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All Journal Jurnal Teknik Kimia USU ABDI SABHA (Jurnal Pengabdian kepada Masyarakat) Jurnal Teknik Kimia USU

Iriany

Departemen Teknik Kimia, Fakultas Teknik Universitas Sumatera Utara

Author-ID : 4065296

Religion Arts Humanities Chemical Engineering, Chemistry & Bioengineering Chemistry Education Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Social Sciences

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HIDROLISIS SELULOSA MENGGUNAKAN KATALIS KARBON TERSULFONASI BERBASIS CANGKANG KEMIRI Dian Halimah Batubara, Taslim, Seri Maulina, Iriany
Jurnal Teknik Kimia USU Vol 7, No 2 (2018)
Publisher : Universitas Sumatera Utara

Cogon grass (Imperata cylindrica) contains cellulose which is convertible to glucose through hydrolysis by using inorganic liquid acid catalyst. However, the use of such catalyst leads to corrosion problem, environment pollution, and complex separation. To overcome this problem, a sulfonated carbon catalyst was proposed. This study aimed to evaluate candlenut shell as carbon source for catalyst support in sulfonated carbon catalyst, and its application in cellulose hydrolysis. Candlenut shell was carbonized at 300-550oC for 4 h. Resulting carbon was sulfonated at 120-150oC for 6 h. Sulfonated carbon was assessed for its H+ capacity/acidity. The carbon with highest acidity was applied as solid acid catalyst in cogon grass hydrolysis. Resulting glucose was analyzed by dinitrosalicylic acid (DNS) method. Results suggest that sulfonated carbon from candlenut shell can be utilized as heterogeneous catalyst in cogon grass hydrolysis.

PENENTUAN KONDISI KESEIMBANGAN UNIT LEACHING PADA PRODUKSI EUGENOL DARI DAUN CENGKEH Tagora Bangkit P.S; Rinaldry Sirait; Iriany
Jurnal Teknik Kimia USU Vol. 1 No. 1 (2012): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Leafs of clove is an alternative source to obtain clove oil. Clove oil is classified into essential oil with eugenol as its main component. Clove oil is widely used in pharmaceutical, food and beverage industries. The objective of this research is to obtain clove oil by solid-liquid extraction (leaching). This research was expected to give data of solid-liquid equilibrium for designing solid liquid extractor. This research was carried out by leaching process with ethanol as its solvent. The extract was then purified by distillation to separate solvent from oil. The fixed variables which were used in this research were stirring rate of 460 rpm and 90 grams dry-based clove leaf. Extraction process was carried out by using solvent with temperature of 30oC and 50oC, extraction time of 1-3 hours with 0.5 hour increment and solvent volume of 500 ml and 600 ml. The results showed that the highest yield of clove oil extraction was obtained at temperature of 50oC and solvent volume of 600 ml. Equilibrium was reached after 2.5 hours and 79% eugenol concentration in the solvent.

PRODUKSI BIODIESEL DARI LEMAK SAPI DENGAN PROSES TRANSESTERIFIKASI DENGAN KATALIS BASA NaOH Ranggita Dwi Nindya Affandi; Toni Rizki Aruan; Taslim; Iriany
Jurnal Teknik Kimia USU Vol. 2 No. 1 (2013): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Biodiesel is an alternative fuel commonly produced from vegetable oil or animal fat with methanol through transesterification. Beef tallow was used as a raw material of transesterification to make biodiesel, because the price of beef tallow was driven down by the market and to reduce the pollution to the surrounding. In this research variable observed were reaction temperature, reaction time and amount of catalyst. Transesterification was carried out in a three necked spherical Pyrex vessel equipped with reflux condenser, stirrer and thermometer. In the present investigation an attempt has been made to use beef tallow as low cost sustainable potential feedstock for biodiesel production by single step transesterification process. Under optimal condition, the maximum yield of 95,67 % beef tallow methyl ester was obtained by using 6 : 1 molar ratio of beef tallow to methanol at 50 oC for a reaction time 30 minutes in the presence of 0,8 wt% of NaOH catalyst. The biodiesel properties were comparable to Indonesian National Standard (SNI). The results of this work showed that the use of beef tallow is suitable for feedstock of biodiesel production with low cost.

