cover
Contact Name
Muhamad Maulana Azimatun Nur
Contact Email
lanaazim@upnyk.ac.id
Phone
-
Journal Mail Official
editor.eksergi@gmail.com
Editorial Address
Prodi Teknik Kimia UPN Veteran Yogyakarta"</span>. Jl. SWK. 104 Lingkar Utara Condong Catur- Yogyakarta (55283)
Location
Kab. sleman,
Daerah istimewa yogyakarta
INDONESIA
Eksergi: Chemical Engineering Journal
ISSN : 1410394X     EISSN : 24608203     DOI : https://doi.org/10.31315
Eksergi is an open-access, peer-reviewed scientific journal that focuses on research and innovation in the fields of energy and renewable energy. The journal aims to provide a platform for scientists, researchers, engineers, and practitioners to share knowledge and advancements that contribute to sustainable development and energy transition. In addition to energy topics, the journal also accepts high-quality manuscripts related to, but not limited to, the following areas: Separation processes Bioprocesses related to food, energy, and environmental applications Wastewater treatment and resource recovery Process optimization and intensification Carbon capture, utilization, and storage (CCUS) Chemical reaction engineering and reactor design Life cycle assessment (LCA) and sustainability evaluation Process Design and Control Engineering Process Simulations Process System Engineering The journal welcomes original research articles, reviews, and short communications that demonstrate novelty, scientific rigor, and relevance to chemical engineering and interdisciplinary applications.
Articles 298 Documents
A Critical Review of Carbonization Hydrothermal and Pyrolysis for Adsorbent Production and the Application in Industrial Dye Removal Nyamiati, Retno Dwi; Putri Restu Dewati; Muhammad Redo Ramadhan; Ika Wahyuning Widiarti; A Hidayat Nurwahid; Nabila Aulia Balqis
Eksergi Vol 22 No 2 (2025)
Publisher : Prodi Teknik Kimia, Fakultas Teknik Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/eksergi.v22i2.14742

Abstract

Biochar is increasingly recognised as a low-cost and efficient adsorbent for removing organic dyes from wastewater. This review outlines recent developments in biochar production, particularly comparing biochars produced via pyrolysis and hydrothermal carbonisation (HTC). While pyrolysis biochar often exhibits a higher surface area, HTC biochar offers improved oxygen-containing functional groups, contributing to enhanced dye affinity. Studies indicate that biochar can achieve adsorption capacities ranging from 2 to 1353.09 mg/g for dyes such as methylene blue and crystal violet, comparable to or exceeding that of pyrolysis-derived biochars. The review also highlights characterisation techniques such as XRD, FTIR spectroscopy, and SEM to evaluate surface functionality, porosity, and morphology, which directly influence adsorption performance. Practical implications include the suitability of HTC biochar for low-energy, decentralised wastewater treatment systems, particularly in textile and dyeing industries. By connecting production parameters with biochar properties, this review provides insights into optimizing biochar as an adsorbent, particularly for the treatment of dye-contaminated wastewater.
Comparative Analysis of CO₂ Content in Biogas and Synthetic Gas Using Chittick Titration Validated by Gas Chromatography Pambudi, Alfian Wisnu; Rahmawati, Yeni; Taufany, Fadlilatul; Altway, Ali; Susianto
Eksergi Vol 22 No 2 (2025)
Publisher : Prodi Teknik Kimia, Fakultas Teknik Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/eksergi.v22i2.14809

Abstract

This study aimed to validate the Chittick titration method for measuring carbon dioxide (CO2) content using gas chromatography (GC) as the reference method. Two types of gas samples were analyzed: synthetic CO2/N2 gas with a theoretical composition of 40:60 and biogas produced by anaerobic fermentation. Analyses were conducted in parallel using both methods to compare CO2 measurements. For synthetic gas, the Chittick titration recorded an average CO2 content of 39.11%, whereas GC recorded 40.52%. For biogas, Chittick titration produced 30.16%, whereas GC measured 31.40%. The differences between the methods were 0.81% for synthetic gas and 1.55% for biogas, with relative errors of 2.00% and 3.45%, respectively. The t-test results showed statistically significant differences (p < 0.05) between the methods for both gas types. However, the observed deviations remained within practically acceptable limits for small-scale laboratory applications. These findings suggest that Chittick titration is a practical and cost-effective alternative for estimating CO2 content, particularly in laboratories with limited access to gas chromatography equipment. This study is expected to serve as a useful reference for educational institutions and small laboratories that are seeking to develop simple gas analysis methods with adequate validity.
Achieving Net Zero Emissions Target: Development of Carbon Dioxide Handling Technologies, Its Challenges and Barriers Mahidin; Maulana, Farid; Mukramah; Adisalamun; Hisbullah; Hadi, Abdul; MH, Nurdin; Abnisa, Faisal
Eksergi Vol 22 No 2 (2025)
Publisher : Prodi Teknik Kimia, Fakultas Teknik Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/eksergi.v22i2.14655

