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All Journal Majalah Forum Teknik UGM Jurnal Rekayasa Proses EKSAKTA: Journal of Sciences and Data Analysis International Journal of Renewable Energy Development Jurnal Sains dan Teknologi Jurnal Teknosains Jurnal Ketahanan Nasional Seminar Nasional Teknik Kimia Kejuangan Journal of Engineering and Technological Sciences Jurnal Kimia dan Kemasan Jurnal Sains Dan Teknologi Lingkungan Jurnal Sains & Teknologi Lingkungan Konversi Indonesian Journal of Chemistry Communications in Science and Technology Jurnal Rekayasa Proses Jurnal Inovasi Teknik Kimia ASEAN Journal of Chemical Engineering Buletin Profesi Insinyur Prosiding Conference on Research and Community Services Jurnal Teknik Kimia Indonesia Jurnal Kimia dan Kemasan Jurnal Teknologi Lingkungan Lahan Basah Jurnal Manusia dan Lingkungan International Journal of Renewable Energy Development Bulletin of Chemical Reaction Engineering & Catalysis
Suryo Purwono
Departemen Teknik Kimia, Fakultas Teknik, Universitas Gadjah Mada
Agriculture, Biological Sciences & Forestry Humanities Automotive Engineering Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Computer Science & IT Control & Systems Engineering Earth & Planetary Sciences Economics, Econometrics & Finance Education Electrical & Electronics Engineering Energy Engineering Environmental Science Immunology & microbiology Industrial & Manufacturing Engineering Materials Science & Nanotechnology Mathematics Mechanical Engineering Public Health Social Sciences Other

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Pengaruh Penambahan Silica Nanopartikel dan Surfaktan SLS (Sodium Lignosulfonat) terhadap Proses Adsorpsi pada Enhanced Oil Recovery (EOR) Handayani, Destias Selly; Yuliansyah, Ahmad Tawfiequrrahman; Purwono, Suryo
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

Surfactant flooding is a chemically enhanced oil recovery (EOR) technique that removes trapped residual oil by lowering the oil-water interfacial tension. The success of surfactant flooding is strongly affected by surfactant loss through its adsorption process on reservoir mineral rocks. Surfactant adsorption is a test method to determine whether surfactant is adsorbed in the reservoir rocks. In the surfactant adsorption test, only static adsorption was carried out. The mixed-surfactant formulation used 70% surfactant SLS, 22% PFAD, and 8% 1-octanol (w/v). Mixed-surfactant concentration variations are 0.25, 0.5, 0.75, and 1% (w/v). The IFT test results showed that the smallest IFT value at a concentration of 1% is 3.15 x 10-3 mN/M. In this research, adding silica nanoparticles (SNPs) to the mixed-surfactant solution is expected to reduce the interfacial tension (IFT) value and the amount of surfactant adsorbed in the reservoir rocks. Variations of SNPs concentration used are 0.05, 0.09, 0.15, and 0.3% (w/v). The lowest IFT test result by adding concentration SNPs of 0.09% is 2.07 x 10-4 mN/M. The adsorption test result showed that by adding SNPs with concentration 0.09%  with adsorption time of 24h is effective to used for adsorption.
Demineralisasi Batubara Berkadar Abu Tinggi dengan Leaching Menggunakan Alkali Ikhsana, Mifta Aulia; Azis, Muhammad Mufti; Purwono, Suryo
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

The study was comdustred on the demineralization of Jambi coal with high ash content as an effort to improve quality. The coal selected first crushed to -80 + 115 mesh. Demineralization was carried out using leacjing process with NaOH 20, 25, and 30% (%weight). The best parameter was used in subsequent leaching process to determine the effect of temperature of 50, 70, 90oC. The result showed that the percentage of demineralization increased with increasing demineralization reduction 34%
Preparation of Mo-impregnated mordenite catalysts for the conversion of refined kernel palm oil into bioavtur Trisunaryanti, Wega; Triyono; Wijaya, Karna; Kartini, Indriana; Purwono, Suryo; Rodiansono; Mara, Ady; Budiyansah, Amsal
Communications in Science and Technology Vol 8 No 2 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.2.2023.1288