PEMBUATAN ETIL ASETAT DARI HASIL HIDROLISIS, FERMENTASI DAN ESTERIFIKASI KULIT PISANG RAJA (Musa paradisiaca L.) Sari Liza Azura Nst; Reni Sutri; Iriany
Jurnal Teknik Kimia USU Vol. 4 No. 1 (2015): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Ethyl acetate is a clear liquid, colorless, smelling typical which commonly used as a flavor enhancer. Banana peels contain high valuable components, such as carbohydrates, vitamin C, calcium and other nutrients. The purpose of this study was to utilize the ‘raja’ banana peel waste (Musa paradisiaca L.) in the making of ethyl acetate. Variations in this experiment is comparison of raw materials and water 1: 4; 1: 7; 1:10 and hydrolysis temperature of 50oC, 60oC, 70oC. At first banana peel was scraped, dried and mashed to make banana peel powder.The content of carbohydrates in the ’Raja’ banana peel powder is 45.21% (w/w). Banana peel powder was hydrolyzed into water for 180 minutes using acid hydrocloric acid as catalist. The hydrolysis product was fermented for 24 hours using instant yeast 'Fermipan' and then was distilled. The Distillation product was esterified with acetic acid and hydrochloric acid as catalyst for 15 minutes at 60°C. The influence of various process variables were observed in this experiment. The maximum ethyl acetate yield was obtained 70.377% at condition of raw materials and water ratio = 1:10 and hydrolysis temperature of 50oC. The results obtained in this experiment showed that the ‘raja’ banana peel can be used as an alternative raw material which low cost and easy to obtain to produce ethyl acetate.

PENJERAPAN LOGAM KADMIUM (Cd2+) DENGAN ADSORBEN CANGKANG TELUR BEBEK YANG TELAH DIAKTIVASI Krisnawati; Jasinda; Iriany
Jurnal Teknik Kimia USU Vol. 2 No. 3 (2013): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Harzadous waste water is the waste that can be harmful to human’s health. One of heavy metals that contains in harzadous waste is cadmium. This research aims to investigate the characteristic of cadmium adsorption, equilibrium time, percentage adsorption, adsorption kinetic, adsorption isotherm and capacity of cadmium adsorption by using duck egg’s shell adsorbent. Duck egg’s shell adsorbent that had been activated at 600 oC were put into cadmium solution and mixed together. Every 10 minutes experimental samples were analyzed using AAS. The results indicated that percentage adsorption increases and the longer equilibrium time will be reached with an increase of adsorbent dosage. The Lagergen first order Models was applied as adsorption kinetics model and the Bangham Models was applied as adsorption isotherms models.

PEMBUATAN ASAM OKSALAT DARI ALANG-ALANG (Imperata Cylindrica) DENGAN METODE PELEBURAN ALKALI Iriany; Andrew Faguh Sitanggang; Rahmad Dennie A. Pohan
Jurnal Teknik Kimia USU Vol. 4 No. 1 (2015): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Imperata grassland is one of the wild plant which have a low economic value but containing high cellulose. Therefore it is potentially to be used as raw material for oxalic acid manufacturing. The oxalic acid can be produced from imperata grassland through 4 steps: alkaline hydrolysis, precipitacion, acidification and crystallization. Experiments are carried out in a three necks glass equipped with thermometer, mixer, heater and condenser. Cooking solution NaOH were varied 3,5 N; 4 N and 4,5 N and cooking time 50, 60, 70 and 80 minutes. According to the result from the experiment, at the condition 98oC of cooking temperature, the highest yield of oxalic acid about 44,39% is obtained at 4 N concentration of sodium hydroxide and 60 minute of cooking time. Oxalic acid produced has 104oC of melting point and 1,2 of degree of acidity (pH).

PEMANFAATAN LIMBAH CANGKANG KERANG BULU SEBAGAI ADSORBEN UNTUK MENJERAP LOGAM KADMIUM (II) DAN TIMBAL (II) Akhmad Anugerah S; Iriany
Jurnal Teknik Kimia USU Vol. 4 No. 3 (2015): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Adsorbent from fur shells could be used to adsorb heavy metal ions such, as Cd (II) and Pb (II). This is shown by the research of adsorption using the fur shells. This research was aimed to characterize the fur shells. Variables in this research were the activation temperature and concentration of the metal solution. This research was begun with reduction of the shell size to 140 mesh, then thermal activation at temperature 110ᴼC, 500ᴼC and 800ᴼC in the furnace. After that adsorbent was characterized using BET, measured its density, moisture content and ash, the adsorption capacity of the adsorbent was tested by using solution of Cd (II) and Pb (II), and then the concentration of the remaining solution was measured by AAS. The result showed that activated adsorbent at temperatures 110ᴼC, 500ᴼC and 800ᴼC had surface area of 725.43; 807.94; and 803.822 m2/g. Density was inversely proportional to the activation temperature, the value of moisture content and ash obtained were in accordance to SNI. Activated adsorbent at 500ᴼC suitabled with the Freundlich Isotherm.

PENGARUH PERBANDINGAN MASSA ECENG GONDOK DAN TEMPURUNG KELAPA SERTA KADAR PEREKAT TAPIOKA TERHADAP KARAKTERISTIK BRIKET Iriany; Meliza; Firman Abednego S. Sibarani; Irvan
Jurnal Teknik Kimia USU Vol. 5 No. 1 (2016): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

The purpose of this research is to know the characteristics of briquettes including ash content, moisture content, volatile matter content, heating value, density, burning rate, tensile strength and to know the proper ratio of water hyacinth and coconut shell mixture under tapioca gluten variation. The ratios of water hyacinth and coconut shell in this research were 1:1, 1:2, 1:3, 1:4 with variation of tapioca gluten 5%, 10%, and 15% of the raw materials. From this research, the ideal composition of briquette is obtain in a mixture of water hyacinth and coconut shell at a ratio of 1:4 with tapioca gluten 10%, ash content 9.718%, moisture content 1.374%, volatile matter content 14.814%, heating value 6,879.596 cal/g, density 0.983 g/cm3, burning rate 3.021 × 10-3 g/second and tensile strength 18.400 g/cm2.

