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Pengaruh Binder Akrilik terhadap Sifat Fisik dan Mekanik Mortar Polimer Sitanggang, Ronal Rius; Ismeddiyanto; Edy Saputra
Jurnal Teknologi dan Rekayasa Sipil Vol. 2 No. 1 (2023): VOL 2 NO 1 (JULI 2023)
Publisher : Departemen Teknik Sipil, Fakultas Teknik Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.56208/jtrs.v2.i1.hal1-9

Abstract

Initial damage to the structure occurs in the outer layers of the affected surface exposure to the peat environment and the static and dynamic movement of the structure. To prevent structural damage, the latest technological innovations are needed in the use of mortar constituent materials to increase the strength of the mortar. Polymer mortar is a composite material formed from a mixture of fine aggregates, cement, water and polymer binders or binders with a certain level. The purpose of this study is to determine the effect of the use of acrylic binders on the physical and mechanical properties of polymer mortars and the influence of peat water on the future of the mortar. The substitution of acrylic binders with water consists of 3 substitutions, namely 20%, 30% and 40% and 0% as controls. The results of the search for acrylic binders on the mortar mixture obtained a minimum physical property value at 30% acrylic use in the 28-day test, namely. The porosity value of the mortar is 9.80%, the waterabsorption value of the mortar is 4.67% and 4.72%, and the sorptivity value of the mortar is 0.70. From the value of physical properties obtained the degree of tightness of the polymer mortar well with the use of acrylic binders in the mixture. For the mechanical properties of polymer mortar, compressive strength testing is carried out with optimum compressive strength at the use of 30% acrylic. The value of the compressive strength of the mortar is 33 Mpa.
KARAKTERISTIK MORTAR POLIMER DENGAN BINDER AKRILIK PADA AIR NORMAL DAN KONDISI NORMAL Rianti Ratna Dewi; Ismeddiyanto; Edy Saputra
Jurnal Teknologi dan Rekayasa Sipil Vol. 3 No. 2 (2024): VOL 3 NO 2 (NOVEMBER 2024)
Publisher : Departemen Teknik Sipil, Fakultas Teknik Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/jtrs.3.2.25-33

Abstract

Mortar is an important binding matrix in construction, playing a role in protecting structures from damage and cracking. Handling seepage and corrosion in structures is a major concern. Research shows that the addition of Acrylic Binder to mortar mixes improves weathering, chemical, abrasion resistance and adhesive strength. This study aims to assess the characteristics of mechanical and physical properties of mortar with the addition of acrylic binder in polymer mortar. The results of the study with the addition of acrylic binder through treatment in normal water and normal conditions with a variation of 3 substitutions namely 40%, 30%, 20% and 0% which is needed as a control, showed an increase in the highest compressive strength value in the addition of 30% acrylic binder with the strength obtained of 26 Mpa at the age of 28 days. The lowest water absorption was 4.35% at 28 days, with a porosity of 9.3% and surface absorption of 0.14. These results show that the addition of acrylic binder increases the water tightness of the mortar, demonstrating the potential application of this polymer mortar in improving structural performance.
Pembuatan Biodiesel Dari Minyak Biji Kapuk (Ceiba Pentandra) Dengan Katalis Lempung Teraktivasi; Pengaruh Kecepatan Pengadukan Putri, Erlisa Yanuari; Bahri, Syaiful; Saputra, Edy
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5, No 1 (2018): Wisuda April Tahun 2018
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

Biodiesel producted by transesterifiation reaction which on energy source. Biodiesel was developed in Indonesia as an anticipatis of energy crisis problem suppported by goverment national energy policy. This research is aimed to make biodiesel from cotton seed oil, studying the effect of agitation speed to the amount of biodiesel produced and determined the best catalyst activated by acid or base, and determined the characteristics of biodiesel produced. The transesterification process was occured at a temperature of 60oC, on weight of oil 100 grams, reaction time 1,5 hours, mole ratio of oil to methanol 1 : 9, catalyst concentration 0,5% -weight of oil for varions of agitation rate 400, 500 and 600 rpm, and variations of catalyst acid 0,47, 0,62 and 0,78% and alkaline activated with a concentration of 0,33, 0,44 and 0,66%. From the result was obtained the highest biodiesel yield of 95,45% for alkaline activated 0,66% for agitation speed of 400 rpm. Characterization of physical properties of biodiesel obtained here density of 878 kg/m3, 3,03 mm2/s kinematic viscosity, acid number 0.34 mg KOH/g sample, and the flash point 195oC.Keywords: biodiesel, clay catalysts, activation of acids and bases, transesterification
Pengolahan Limbah Cair Sawit Dengan Metode Aop (Advanced Oxidation Process) Menggunakan Katalis LaMnO3 Perovskite Dengan Variasi Oksidan Peroxymonosulfate Hasrul, Hasrul; Saputra, Edy; Khairat, Khairat
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5, No 1 (2018): Wisuda April Tahun 2018
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

