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Evaluasi Cemaran Lemak Babi Pada Minyak Goreng Sawit Menggunakan Metode Polarisasi Transmisi heri sugito; Ketut Sofjan Firdausi
Jurnal Ilmiah Teknosains Vol 4, No 1 (2018): JiTek
Publisher : Universitas PGRI Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (417.414 KB) | DOI: 10.26877/jitek.v4i1.1855

Abstract

This research was conducted for evaluation of contamination of pig fat on vegetable cooking oil using transmission polarization method. The sample used is palm oil that has been contaminated with chicken oil and pork oil, with variations of chicken oil and pork oil content. The light source used is a green laser with a wavelength of 532 ± 10 nm. Measurements are made by observing the change in the transmission polarization angle that occurs when no external electric field is provided and by external electric field generated from two copper plates given a voltage of 0-6 kV. Test results show that palm oil contaminated with pig oil has the greatest change in polarization angle compared to pure palm oil and palm oil that has been contaminated with chicken oil. This is because the content of saturated fatty acids in pig oil is greater than pure palm oil and chicken oil. With these results, the transmission polarization method is expected to become a method for the evaluation of halal of cooking oil.Keywords: Transmission Polarization, Electrooptics, Cooking Oil, Impurities of Lard, Halal
Rapid Detection Of Heavy Metals On Waste-Water Polluted Soils Using Laser Induced Breakdown Spectroscopy Heri Sugito; Ali Khumaeni; Qidir Maulana Binu Soesanto
Journal of Physics and Its Applications Vol 2, No 2 (2020): May 2020
Publisher : Diponegoro University Semarang Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/jpa.v2i2.7520

Abstract

The Laser Induced Breakdown Spectroscopy (LIBS) method was successfully used to detect heavy metal elements in the soil polluted by wastewater from paper mills. The study was conducted using a Nd: YAG pulse laser with a wavelength of 532 nm at 83 mJ energy and 5 torr air pressure. The laser is fired at a soil sample that has been made in the form of pellets to produce plasma. The plasma emission spectrum formed is then detected by multichannel analyzer (OMA) to obtain the emission line spectrum that represents the content of atoms and molecules in the soil sample. The spectrum detected by OMA is then compared to the standard reference spectrum at NIST (National Institute of Standards and Technology) to find out the contents of an element on a contaminated soil sample. several types of heavy metal elements Fe, Cr, Cu, Al, Cd and Mn in soils contaminated by wastewater were detected using LIBS method. Based on research results, the LIBS method is very well used for the detection of heavy metal content in polluted soils.
Determination of relative dissociation energy from electro-optics as a new single-proposed parameter of vegetable oil quality Ketut Sofjan Firdausi; Izzah Afiefah; Heri Sugito; Ririn Widya Septianti; Very Richardina; Qidir Maulana Binu Soesanto; Much Azam
Journal of Physics and Its Applications Vol 2, No 1 (2019): November 2019
Publisher : Diponegoro University Semarang Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/jpa.v2i1.5181

Abstract

In this report, we study the electro-optics effect on cooking oil to obtain the relative dissociation energy as a new single proposed parameter of oil quality. The sample was canola oil which had been heated in 0.5 hours, 2 hours and 4 hours. The light source used in the experiment was a green pointer laser with a wave length of 532 nm. The sample was applied to a potential difference from 0 to 9 kV to obtain the electro-optics effect in form of the change of the polarization angle Dq as function of potential difference DV. The relative dissociation energy was obtained from the fitting data of the relative Lenard-Jones potential energy curves represented by change of polarization per unit change of potential difference, Dq/DV. The result shows that the relative dissociation energy is reduced as the oil quality decreased after heated. The relative dissociation energy provides simple physical understanding about electro-optics effect on cooking oils. The study of electro-optics polarization that represents relative Lenard-Jones potential energy is a new but somewhat intuitive, which can be further improved and emphasized for grouping, mapping, and determining various cooking oil quality and halal food due to the lard contamination.
Mapping Various Cooking Oil using Fluorescence Polarization Ketut Sofjan Firdausi; I. Afiefah; Heri Sugito; Much. Azam
Journal of Physics and Its Applications Vol 1, No 1 (2018): November 2018
Publisher : Diponegoro University Semarang Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/jpa.v1i1.3913

