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Eksergi: Chemical Engineering Journal
Published by Universitas Pembangunan Nasional Veteran Yogyakarta
ISSN : 1410394X     EISSN : 24608203     DOI : https://doi.org/10.31315
Core Subject : Science, Engineering,
Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Industrial & Manufacturing Engineering Materials Science & Nanotechnology
Eksergi is an open-access, peer-reviewed scientific journal that focuses on research and innovation in the fields of energy and renewable energy. The journal aims to provide a platform for scientists, researchers, engineers, and practitioners to share knowledge and advancements that contribute to sustainable development and energy transition. In addition to energy topics, the journal also accepts high-quality manuscripts related to, but not limited to, the following areas: Separation processes Bioprocesses related to food, energy, and environmental applications Wastewater treatment and resource recovery Process optimization and intensification Carbon capture, utilization, and storage (CCUS) Chemical reaction engineering and reactor design Life cycle assessment (LCA) and sustainability evaluation Process Design and Control Engineering Process Simulations Process System Engineering The journal welcomes original research articles, reviews, and short communications that demonstrate novelty, scientific rigor, and relevance to chemical engineering and interdisciplinary applications.
Arjuna Subject : Energi (semua kategori) - Energi Terbarukan, Keberlanjutan dan Lingkungan
Articles 301 Documents
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Influence of solvents to Distillation Extraction in Separating of Methanol- Acetone Mixture using Separating Wall Reynardi Risyad Raytama; Herry Santoso; Yansen Hartanto
Eksergi Vol 18, No 2 (2021)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v0i0.4563

Abstract

Methylene blue is one of dying waste that causes harmful effect both enviromental and public health risks. A method to overcome the problem is to adsorb it with the activated carbon. Apart from that, corn cob is potential biomass with can convert to activated carbon. The aim of this research is to syntethic and to modify corn cob activated carbon with iron oxide. It is expected to increase the afinity of methylene blue to the activated carbon surface. The modification is done by wet impregnation and the effectiveness of the impregnated corn cob activated carbon is studied by analyse the persen removal of methylene blue in every interval time. The result show that in the concentration range of Fe load impregnation between 1%-3% which has been used, the corn cob activated carbon with concentration of Fe load 2% has the most optimum ability in methylene blue adsorption with the adsorption capacity 44,9%. Moreover, the effect pH shows that in acidic condition the adsorption of methylen blue is better than in netral condition
Influence of Particle Size and Chemical Activation on Rice Husk Biochar as Slow Release Fertilizer Natasha Amelia Rigitha Akhwan; Avido Yuliestyan
Eksergi Vol 17, No 2 (2020)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v17i2.3730

Abstract

Nitrogen, Phosphate, and Potassium are important nutritional elements contained in the fertilizers for plants but their presence in the soil could be easily wash out by rain water. Biochar, originated from rice husks with a high absorbance ability, might be able to be used to inhibit the release of those nutrients. This research aims to investigate the influence of biochar size and the HCl chemical activation. Biochar, which has been pyrolyzed, was ground and sieved to obtain powder with the size average equivalent to 0.2735 mm; 0.4485 mm; 0.725mm; and 0.925 mm. The optimized biochar size were opted for later being activated using HCl with a concentration of 3%; 9%; and 15%. The leaching process of fertilizer, aiming to imitate the rain water washing, was performed by pouring water on a daily basis on a sand column with the presence of biochar saturated with colorized fertilizer. The obtained solution were then characterized using Spectrophotometer. The results show that the estimated release time for the case with the absence of biochar is 36 days, in contrast to 55 days for the case with the presence of biochar. 
Effect of particle sizes and sodium hydroxide concentrations on silica extraction from minerals obtained in Kalirejo village, Kokap, Kulonprogo, Yogyakarta Tutik Muji Setyoningrum; Wibiana Wulan Nandari; Sri Wahyu Murni; Muhamad Maulana Azimatun Nur
Eksergi Vol 18, No 1 (2021)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v0i0.4576

