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KARAKTERISASI POLIMER KONDUKTIF POLIPIROL BERPENGISI SERBUK BAN UNTUK MENDETEKSI KONDUKTIVITAS MINYAK Satriaji Sudigdo; Rizky Dharmawan; Hamidah Harahap
Jurnal Teknik Kimia USU Vol. 3 No. 2 (2014): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Conductive polymer sensor based polypyrrole (ppy) and tire dust and 1,4-methyl-pyrrolidinone was made by using polymerization process. The polymerization process was prepared at temperature 100°C in boiling water for 30 minutes. Conductive polymer sensor is undergone several type of analysis including electrical conductivity, Scanning Electron Microscopy (SEM), Fourier Transform Infrared (FTIR),and X-Ray Diffraction (XRD). The test used some kind of oil (palm oil,corn oil, diesel, and engine oil). The conductivity test result shows that sensor-4 (contain 20 phr of tire dust) in 80°C at 30 minutes had the highest conductivity. Scanning Electron Microscopy result shows the rough surface and well dispersed of tire dust in polypyrrole/tire dust blends. The XRD analysis shows the Face Centered Cubic (FCC) crystallographic structure of the sensor. The oil conductivity test shows that the corn oil is more reactive than others.

KARAKTERISASI SENSOR POLIMER KONDUKTIF POLIANILIN BERPENGISI SERBUK BAN UNTUK MENDETEKSI KONDUKTIVITAS MINYAK Rizky Dharmawan; Satriaji Sudigdo; Hamidah Harahap
Jurnal Teknik Kimia USU Vol. 3 No. 2 (2014): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Conductive polymer sensor with varying amounts of poly aniline and tire dust and 1.4-methyl-pyrrolidinone as solvent using polymerization process have been developed. The polymerization process was prepared at temperature 100o C in the boiling water at 30 minutes. Conductive polymer sensor¬ is undergone several type of the analysis including electrical conductivity, Scanning Electron Microscope, Fourier Transform Infra-Red (FTIR), X-Ray Diffraction (XRD). The test used some kind of oil (palm oil, corn oil, diesel oil, and engine oil). The result showed that the highest electrical conductivity for the sensor-4 (20 per hundred resin of the tire dust) at 80oC for 30 minutes. Scanning electron microscope result shows rough surface and well dispersed of the tire dust in poly aniline / tire dust conductive blends. The analysis of X-RD shows the face center cubic (FCC) crystallographic structure of the sensor. The optimum of the electrical conductivity of the sensor was applied to detect the palm oil. The sensor given response towards palm oil (Neptune) compered to corn oil, diesel oil, and engine oil.

PENGARUH SUHU VULKANISASI DAN KOMPOSISI BENTONITE CLAY YANG DIMODIFIKASI DENGAN ALKANOLAMIDA DARI BAHAN BAKU RBDPKO PADA PRODUK LATEKS KARET ALAM Friska Erdiana Tambunan; Hamidah Harahap
Jurnal Teknik Kimia USU Vol. 4 No. 4 (2015): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

The is research aims to determine the effect of vulcanization temperature and composition of bentonite clay as good filler on mechanical properties of natural rubber latex product. In this study, we use bentonite clay as filler and alkanolamide as compatibilizer. The material used in this study are high ammonia latex 60%, curative agents such as sulfur, ZnO, ZDEC, AO, KOH, bentonite clay and alkanolamide. Alkanolamide is synthesized from amidation reaction between Refined Bleached Deodorized Palm Kernel Oil and diethanolamine. The methodology includes pre-vulcanizing natural rubber latex with certain formulation, then vulcanized using dipping method. The variable used in this study is filler loading, from 5, 10, 15, 20, and 25 gram, and vulcanization time 10 minutes. The products were then tested in order to observe its mechanical properties, FTIR characterization, SEM characterization and crosslink density. The results show that the synthesized alkanolamide possess the functional group desired. Alkanolamide modified bentonite clay loading is capable of increasing crosslink density and mechanical properties of the products. Optimum filler loading is reported on 10 gram and optimum vulcanization at 120oC.

PENGARUH AGING PADA KEKUATAN TARIK (TENSILE STRENGTH) FILM LATEKS KARET ALAM BERPENGISI NANOKRISTALIN SELULOSA DAN PENYERASI ALKANOLAMIDA Marfuah Lubis; Nuim Hayat; Hamidah Harahap
Jurnal Teknik Kimia USU Vol. 5 No. 2 (2016): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Nanocrystalline cellulose is nano sized filler with high crystallinity and obtanained by hydrolysis of alpha cellulose from sugarcane bagasse. Tensile test of natural rubber latex film filled nanocrystalline cellulose and alkanolamide as compatibilizer after aging treatment have been done. Natural rubber latex films were prepared by coagulant dipping method and followed by vulcanization process at temperature 100 oC and 20 minutes. Aging treatment of natural rubber latex films have done at temperature 70 oC for 24 hours. Tensile test result of natural rubber latex filled nanocrystalline cellulose showed the tensile strength value of aged natural rubber latex film were lower than unaged one. However, tensile strength value of aged natural rubber latex film filled nanocrystalline cellulose modified alkanolamide were higher than unaged film.

