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Seminar Nasional Teknik Kimia Kejuangan
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Prosiding Seminar Nasional Teknik Kimia Kejuangan adalah media online dari makalah yang telah diseminarkan pada acara Seminar Nasional Teknik Kimia “Kejuangan” (SNTKK). SNTKK merupakan agenda tahunan yang diselenggarakan oleh Program Studi Teknik Kimia FTI UPN ”Veteran” Yogyakarta. Seminar ini merupakan sarana komunikasi bagi para peneliti dari perguruan tinggi, institusi pendidikan, serta lembaga penelitian maupun industri, dalam mengembangkan teknologi kimia untuk pengolahan sumber daya alam Indonesia.
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Articles 588 Documents
Production of Magnesium Silicate from Rice Husk with Variation of NaOH Concentration and Reaction Time Length Using Sol-gel Method Kalloka, Sultan Hendra Mahardi; Rabbani, Sulthan; Andesra, Zel; Qomariyah, Lailatul
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

Rice husk is a by-product of rice production where as much as 9.9 million tons become organic waste. Rice husk ash, which is rich in silica, can be processed into materials that have high selling value. Magnesium silicate is one of the silica-based composite materials with the chemical formula MgSiO3 with an example of its application as a material in the manufacture of magnesium cement. The manufacture of magnesium silicate is done by sol-gel method with NaOH solvent where this method is relatively easy and uses simple equipment. This study was conducted to know the best NaOH concentration and length of reaction time to produce optimal magnesium silicate. The NaOH concentration variables used were 3 M, 5 M, 7 M, and 9 M, while the variable length of reaction time was 90 minutes and 150 minutes. The best NaOH concentration is 7M with 90 minutes of reaction time. This variable gave 49,9% yield of magnesium silicate compared to 3M with 90 minutes reaction time where it gave 17,4% yield. The analytical tests carried out were FITR where this test was carried out to confirm the formation of magnesium silicate
Demineralisasi Batubara Berkadar Abu Tinggi dengan Leaching Menggunakan Alkali Ikhsana, Mifta Aulia; Azis, Muhammad Mufti; Purwono, Suryo
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
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The study was comdustred on the demineralization of Jambi coal with high ash content as an effort to improve quality. The coal selected first crushed to -80 + 115 mesh. Demineralization was carried out using leacjing process with NaOH 20, 25, and 30% (%weight). The best parameter was used in subsequent leaching process to determine the effect of temperature of 50, 70, 90oC. The result showed that the percentage of demineralization increased with increasing demineralization reduction 34%
Penentuan Dimensi Pipa Pada Lapangan Panasbumi Gedongsongo Pramudiohadi, Eko Widi
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
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Abstract

