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Deoksigenasi berkatalis Pd/C dari Asam Oleat sebagai senyawa model minyak nabati untuk sintesis solar terbarukan Bambang Heru Susanto; M. Nasikin; S Sukirno; Gita Agitia Fransisca
Jurnal Teknik Kimia Indonesia Vol 11, No 3 (2012)
Publisher : ASOSIASI PENDIDIKAN TINGGI TEKNIK KIMIA INDONESIA (APTEKIM)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/jtki.2012.11.3.5

Pd/C-catalized deoxygenation of Oleic Acid as a vegetable oil model for renewable diesel fuel synthesis.Second-generation biofuels called renewable diesel that are drop-in replacements for traditional petroleum derived transportation fuels (diesel, gasoline, and jet fuel) can be produced from triglycerides by thermocatalytic processes. One of the alternatives of renewable solar synthesis is through deoxygenation reaction using heterogeneous catalysts. In this experiment, oleic acid was used as model compounds to study the catalytic deoxygenation process of triglycerides to hydrocarbons like diesel (renewable diesel). The 1% Pd/C catalyst used in the study was prepared by microwave polyol process. At 400 oC and under H2 pressure of 9 bar and 15 bar, The Pd/C catalysts tended to be more selective toward decarboxylation pathway. Under H2, the main liquid-phase product was alkanes and aromatic, while the main gaseous products were CO and CO2. The conversion was around of 75% with selectivity of renewable diesel was 50.14%. Measured physical properties of renewable diesel (density and viscosity) is comparable to those specified for commercial diesel.Keywords: deoxygenation, oleic acid, Pd/C catalys, microwave polyol process, renewable dieselAbstrakGenerasi ke-2 dari bahan bakar nabati yang disebut dengan solar terbarukan dapat menggantikan bahan bakar turunan dari minyak bumi untuk transportasi (solar, bensin dan bahan bakar pesawat) dengan cara diproduksi dari trigliserida melalui reaksi termokatalitik. Salah satu rute sintesis solar terbarukan adalah melalui proses reaksi deoksigenasi berkatalis heterogen. Di dalam penelitian ini, asam oleat digunakan sebagai senyawa model untuk mempelajari deoksigenasi katalitik dari trigliserida menjadi hidrokarbon seperti solar (solar terbarukan). Katalis Pd/C yang digunakan dalam studi ini dipersiapkan dengan metode microwave polyol process. Pada kondisi operasi suhu 400 oC dan tekanan H2 sebesar 9 bar dan 15 bar, katalis 1 %-berat Pd/C lebih cenderung mengarahkan reaksi ke jalur dekarbokasilasi. Pada kondisi tekanan H2 didapatkan produk cair yang utama adalah alkana dan aromatik sedangkan produk gasnya adalah CO dan CO2. Konversi reaksi yang dihasilkan adalah sekitar 75% dengan selektifitas produk solar terbarukan adalah 50,14%. Sifat fisik (densitas dan viskositas) solar terbarukan mendekati sifat fisik solar komersial.Kata kunci: deoksigenasi, asam oleat, katalis Pd/C, microwave polyol process, solar terbarukan

Synthesis of diesel-like hydrocarbon from Jatropha oil through catalytic pyrolysis Bambang Heru Susanto; Muhammad Nasikin; Ayuko Cheeryo Sinaga; F Fransisca
Jurnal Teknik Kimia Indonesia Vol 11, No 1 (2012)
Publisher : ASOSIASI PENDIDIKAN TINGGI TEKNIK KIMIA INDONESIA (APTEKIM)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/jtki.2012.11.1.7

