi PEMFC. Variasi dilakukan pada konsentrasi silika sebesar 0%, 3%, 5%, 10%, dan 15% dari berat polimer. Tujuan penambahan silika adalah untuk mendapatkan konsentrasi silika optimum pada membran SPEEK-ABS. Hasil penelitian menunjukkan konsentrasi silika optimum berada pada penambahan silika 3%. Penambahan silika 3% memberikan karakteristik pada membran yaitu mampu meningkatkan konduktivitas ionik sebesar 0.0075 x 10-3 S/cm. Dengan penambahan silika juga dapat meningkatkan swelling terhadap air dan metanol. Analisis gugus sulfonat pada membran dilakukan dengan FTIR dan memperoleh hasil gugus sulfonat membran SPEEK-ABS berada pada bilangan gelombang 1203.58 cm-1.Kata kunci : membran elektrolit, SPEEK, ABS, silika, konduktivitas ionik, swelling. Has done research on the effect of silica on membranes sulfonated polyether ether ketone – acrylonitrile butadiene styrene for applications PEMFC. Variation performed on silica concentration of 0%, 3%, 5%, 10%, and 15% by weigh of use polymer. The purpose of this addition silica is to find the optimum of silica concentration on membranes SPEEK-ABS. The result experiment showed that optimum of silica concentration is 3%. Additionally of 3% silica can be characteristic on membranes is to be increasing ionic conductivity of of 0.0075x10-3 S/cm. With addition silica can be increasing swelling water and methanol. Analysis of group sulfonated membranes is done by FT-IR and getting the wave value is 1203.58 cm-1.Keywords : membranes electrolyte, SPEEK, ABS, silica, ionic conductivity, swelling
PEMANFAATAN SILIKA DARI SEKAM PADI PADA KOMPOSIT POLIESTER TEK JENUH-SILIKA Yusmaniar Yusmaniar; Maria P. Suryani
Jurnal Riset Sains dan Kimia Terapan Vol 2 No 2 (2012): JRSKT - Jurnal Riset Sains dan Kimia Terapan, Volume 2 Nomor 2 Desember 2012
Publisher : Program Studi Kimia Universitas Negeri Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (106.993 KB) | DOI: 10.21009/JRSKT.022.04

Abstract

Silica was extracted from rice husk ash, and then applied as a filler in Unsaturated polyester/silica(UP/SiO2) composite. The aim of this rpicle were artesearch to know the characteristic of silica and it uses as a filler in composite by tensile strength test. The size variation of silica were 60, 100, 230 and 400 mesh, while variation of silica concentration (% w/w) were 0.5%, 1 %, 1.5 % and 2 %. The analysis concluded that variation of particle size and concentration of silica were reduce the tensile strength of composite Key word: silica, composite, tensile strength
Pengaruh Perbandingan Pati Biji Sorgum (Sorghum Bicolor (l.) Moench) dan Poly Lactic Acid (PLA) terhadap Karakteristik Plastik Biodegradable Siti Sarifah; Yusmaniar Yusmaniar; Zulmanelis Darwis
Jurnal Riset Sains dan Kimia Terapan Vol 7 No 1 (2017): JRSKT - Jurnal Riset Sains dan Kimia Terapan, Volume 7 Nomor 1 Juli 2017
Publisher : Program Studi Kimia Universitas Negeri Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (586.93 KB) | DOI: 10.21009/JRSKT.071.05

Abstract

This study aims to determine the effect of Sorghum and Poly lactic acid (PLA) on the plastic characteristics that can be seen from tensile strength, water resistance, and biodegradability. The method used blending (mixing) sorghum seed starch, PLA, glycerol, acetic acid, and maleic anhydride. From the results of infrared spectrum analysis on the visible plastic peak area 2250-2300 cm-1 which indicates the absorption of carbon dioxide. This plastic has an optimum water resistance of 92.76% in the ratio of Pati 0.6g: PLA 2.6g. The optimum tensile test results in a comparison of 0.2g starch: PLA 3g with a value of 10.58 Mpa. Optimum biodegradation test results in starch ratio of 0.6g: PLA 2.6g of 13.61%. From the data obtained can be concluded the optimum biodegradation and water endurance test on the ratio of starch 0.6g: PLA 2.6g. Keyword: Seaweed starch, PLA, glycerol, maleic anhydrous, biodegraded plastic
Sintesis Komposit Silika Gel dari Sekam Padi – 3-Aminopropiltrietoksisilan (APTES) dengan Karbon Aktif dari Tempurung Kelapa dan Uji Adsorpsi Terhadap Logam Cd (II) Ratih Noviasari; Yusmaniar Yusmaniar; Arif Rahman
Jurnal Riset Sains dan Kimia Terapan Vol 7 No 1 (2017): JRSKT - Jurnal Riset Sains dan Kimia Terapan, Volume 7 Nomor 1 Juli 2017
Publisher : Program Studi Kimia Universitas Negeri Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (699.316 KB) | DOI: 10.21009/JRSKT.071.06