Abstract

Abatement of carbon emission to net zero level in 2050 is a serious work for Indonesia in all sectors. In this article, review on the current status of CC technologies was conducted including commercial scale and R&D works. The technologies performance was also inserted in order to provide the information that valuable and useful in technological selection. However, the challenges and barriers for Indonesia in their efforts to reduce carbon emissions are not only about technological aspects; the issues of policy, socio culture, law and human resources also play an important role. In order to ensure the project going well, regulations and policies are needed both at the national and provincial levels, besides the massive socialization efforts from various stakeholders.
Effect of Diethanolamine (DEA) Solvent Flow Rate on the CO2 Absorption-Desorption Process Using a Hollow Fiber Membrane Contactor Pamungkas, Raditya; Nurkhamidah, Siti; Taufany, Fadlilatul; Altway, Ali; Susianto, Susianto; Rahmawati, Yeni
Eksergi Vol 22 No 3 (2025)
Publisher : Prodi Teknik Kimia, Fakultas Teknik Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/eksergi.v22i3.14951

Abstract

One of the primary objectives in decarbonization is the separation of CO₂ from industrial gas mixtures, particularly in application such as biogas purification and flue gas treatment. A dual-layer crossflow membrane module was utilized under both circulation and batch operating modes with a 30% DEA solution. This study investigates the influence of solvent flow velocity on CO₂ separation performance using a hollow fiber membrane contactor with a 30% DEA solvent. the process was evaluated under two operating modes: batch and solvent circulation. Key variables measured include the solvent flow rate (40–160 mL/min), operating temperature (30–50°C), and sweep gas flow rate (100–300 mL/min). The results indicate that under continuous operation with a solvent flow rate of 160 mL/min, a temperature of 30°C, and a sweep gas flow rate of 100 mL/min, 50.42% of the CO₂ was successfully removed. In contrast, the batch system, under identical conditions achieved only a 27.8% removal rate. The superior performance in circulation mode is attributed to the continuous renewal of the solvent, which sustains a stable concentration gradient and minimizes mass transfer resistance. These findings underscore the potential of membrane-based systems with optimized solvent circulation for efficient and stable CO₂ capture in industrial applications.
Optimization of Rotation Speed, Disc Diameter, and Lighting Time in Batik Waste Treatment Using Rotary Algae Biofilm Reactor (RABR) with Ulva sp. Raharjo, Sonya Hakim; Palupi, Bekti; Syaifullah, Rangga Yudha; Yohanes; Sekaringgalih, Ratri; Hidayati, Nurul
Eksergi Vol 22 No 3 (2025)
Publisher : Prodi Teknik Kimia, Fakultas Teknik Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/eksergi.v22i3.15084

Abstract

Batik is one of the cultural heritages in Indonesia that must be maintained and preserved. The batik industry process itself produces liquid waste that comes from the coloring processing, washing, wax removing, also rinsing. Batik waste, if not treated properly, can harm the environment. Various studies have shown that effluent treatment using the Rotary Algae Biofilm Reactor (RABR) method is promising. This research focuses on improving the RABR design and optimal conditions for treating batik wastewater, as well as utilizing the synergy between batik production and Ulva sp. The variables used in this research are the rotation speed of 20, 30, and 40 rpm, the lightning time for 0, 6, and 12 hours, and the disk diameter size of 9, 11, and 13 cm. The parameters that analyzed are BOD, COD, and pH levels. Waste treatment optimization in this research uses the RSM with a combination of Design Expert 13 software. Based on the results, the most optimal batik wastewater treatment variable is when the disk diameter is 10.306 mm, the rotation speed is 20 rpm, and the lightning time is 7.805 hours, yielding response values of 55.673 mg/L for BOD, 25.538 mg/L for COD, and 10.406 for pH.
Production of Fragrance Tag (Paper-Based Air Fresheners) from Agarwood Powder Waste (Aquilaria malaccensis) Yuniarti, Reni; Wardani Putri, Elfira; Sida Mubin, Abror; Achmad, Feerzet
Eksergi Vol 22 No 3 (2025)
Publisher : Prodi Teknik Kimia, Fakultas Teknik Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/eksergi.v22i3.15114