Processing of palm oil into Crude Palm Oil (CPO) will produce a large amount of liquid waste. To produce a ton of crude palm oil (CPO) produced 6 m3 of palm oil mill effluent. In this study, a process for removing organic compounds in wastewater using the advanced oxidation process by combining peroxymonosulfate (2KHS5.KHSO4.K2SO4) and a catalyst of LaMnO3 Perovskite. The combination will produce sulfate free radicals that capable degrading harmful organic compounds in effluent effectively. Nanocrystalline LaMnO3 was obtained by calcination at a temperature of 800 °C for 2 hours with an average crystal diameter of the highest peak of 17 μm in the shape of the Rhombohedral catalyst and the catalyst has qualified the catalyst with a nanoparticle structure. Several variations of oxidation process variables were performed to assess their effect on organic matter decline. Some fixed variables were oxidation reaction temperature 30 oC, reaction time 120 min, stirring speed 400 rpm, and concentration of peroxymonosulfate solution 2 g/L and catalyst concentration 0,4 g / L. Conclution of this research is efficiency of 63.54 % for decreasing COD and efficiency by 27,4% for TOC reduction. This proved that the LaMnO3 catalyst is capable of activating peroxymonosulfate.Keywords : AOP, LaMnO3 Perovskite, Oxidation, Peroxymonosulfate
Sintesis Biodiesel Dari Minyak Nyamplung Menggunakan Katalis Geopolimer: Pengaruh Suhu Reaksi Transesterifikasi Dan Rasio Mol Minyak Terhadap Metanol Syafi’i, Abdullah; Saputra, Edy; Helwani, Zuchra
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5, No 1 (2018): Wisuda April Tahun 2018
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

Petroleum reserves in Indonesia are increasingly depleted, requiring the use of alternative energy that is environmentally friendly and renewable like biodiesel. Biodiesel can be made by transesterification process of vegetable oils. Process of making biodiesel commonly use homogeneous catalyst which has the disadvantage the formation of by products such as complexity of the separation of catalyst. Therefore, in this study biodiesel was synthesized from calophyllum inophyllum oil by using geopolymer catalyst. Geopolymer catalyst is first synthesized by reacting sodium silicate, metakaolin, NaOH, and water. Several variations of the process variables were done to assess its influence on yield of biodiesel. The variables were used consist of a dependent variables and independent variables. The dependent variables were calophyllum inophyllum oil weight of 50 grams, 3%-wt of catalyst concentration, reaction time of 120 minutes, and stirring speed of 400 rpm, while the independent variables which variation molar ratio of oil:methanol 1:6 and 1:9 and variations of temperature 55 and 65 oC. Physical characterization were done including density 871 kg/m3, kinematic viscosity 4.38 mm2/s, acid number 0.41 mg-KOH/g biodiesel and flash point 140°C respectively accordance with the standards of Indonesian biodiesel (SNI 7182:2015).Keywords: biodiesel, catalyst, calophyllum inophyllum oil, geopolymer, yield
Sintesis ZSM-5 Menggunakan Silika Presipitasi Dari Fly Ash Pabrik CPO Saputra, Rio; Saputra, Edy; Yelmida, Yelmida
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5, No 1 (2018): Wisuda April Tahun 2018
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

Palm fly ash is waste in the palm oil industry. Palm fly ash has high content of silica. ZSM-5 is one of synthetic zeolite which used as catalyst. It can be synthesized from silica and alumina using hidrothermal method. Source of silica that can be used to ZSM-5 synthesis are sodium silicate, gelled silica and precipitated silica. the purpose of this research is to synthesis ZSM-5 using precipitated silica hydrothermally. The result was analyzed using FTIR. ZSM-5 can be synthesized using precipitated silica hydrothermally. Based on infrared spectrum,the product synthesis shows four characteristic of ZSM-5 characters.Key words : fly ash, silica, hydrothermal and ZSM-5
Pengolahan Limbah Cair Sawit Dengan Metode Aop (Advanced Oxidation Process) Menggunakan Katalis LaMnO3 Perovskite Dan Oksidan Peroxymonosulfate Riandy, M Arief; Saputra, Edy; Pinem, Jhon Armedi
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5, No 1 (2018): Wisuda April Tahun 2018
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Processing of palm oil into Crude Palm Oil (CPO) will produce a large amount of liquid waste. To produce a ton of crude palm oil (CPO) produced 6 m3 of palm oil mill effluent. In this study, a process for removing organic compounds in wastewater using the advanced oxidation process by combining peroxymonosulfate (2KHS5.KHSO4.K2SO4) and a catalyst of LaMnO3 Perovskite. The combination will produce sulfate free radicals that capable degrading harmful organic compounds in effluent effectively. Nanocrystalline LaMnO3 was obtained by calcination at a temperature of 800 °C for 2 hours with an average crystal diameter of the highest peak of 29 nm in the shape of the Rhombohedral catalyst and the catalyst has qualified the catalyst with a nanoparticle structure. Several variations of oxidation process variables were performed to assess their effect on organic matter decline. Some fixed variables were oxidation reaction temperature 30 oC, reaction time 120 min, stirring speed 400 rpm, and concentration of peroxymonosulfate solution 2 g/L, pH of liquid waste is 8 and catalyst concentration 0,4 g / L. Conclution of this research is efficiency of 80.5 % for decreasing COD and efficiency by 15,6% for TOC reduction. This proved that the LaMnO3 catalyst is capable of activating peroxymonosulfate.Keywords : AOP, LaMnO3 Perovskite, Oxidation, Peroxymonosulfate
Sintesis dan Karakterisasi Katalis Nikel Zeolit Alam Ni/NZA Bahri, Syaiful; Saputra, Edy; Herman, Syamsu; Muhdarina, Muhdarina
Journal of Bioprocess, Chemical and Environmental Engineering Science Vol 5 No 1 (2024): Journal of Bioprocess, Chemical, and Environmental Engineering
Publisher : Department of Chemical Engineering, Faculty of Engineering, UNRI