Abstract

The research aims to study the effects of Mo metal embedded on H-Mordenite on its activity and selectivity of hydrodeoxygenation (HDO) for Refined Palm Kernel Oil (RPKO) into bioavtur. The RPKO was obtained from the results of degumming and bleaching process of palm kernel oil and then analyzed using Gas Chromatography-Mass Spectrometer (GC-MS). The impregnation of Mo metal was carried out by spraying using an ammonium heptamolybdate precursor solution ((NH4)6Mo7O24•4H2O) with an initial Mo metal content of 5, 10, and 15wt% of H-Mordenite to produce 5-Mo/Mor, 10-Mo/Mor, and 15-Mo/Mor. The 15-Mo/Mor catalyst produced the highest amount of liquid product (46.08wt%) with bioavtur yield of 43.19wt%. The usability test showed that 15-Mo/Mor catalyst still produced a good performance after three times of use in the RPKO feed HDO with the second and third run test liquid product of 34.82 and 46.14wt% respectively with bioavtur yield of 32.58 and 43.45wt%, respectively.
Reaction Kinetics of Waste Cooking Oil Hydrocracking into Biofuel Using Ni-Impregnated Mesoporous Silica Catalyst Salamah, Siti; Trisunaryanti, Wega; Kartini, Indriyana; Purwono, Suryo
Bulletin of Chemical Reaction Engineering & Catalysis 2025: BCREC Volume 20 Issue 3 Year 2025 (October 2025)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20399

Abstract

The growing demand for energy and the scarcity of fossil fuel resources have driven research into alternative fuels, one of which being the conversion of waste cooking oil into biofuel through hydrocracking. This study investigates the reaction kinetics of waste cooking oil hydrocracking using a Ni-impregnated mesoporous silica catalyst. The process was conducted at 450 °C with a hydrogen gas flow to produce products such as green naphtha, green gasoline, and green diesel. The proposed reaction kinetics model was the pseudo-first order, solved using differential and integral methods. The results showed that the first-order reaction provided a more representative outcome, with a reaction rate constant (k’) of 0.276 h⁻¹ at 450 °C. Additionally, the Arrhenius kinetic model revealed an activation energy of 37.8748 kJ/mol for this process. Thus, this study demonstrates a significant potential of using mesoporous silica catalysts in waste cooking oil hydrocracking to produce environmentally friendly and economically viable biofuels. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
Thermal Stability Test and Formulation of Sodium Lignosulfonate with Isoamyl Alcohol as EOR Surfactant Andriani, Anisa Novi; Azis, Muhammad Mufti; Purwono, Suryo
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

Sodium lignosulfonate (SLS) is a promising low-cost surfactant that can be prepared from biomass. There has been large interest to utilize SLS as a chemical Enhanced Oil Recovery (EOR) surfactant. For that purpose, SLS is often mixed with other chemicals such as alcohols. The aim of this study was to find the best formulation of mixed-surfactant and to perform its thermal stability. The resulting mixed-surfactant was then characterized with variety of tests: aqueous stability, phase behavior, and IFT values. We found that a mixture that consists of 50 wt.% SLS, 30 wt.% Isoamyl Alcohol, and 20 wt.% of Palm Fatty Acid Distillate (PFAD) soap gave ultralow IFT at 1.864 × 10-3 mN/m. Phase behavior test shows that 1 wt% of mixed-surfactant formed a Winsor Type III. Subsequently, thermal stability test was conducted at 70°C for 90 days. The results showed that the IFT value fluctuates within the range of 10-3 mN/m for the first three weeks. After three weeks, the IFT values tend to increase to 10-2 mN/m until the end of the test. Hence, although ultralow IFT was achieved in the beginning of the test, further study is needed to improve the long-term stability of the present mixed-surfactant
Demineralisasi Batubara Berkadar Abu Tinggi dengan Leaching Menggunakan Alkali Ikhsana, Mifta Aulia; Azis, Muhammad Mufti; Purwono, Suryo
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

