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All Journal Chemistry Indonesian Journal of Chemical Research Kalwedo Sains (KASA) Jurnal Akademika Kimia JURNAL REKAYASA KIMIA & LINGKUNGAN
Bijang, Catherina M.
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Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Education Energy Engineering Environmental Science

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Base Activated Clay And Its Application As Cation Exchanger To Reduce The Mg2+ AND Ca2+ Ions Concentration In The Well Bijang, Catherina M.; Sekewael, Serly J.; Koritelu, J. A.
Indonesian Journal of Chemical Research Vol 1 No 2 (2014): Edisi Bulan Januari (Edition For January)
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2014.1-cat

Abstract

The research about base activated clay and its application as cation exchanger to reducing the concentration of ions Mg2+ and Ca2+ in the well water has been caried out. Base solution used for clay activation was NaOH with variation of concentration at, 0.5 M, 1 M, and 1.5 M. Particle size of clay also have been variated at 40 mesh, 60 mesh, and 80 mesh. The result of this research shown that the best cation exchanging for Mg2+ was found in clay with 60 mesh particle sizes and concentration of NaOH 0.5 M, whereas for Ca2+ was found in clay with 80 mesh particle sizes and concentration of NaOH was 1.5 M.
Biosorpsi Ion Logam Tembaga (Cu2+) Pada Biosorben Rumput Laut Coklat (Padina australis) Bijang, Catherina M.; Latupeirissa, Jolantje; Ratuhanrasa, Marike
Indonesian Journal of Chemical Research Vol 6 No 1 (2018): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2018.6-cat

Abstract

The research on the biosorption of Cu2+ metal ions in brown seaweed biosorbent (Padina australis) has been done. This study aims to determine moisture content, ash content, biomass content, pH and optimum contact time of Cu2+ metal ions absorption pH and optimum contact time of Cu2+ metal ions absorption. The method used is batch method. The adsorption result of Cu2+ metal ions was analyzed by using atomic absorption spectrophotometer (AAS). The results showed that the optimum pH was 7 with 99.8308 % absorption ability of biosorbent and the optimum contact time was 5 hours with 99.5570 % biosorbent absorbency.
Biosorpsi Ion Logam Kadmium (Cd2+) Pada Biosorben Rumput Laut Coklat (Padina australis) Asal Pantai Liti Pulau Kisar Bijang, Catherina M.; Tehubijuluw, Helna; Kaihatu, Terence Ghereds
Indonesian Journal of Chemical Research Vol 6 No 1 (2018): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2018.6-cath

Abstract

The research about biosorption of Cadmium (Cd2+) metal ion in brown seaweed biosorben (Paladina australis) from Liti beach, Kisar island has been done. Analysis of decreasing Cd2+ content using Atomic Absorption Spectrophotometer (SSA) and also use FTIR to know functional groups contained in alginate compounds. A total of 0.5 g of brown seaweed powder was introduced into 25 mL of Cd2+ 50 ppm solution with variations of pH 1-7 and shaker for five hours. After the optimum pH was obtained, the adsorption process was applied on pH 5 solution with variation of contact time 1, 3, and 5 hours, after which it was filtered. The result of analysis and calculation showed that Cd2+ ion was optimum at pH 5 of 99.64% and 3 hours contact time was 74.54%.
Preparation of Natural Ouw Clay-Chitosan Composite and Its Application as Lead and Cadmium Metal Adsorbent Bijang, Catherina M.; Tanasale, M.F.J.D.P.; Kelrey, Adhi G.; Mansur, Inda Ulfa; Azis, Thamrin
Indonesian Journal of Chemical Research Vol 9 No 1 (2021): Edition for May 2021
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2021.9-bij

Abstract

This study aims to obtain the optimum ratio of Ouw Natural Clay (LAO):Chitosan in the manufacture of chitosan-LAO composites. The composite will be used as an adsorbent for heavy metals Lead (Pb) and Cadmium (Cd). LAO-Chitosan composites were made with the ratio of LAO:Chitosan = 1.25:1, 2.5:1, 5:1. XRD and SEM were carried out for each composite. The performance as a Cd metal adsorbent was determined by calculating the adsorption capacity. Composites with a ratio of 1.25:1 have the best adsorption capacity. The performance as adsorbent for Cd metal was determined by calculating the absorbed Cd concentration. Maximum results are achieved by composites with a ratio of 5:1.
The Ouw Natural Clay Impregnation Using Titanium Dioxide as a Rhodamine B Dyestuff Degrader Bijang, Catherina M.; Nurdin, M.; Latupeirissa, Jolantje; Aziz, Thamrin; Talapessy, Firda
Indonesian Journal of Chemical Research Vol 9 No 3 (2022): Edition for January 2022
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2022.9-cat