Abstract

Silica is mainly used in the production of rubber, glass, cement, glass, ceramics, paper, cosmetics, electronics, paintings, healthcare and other industries. Kalirejo village has a potential abundant resource of silica minerals. However, to refine it, high cost of extraction should be done to obtain high purity of silica. Different refining methods influence different purity of the silica. The purpose of this research was to study the refining process of mineral rock silica from Kalirejo village, Kokap, Kulonprogo by emplying simple and cheap solid-liquid extraction. Extraction was done by varying the particle size at 100 - 200 mesh, while NaOH concentration was varied in 0.5 N to 5 N.  Results showed that minerals taken from Kalirejo village was dominated by silica (23%).  The largest extract (4.89 gram) was obtained at 200 mesh and using NaOH 5 N with yield of 15.07%. Higher NaOH and higher particle size enhanced the extraction yield. This finding could help small communities in Kalirejo village to enhance the quality of silica by employing simple and cheap extraction process.
Pengaruh Konsentrasi Fenol terhadap Efektivitas Fotodegradasi Fenol menggunakan Komposit Titania-Carbon Nanotube (Surfaktan) Desi Heltina; Nadhia Gasani Putri; Panca Setia Utama
Eksergi Vol 17, No 2 (2020)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v17i2.3691

Abstract

Aromatic compounds in industrial wastewater such as phenols can contribute as pollutants which are highly toxic and carcinogenic. Phenol degradation can be carried out by a photocatalytic process which can convert phenol into non-toxic and enviromentally friendly compounds. The performance of titania (TiO2) photocatalyst was enhanced by using carbon nanotube as a doping agent for titania. To reduce carbon nanotube agglomeration, the surface of carbon nanotube was modified with cocoPAS surfactant. The purpose of this study was to synthesize titania-carbon nanotube-cocoPAS composite and evaluated the effect of initial phenol concentration (10, 20, 30 ppm) on the phenol photodegradation effectivity using titania-carbon nanotube-cocoPAS composite. Titania-carbon nanotube-cocoPAS composite synthesis was carried out by forming a composite between TiO2 and carbon nanotube that had been modified by surfactant. Composite were characterized by SEM, FTIR, and XRD. Phenol photodegradation was carried out at a degradation temperature of 50ºC for 4 hours under UV light. Samples were drawn at regular intervals and residual concentration of phenol in each sample was analysed using UV-Visible spechtrophotometer. The highest degradation effectivity in 4 hours was 81% at initial phenol concentration of 10 ppm.
Optimization of Coagulant Dosage for Suko River Water Treatment syarifah aini; H.D. Wahyudi; Kukuh Priyono
Eksergi Vol 18, No 1 (2021)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v0i0.4497

Abstract

Sungai Suko, Drono village, Ngawen sub-district, Klaten district, is located near residential area and tofu factory, the possibility of water contamination is quite high, which is caused by household waste. This river water can be processed into clean water by a coagulation process of the Jar Test method using coagulant alum, PAC and chlorine. The purpose of this study was to determine the optimum dose of coagulant in processing Suko river water into clean water using the Jar test method and knowing which coagulant is most suitable for processing the Suko river water into clean water. This research method is to use the Jar Test experiment to determine the optimum coagulant dose in processing Suko river water into clean water. The quality of the water samples before the experiment were tested which included the physical parameters, i.e. temperature, color, odor, and turbidity, also the chemical parameters, i.e. Fe, hardness, CO2, alkalinity, pH, COD, BOD, then the experimental results will determine the level of water clarity. The results showed that the optimum alum content in the experiment was 120 ppm by adding 6 mL of alum to 500 mL of water, the optimum level of PAC in the experiment is 200 ppm by adding 10 mL of PAC to 500 mL of water, and the optimum chlorine level in the experiment is 160 ppm by adding 8 mL of chlorine to 500 mL of water.
Biokeramik Hidroksiapatit (HAp) Berbahan Dasar Cangkang Tiram Anodonta nuttaliana dari Danau Poso Agung Rimayanto Gintu; Elizabeth Betty Elok Kristiani; Yohanes Martono
Eksergi Vol 17, No 2 (2020)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v17i2.3758