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/jbchees.5.1.36-45

Abstract

Research has been conducted to manufacture Ni/NZA for catalytic cracking of empty palm fruit bunches into liquid fuel. The study aims to investigate the impact of metal impregnation and calcination time variations on catalyst crystallinity and morphology. The catalyst is produced in multiple stages, including NZ activation using acid, followed by metal impregnation at 0%, 1%, 3%, and 5% w/w, and calcination at 500oC for 2, 4, and 6 hours, respectively. It is then oxidized at 400oC for 2 hours and reduced at 400oC for 2 hours. The catalyst's crystallinity, morphology, and metal distribution are determined through X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) analysis. The catalyst with the best crystallinity and metal distribution is found to have 3% metal loading and a calcination time of 2 hours.
The Application of Nanofiltration Membrane for Palm Oil Mill Effluent Treatment by Adding Polyaluminium Chloride (PAC) as Coagulant Pinem, Jhon Armedi; Tumanggor, Imanuel; Saputra, Edy
Jurnal Rekayasa Kimia & Lingkungan Vol 15, No 1 (2020): Jurnal Rekayasa Kimia & Lingkungan (June, 2020)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v15i1.13952

Abstract

The rapid development of Crude Palm Oil (CPO) production has led to an increase in the production of Palm Oil Mill Effluent (POME) as well. POME will cause problems in the environment because contains high contaminants. This study aims to investigate the effect of the coagulant Polyaluminium Chloride (PAC) variations and the membranes operating pressure on the POME treatment process using the nanofiltration membrane (NF) with the coagulation-flocculation process as pre-treatment. The PAC was used in the coagulation-flocculation process with variations in concentration (5.0; 5.5; 6.0; 6.5; 7.0 g/L). The process was completed by a rapid stirring of 200 rpm for 5 minutes, followed with slow stirring at 60 rpm for 15 minutes and settling time for 30 minutes. The process of membrane nanofiltration was carried out for 60 minutes with variations in operating pressure (8.0; 9.0; and 10 bars). In each treatment process, effluent quality testing was carried out with Biochemical Oxygen Demand (BOD5), Chemical Oxygen Demand (COD), Total Suspended Solid (TSS) and oil/fat as parameters. In addition, an analysis of permeate fluxes and rejection of NF membrane was also carried out. The results of the analysis suggested that the best coagulant doses are 6.0 g/L with the reduction percentage of BOD, COD, TSS and oil/fat at 78.85%; 68.57%; 92.77% and 92.31% respectively. The highest percentage of NF membrane rejection was found at a pressure of 10 bar, which is equal to 94.71%; 94.86%; 97.92% and 95% respectively for BOD, COD, TSS and oil/fat with a flux value of 7.16 L/m2.hours.
Pengolahan Sampah Plastik Polypropylene (PP) Menjadi Bahan Bakar Minyak dengan Metode Perengkahan Katalitik Menggunakan Katalis Zeolit X Wahyudi, Ekky; Zultiniar, Zultiniar; Saputra, Edy
Jurnal Rekayasa Kimia & Lingkungan Vol 11, No 1 (2016): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v11i1.2958

Abstract

Penelitian ini dilakukan untuk mengkonversi sampah plastik menjadi bahan bakar minyak menggunakan katalis Zeolit X yang disintesis dari abu layang batubara yang selanjutnya dikarakterisasi menggunakan XRD. Dalam penelitan ini, sebanyak 100 gram plastik jenis polypropylene direngkah di dalam reaktor batch pada suhu 350o C, 400o C dan 450o C selama 60 menit dengan variasi rasio katalis/plastik 0,5; 1; 1,5 (% berat). Yield (%) tertinggi adalah 76,09% yang diperoleh pada variasi suhu 450o C dan rasio katalis/plastik 1,5%. Nilai kalor produk adalah 45,56 MJ/kg. Hasil analisa GC-MS menunjukkan % area produk mengandung bahan bakar seperti bensin (60,46%), kerosin dan solar (7,48%).