PEMANFAATAN GLISERIN DARI RESIDU GLISERIN SEBAGAI PLASTICIZER UNTUK PEMBUATAN BIOPLASTIK DENGAN BAHAN BAKU PATI BONGGOL PISANG KEPOK Azaria Robiana; M. Yashin Nahar; Hamidah Harahap
Jurnal Teknik Kimia USU Vol. 5 No. 4 (2016): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Glycerin residue is waste oleochemical industry that still contain glycerin. To produce quality and maximum quantity of glycerin, then research the effect of pH acidification using phosphoric acid. Glycerin analysis includes the analysis of pH, Fatty Acid and Ester (FAE), and analysis of the levels of glycerin. The maximum yield obtained at pH acidification 2 is grading 91,60% glycerin and Fatty Acid and Ester (FAE) 3,63 meq/100 g. Glycerin obtained is used as a plasticizer in the manufacture of bioplastics. Manufacture of bioplastics using the method of pouring a solution with varying concentrations of starch banana weevil (5% w/v and 7% w/v), variations of the addition of glycerin (1 ml, 3 ml, 5 ml and 7 ml), and a variety of gelatinization temperature (60°C, 70°C, and 80°C). Analysis of bioplastics include FTIR testing, tensile strength that is supported by SEM analysis. The results obtained in the analysis of FTIR does not form a new cluster on bioplastics starch banana weevil, but only a shift in the recharge area only, it is due to the addition of O-H groups originating from water molecules that enter the polysaccharide through a mechanism gelatinitation that generates interaction hydrogen bonding strengthened. The maximum tensile strength of bioplastics produced at a concentration of starch 7% w/v, 1 ml glycerine and gelatinization temperature of 80°C is 3,430 MPa. While the tensile strength bioplastic decreased with increasing glycerin which can be shown from the results of SEM where there is a crack, indentations and lumps of starch insoluble.

PENGARUH PERLAKUAN LEACHING TERHADAP SIFAT MEKANIK FILM LATEKS KARET ALAM BERPENGISI SELULOSA MIKROKRISTAL DARI AMPAS TEBU Rismadhani Elita; Rojiyatul Ikhwani Lubis; Hamidah Harahap
Jurnal Teknik Kimia USU Vol. 5 No. 4 (2016): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Leaching process is one of many factors to raise up the mechanical properties of latex products. Studies on the effect of leaching on film natural rubber latex with the filler microcrystalline cellulose from bagasse with alkanolamide using different temperatures and times vulcanization has been done to produce the better mechanical properties such as strenght tensile and elongation at break. Filming of natural rubber latex is done by coagulants dyeing techniques. The study started with the process of pre-vulcanised natural rubber latex at 70 °C with a loading filler by 0 phr, 5 phr, 10 phr and 15 phr and followed by a vulcanization process at a temperature of 100 °C and 150 °C for 10 minutes and 20 minutes. The film result will be have leaching treatment using a solution of water and ammonia 1%. Test results of tensile strength of natural rubber latex film howed that the tensile strength of natural rubber latex film with microcrystalline cellulose as filler and alkanolamides after leaching less than the tensile strength of natural rubber lateks film before leaching

Pengaruh Konsentrasi Asam Sulfat (H2SO4) pada Hidrolisa Tongkol Jagung (Zea mays) Menjadi Nanokristal Selulosa sebagai Filler Penguat pada Produk Lateks Karet Alam Harahap, Hamidah; Harfansah Nst, Azwin; Fujian Junaidi, Ilhamdi
Jurnal Teknik Kimia USU Vol. 8 No. 2 (2019): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v8i2.1873

This research studied about the effect of concentrations sulfuric acid (H2SO4) on the hydrolysis process of corn cobs waste to manufacture of cellulose nanocrystal (NCC) which will be applied as fillers in natural rubber latex. This study began with a pre-vulcanization process of natural rubber latex at a temperature of 70 oC and followed by a vulcanization process at 110 oC for 10 minutes. The results of the testing of physical properties indicate that the higher amount of NCC loading will result in higher crosslinked denotes, while the results of testing the mechanical properties indicate that the maximum value is achieved at the loading of NCCs as much as 6 phr. The mechanical test results supported by the analysis of Scanning Electron Microscopy (SEM) showing the NCC have spread well. Characterization of the Transform Electron Microscope (TEM) shown the resulting of NCC was spherical shape with the size of NCC produced for each concentration of sulfuric acid (H2SO4) 45%, 55%, and 65% respectively 57.65 nm; 28.43 nm; and 82.61 nm with an amount of each 0.849 g; 1,824 g; and 0.681 g. The mechanical and physical properties of the optimum natural rubber latex products occurred in the loading of nanocrystal cellulose with a number of 6 bsk, where the values â€‹â€‹of cross-connect density, tensile strength, elongation at break, M200 and M300 were respectively 10.6234 2Mc-1x10- 5; 18.2 MPa; 780%; 2.23 MPa and 2.7 MPa.

