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BIOSORPTION OF Ni (II) IONS BY ARABICAN COFFEE FRUIT (Coffea arabica) Serly Tandigau; Nursiah La Nafie; Prastawa Budi
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 11, No.1: June 2018
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v11i1.6402

Abstract

Arabica coffee fruit peel is a material that is abundant and cheap. The material has been used as an adsorbent in the biosorption process for the removal of metal ions of Ni(II) from wastewater. Biosorption of Ni(II) ion by dragon fruit peel was done on the variation of particle size, variation of contact time, pH and concentration. Adsorption capacity was studied by both isotherm adsorptions of Langmuir and Freundlich. The concentration of metal ions Ni(II) before and after adsorption was determined using Atomic Absorption Spectrophotometer (AAS). Results showed that the optimum time was 50 minutes and the optimum pH was 6 with 120 mesh of particle size of biosorption. Results showed that the biosorption of Ni(II) ion using Arabica coffee fruit peel fullfilled the isotherm Langmuir model with the biosorption capacity (Qo) of 18.86 mg/g. The functional group involved in metal ion biosorption of Ni(II) by the peel of coffee fruit is a hydroxyl group (-OH). 
Adsorption of Bismarck Brown R Dyes Using Mesoporous Silica MCM-48 Zakir, Muhammad; Nuraeni, Andi; Taba, Paulina; Wahab, Abdul Wahid; Dali, Seniwati; Kasim, Syaharuddin; Nafie, Nursiah La
Indonesian Journal of Chemical Research Vol 10 No 2 (2022): Edition for September 2022
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2022.10-muh

Abstract

The adsorption of Bismarck Brown R (BBR) dye has been conducted using mesoporous silica (MCM-48). We synthesized the adsorbent using Ludox HS-40 as a silica source and surfactants of Cetyl Trimethylammonium Bromide (CTAB) and Triton X-100. The characterization of MCM-48 was performed using Fourier transform infrared (FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). Various contact times were used to study the adsorption kinetics, and concentrations were used to study the adsorption isotherm. The optimum contact time of Bismarck Brown R dye was 120 minutes, and the adsorption followed a pseudo-second-order model. Based on the equation Langmuir and Freundlich adsorption isotherms, the adsorption capacity values of each are obtained 158.7301 mg g-1 and 4.3601 mg g-1. Our results showed that the material can be used as a new dye adsorbent.