Due to economical, social and ecological reason, several studies have been done in order to obtain alternative fuel sources. In this respect, fermentation, trans-esterification and pyrolysis if biomass have been proposed as alternative solutions. Among these different approaches, pyrolysis seems to be a simple and efficient method fuel production. Pyrolysis, assisted by solid catalysts, has also been reported and it was recognized that the product selectivity is strongly affected by the presence and the nature of heterogeneous catalysts. The catalytic pyrolysis of straight Jathropha curcas oil (SJO) over nanocrystalline NiO/Al2O33 at 475 OC was studied. NiO/Al2O3 catalyst was used in pyrolysis for purpose of selectively cracking of triglyceride. Nanocrystalline NiO/Al2O3 was prepared by simple heating method with polymer solution as growth inhibitor. The liquid product (bio-oil) were analyzed by GC-FID and FTIR, showing the formation of carboxylic acids, paraffin, olefins, and ketones. Measured physical properties of bio-oil is comparable to those specified for diesel oil. Keywords: SJO, nanocrystalline, simple heating method, catalytic pyrolysis, bio-oilAbstrakAdanya pertimbangan keekonomian, sosial, dan ekologi, menyebabkan dilakukannya penelitian guna mendapatkan sumber bahan bakar alternatif. Berkaitan dengan hal tersebut, maka reaksi-reaksi seperti permentasi, transesterifikasi dan pirolisis dari biomasa telah digunakan sebagai alternatif solusi. Diantara pendekatan-pendekatan yang berbeda tersebut, pirolisis merupakan metode yang sederhana dan efesien untuk menghasilkan bahan bakar. Pirolisis, yang dibantu dengan katalis padat, telah juga dilaporkan dan diketahui bahwa selektifitas produknya sangat dipengaruhi oleh kehadiran dan sifat dari katalis-katalis heterogen yang digunakan. Pirolisis berkatalis dari minyak jarak pagar (straight Jathropha curcas oil, SJO) melalui nanokristal NiO/Al2O3 pada suhu 475 OC telah dilakukan percobaanya. Katalis NiO/Al2O3 digunakan dalam pirolisis dengan tujuan untuk perengkahan selektif dari trigliserida. Nanokristal NiO/Al2O3 dibuat dengan menggunakan metode simple heating dengan pelarut polimer sebagai penghambat pertumbuhan. Produk cair yang dihasilkan (bio-oil) telah dianalisa dengan menggunakan GC-FID dan FTIR, memperlihatkan adanyanya gugus asam-asam karboksilat, parafin, olefin dan keton. Sifat fisik yang diukur dari biooil dapat diperbandingkan kesetaraanya dengan spesifikasi dari minyak solar.Kata kunci: SJO, nanokristal, metode simple heating, pirolisis berkatalis, bio-oil

Preparation and Characterization NiMo/Zeolite Catalyst using Microwave Polyol Process Method for Synthesizing Renewable Diesel from Jathropa Oil Bambang Heru Susanto
Sriwijaya International Seminar on Energy-Environmental Science and Technology Vol 1, No 1 (2014)
Publisher : Sriwijaya International Seminar on Energy-Environmental Science and Technology

Show Abstract | Download Original | Original Source | Check in Google Scholar

Biofuels have great potential to fulfill the energy needs of Indonesia. The process used is hydrodeoxygenation reaction (HDO) whose products are known as renewable diesel. This study focuses on preparation NiMo/Zeolite catalyst for synthesizing renewable diesel from jatropha oil. Preparation of NiMo/Zeolite catalyst is done by using microwave polyol process method. Microwave polyol method is a modification from incipient wetness method to overcome energy consumption and preparation time problem. Microwave polyol method is done by using a fast and uniform electric radiation from microwave as heating medium to dry catalyst. The catalyst result by using microwave polyol method gives the surface area of â€‹â€‹5.45m2/g and has average crystal size of 62.98nm. NiMo/Zeolit catalyst used to synthesize renewable diesel at 375oC, pressure 12 bar, catalyst loading 1% mass of Jathropa Oil and stirer speed 800 rpm. Based on the characterization results of GC-MS, the catalyst NiMo/Zeolit has conversion of jatropha oil 88,61% with renewable diesel product selectivity and yield are 35.26 and 21.5% respectively. According to result of FTIR and product physical properties, renewable diesel products have similar functional group and have better specifications than commercial diesel with density valuesâ€‹â€‹: 0.833 gr/cm3, viscosity: 3.02 cst, cetane index: 61.01

Dealumination Effect on ZSM-5 as a Bimetal Fe-Co Support for The Oxidative Desulfurization Process Catalyst Adhani, Lisa; Susanto, Bambang Heru; Nasikin, Mohammad
Jurnal Kimia Valensi Jurnal Kimia VALENSI, Volume 10, No. 1, May 2024
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15408/jkv.v10i1.38456