To meet the demand for electricity in the Ungaran area in particular, it is necessary to build geothermal power in the Gedongsongo area, but there are no production facilities, both below and on the surface, so the authors plan production facilities on the surface, regarding the selection of optimum pipe diameters. The goal is to build a power plant with a capacity of 110 MWe based on the optimum diameter, which provides the smallest possible loss of pressure and temperature and the maximum possible mass flow, for this the authors use the pressure loss profiles from Begg and Brill and temperature loss using the 1st law of thermodynamics, With two-dimensional Newton Rapson manipulation, it can be seen that the drop in pressure and temperature at the exit point simultaneously on a pipe segment. In this field, there are 4 clusters, including: cluster 1 (4 wells), cluster 2 (5 wells), cluster 4 (2 wells), each 2 wells served by 1 separator, starting from the pressure of each wellhead 15 Barg, dryness 0.25 and rate 105.5 kg/s, insulation thickness 8 cm, polyurethane type, pipe length from wellhead to separator 150 m, resulting in pipe diameter from 18-24 in, minimum thickness from 30.82-39.62 mm, pressure drop 0.55 Barg, temperature 1.67 oC, from separator to turbine input, pipe 50-1200 m long, yield diameter from 16-48 in, minimum thickness 25.01-61.50 mm, pressure drop 1.61 Barg, temperature 3.11 oC, with a generated power of 154 MWe
Pengaruh Konsentrasi Polyaluminium Choride (PAC) dan Polydadmac Terhadap Proses Koagulasi dan Flokulasi pada Pengolahan Air Sungai Cengkareng Drain Redjeki, Athiek Sri; Darmi, Hedro; Yudistirani, Sri Anastasia; Purnawan, Irfan; Hasyim, Ummul Habibah
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
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This study was conducted to determine the effect of the concentration ratio of Polyaluminium Choride (PAC) and Polydadmac coagulants on the coagulation and flocculation processes in river water treatment. The raw water used is raw water that is processed by IPA Taman Kota PT. XYZ namely Cengkareng Drain river water with a turbidity of 19.3 NTU and a pH of 7.22. This study uses the jar test method. The selected variables are variations in the concentration of PAC and polydadmac. The water produced from the jar test was tested for its turbidity and pH. This research was started by sampling raw water, then 1000 ml was put in each glass jar test tool. Then the flocculation process was carried out with a stirring speed of 200 rpm for 2 minutes. Followed by the coagulation process with a stirring speed of 40 rpm for 18 minutes. The process continued with sedimentation for 10 minutes. The optimum dose obtained was the combination of 20 ppm PAC and 0.4 ppm polydadmac with a turbidity value of 1.08 NTU or with a removal efficiency value of 94.40% and a pH value of 7.06.
Karakter Lumpur Pemboran Berbahan Dasar Bentonite Lokal Tulungagung dan Boyolali Mengacu Standar API 13A dengan Variasi Additive Polyamine Ilcham, Adi; Gardatoga, Obed Rama; Irma, Ade
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
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This study examined the feasibility of using locally sourced bentonite as drilling mud, with the aim of reducing the cost of imported drilling mud. Bentonite, a soil type containing a high concentration of smectite or montmorillonite, is widely used in drilling mud. The physical properties of drilling mud made from bentonite from Boyolali and Tulungagung were compared, with the addition of various additives to meet the API 13A standard. The research found that drilling mud made from Boyolali bentonite showed physical properties that were closer to the API 13A standard compared to Tulungagung bentonite. Specifically, adding 7 grams (12%) of polyamine to Boyolali bentonite mud produced a volume of filtrate loss and mud cake thickness closest to the API 13A standard, namely 10.8 ml (maximum 15 ml) and 0.14 cm (maximum 0.28 cm), respectively. Adding 2.3 grams (5.04%) of KOH resulted in the highest pH value of 13, while adding 2.5 grams (1.17%) of Na2CO3 produced the least amount of filtrate loss, namely 7.2 ml (maximum 15 ml), with a mud cake thickness of 0.27 cm (maximum 0.28 cm)
Evaluasi Perbandingan Kinerja Attached Culture Bioreaktor dan Hybrid Membran Bioreaktor dalam Mendegradasi Air Limbah Juniawan, Asyhar Sururi; Budhijanto, Wiratni; Marbelia, Lisendra
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
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Abstract

