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Journal : JURNAL KIMIA SAINS DAN APLIKASI

Identifikasi Asam Lemak Penyusun Minyak Biji Karet (Hevea Brasiliensis) Menggunakan GC-MS Ismiyarto, Ismiyarto; Prasetya, Nor Basid Adiwibawa; Wibawa, Pratama Jujur
Jurnal Kimia Sains dan Aplikasi Vol 6, No 2 (2003): Volume 6 Issue 2 Year 2003
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2060.536 KB) | DOI: 10.14710/jksa.6.2.19-21

Abstract

Isolation of rubber seed (Hevea brasiliensis) oil have carried out by using soxhlet extraction with n-hexane as solvent. This research have been determined of fatty acid composition of rubber seed oil. Separation of free fatty acid from triglyceride done by ethanol 96 %. The oil phase was analysed by gas chromatography - mass spectrophotometer. It was resulted five chromatogram peaks of fatty acid methyl ester, there are methylester from palmitic acid (9.12%), linoleic acid (44.69 %), elaidic acid (44.69 %), stearic acid (8.89 %>) and 11,14-eicosadienoic acid (5.30 %) respectively.
Identifikasi Senyawa Penyusun Minyak Kulit Batang Kayu Manis (Cinnamomum cassia) Menggunakan GC-MS Prasetya, Nor Basid Adiwibawa; Ngadiwiyana, Ngadiwiyana
Jurnal Kimia Sains dan Aplikasi Vol 9, No 3 (2006): Volume 9 Issue 3 Year 2006
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (259.775 KB) | DOI: 10.14710/jksa.9.3.81-83

Abstract

The steam-distilled volatile oil of the cinnamon bark (Cinnamomum cassia) has been analysed by gas chromatography – mass spectrophotometer (GC-MS). It was resulted three chromatogram peaks, there were identified as cinnamaldehyde (91.18 %), eugenol (7.64 %) and cinnamyl acetate (1.18 %) respectively.Keywords: Cinnamomum cassia, GC-MS, Cinnamadehyde, eugenol, cinnamyl acetate
Synthesis, Characterization of Ag2s from AgCl Waste of Argentometry Titration with Heating Temperature Variations and Its Application as a Temperature Sensor Based on Negative Temperature Coefficient (NTC) Gunawan Gunawan; Sarahtrinita Glikeria Like Megawati; Nor Basid Adiwibawa Prasetya; Roni Adi Wijaya
Jurnal Kimia Sains dan Aplikasi Vol 25, No 8 (2022): Volume 25 Issue 8 Year 2022
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/jksa.25.8.292-299

Abstract

Synthesis of Ag2S from AgCl waste of argentometric titration with heating temperature variations as a temperature sensor has been done. This study aims to synthesize Ag2S and examine the effect of heating temperature on crystal quality and electrical characteristics as a temperature sensor based on the Negative Temperature Coefficient (NTC). Ag2S synthesis was carried out by precipitation in a water bath with various heating temperatures of 40°C, 60°C, and 80°C. The success of the synthesis was confirmed by X-Ray Diffraction (XRD) with a typical peak of 2θ from Ag2S standard at 29.07°, 31.60°, 36.97°, 37.81°, and the highest crystallinity was obtained at a heating temperature of 60°C. Meanwhile, UV-Vis Diffuse Reflectance Spectroscopy (DRS UV-Vis) showed a band gap corresponding to Ag2S (0.9-1.05 eV). Furthermore, the Ag2S powder was made into pellets and applied as a temperature sensor. Then the resistance value and the electrical characteristics of the resulting sensor were measured. The best resistance was obtained from Ag2S synthesized at a temperature of 60°C with constant (B) and sensitivity (α) values of 2974 K and −3.35%, respectively. This indicated that Ag2S had been successfully synthesized, and the best sensor quality was obtained from Ag2S heated at a temperature of 60°C.