Abstract

This study aims to determine the effect of calcination temperature on Titanium dioxide impregnated Ouw Natural Clay (LAO) on the degradation of Rhodamine B dye. The calcination temperature used was 200, 300, and 400 °C. Their radiation was carried out with 3x8 watt UV lamps and sunlight. The degradation percentage of Rhodamine B dye produced by LAO-TiO2 calcined at a temperature of 200, 300, and 400 °C with sunlight were 98.80%, 98.87%, and 96.07%, respectively. The degradation percentage of Rhodamine B dye produced by LAO-TiO2 calcined at temperatures of 200, 300, and 400 °C with the help of UV light were 96.01%, 97.41 %, and 97.18%, respectively.
Antibacterial Activity Test of Silver Nanoparticle Composites With Gandaria Seed (Bouea macrophylla G.) Bioreductor and Ouw Natural Clay Matrix (ONC) Bijang, Catherina M.; Hasanela, Nurani; Joris, Shielda N.; Lihi, Risma; Salmawati, Mimi
Indonesian Journal of Chemical Research Vol 13 No 1 (2025): Edition for May 2025
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2025.13-cat

Abstract

An antibacterial activity test of silver nanoparticle composite with bioreductor of gandaria seeds (Bouea macrophylla G.) and Ouw natural clay (ONC) matrix was conducted. Silver nanoparticles (AgNPs) were synthesized by forming the colloidal silver solution by chemical reduction method using gandaria seed bioreductor. The formation of AgNPs can be known through UV-Vis absorption when there is a color change. Based on the results, the maximum wavelength of colloidal NPP is 435-444 nm. Silver nanoparticles synthesized through the preparation process were tested to determine their effectiveness as antibacterial agents against Escherichia coli and Staphylococcus aureus. The test results showed that the NPP formulation, containing an aqueous extract of gandaria seeds with the addition of polyvinyl alcohol (PVA), produced an inhibition zone of 10.6 mm against E. coli, indicating strong antibacterial activity. In contrast, the activity against S. aureus was classified as moderate, with an inhibition zone measuring 6.8 mm. For the antibacterial activity test with Ag/ONC nanocomposite samples on both test bacteria, there was no inhibition zone or antibacterial activity.
Electrochemical Performance of Tellurium Oxide on TiO2/Ti Array for Photoelectrocatalytic Chemical Oxygen Demand Sensor Applications Maulidiyah, Maulidiyah; Irwan, Irwan; Indriani, Annisa; Salim, La Ode Agus; Arham, Zul; Bijang, Catherina M.; Kurniawan, Kurniawan; Nurdin, Muhammad
Jurnal Rekayasa Kimia & Lingkungan Vol 17, No 2 (2022): Jurnal Rekayasa Kimia & Lingkungan (December, 2022)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v17i2.27784

Abstract

The experiments were carried out using Te-TiO2/Ti as working electrodes, prepared by the simple anodization technique and dip coating method, on Ti substrates (TiO2/Ti). The measurements were performed in an electrochemical cell using a three-electrode system, with Te-TiO2/Ti as the working electrode, Ag/AgCl as the reference electrode and pt as the auxiliary electrode. A flow system for determining the profile and photocurrent response of reactive orange 84 was developed using Linear Sweep Voltammetry (LSV) and Multi-Pulse Amperometry (MPA). The physicochemical properties of Te-TiO2/Ti electrodes have been studied using UVvis DRS analysis techniques and compared with un-doped TiO2/Ti electrodes. The UVvis DRS showed that the TiO2/Ti doped Te functionally decreases bandgap to 3.0 eV. The results showed that the photocurrent of reactive orange 84 was observed in the concentration range (1-5 M), with a linear response between concentration and charge.
Performance of The Composite Electrode of Reduced Graphene Oxide Palm Oil Shell - Zinc Oxide (rGOCKS - ZnO) as a Chemical Oxygen Demand (COD) Sensor by Photoelectrocatalysis Azis, Thamrin; Muzakkari, Muhammad Z.; Nurdin, Muh.; Maulidiyah, Maulidiyah; Muslia, Wa O.; Bijang, Catherina M.; Tahril, Tahril
Jurnal Akademika Kimia Vol. 12 No. 2 (2023)
Publisher : Universitas Tadulako

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/j24775185.2023.v12.i2.pp123-131