Abstract

Bioceramic Hydroxyapatite (HAp) was a derivated chemical synthetic compound from calcium phosphate commonly used to care the damage of hard tissues. Bioceramic Hydroxyapatite can synthetized from the compounds which rich with calcium contains. In this study threated the synthesis and physicochemical characterization to the HAp made from Anodonta nuttaliana clam shells obtained from Poso lake. From the characterization of the sample A. nuttaliana shells obtained the water contains 0,50±0,00%; ash contains 0,9827±0,0022g/g; potasium 0,00135±0,0002g/g; calcium 0,0165±0,0034g/g; phosphate 0,1920±0,0424g/g and the ratio of Ca/P 1,9389±0,3039%. The synthesis of HAp by base precipitation method showed the yield of synthesis 95,4320±0,7085% with the characteristic of the HAp showed that the potassium contains 0,0005±0,00004g/g; calcium 0,95476±0,0012g/g; phosphate 0,528±0,0075; ratio of Ca/P 1,0307±0,0932%; porosity 73,9598±1,1320%; swelling ability 9,6067±2,5365%; and biodegradability 8,8206±0,2176%. From the overall results concluded that the A. nuttaliana clam shells was very potential to became a source of Bioceramic Hydroxyapatite (HAp).
Design of a Water Filter Model with Ceramic Powder for Filter Media Bambang Wisaksono; Hari Wahyudi; Syarifah Aini
Eksergi Vol 18, No 1 (2021)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v0i0.4554

Abstract

Groundwater in the UPN Veteran Yogyakarta integrated campus complex smells and has a reddish brown color, and if the water also causes sediment in the water reservoir, it is assumed that the groundwater contains quite high levels of Ferro (Fe) and Manganese (Mn). Efforts are needed to reduce levels of Ferro (Fe) and Manganese (Mn) in accordance with the required regulations. The main focus of this research is to make a prototype of a clean water filter instrument to reduce levels of Ferro (Fe) and Manganese (Mn) in well water which functions to filter well water into clean water that is fit for consumption in accordance with the standards of the Regulation of the Minister of Health of the Republic of Indonesia number 32 at 2017. Based on the results of the well water quality test, 4 water quality parameters have a value that exceeds the required quality standard threshold, namely the pH value, Ferro (Fe) content, Manganese (Mn) content, and Cadmium (Cd) content. The composition of the water filter media composition is designed based on the results of the preliminary test analysis of the quality of well water as an example of raw water. The water filter tube is made of 4 inch diameter PVC pipe with a length of 80 cm. The composition of the filter media consists of: activated carbon, 25 cm; ceramic powder, 25 cm; volcanic sand, 15 cm; and gravel, 10 cm
Process Dynamic of Two-Thermal-Tank-Series with Dead Time Yulius Deddy Hermawan; Wibiana Wulan Nandari; Fauzan Irfandy; Riski Ajin Rahmadi; Aryandhanu Mukti Tri Perkasa
Eksergi Vol 17, No 2 (2020)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v17i2.3700