Petroleum fuel is still the main energy source today but causes environmental problems such as SOx gas emissions. The Oxidative Desulfurization (ODS) method removes sulfur from fuel under mild conditions. ZSM-5 is a catalyst framework considered promising in the ODS process but the small pores cause a steric barrier. The hydrophobic, mesoporous Fe-Co/ZSM-5Hierarchy catalyst was designed using the dealumination method with steam treatment to overcome the steric barrier and biphasic hindrances which are problems in this ODS process. The Fe-Co/ZSM-5Hierarchy catalyst is effective for the ODS process at a temperature of 45 °C, 45 min, the amount of catalyst used is 0.2 g, oxidant at an O/S ratio of 2, and without mass transfer agents. The embedded Fe-Co ratio shows effective mass activity by providing a TOF number of 205 h-1 on the Fe-Co(5)/ZSM-5 Hierarchy and 157 h-1 on the Fe-Co(15)/ZSM-5 Hierarchy catalyst.

Facile Creating a Hierarchical and Hydrophobic Fe-Co/LZSM-5 Catalyst for the Oxidative Desulfurization Process Adhani, Lisa; Susanto, Bambang Heru; Nasikin, Mohammad
Indonesian Journal of Chemistry Vol 24, No 5 (2024)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.95267

This research involved top-down dealumination and steam treatment methods to design the hierarchical pores of ZSM-5, which is then wet-impregnated with a Fe-Co. This method overcomes the steric barrier that hinders the oxidative desulfurization (ODS) process and makes the catalyst hydrophobic, thereby allowing it to overcome the biphasic hindrance caused by the difference in polarity between the fuel oil and the oxidant. Characterization of the catalyst's properties based on BET and BJH, XRF, and contact angle, as well as testing its performance on DBT model oil in n-hexadecane and Indonesian commercial diesel were conducted. Simulation of the reaction energy profile using density functional theory calculations was also carried out to deepen insight into the mechanism of the reaction. Results of this study show that the catalyst has excellent catalytic reactivity in the long-chain hydrocarbon ODS process, with a TOF number of 183 h−1.

Development of WO3/TiO2-NT/Ti photoanode for simultaneously POME degradation, electricity generation, and hydrogen production in a photocatalysis-fuel cell system Bachri, M. Febriansyah; Husein, Saddam; Susanto, Bambang Heru; Ratnawati, Ratnawati; Slamet, Slamet
International Journal of Renewable Energy Development Vol 14, No 3 (2025): May 2025
Publisher : Center of Biomass & Renewable Energy (CBIORE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/ijred.2025.60978

This research presents a WO₃/TiO₂-NT/Ti photoanode for processing POME waste as well as producing electricity and hydrogen simultaneously. The photoanode in the form of nanocomposites was synthesized using an in-situ anodization method and characterized using Field Emission Scanning Electron Microscopy with Energy Dispersive X-ray (FESEM-EDX), X-ray Diffraction (XRD), Photoluminescence Spectroscopy (PL-Spectra), photocurrent transient, X-ray Photoelectron Spectroscopy (XPS), and UV-Visible Diffuse Reflectance Spectroscopy (UV-Vis DRS). The results showed that the WO₃/TiO₂-NT/Ti photoanode with 0.3 g of WO₃ precursor added during anodization exhibited the best PFC performance. The system achieved a COD degradation of 84%, hydrogen production of 11.18 mmol/m², and a maximum power density of 0.0375 mW/cm² under visible light irradiation, outperforming the variations with 0.5 g and 0.78 g WO₃ precursor. The enhanced performance was attributed to the formation of a heterojunction between WO₃ and TiO₂, as confirmed by characterization results and performance tests in COD degradation, electricity generation, and hydrogen production. Meanwhile, the addition of 0.5 g and 0.78 g WO₃ precursor reduced photocatalytic performance, likely due to excessive Na₂WO₄·2H₂O during anodization, which could partially cover the active TiO₂-NT/Ti surface and alter the electrochemical oxidation process. The developed WO₃/TiO₂-NT/Ti photoanode offers a promising solution for simultaneous wastewater treatment, clean hydrogen production, and electricity generation, with potential applications in sustainable palm oil processing industries and future renewable energy technologies.

