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Fullerene Journal of Chemistry
Published by Universitas Negeri Manado
ISSN : 25981269     EISSN : 25985868     DOI : -
Core Subject : Science,
Chemistry
Fullerene Journal Of Chemistry is an chemistry indonesian journal presented by chemistry department, State University of Manado.
Arjuna Subject : -
Articles 160 Documents
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Optimasi Spesiasi Kromium Ke Bentuk Cr(III) - Tanat Jenifer Alfonda Walewangko; Djefry Tani; Joice Caroles
Jurnal Kimia Fullerene Vol 5 No 1 (2020): Fullerene Journal of Chemistry
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (370.156 KB) | DOI: 10.37033/fjc.v5i1.103

Abstract

This research was conducted to determine the heavy metal species of Cr (III). Determination of heavy metals is determined based on the required chromium species using the UV-Vis spectrophotometry method. The sample used was CrCl3.H2O and the complexing agent was tannic acid. This research was conducted to determine the effect of pH, concentration and time of stability by finding the optimum conditions of the chromium - tanic acid complex. The optimum pH is at pH 11, the optimum concentration is at a ratio of 5: 1 concentration (Cr: tanic acid), the stability of time is at the 10th minute.
Pengaruh penambahan Ion Logam Natrium, Kalium, Magnesium, Kalsium pada biokonversi tepung jagung (Zea Mays L.) oleh Ragi Endomycopsis Fibuligera menjadi Senyawa Prebiotik Astuti Amin; asnita asnita
Jurnal Kimia Fullerene Vol 5 No 1 (2020): Fullerene Journal of Chemistry
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (584.836 KB) | DOI: 10.37033/fjc.v5i1.136

Abstract

In this study made prebiotic from bioconversion of corn flour (Zea mays L.) by yeast Endomycopsis fibuligera as an alternative substitute for antibiotics. In this study, the addition of Na+, K+, Ca2+, and Mg2+ ions aimed to determine the optimum type and concentration of metal in prebiotic and testing the effect of prebiotic compounds produced on broiler weight gain. The analysis carried out included: reducing sugars, α-amylase and glucoamylase enzyme activity, protein content and cell biomass. To determine the existence of a significant effect, the analysis was carried out on broiler body weight given prebiotic compounds which were added to optimum metal ions and which were given prebiotic compounds without the addition of metal ions. The results showed that the addition of optimum metal ions was obtained on Ca2+ ions with a concentration of 0.25%, where the reducing sugar content of 0.600 mg / mL, the activity of the enzyme α-amylase and glucoamylase 0.519 and 0.287 units / mL, protein content 2.724 mg / mL, cell biomass 10.8933 mg / mL, from observations and statistical tests carried out by giving prebotic compounds by adding metal ions and giving prebiotic compounds without adding metal ions influence broiler weight gain with an average weight difference of 261 grams or 15% on day 30.
Destilasi Kering Sampah Plastik Low Density Polyethylene (LDPE) Rivaldo Lee Mogot; Dewa Anom; Jenny Kumajas
Jurnal Kimia Fullerene Vol 5 No 1 (2020): Fullerene Journal of Chemistry
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (530.213 KB) | DOI: 10.37033/fjc.v5i1.131

Abstract

Indonesia is the second largest contributor of plastic waste in the world. Lack of public knowledge about the negative effects of plastic waste and the management of plastic waste that has not been good causes a buildup of plastic waste. This study aims to convert LDPE plastic waste into a liquid similar to petroleum, separate and analyze the chemical components present in the liquid produced by the distillation of dry plastic waste. Plastic waste is dry distilled at temperatures up to 300 oC, without solvents involved. Liquid distilled from a distillation of dry distillation (Fractionation) to separate the chemical components. To find out what chemical components are present, the resulting liquid from multilevel distillation (Fractionation) was analyzed by means of Infrared Spectroscopy (IR) and Gas Chromatography-Mass Spectrometry (GC-MS). The results of IR analysis on the LDPE plastic waste fractionation distillation fluid showed the presence of Aromatic, Alkane and Alkene functional groups. The results of GC-MS analysis on the LDPE plastic waste fractionation distillation fluid for each fraction showed that in general it is a group of hydrocarbon compounds with different molecular masses.
Sintesis Graphene Melalui Iradiasi Microwave Sebagai Sensor Metanol Endah Fitriani Rahayu; Alfi Nurul Amalia
Jurnal Kimia Fullerene Vol 5 No 1 (2020): Fullerene Journal of Chemistry
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (455.375 KB) | DOI: 10.37033/fjc.v5i1.137