Abstract

In this research, silica gel composite modified adsorbents were made with APTES and activated carbon. Silica gel comes from rice husk and activated carbon comes from coconut shell. This rice husk ash is processed in such a way as a sodium silicate solution to produce a silica gel product. The silica gel was then mixed with 3-aminopropylsylatedoxylic reagent (APTES) and activated carbon previously with ZnCl 2 solution and processed into composite. Characterization of composite synthesis using FTIR spectroscopy shows uptake of N-H, silanol (Si-OH), siloxane (Si-O-Si), and C-H bonds. The content of the silica gel composite modified by APTES and activated carbon is indicated through EDX analysis results that the composite of the synthesis has a mass percentage of each atom of 32.92% carbon, 25.88% nitrogen, 26.04% oxygen, and 15.16% silica. The results showed that the optimum pH required for the adsorption of Cd (II) ions with silica gel composite was modified with APTES and the activated carbon was 5.0 and the optimum contact time was 30 minutes. Adsorption of Cd (II) ions by silica gel composites was modified by APTES and activated carbon followed Freundlich adsorption isotherm. Therefore, adsorption occurs forming a heterogeneous monolayer layer. Keywords rice husk ash, silica gel, APTES, activated carbon, composite, adsorption
Adsorbsi Pewarna Direct Black 38 Menggunakan Komposit Silika Mesopori Dari Abu Sekam Padi/Karbon Aktif Dari Tempurung Kelapa Dilma Purnama Ubit; Yusmaniar Yusmaniar; Erdawati Erdawati
Jurnal Riset Sains dan Kimia Terapan Vol 8 No 1 (2019): Jurnal Riset Sains dan Kimia Terapan, Volume 8 Nomor 1, Maret 2019
Publisher : Program Studi Kimia Universitas Negeri Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (304.303 KB) | DOI: 10.21009/JRSKT.081.01

Abstract

Abstrak Pada penelitian ini adsorben komposit silika mesopori dan karbon aktif dibuat untuk mengadsorpsi zat warna direct black 38. Silika mesopori dibuat dari abu sekam padi dan karbon aktif dibuat dari tempurung kelapa. Silika direaksikan dengan NaOH menjadi larutan natrium silikat lalu direaksikan dengan PEG yang selanjutnya PEG diekstraksi secara solvotermal sehingga menghasilkan produk silika mesopori dengan luas permukaan dan pori yang lebih besar. Silika mesopori diproses menjadi komposit dengan karbon aktif yang telah diaktivasi sebelumnya dengan larutan ZnCl2. Kandungan dari komposit silika mesopori/karbon aktif ditunjukkan melalui hasil analisis SEM bahwa komposit hasil sintesis menunjukkan penyebaran karbon dan silika terlihat pada morfologi komposit. Hasil analisis EDX menunjukan komponen penyusun komposit yaitu 38,6% karbon; 46,8% oksigen dan 14,6% silika. Hasil penelitian menunjukan bahwa kondisi optimum yang diperlukan untuk adsorpsi direct black 38 dengan komposit silika mesopori/karbon aktif yaitu pH 2 dan waktu optimum 30 menit. Adsorpsi direct black 38 oleh komposit silika mesopori/karbon aktif mengikuti isoterm adsorpsi Langmuir. Oleh karena itu, adsorpsi yang terjadi membentuk lapisan monolayer dengan kapasitas adsorpsi 68,493 mg g-1 Kata kunci: abu sekam padi, adsorpsi, karbon aktif, komposit, PEG, silika mesopori Abstract In this research, mesopore silica/activated carbon composite adsorbent was formed for dye adsorption direct black 38. The mesopore silica was from rice husk ash and activated carbon was from coconut shell. This rice husk ash is processed into sodium silicate solution and the solution was hybrid with PEG. Then PEG was extracted with solvotermal method to produce a higher surface area of mesopore silica. The mesopore silica was processed into composite with activated carbon that has been activated by ZnCl2 solution. The mesopore silica/activated carbon composite was analysed by SEM and showed the distribution of carbon, silica and oxygen as composite morphology. The EDX analysis showed that the composite contains of 46.8% carbon; 3.6% oxygen and 14.6% silica. The results showed that the optimum condition required for the adsorption of direct black 38 dye with mesopore silica/activated carbon composite pH was 2 and the optimum contact time was 30 minutes. Adsorption of direct black 38 by mesopore silica/activated carbon composite followed Langmuir adsorption isotherm and formed a monolayer layer with adsorption capacity 68.493 mg g-1. Keywords: activated carbon, adsorption, composite, mesopore silica, PEG, rice husk ash Abstrak Pada penelitian ini adsorben komposit silika mesopori dan karbon aktif dibuat untuk mengadsorpsi zat warna direct black 38. Silika mesopori dibuat dari abu sekam padi dan karbon aktif dibuat dari tempurung kelapa. Silika direaksikan dengan NaOH menjadi larutan natrium silikat lalu direaksikan dengan PEG yang selanjutnya PEG diekstraksi secara solvotermal sehingga menghasilkan produk silika mesopori dengan luas permukaan dan pori yang lebih besar. Silika mesopori diproses menjadi komposit dengan karbon aktif yang telah diaktivasi sebelumnya dengan larutan ZnCl2. Kandungan dari komposit silika mesopori/karbon aktif ditunjukkan melalui hasil analisis SEM bahwa komposit hasil sintesis menunjukkan penyebaran karbon dan silika terlihat pada morfologi komposit. Hasil analisis EDX menunjukan komponen penyusun komposit yaitu 38,6% karbon; 46,8% oksigen dan 14,6% silika. Hasil penelitian menunjukan bahwa kondisi optimum yang diperlukan untuk adsorpsi direct black 38 dengan komposit silika mesopori/karbon aktif yaitu pH 2 dan waktu optimum 30 menit. Adsorpsi direct black 38 oleh komposit silika mesopori/karbon aktif mengikuti isoterm adsorpsi Langmuir. Oleh karena itu, adsorpsi yang terjadi membentuk lapisan monolayer dengan kapasitas adsorpsi 68,493 mg g-1 Kata kunci: abu sekam padi, adsorpsi, karbon aktif, komposit, PEG, silika mesopori Abstract In this research, mesopore silica/activated carbon composite adsorbent was formed for dye adsorption direct black 38. The mesopore silica was from rice husk ash and activated carbon was from coconut shell. This rice husk ash is processed into sodium silicate solution and the solution was hybrid with PEG. Then PEG was extracted with solvotermal method to produce a higher surface area of mesopore silica. The mesopore silica was processed into composite with activated carbon that has been activated by ZnCl2 solution. The mesopore silica/activated carbon composite was analysed by SEM and showed the distribution of carbon, silica and oxygen as composite morphology. The EDX analysis showed that the composite contains of 46.8% carbon; 3.6% oxygen and 14.6% silica. The results showed that the optimum condition required for the adsorption of direct black 38 dye with mesopore silica/activated carbon composite pH was 2 and the optimum contact time was 30 minutes. Adsorption of direct black 38 by mesopore silica/activated carbon composite followed Langmuir adsorption isotherm and formed a monolayer layer with adsorption capacity 68.493 mg g-1. Keywords: activated carbon, adsorption, composite, mesopore silica, PEG, rice husk ash
Adsorpsi Pewarna Eosin Y Menggunakan Komposit Silika Gel Termodifikasi 3- aminopropiltrietoksisilan (APTES)-Karbon Aktif dari Bahan Alam Ahmad Nubail; Yusmaniar yusmaniar; Arif Rahman
Jurnal Riset Sains dan Kimia Terapan Vol 8 No 2 (2019): Jurnal Riset Sains dan Kimia Terapan, Volume 8 Nomor 2, Oktober 2019
Publisher : Program Studi Kimia Universitas Negeri Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21009/JRSKT.082