Abstract

The preparation of reduced graphene oxide composite electrodes from palm shells (rGOCKS-ZnO) as a chemical oxygen demand (COD) sensor by photoelectrocatalysis has been successfully carried out. The preparation of rGOPS - ZnO electrodes by thermal reduction method and modified Hummer. The XRD results showed several peaks of rGOCKS - ZnO namely 23.287 º, 26.781 °, 29.889 °, 32.468 °, 35.109 °, 37.14 °, 39.822 °, 43.559 °, 47.927 °, and 48.537 °. SEM-EDX analysis reveals the surface of graphene sheets containing aggregates in the shape of small particles attached to graphene sheets. The results of the EDX analysis consisted of C 67.82 %, O. 19.2 %, Zn. 7.85 % and 5.13 % impurity. The CV and LSV tests showed that the rGOAK - ZnO electrode with a variation of 1 gram: 0.3 gram had a good response to the oxidation process under visible light. The profile tests of these organic dyes (methylene blue) in concentrations of 0.5 ppm, 1.0 ppm, 2.0 ppm, and 3.0 ppm were applied by Multi Pulse Amperometry (MPA). The performance of the rGOPS - ZnO electrode has been in determining the value of COD by photo electrocatalytic good sensitivity, linearity, limit of detection, repeatability, and service life. The COD value was determined using the rGOPS - ZnO electrode and obtained 2.97897 mg/LO2 close to the theoretical value.
Synthesis of Silver Nanoparticles using Gandaria Seeds Bioreductor Bijang, Catherina M.; Hasanela, Nurani; Joris, Shielda N.; Fransina, Eirene G.; Tahril, Tahril; Azis, Thamrin; Tehuayo, Ahmadin
Jurnal Akademika Kimia Vol. 12 No. 2 (2023)
Publisher : Universitas Tadulako

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/j24775185.2023.v12.i2.pp142-148

Abstract

The silver nanoparticles (NPP) are synthesized with the chemical reduction method by using a water extract bioreductor of gandaria seed (Bouea macrophylla G.) which acts as a reducing precursor, in this case, AgNO3 Ag+ is reduced to AgO. The concentration of AgNO3 is made between 0.5 mm and 1 mm. The characteristic of NPP is unstable, so a modification is needed with and without the addition of PVA 1 %. The process of NPP shaping is monitored by observing the uptaken of UV - Vis when the color changes occur. The high NPP concentration of AgNO3 has higher absorbance and is wider if compared to the lower AgNO3 concentration. The result of this research based on the absorbance value and the wavelength showed the NPP synthesized without the addition of PVA 1 % (b/v) is wider. The addition of PVA 1 % (b/v) provides better stability and maintains the absorbance of spectrum changes from day to day. The maximum uptaken of UV-Vis from NPP AgNO3 0.5 mm by using green synthesis and 1 mm without adding PVA are 0.946 and 0.980, respectively. However, NPP with the addition of PVA has 0.968 and 0.978 absorbance. The best concentration of NPP produced was 1 mm AgNO3.
Analysis Of Mineral Types And Contents Of Copper (Cu) And Lead (Pb) In Copper Mining Area In Wetar Island Male, Yusthinus T.; Bijang, Catherina M.; Naharuik, Sintia
Kalwedo Sains (KASA) Vol 1 No 2 (2020): Kalwedo Sains (KASA), September 2020
Publisher : Program Studi Di Luar Kampus Utama Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/kasav1i2p96-102

Abstract

The research to determine content of metal Cu and Pb in six samples (three ore rocks and three waste rocks) in the copper mining area on Wetar Island. The results showed that the highest concentration of Cu metal for ore rocks was in the first sample (MS KK) of 106,800 ppm and the smallest Cu concentration was in the third sample (PBx 1 KK) of 411 ppm. While the largest concentration of Cu metal waste rock is the first sample (Vol 1 KK) is 1.894 ppm and the smallest Cu metal concentration is in the second sample (BA 1 KK) is 310 ppm. As for the concentration of metal Pb in the largest ore rocks is in the first sample (MS KK) of 9,890 ppm, the small metal concentration of Pb is in the third sample (PBx 1 KK) is 660 ppm and the concentration of metal Pb for waste rock is found only in the first sample (Vol 1 KK) with a concentration of 1,631 ppm. This study shows that Wetar Island contains high copper and lead deposits.
Co-Authors Arham, Zul Aziz, Thamrin Fransina, Eirene G. Hasanela, Nurani Indriani, Annisa Irwan Irwan Joris, Shielda N. Kaihatu, Terence Ghereds Kelrey, Adhi G. Koritelu, J. A. Kurniawan Kurniawan Latupeirissa, Jolantje Lihi, Risma M. Nurdin Mansur, Inda Ulfa Maulidiyah Maulidiyah Muh. Nurdin, Muh. Muhammad Nurdin Muslia, Wa O. Muzakkari, Muhammad Z. Naharuik, Sintia Ratuhanrasa, Marike Salim, La Ode Agus Salmawati, Mimi Sekewael, Serly J. Tahril Talapessy, Firda Tanasale, M.F.J.D.P. Tehuayo, Ahmadin Tehubijuluw, Helna THAMRIN AZIS Yusthinus T. Male