The study was comdustred on the demineralization of Jambi coal with high ash content as an effort to improve quality. The coal selected first crushed to -80 + 115 mesh. Demineralization was carried out using leacjing process with NaOH 20, 25, and 30% (%weight). The best parameter was used in subsequent leaching process to determine the effect of temperature of 50, 70, 90oC. The result showed that the percentage of demineralization increased with increasing demineralization reduction 34%
Pengaruh Penambahan Silica Nanopartikel dan Surfaktan SLS (Sodium Lignosulfonat) terhadap Proses Adsorpsi pada Enhanced Oil Recovery (EOR) Handayani, Destias Selly; Yuliansyah, Ahmad Tawfiequrrahman; Purwono, Suryo
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Surfactant flooding is a chemically enhanced oil recovery (EOR) technique that removes trapped residual oil by lowering the oil-water interfacial tension. The success of surfactant flooding is strongly affected by surfactant loss through its adsorption process on reservoir mineral rocks. Surfactant adsorption is a test method to determine whether surfactant is adsorbed in the reservoir rocks. In the surfactant adsorption test, only static adsorption was carried out. The mixed-surfactant formulation used 70% surfactant SLS, 22% PFAD, and 8% 1-octanol (w/v). Mixed-surfactant concentration variations are 0.25, 0.5, 0.75, and 1% (w/v). The IFT test results showed that the smallest IFT value at a concentration of 1% is 3.15 x 10-3 mN/M. In this research, adding silica nanoparticles (SNPs) to the mixed-surfactant solution is expected to reduce the interfacial tension (IFT) value and the amount of surfactant adsorbed in the reservoir rocks. Variations of SNPs concentration used are 0.05, 0.09, 0.15, and 0.3% (w/v). The lowest IFT test result by adding concentration SNPs of 0.09% is 2.07 x 10-4 mN/M. The adsorption test result showed that by adding SNPs with concentration 0.09%  with adsorption time of 24h is effective to used for adsorption.
Tin (II) Chloride Catalyzed Esterification of High FFA Jatropha Oil: Experimental and Kinetics Study Ratna Dewi Kusumaningtyas; Prima Astuti Handayani; Rochmadi Rochmadi; Suryo Purwono; Arief Budiman
International Journal of Renewable Energy Development Vol 3, No 2 (2014): July 2014
Publisher : Center of Biomass & Renewable Energy (CBIORE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.3.2.75-81

Abstract

Biodiesel is one of the promising energy source alternatives to fossil fuel. To produce biodiesel in a more economical way, the employment of the low-cost feed stocks, such as non-edible oils with high free fatty acid (FFA), is necessary. Accordingly, the esterification reaction of FFA in vegetable oils plays an important role in the biodiesel production. In this work, esterification of FFA contained in Crude Jatropha Oil (CJO) in the presence of tin (II) chloride catalyst in a batch reactor has been carried out. The esterification reaction was conducted using methanol at the temperature of 40-60 °C for 4 hours. The effect of molar ratio of methanol to oil was studied in the range 15:1 to 120:1. The influence of catalyst loading was investigated in the range of 2.5 to 15% w/w oil. The optimum reaction conversion was obtained at 60 °C with the catalyst loading of 10% w/w oil and molar ratio of methanol to oil of 120:1. A pseudo-homogeneous reversible second order kinetic model for describing the esterification of FFA contained in CJO with methanol over tin (II) chloride catalyst was developed based on the experimental data. The kinetic model can fit the data very well.
Co-Authors Ady Mara, Ady Ahmad Tawfiequrahman Yuliansyah Ahmad Tawfiequrrahman Yuliansyah Anak Agung Gede Sugianthara Andriani, Anisa Novi Aprilia Siti Purwanti Arief Budiman Arief Budiman Arief Budiman Ariff Trisetia Anggara Arista Putranto Atika Dwi Farini Bambang Soehendro Bardi Murachman Bardi Murachman Bardi Murachman Budiyansah, Amsal Chitra Ria Ariska dan Suwati Danang Wahyuhono Desi Amalia Fenyka Dyah Mutiarin Dyah Tri Yulianti Eka Sari, Eka Eni Budiyati Fergie Febrina Fitri Trapsilawati Fitriani Fitriani Galuh Almas Darmawati Handayani, Destias Selly Handirofa Handirofa Ignesti Anindia Ikhsana, Mifta Aulia Indriana Kartini Indriana Kartini Jonas Kristanto Karna Wijaya Kartini, Indriyana Mohammad Fahrurrozi Muhamad Johar Ardany Muhammad Irsan B Muhammad Khoirul Anam Muhammad Kusumawan Herliansyah Muhammad Mufti Azis Muhammad Mufti Azis Nurcahyo Iman Prakoso Panut Mulyono Pasca Giffari Jusuf Prima Astuti Handayani Ratna D Kusumaningtyas Ratna Dewi Kusumaningtyas Rizki Purnaini Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rochmadi Rodiansono Rukmana Rully Septria Rully Septria, Rully Sang Kompiang Wirawan Sarto Sarto Satriyo Dibyo Sumbogo Siti Salamah Siti Salamah Siti Syamsiah Siti Syamsiah Subagyo Sudarmadji Sudarmadji Sudarmadji Sudarmadji Sudarmadji Sudarmadji Supranto Supranto Supranto Sutijan Sutijan Teguh Ariyanto Triyono Triyono Triyono Triyono Triyono Wega Trisunaryanti Wega Trisunaryanti Wega Trisunaryanti Wega Trisunaryanti Wega Trisunaryanti Yelmira Zalfiatri Yundari, Yundari Yusmardhany Yusuf