Abstract

Agarwood is a non-timber forest product known for its distinctive fragrance. Its processing generates powder waste that is often undervalued and underutilized, despite containing aromatic compounds with potential for value-added products such as fragrance tags. This study aimed to determine the optimal composition of agarwood powder and waste paper, assess the effects of NaOH treatment on product characteristics, and evaluate economic feasibility. The process involved preparing agarwood and HVS paper waste, treating with or without NaOH, producing pulp at ratios of 75:25, 50:50, and 25:75 (% w/w), and adding essential oil. Results showed that NaOH treatment significantly improved physical and sensory properties such as color brightness, grammage, and tensile strength but reduced thickness, absorbency, and aroma retention. Material ratio also influenced performance: 25:75 (% w/w) with NaOH yielded the best color and tensile strength, while 75:25 without NaOH showed the highest thickness, absorbency, and aroma stability up to day 5. Economic analysis indicated feasibility, with a break-even point of 181 units, a return cost ratio (RCR) of 1.44, and a payback period of 2.27 months.
Effect of Stearic Acid on Barrier and Mechanical Properties of Edible Films Based on Carboxymethyl Cellulose (CMC), Konjac Glucomannan (KGM), and κ-Carrageenan (κCarr) Widyasti, Lintang Dian; Meka, Wahyu; Nurkhamidah, Siti
Eksergi Vol 22 No 3 (2025)
Publisher : Prodi Teknik Kimia, Fakultas Teknik Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/eksergi.v22i3.15127

Abstract

The development of edible films using natural polysaccharides presents a sustainable alternative to synthetic packaging materials. This study aimed to enhance the barrier properties of edible films composed of carboxymethyl cellulose (CMC), konjac glucomannan (KGM), and κ-carrageenan (κCarr) by incorporating stearic acid (SA). Films were prepared by blending the biopolymers with SA at varying concentrations (0.1–0.5% w/w) and characterized for their structural, physical, and mechanical properties. Fourier-transform infrared (FTIR) spectroscopy confirmed molecular interactions between SA and the polysaccharide matrix, evidenced by reduced O–H absorption bands and intensified –CH₂– peaks. SA incorporation increased film thickness and moisture content but reduced tensile strength, elongation at break, solubility, and water vapor permeability (WVP). Although the WVP of SA-modified films did not meet the Japanese Industrial Standard at the tested concentrations, the observed trend suggests that higher SA levels could further improve barrier performance. The optimal formulation (0.5% SA) demonstrated enhanced hydrophobicity, acceptable water activity, and moderate tensile strength and opacity. These findings indicate that stearic acid can effectively modify the functional properties of polysaccharide-based edible films, advancing their potential as eco-friendly food packaging materials. Further optimization of SA concentration is recommended to achieve industrial moisture barrier standards.
Production of Liquid Fuel from Motorcycle Used Tire via Pyrolysis: Effect of Temperature on Yield and Calorific Value Wulandary, Indah Retno; Octavia, Yona
Eksergi Vol 22 No 3 (2025)
Publisher : Prodi Teknik Kimia, Fakultas Teknik Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/eksergi.v22i3.14918

Abstract

The continuous accumulation of used tires has raised serious environmental concerns due to their non-biodegradable nature. Pyrolysis offers a promising thermal conversion method to transform used tires into alternative energy sources. This study investigates the pyrolysis of used motorcycle tires, cut into 1 x 1 cm pieces, under atmospheric pressure at various temperatures ranging from 400°C to 750°C, using 500 grams of tire material for each run. The tar and char yields were collected, and the calorific values of the liquid product were analyzed. The optimum operating condition was found at 700°C, yielding 276.56 g of tar and 184.55 g of char after 2 hours and 35 minutes of reaction. The highest calorific value obtained was 39.98 MJ/kg. Although the liquid fuel produced exhibits significant energy content, its calorific value remains lower than that of conventional fuels used in vehicles. This indicates the potential of tire-derived oil as a supplementary fuel, with further improvement needed in quality and performance.