Abstract

The multi-tank-series system could come up the problem of instability due to dead-time. The goals of this work are to study the dynamic behavior of Two-Thermal-Tanks-Series (TTTS) with dead time through the open loop experiment in laboratory, and to propose the new-module of fundamental chemical engineering practicum in field of process dynamic for undergraduate program. The two stirred-tank-heaters @10L were designed for heating of water fluid. Both of tanks were designed overflow to maintain their volume constant. The gate valve was installed in the inlet pipe of Tank-1 to adjust its volumetric flowrate (f). The inlet temperature of Tank-1 (T1), the liquid temperatures in Tank-1 (T2) and Tank-2 (T3) were measured by thermocouple multi-channels. The volt-ampere-regulators were used to adjust the electrical energy in Tank-1 (q1) and Tank-2 (q2). The mathematical model was solved and rigorously examined in Xcos/Scilab. In order to study the dynamic behavior of TTTS, the inlet flowrate disturbance was made based on step input change. According to our investigation in laboratory and open loop simulation, both Tank-1 and Tank-2 gave stable responses, the model’s responses showed the closed and similar trend with laboratory’s responses, and time delay of about 30 seconds has been found in Tank-2.
Pretreatment Spirulina platensis Residue untuk Produksi Bioetanol Heni Anggorowati; Indriana Lestari; Arief Budiman; Yano Surya Pradana
Eksergi Vol 18, No 1 (2021)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v0i0.4551

Abstract

Pemerintah Indonesia berusaha untuk menggurangi penggunaan bahan bakar fosil dengan mendorong adanya transisi ke sumber energi terbarukan. Bioetanol merupakan salah satu alternatif energi terbarukan yang mampu mengurangi penggunaan bensin di sektor transportasi. Bioetanol dapat diproduksi dari spirulina platensis residu (SPR) yang masih mengandung karbohidrat yang tinggi. Untuk memaksimalkan perolehan bioethanol diperlukan proses pretreatment yang sesuai untuk memecah dinding sel SPR sehingga diperoleh glukosa yang siap difermentasi. Pada penelitian ini dilakukan tiga metode pretreatment yaitu ultrasonikasi, autoclave dan enzimatis. Pretreatment dengan ultrasonikasi dilakukan dengan ultasonicator batch 40 kHz selama 30 menit dan menghasilkan glukosa sebesar 147,1154 mg/L. Sedangkan dengan autoclave pada suhu 121 oC selama 30 menit menghasilkan glukosa sebesar 21.15385 mg/L. Pretreatmen enzimatis dilakukan dengan menggunakan kombinasi enzim α-amylase dan amyloglucosidase (1:0; 0,75: 0,25; 0,5:0,5; 0,25:0,75 dan 0:1) pada suhu 40 oC selama 180 menit. Yield glukosa maksimum diperoleh pada pengguanaan enzim α-amylase: amyloglucosidase = 0,25:0,75 yaitu sebesar 33,15%.
POST-COMBUSTION COAL DESULFURIZATION Review Silky Amanda Yuniar; Edy Nursanto; Rika Ernawati
Eksergi Vol 17, No 2 (2020)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v17i2.3828

Abstract

The sulfur content in coal ranges from 0.5 to 5%, and it is an impurity that must be removed before burning coal, due to the toxic effects and acid rain caused by SO2 gas generated from sulfur oxidation. Sulfur cleaning technology can be carried out on coal before combustion (pre-combustion), and can reduce the inorganic sulfur content by up to 50%; however, it cannot reduce the organic sulfur content. Therefore, the industry relies on post-combustion desulfurization to remove SO2 from the gas from coal combustion. The aim of the coal desulfurization review is to direct desulfurization research to be efficient and effective, as well as to be environmentally friendly. Sulfur in coal consists of organic sulfur and inorganic sulfur. Coal inorganic sulfur consists of pyrite (FeS2), sulfate, and sulfide. The largest composition is pyrite. Organic sulfur consists of hetero-atomic and heterocyclic (thiophenic) macromolecules that bind N and O atoms, aromatic sulfides, and aromatic disulfides (small amounts). Inorganic sulfur can easily be separated from coal by means of flotation, microwave energy, magnetic forces, ultrasonic energy, and as well as microorganisms. Meanwhile, organic sulfur cannot be separated from coal by using the methods used in the inorganic sulfur separation process. Organic sulfur can be removed by chemical and biodesulfurization, however, this process is inefficient for industrial scale. The most recommended method is the absorption of SO2 gas in the gas from coal combustion, or post-combustion desulfurization. Various methods have also been investigated to separate SO2 gas, and more details will be described in this paper.

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