Restaurant wastewater is categorized as grey wastewater, which is low strength wastewater with a chemical oxygen demand (COD) concentration of <1,000 mg/L. Therefore, further treatment is necessary before it is discharged into the environment. This study focused on comparing the performance of an attached culture bioreactor and a Hybrid Membrane Bioreactor (HMBR) in degrading restaurant wastewater. The bioreactors used a mesh filter support media of 70-80 μm. The bioreactors were operated with COD feed concentration 600 ppm and HRT 13 hour, with artificial grey water waste feed consisting of sugar, urea, KH2PO4, and tapioca flour. The %COD removal achieved by the attached culture bioreactor and HMBR was 90,48% – 90,95% and 96,28%– 96,79%, the turbidity out achieved by the attached culture bioreactor and HMBR was 57,42 – 60,25NTU and 4,95 – 5,62NTU, MLSS value reached  2,36 – 2,86ppm and 2,36 – 2,86ppm. The conclusion of this research shows that the HMBR has relatively better performance than the attached culture bioreactor
Preparasi Katalisator Berbasis Biochar dari Ampas Buah Merah untuk Reaksi Transesterifikasi Minyak Jelantah Rahmah, Puspa; Yuliansyah, Ahmad Tawfiequrrahman; Wintoko, Joko
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
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Biodiesel can be produced from plant and animal oils by transesterification reaction using homogeneous or heterogeneous catalysts. In this study, we prepare a biochar-based catalyst, as a heterogeneous catalyst, for transesterification of used cooking oil. The biochar was made by the pyrolysis of the solid waste from the oil extraction of Papuan red fruit (Pandanus conoideus). After the pyrolysis, the solid was immersed in KOH solution to provide the kalium in the produced biochar. The biochar was then sulfonated by H2SO4 5M for 15h at 120°C. Afterwards, the catalysts were characterized by BET for surface area measurement, FTIR for functional groups on the catalyst surface determination and XRD for successive crystallography characterization. The catalytic performance was studied by conducting transesterification of used cooking oil using methanol with the prepared biochar-based catalysts. The transesterification optimum conditions were found to be oil to methanol molar ratio of 1:15, temperature of 60°C, reaction time of 2 hours and the catalyst amount of 3% of the oil weight. Furthermore, the highest biodiesel yield was obtained by the catalyst prepared from biochar that was sulfonated with 5M H2SO4 solution
Pengaruh Waktu Pemasakan dan Konsentrasi NaOH Terhadap Penurunan Kadar Lignin Pulp dari Batang Pisang Kepok dengan Proses Soda Maulana, Imam; Widayatno, Tri
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
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Banana is a plant that has very high cellulose content so it can be used as a raw material for making pulp. This research was conducted with the aim of knowing the effect of cooking time and sodium hydroxide concentration on reducing the lignin content of banana stem pulp by soda process. The cooking solution used in the soda process is NaOH solution. With various concentrations of NaOH 20%, 25%, and 30% and cooking time 40, 80, and 120 minutes. The highest lignin content was 1.8785% during pulping for 40 minutes with 20% NaOH concentration. While the lowest lignin content was 1.3093% during pulping for 120 minutes with 30% NaOH concentration.
Effect of Cycling and Washing in Fouling Level from Theaflavin Filtration on Ultrafiltration Membrane Nyamiati, Retno Dwi; Yulianto, Mohamad Endy; Nanda, Dodi Eko; Diwiyanto, Yusron Mahendra
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
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Abstract

Ultrafiltration membranes, characterized by their molecular weight cutoff ranging from 50 to 100 kDa, are extensively employed for the filtration of macromolecules including suspended solids, carbohydrates, proteins, and various other components. However, the prolonged usage of these membranes leads to a notable decline in their performance due to fouling. Membrane fouling entails the accumulation of filtered foulant media and the formation of deposits, adversely impacting the filtration efficiency. This study focuses on evaluating the impact of repeated filtration cycles on membrane fouling and investigates the effectiveness of membrane washing in restoring membrane performance. The ultrafiltration membrane was subjected to five consecutive repetition cycles using theaflavin as the filtration media. The observed flux exhibited a substantial decline of 87%, decreasing from an initial value of 0.0574 L/m2.hr to 0.0073 L/m2.hr. To mitigate fouling and enhance membrane performance, a thorough washing process was carried out. Following the washing procedure, the flux was found to increase to 0.034 L/m2.hr, indicating a significant improvement in the membrane's performance. These findings are further supported by the morphological analysis of the membrane using Scanning Electron Microscope (SEM) photographs, which reveal the distinct differences between the membrane's morphology before and after washing.
Review: Biomassa Sebagai Adsorbent untuk Pengolahan Logam Berat Pada Air Limbah Industri Veranica, Veranica; Rahayu, Aster; Maryudi, Maryudi
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
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Abstract

Industrial wastewater generally contains heavy metalssuch as lead, cadmium, arsenic, nickel, chromium and mercury. Contamination of water with these elements is very dangerous and will pollute the environment, so a suitable waste water treatment is required. This review aims to find out the efficient methods of handling industrial wastewater and the benefits of biomass. Many scientific methods are used in this regard, including adsorption, chemical precipitation, ion exchange, electrochemical treatment, membrane filtration, coagulation and flocculation. However, some of these techniques have drawbacks such aswill produce a large amount of metal sludge, making it difficult to recycle metal, and the formation of toxic sludge or other wastes. Of all these techniques, adsorption with adsorbent biomasshas been widely known because it is an economical, effective and environmentally friendly processing technique, so this method is suitable for treating industrial wastewater. The use of biomass as an adsorbent is intendedto help reduce dependence on fossil raw materials and greenhouse gas emissions that contribute to climate change.