Abstract

Pewarna Eosin Y telah berhasil diuji kapasitas serta persen adsorpsi menggunakan adsorben silika gel, karbon aktif dan komposit silika gel APTES-karbon aktif dari bahan alam. Penentuan optimasi pH dan kontak waktu menunjukkan bahwa ketiga adsorben berada pada pH optimum dan waktu kontak masing-masing sebesar 4 dan 30 menit. Penentuan model isotherm adsorpsi eosin Y terhadap komposit silika gel termodifikasi APTES-karbon aktif mengikuti isotherm adsorpsi Langmuir dengan kapasitas adsorpsi dan konstanta Langmuir masing-masing sebesar 21,28 mg g-1 dan 0,165.
Influence of Nanoparticle CaCO3 Addition to the Physical and Mechanical Properties of Polypropylene-CaCO3 Composite Deswita Deswita; Yusmaniar Yusmaniar; Grace Tj. Sulungbudi; Aloma Karo Karo; Sudirman Sudirman
Journal of Fibers and Polymer Composites Vol. 1 No. 1 (2022): Journal of Fibers and Polymer Composites
Publisher : Green Engineering Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (718.956 KB) | DOI: 10.55043/jfpc.v1i1.34

Abstract

Influence of Nanopaticle CaCO3 Addition to the Physical and Mechanical Properties of Polypropylene-CaCO3 Composite. This research was carried out to study the effect of adding CaCO3 nanoparticle on the physical and mechanical properties of polypropylene-CaCO3 composites. It was characterized by several parameters such as tensile strength, hardness, and thermal analysis including both melting point and heat of fusion using Differential Scanning Calorimetry (DSC). Based on XRD results, the particle size of CaCO3 after 24 hours of milling was 39 nm. There are various compositions of polypropylene-CaCO3 composites (PP MF35: nano-CaCO3) made in this study, namely 40%:60%, 35%:65%, 30%:70%, and 25%:75%. The results showed that the tensile strength of the PP MF35-CaCO3 composites decreased with increasing nano-CaCO3 content. Meanwhile, the hardness of the nanocomposites increased with increasing nano-CaCO3 content, but decreased the melting point and heat of fusions (ΔHm) of the nanocomposites. The infrared spectrum showed that the interaction between PP MF35 and nano-CaCO3 was only physical interaction and there was no chemical reaction.