Pengaruh Konsentrasi Asam Sulfat (H2SO4) pada Hidrolisa Tongkol Jagung (Zea mays) Menjadi Nanokristal Selulosa sebagai Filler Penguat pada Produk Lateks Karet Alam Harahap, Hamidah; Harfansah Nst, Azwin; Fujian Junaidi, Ilhamdi
Jurnal Teknik Kimia USU Vol. 8 No. 2 (2019): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

This research studied about the effect of concentrations sulfuric acid (H2SO4) on the hydrolysis process of corn cobs waste to manufacture of cellulose nanocrystal (NCC) which will be applied as fillers in natural rubber latex. This study began with a pre-vulcanization process of natural rubber latex at a temperature of 70 oC and followed by a vulcanization process at 110 oC for 10 minutes. The results of the testing of physical properties indicate that the higher amount of NCC loading will result in higher crosslinked denotes, while the results of testing the mechanical properties indicate that the maximum value is achieved at the loading of NCCs as much as 6 phr. The mechanical test results supported by the analysis of Scanning Electron Microscopy (SEM) showing the NCC have spread well. Characterization of the Transform Electron Microscope (TEM) shown the resulting of NCC was spherical shape with the size of NCC produced for each concentration of sulfuric acid (H2SO4) 45%, 55%, and 65% respectively 57.65 nm; 28.43 nm; and 82.61 nm with an amount of each 0.849 g; 1,824 g; and 0.681 g. The mechanical and physical properties of the optimum natural rubber latex products occurred in the loading of nanocrystal cellulose with a number of 6 bsk, where the values â€‹â€‹of cross-connect density, tensile strength, elongation at break, M200 and M300 were respectively 10.6234 2Mc-1x10- 5; 18.2 MPa; 780%; 2.23 MPa and 2.7 MPa.

Production Process of Large Pore Size Activated Carbon from Palm Kernel Shell using Sodium Chloride as An Activator Nurdin, Ahmad; Iriani, Iriani; Harahap, Hamidah; Fahmi, Aliyah
Indonesian Journal of Chemical Research Vol 10 No 1 (2022): Edition for May 2022
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2022.10-ahm

This study aimed to determine the yield of activated carbon, iodine number, and surface area of palm activated carbon. Samples were produced by using sodium chloride (NaCl) as an activator. Palm shells that had been produced by the milling process were then sieved with a 12 mesh sieve and soaked in 20 % NaCl solution. The sample solution was heated over a water bath at 70 oC and continued with the drying process at a constant temperature of 105 oC. The activated shells continued the pyrolysis process at temperatures of 300, 400, and 500 oC for 3 hours. The activated carbon obtained from the pyrolysis process was weighed and then washed using hot distilled water. The samples were dried in an oven at a temperature of 105 oC for 24 hours. The results were analyzed for iodine number using iodometric titration method, surface area using Brunauer- Emmett-Teller (BET) method, and pore structure using the Scanning Electron Microscope (SEM) method. The results showed the best yield was 38.13 % obtained at 20% NaCl and a temperature of 400 oC. The best iodine number was 767.745 mg/g and surface area was 6.790 m2/g, pore volume 4.377 cc/g with pore size 9.781 A.

Sintesis dan Karakterisasi Edible Film Berbahan Dasar Limbah Kulit Kopi dengan Penambahan Gliserol dan Sorbitol sebagai Plasticizer Wahyu, Evita; Nasution, Halimatuddahliana; Harahap, Hamidah
Jurnal Teknik Kimia USU Vol. 14 No. 1 (2025): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v14i1.15567

Edible film merupakan kemasan ramah lingkungan (biodegradable) dan bersifat edible (bisa dikonsumsi). Bahan penyusun utama edible film adalah hidrokoloid (polisakarida), lipid dan komposit keduanya. Salah satu jenis polisakarida berpotensi tinggi dan sedang menjadi pusat perhatian para peneliti untuk dijadikan edible film adalah pati. Namun edible film bersifat keras dan mudah rapuh sehingga perlu penambahan plasticizer untuk memperbaiki kelemahan tersebut. Pada penelitian ini digunakan campuran plasticizer gliserol dan sorbitol dengan perbandingan campurannya terhadap bahan baku 10%, 30%, 50% dan 70% (v/b pati) dan variasi konsentrasi gelatin 2 g, 4 g dan 6 g. Pati yang diekstrak dari kulit kopi memiliki kadar air 16% dengan persentase rendemen sebesar 4,39%. Hasil karakteristik edible film terbaik adalah variasi konsentrasi campuran plasticizer 10% dan konsentrasi gelatin 6 g dengan nilai kelarutan dalam air yang dihasilkan 71,37%, ketebalan 0,07 mm, kuat tarik 6,66 MPa, elongasi 22,93% dengan laju permeabilitas terhadap uap air sebesar 0,00433 g/m2s.

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