Abstract

In this report we have succeeded to map various cooking oils using change of fluorescence polarization. Various cooking oils consisted of several vegetables oils and animal oils (chicken oil and lard) were used in the experiment, and some oils were measured in two different times. The change of polarization angle &tetha; was measured as the difference between linear polarized green pointer laser as incoming light and fluorescence light using a pair of polarizers. The direct measurement of fluorescence polarization gives a new unique result of critical polarizer’s angle φc that can group vegetable cooking oils into group 1 (at φc = 10o for VCO, olive, and soybean), group 2 (at φc = 20o for palm, corn and rice bran), group 3 (at φc = 30o for sunflower and canola), and also animals cooking oils into group 4 (at φc = 20o for chicken oil), and group 5 (at φc = 40o for lard). Mostly cooking oils can be distinguished using modified maps. The large difference φc and &tetha; of lard from vegetable oils provides an advantage to develop for testing halal oil due to lard contamination. The capability of this method has benefits, at least, as a complement and simple method in comparison to other expensive sophisticated instruments such as fluorescence spectroscopy or GCMS methods with their derivation’s instruments.
Characteristics of colloid silver solution based on changes in concentration and electric field using electrooptic equipment Heri Sugito; Ketut Sofjan Firdausi; Ali Khumaeni; Syifa Azahra
Journal of Physics and Its Applications Vol 4, No 1 (2021): November 2021
Publisher : Diponegoro University Semarang Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/jpa.v4i1.12419

Abstract

Research on the characteristics of colloidal silver solutions based on changes in concentration and electric field using electrooptic devices has been carried out. The purposes of this study was to determine the characteristic of colloidal silver solution based on variations in concentration and electrooptic effects. Electrooptics work based on changes in the polarization angle of the sample. The sample used is a colloidal silver solution with various concentrations. The colloidal silver solution was obtained by laser ablation method and then dissolved in aquabidest. The light source used is a laser pointer with = 532 nm. The electric field applied to the sample is 0-9 kV. The results showed that colloidal silver solution at an angle of 0º showed active plasmon resonance at the peak of polarization with concentrations of 1.9 ppm, 2.28 ppm, and 3.8 ppm. An angle of 90º also shows active plasmon resonance at the peak of polarization with a concentration of 3.8 ppm. From the results, it can be concluded that the characteristics of colloidal silver solution on change in the polarization angle due to an electric field show non-linier properties with increasing concentration.
Design of Integrated Polarizer to Evaluate Quality of Cooking Oil Based on the Fluorescence Polarization Method Heri Sugito,; Ketut Sofjan Firdausi
Journal of Physics and Its Applications Vol 1, No 1 (2018): November 2018
Publisher : Diponegoro University Semarang Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/jpa.v1i1.3915

Abstract

An integrated polarizer was designed as an alternative test tool to evaluate quality of cooking oils. Integrated Polarizer was composed of light source with wavelength of 532 ± 10 nm, polarizer, analyser, cuvette, electrodes, and high voltage source. In this research, the tool works based on the fluorescence polarization method. Measurements were made by observing the fluorescence polarization angle changes that occur and by applying an external electric field at the samples using high voltage of 0-9 kV in the parallel plate. The results show that the expired cooking oil has a greater polarization angle than the edible cooking oil. The results also show that the change in the polarization angle will increase in proportion to the increase of the heating time. The condition of saturated fatty acids in each sample has an effect on the change of polarization angle.
Mesh-Assisted Laser-Induced Plasma Spectroscopy Using Pulse Carbon Dioxide Laser for Analysis of Powder Material by Confining the Powder in a Hole and Employing a Condensation Technique Ali Khumaeni; Asep Yoyo Wardaya; Heri Sugito; Nasrullah Idris; Kiichiro Kagawa
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (362.146 KB) | DOI: 10.22146/ijc.34778

Abstract

Analysis of impurity in powder samples has been made by using metal-assisted laser-induced plasma spectroscopy utilizing a pulsed CO2 laser. Various powders including food powder, supplement powder, baby powder, and medicine powder were employed as sample materials. Experimentally, the powder sample was tightly put in a hole made on a metal plate and a metal mesh was placed on the powder surface. A pulse CO2 laser (10.6 μm, 1500 mJ) was irradiated on the powder surface passing through the metal mesh. Luminous plasma was induced by mesh just above the mesh when a part of laser energy attacked the mesh. The other part of laser energy impinged the powders and ablated fine particles of powder to the plasma to be atomized and excited. Identification and analysis of elements in powder were successfully conducted. A linear calibration curve of Cu in baby powder has been demonstrated with an intercept zero, certifying that the present technique was a high possibility to be employed for semi-quantitative analysis of elements in powder material. It was proved that by applying the present technique and employing a condensation technique, the detection sensitivity of Cr impurity in the powder sample increased about twenty times compared to the case without condensation. The limit of detection of Cr in rice powder sample was 25 mg/kg. The proposed method was very convenient for the identification and analysis of elements in the powder sample.