ADSORPSI β-KAROTEN YANG TERKANDUNG DALAM MINYAK KELAPA SAWIT (CRUDE PALM OIL) MENGGUNAKAN KARBON AKTIF Irvan; Olyvia Putri Wardhani; Nurul Aini; Iriany
Jurnal Teknik Kimia USU Vol. 5 No. 1 (2016): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Crude palm oil (CPO) is the richest natural source of carotenoids which gives the reddish-orange color in crude palm oil. The reddish color in unprocessed palm oil is disliked by consumer. This research is aimed to adsorb the β–carotene from the CPO using activated carbon, then the kinetics, isotherm models and thermodynamics data of the adsorption process were obtained. The main materials used in this research were CPO and activated carbon. The observed parameters were final concentration and the amounts of adsorbed β–carotene in activated carbon. The adsorption process was conducted by mixing the adsorbent with CPO with the variation of adsorbent: CPO (w/w) ratio = 1 : 3; 1 : 4; 1 : 5 and 1 : 6 with mixing speed 120 rpm and the temperature of 40, 50 and 60 oC. The sample of CPO and activated carbon was analyzed at every 2 minutes until the equilibrium was achieved. The final concentration of the unadsorbed β–carotene was analyzed using UV-Vis spectrophotometer. The results showed that the more CPO used in the process, the lower the adsorption percentage. The higher the adsorption temperature, the higher adsorption percentage. Moreover, the maximum adsorption percentage was 95.108% obtained at ratio 1 : 3 and T = 60 oC. The adsorption isotherm model which fit with the β–carotene adsorption at T = 60 oC was Langmuir model with the correlation coefficient of 0.959. The adsorption kinetics model which fit with the β–carotene adsorption was the second order kinetics model with the correlation coefficient of 0.998. The value of free energy Gibbs (ΔG) = -24,482.484 ; -24,708.059 and -24,933.634 J/mol for each temperature respectively, value of entropy changes (ΔS) = 22.557 J/mol K, and value of enthalpy changes (ΔH) = -17,421.987 J/mol.

ISOLASI PROTEIN SELAMA PROSES PENGAMBILAN KITIN DARI KULIT UDANG Kherliyanda Febriani; Fitri Hariani Nurza; Iriany
Jurnal Teknik Kimia USU Vol. 5 No. 2 (2016): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Shrimp is one of the Indonesia fishery commodities with high economic value. The production of shrimp shells is usually 40-45% from crude shrimp. Shrimp shell contain protein, chitin, minerals and carotenoids. It is very potential to be used as materials for isolation of protein.This experiment is to determine factors that effect protein recovery and optimize deproteination processconditions to produce high yield of protein. The design of experiment used response surface methodology. It is 2 steps consist of deproteination and protein extraction process using shrimp shells and KOH solution in comparison 1:10 (w/v). The concentration of KOH are1,3 M; 2 M; 3 M; 4 M; 4,7 M. The reaction temperatures are37 oC; 40 oC; 45 oC; 50 oC; 53 oCand the reaction times are 40 minutes, 60 minutes, 90 minutes, 120 minutes, 140 minutes. Reaction temperature is the main factor influence protein recovery process. The highest protein yield obtained is 64,5826 % with protein content is 86,24% using KOH solution 2,98 M, reaction temperature 45,76 ºC and reaction time 90,51 minute. Economic potential by protein recovery during isolation of chitin from shrimp shells is profitable.

Co-Authors Akhmad Anugerah S Alvian Andrew Faguh Sitanggang Christina Eka P Cici Novita Sari Cindy Carnella Daniel Reymondo Manurung Dian Halimah Batubara Febrina Iskandar Firman Abednego S. Sibarani Firman Abednego Sarwedi Sibarani Fitri Hariani Nurza Florentina Pandiangan Irsa Septiawan Irvan Jasinda Joko Murtono Josua Manurung Juan Surya Manurung Kenrick Kherliyanda Febriani Krisnawati M. Thoriq Al Fath Meliza Michael Dillo Rizki Ginting Muhammad Zulfadhli Nurul Aini Okta Bani Olyvia Putri Wardhani Rahmad Dennie A. Pohan Ranggita Dwi Nindya Affandi Reni Sutri Reny Arapenta Ginting Rinaldry Sirait Rivaldi Sidabutar Rondang Tambun Salwa Jody Gustia Sari Liza Azura Nst Seri Maulina Tagora Bangkit P.S Taslim Taslim Toni Rizki Aruan Venansia Matondang

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