Dealumination Effect on ZSM-5 as a Bimetal Fe-Co Support for The Oxidative Desulfurization Process Catalyst Adhani, Lisa; Susanto, Bambang Heru; Nasikin, Mohammad
Jurnal Kimia Valensi Jurnal Kimia VALENSI, Volume 10, No. 1, May 2024
Publisher : Department of Chemistry, Faculty of Science and Technology Syarif Hidayatullah Jakarta State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15408/jkv.v10i1.38456

Petroleum fuel is still the main energy source today but causes environmental problems such as SOx gas emissions. The Oxidative Desulfurization (ODS) method removes sulfur from fuel under mild conditions. ZSM-5 is a catalyst framework considered promising in the ODS process but the small pores cause a steric barrier. The hydrophobic, mesoporous Fe-Co/ZSM-5Hierarchy catalyst was designed using the dealumination method with steam treatment to overcome the steric barrier and biphasic hindrances which are problems in this ODS process. The Fe-Co/ZSM-5Hierarchy catalyst is effective for the ODS process at a temperature of 45 °C, 45 min, the amount of catalyst used is 0.2 g, oxidant at an O/S ratio of 2, and without mass transfer agents. The embedded Fe-Co ratio shows effective mass activity by providing a TOF number of 205 h-1 on the Fe-Co(5)/ZSM-5 Hierarchy and 157 h-1 on the Fe-Co(15)/ZSM-5 Hierarchy catalyst.

Community Empowerment in Sajang Village Through Coffee Soap Making and Entrepreneurship Training Zulys, Agustino; Syauqi, Muhammad Iqbal; Adriana, Elva Dissa; Istiqomah, Muhsinatul; Susanto, Bambang Heru; Haidir, Banu Muhammad
ASEAN Journal of Community Engagement Vol. 7, No. 1
Publisher : UI Scholars Hub

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Rural entrepreneurship is believed to be one of the most strategic ways to advance community empowerment that can directly lead to national economic development, by optimizing local resources, technology, and digitalization. This article elaborates on the program conducted to support the community’s economy and increase business and digital marketing literacy in Sajang Village, Sembalun, East Lombok. The program consists of bar soap products making workshop that optimizes coffee and copra as the local potential, targeted for people of productive age who are interested in establishing a home-based business. The soap manufacturing process is informed by laboratory research formulas that have been tested and are safe, and the produced soap offers advantages over ordinary soap for both aromatherapy and skin care capacities to overcome acne and remove dead skin cells. The program’s objective is to stimulate the growth of local entrepreneurship and advance the development of authentic regional products as a sustainable income source that will strengthen the local economy. The analysis of the program’s pre- and post-tests and questionnaires indicates that such programs have enhanced participants’ literacy, skills, and motivation. A small business group was founded in subsequent to the program to launch the business; however, additional support from the local government and company is still required to maintain a supportive atmosphere for new entrepreneurs. Such entrepreneurship training could be an effective way to empower a community and open further opportunities for people in other rural areas.

Seawater utilization through hybrid photocatalysis-electrocoagulation process using pumice-supported g-C3N4/BiOBr for hydrogen production and methylene blue decolorization Sudianto, Julius Rainer; Pratiwi, Reno; Susanto, Bambang Heru; Slamet, Slamet
International Journal of Renewable Energy Development Vol 15, No 2 (2026): March 2026
Publisher : Center of Biomass & Renewable Energy (CBIORE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/ijred.2026.61722

This study investigated the simultaneous photocatalysis-electrocoagulation process using pumice-supported g-C3N4/BiOBr nanocomposites in seawater treatment to remove organic pollutants and generate hydrogen gas. The photocatalyst nanocomposite was synthesized via coprecipitation and immobilized on the pumice surface to enhance light exposure and facilitate catalyst recovery. The performance of the hybrid system was evaluated under various operational parameters, including applied voltage, seawater concentration, and pH. The results showed that the combined process outperformed the individual photocatalysis and electrocoagulation systems. Optimal performance was achieved at pH 3 and 15% seawater concentration, resulting in 99.37% methylene blue decolorization and 211 mL of hydrogen within 2 hours. At higher salinities and lower pH, increased coagulant formation caused a shadowing effect, limiting photocatalytic efficiency despite continued hydrogen evolution. The XPS (X-Ray Photoelectron Spectroscopy) characterization of the photocatalyst material, demonstrated the successful formation of a nanocomposite with a stable surface chemistry. Photoluminescence analysis confirmed that the charge separation mechanism could be enhanced, suppressing the recombination rate and being the primary reason for the enhanced photocatalysis process, although interfacial electronic interactions remained limited. Overall, this study demonstrates that the pumice-supported g-C₃N₄/BiOBr photocatalyst integrated with electrocoagulation provides an effective and stable platform for seawater-based hydrogen production and organic pollutant removal.

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