Abstract

Graphene merupakan material 2 dimensional yang mempunyai sifat unik salah satunya memiliki luas permukaan sangat tinggi (~2630 m2g-1) yang dapat mengadsorbsi gas target. Tidak seperti sensor gas lainnya, sensor graphene dapat dioperasikan di bawah kondisi sekitar dan pada suhu kamar. Interaksi antar gas metanol dengan graphene menghasilkan perubahan pada sifak konduktifitas dan resistensinya yang membuat graphene menjadi elemen sensor yang baik. Struktur dan sifat elektronik graphene tergantung pada proses sintesisnya. Metode Hummers dan microwave irradiation dipilih karena biaya produksi efektif, menghasilkan graphene dengan sensitifitas tinggi terhadap target gas. Dari ketiga variasi pembuatan graphene dari Graphene Oxide (GO) melalui microwave irradiation yaitu 0,1 g-450 Watt, 0,1 g-630 Watt dan 0,02 g-450 Watt menunjukkan sensitifitas paling tinggi pada variasi graphene 0,02 g-450 Watt. Hal ini mengindikasikan semakin kecil massa GO dan semakin tinggi daya microwave membentuk sifat graphene yang lebih optimal terlebih untuk sensor gas.
Penetapan Kadar Klorofil dan Karotenoid Daun Sawi (Brassica) Menggunakan Metode Spektrofotometri UV-Vis Eni Kartika Sari
Jurnal Kimia Fullerene Vol 5 No 1 (2020): Fullerene Journal of Chemistry
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (564.676 KB) | DOI: 10.37033/fjc.v5i1.150

Abstract

Chlorophyll and carotenoids are antioxidant compounds that are very potential. Both of these compounds are found in many vegetables. This research aims to determine the levels of chlorophyll and carotenoids in mustard (Brassica) leaves. There were three types of mustard leaves tested, namely greens mustard (Brassica rapa I.), white mustard (Brassica juncea L.) and pakcoy (Brassica rapa L.). Analysis of samples by the Uv-Vis Spectrophotometry method. The results of the measurement of chlorophyll levels showed that pakcoy (Brassica rapa L.) had the highest chlorophyll level which was 86,76 mg/g. While the lowest chlorophyll level is found in the type of white mustard which is equal to 0,75 mg/g. From the three of the mustard tested, green mustard (Brassica rapa I.) and pakcoy (Brassica rapa L.) were mustard types that contained high carotenoids in the amount of 50,4 mg/g and 198,04 mg/g. While the type of white mustard (Brassica juncea L.) has the lowest carotenoid content for all preparations.
Phytochemical and Antioxidant Test of Binahong (Anredera cordifolia (Tenore) Steenis) Leaves Ethanol Extract Fensia Analda Souhoka; Imanuel Berly Delvis Kapelle; Elisabeth Sihasale
Jurnal Kimia Fullerene Vol 6 No 1 (2021): Fullerene Journal of Chemistry
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37033/fjc.v6i1.248

Abstract

Binahong Anredera cordifolia (Tenore) Steenis leaves contain chemical compounds that can be used as antioxidants. This study aims to examine the phytochemical and antioxidant activity of the ethanol extract of binahong leaves. Binahong leaves were extracted using the maceration method with an ethanol solvent. The phytochemical test showed that the ethanol extract of binahong leaves contained phenolic compounds, flavonoids, alkaloids, and tannins to have potential antioxidants. The antioxidant activity test was carried out using the DPPH method and absorbance measurement with a UV-Vis spectrophotometer at a wavelength of 517 nm. The results showed that the ethanol extract of binahong leaves had strong antioxidant activity, as evidenced by the IC50 value of 87.423 µg/mL.
Uji Efektivitas Beberapa Pelarut Pada Proses Identifikasi Metabolit Sekunder Kulit Pisang (Musa Paradisiaca) Secara Kualitatif Putri Ade Rahma Yulis; Yelfira Sari; Desti Desti
Jurnal Kimia Fullerene Vol 5 No 2 (2020): Fullerene Journal of Chemistry
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37033/fjc.v5i2.196

Abstract

Kulit pisang mengandung komponen aktif yang dapat dijadikan bahan baku pengembangan produk berpotensi antioksidan, selain itu dapat mengatasi pencemaran limbah kulit pisang. Pada penelitian ini dilakukan uji efektivitas beberapa jenis pelarut polar dan non polar dalam mengidentifikasi metabolit sekunder pada simplisia kulit pisang .Dengan tujuan menjadi landasan bagi penelitian lainnya dalam proses ekstraksi kulit pisang, sehingga akan didapatkan kandungan senyawa aktif dalam jumlah maksimal jika pelarut yang digunakan dapat menarik komponen aktif dengan optimal. Penelitian ini menggunakan empat jenis pelarut yakni etanol, metanol, etanol dicampur aseton, dan n-heksan. Kemudian keefektifan nya dilihat dari kemampuannya dalam mengidentifikasi metabolit sekunder pada simplisia kulit pisang. Hasil penelitian ini menunjukan ketiga jenis pelarut yakni, metanol, etanol dan campuran etanol dan aseton dapat mengidentifikasi metabolit sekunder kulit pisang , namun pelarut n-heksan tidak dapat mengidentifikasi metabolit sekunder kulit pisang. Kemudian dari ketiga pelarut tersebut yang mempunyai efektivitas paling besar adalah metanol. Metanol dapat mengidentifikasi empat jenis metabolit sekunder yakni flavonoid, fenolik, tanin dan saponin dengan lebih cepat dan menunjukan perubahan warna yang lebih signifikan. Berdasarkan hasil ini dapat dikatakan bahwa simplisia kulit pisang berpotensi antioksidan karena positif mengandung beberapa metabolit sekunder dan untuk mendapatkan ekstrak yang maksimal dapat digunakan metanol sebagai pelarut untuk proses ekstraksi
Kajian Regiokimia Markovnikov Melalui Mekanisme Reaksi Hidrasi Alkuna Terminal pada Etinilestradiol dengan Katalis FeCl3 Hotma Rotua Br. Simbolon; Rymond Jusuf Rumampuk; Anderson Arnold Aloanis
Jurnal Kimia Fullerene Vol 6 No 1 (2021): Fullerene Journal of Chemistry
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37033/fjc.v6i1.263

