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Journal : KOVALEN: Jurnal Riset Kimia

Pemanfaatan Limbah Puntung Rokok sebagai Inhibitor Korosi pada Baja St40 Menggunakan Metode Microwave Assisted Extraction (MAE) di Lingkungan NaCl 3,56%: Utilization of Cigarette Butts Waste as Corrosion Inhibitor on St40 Steel Using Microwave Assisted Extraction (MAE) Method in 3.56% NaCl Environment Alatif, Ikhsan Akmal; Permatasari, Rahma Puspa; Nurulgina, Rahma; Adzkia, Zahrotul Filza; Andayani, Puri; Putri, Sabrina Aisyah; Adinda; Trirahayu, Dhyna Analyes; Hadiningrum, Kunlestiowati
KOVALEN: Jurnal Riset Kimia Vol. 10 No. 3 (2024): December Edition
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/kovalen.2024.v10.i3.17394

Abstract

Corrosion is a problem that occurs in many industries and causes large losses. The use of corrosion inhibitors is one way to reduce or inhibit corrosion. Cigarette butt waste extract can be utilized as an organic corrosion inhibitor. This study aims to determine the yield of cigarette butt waste extract, the content of cigarette butt waste extract produced using the MAE method qualitatively, determine the optimum conditions for the extraction process with the MAE method based on variations in microwave power of 150 and 300 watts and calculate the efficiency of corrosion inhibitors and the effect of compounds contained in cigarette butt waste extract in 3.56% NaCl environment. The optimum MAE condition was 150 watts and 15 minutes, with an extract yield of 54.38%. Based on the GC-MS test, it is known that cigarette butts waste extract contains alkaloid, terpenoid, and phenol compounds as corrosion inhibitor compounds. Based on corrosion inhibitor testing, the addition of cigarette butt waste extract corrosion inhibitors can suppress or reduce the corrosion rate that occurs on metals with an inhibitor efficiency of 79.19% in non-aerated conditions and 71.53% in aeration with an inhibitor concentration of 1000 ppm in a 3.56% NaCl environment.
Efektivitas Limbah Puntung Rokok sebagai Inhibitor Korosi dalam Medium Asam Klorida pada Baja A36 dengan Metode Microwave Assisted Extraction: Effectiveness of Cigarette Butts Waste as Corrosion Inhibitor in Hydrochloric Acid Medium on A36 Steel by Microwave Assisted Extraction Method Alatif, Ikhsan Akmal; Permatasari, Rahma Puspa; -, Maya Futri Nur Rachmat; Wulandari, Dwi Arsya; Sonia, Gina; Aura, Azma Addina; Trirahayu, Dhyna Analyes; Hadiningrum, Kunlestiowati
KOVALEN: Jurnal Riset Kimia Vol. 10 No. 3 (2024): December Edition
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/kovalen.2024.v10.i3.17395

Abstract

Cigarette butts are one of the wastes found in many places, and their presence can damage the environment. One way to reduce the amount of cigarette butts waste is to process them into corrosion inhibitors. This study aims to extract tobacco from cigarette butts using 96% ethanol solvent by varying the extraction time for 5, 10, 15, and 20 minutes, and microwave power of 150 watts and 300 watts, and calculating the efficiency of corrosion inhibitors in acidic environments. The extraction method used was Microwave Assisted Extraction (MAE). From the extraction process, it is known that the optimum extraction power of 150 watts in 15 minutes produces the highest yield of 64.52%. Based on phytochemical and GC-MS tests, it is known that cigarette butt extract contains antioxidant compounds in the form of alkaloids, pyranones, and terpenoids as corrosion inhibitor compounds. Based on corrosion testing, it is proven that the addition of cigarette butt waste extract corrosion inhibitors can suppress or reduce the corrosion rate that occurs on metals with the most excellent efficiency of 82.26% with an extract concentration of 2000 ppm. And the SEM-EDX test results concluded that the corrosion inhibitor from cigarette butts waste extract can withstand the formation of rust on the metal.