Abstract

The terminal alkynes hydration reaction on 17α-ethynylestradiol (1) with FeCl3 catalyst mediated by dichloromethane aims to determine the reaction products produced and to conduct a Markovnikov regiochemistry study through the proposed reaction mechanism. The reaction conditions were carried out at a temperature of 50oC (48 hours) and 60oC (19 hours), the separation of the reaction properties was carried out using Gravity Column Chromatography, and the reaction products were identification using by Proton Nuclear Magnetic Resonance (1H-NMR). Here we describe the process of the FeCl3 catalyst forming a coordination complex with the terminal alkyne, which is then addition by nucleophilic water following Markovnikov's regiochemistry to finally produce the product of a methyl ketone, 17α-acetylestradiol (6). The catalyst used is a cationic ligand coordinate, where Fe3+ is a Lewis acid and Cl3- acts as a ligand. The dichloromethane solvent used can also increase the reaction rate.
Karakterisasi Asap Cair Hasil Pirolisis Sampah Kantong Plastik sebagai Bahan Bakar Bensin I Dewe Ketut Anom; John Z Lombok
Jurnal Kimia Fullerene Vol 5 No 2 (2020): Fullerene Journal of Chemistry
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37033/fjc.v5i2.206

Abstract

Plastic bag waste is garbage that is difficult to degrade in nature. Hoarding plastic bag waste can reduce soil fertility because it cannot be broken down by microorganisms quickly. Burning plastic bag waste can produce toxic gases and have a negative impact on human health and the environment. To solve the problem, the plastic bag waste is converted into liquid smoke as fuel oil. The method used to convert the plastic bag waste into liquid smoke is pyrolysis. The fractionation of liquid smoke at temperatures below 200oC produces 36.20% clear liquid which has similar properties to gasoline fuel. Characterization of the physical and chemical properties of the gasoline fraction liquid smoke has a density of 0.76 g/mL; a viscosity of 0.80 cP; boiling point at 146.9oC; flash point at 30.60oC; a calorific value of 10,520 cal/g; with the octane number of 98 RON. GC-MS analysis shows that the gasoline fraction liquid smoke consists of 45 chemical compounds which can be classified into alkanes, alkenes, cycloalkanes and alcohols.
Ketahanan Hidup Bibit Ikan Mujair (Oreochromis mossambicus) Dan Nilai Parameter Kimiawi Lingkungan Pada Media Pemeliharaan Bioflok Dengan Debris Daluga Sebagai Sumber Karbon Emma Mauren Moko; Ferencia Esananda Rattu; Ernest Hanny Sakul; Orbanus Naharia; Aser Yalindua; Livana Dethris Rawung
Jurnal Kimia Fullerene Vol 6 No 1 (2021): Fullerene Journal of Chemistry
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37033/fjc.v6i1.253

Abstract

Bioflok adalah teknik budidaya ikan untuk mengelola lingkungan budidaya dengan memanfaatkan mikroorganisme untuk meningkatkan penggunaan pakan dan sisa hasil metabolisme dengan penambahan sumber karbon organik. Penelitian ini bertujuan untuk mengetahui ketahanan hidup bibit ikan mujair (Oreochromis mossambicus) dan nilai parameter kimiawi lingkungan pada media pemeliharaan bioflok dengan debris daluga (Crytosperma merkusii) sebagai sumber karbon. Penelitian ini menggunakan Rancangan Acak Lengkap (RAL) dengan 4 perlakuan dan 3 ulangan. Perlakuan yang dilakukan adalah tanpa bioflok, C:N=15, C:N=20, dan C:N=25. Hewan uji ikan mujair dengan panjang rata-rata 5,5 cm di tebar 10 ekor setiap ember. Parameter yang diamati adalah kualitas air yang meliputi suhu, pH, konduktivitas, dan redoks dan Survival Rate (SR) ikan mujair. Dari hasil penelitian diketahui bahwa perlakuan terbaik pada C:N=25 dengan persentase SR tertinggi yaitu, 86,67%. Kualitas air selama penelitian ada pada kondisi optimal di setiap perlakuan.

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