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The Influence of NaOH Activator Concentration on the Synthesis of Activated Carbon from Banana Peel for Pb(II) Adsorption Abdul Hamid; Zeni Rahmawati; Mohammad Abdullah; Tri Esti Purbaningtyas; Faizatur Rohmah; Ike Dayi Febriana
EKSAKTA: Berkala Ilmiah Bidang MIPA Vol. 23 No. 03 (2022): Eksakta: Berkala Ilmiah Bidang MIPA (E-ISSN : 2549-7464)
Publisher : Faculty of Mathematics and Natural Sciences (FMIPA), Universitas Negeri Padang, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1118.799 KB) | DOI: 10.24036/eksakta/vol23-iss03/323

Abstract

Lead has been known as one of the heavy metals with a high adverse effect to the environment and human health. This study reports the activity of activated carbon from biomass of banana peel as an adsorbent to resolve the hazardous lead-contaminated wastewater. The influence of the activator was studied via the alteration of NaOH concentration from 1, 3, and 5 M, where the sample was denoted as AC-1, AC-3, and AC-5. Some techniques, including FTIR, XRD, and SEM were applied to characterize the sample with the highest adsorption capacity. FTIR result affirmed the presence of hydroxyl group on the activated carbon with NaOH 1 M (AC-1) that was beneficial for adsorption. XRD and SEM confirmed that the activated carbon possessed crystalline and amorphous phases with sheet-like morphology. Regarding Pb(II) adsorption, the higher concentration of activator caused the decline of adsorption capacity as the contact time prolonged. The highest adsorption capacity and efficiency were obtained using 1 M NaOH activator with a contact time of 1 hour, which was 3.71 mg/gram and 97.86%, respectively.
Pemanfaatan Batu Kapur Madura sebagai Katalis dalam Pembuatan Bioedesel dari Minyak Nyamplung Ike Dayi Febriana; Abdul Hamid; Amin Jakfar; Mohammad Abdullah; Faizatur Rohmah; Tri Esti Purbaningtias; Zeni Rahmawati; Septian Dwi Wijaya
Indonesian Journal of Chemical Analysis (IJCA) Vol. 5 No. 1 (2022): Indonesian Journal of Chemical Analysis
Publisher : Universitas Islam Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/ijca.vol5.iss1.art2

Abstract

Pemanfaatan batu kapur dari Pamekasan, Madura sebagai katalis heterogen pada reaksi pembuatan biodiesel dipelajari pada penelitian ini.  Batu kapur dikalsinasi pada suhu 900 ºC selama 3 jam untuk membentuk katalis CaO. Katalis CaO yang terbentuk dikarakterisasi menggunakan difraksi sinar-X (XRD), spektroskopi inframerah (FTIR) dan Scanning Electron Microscopy-Energy Dispersive X-Ray Analysis (SEM-EDX). Proses transesterifikasi dari minyak nyamplung dilakukan dengan rasio mol minyak terhadap methanol sebesar 1:16 pada temperatur 60 °C selama 1 jam dengan katalis CaO sebesar 4 % (w/w). Hasil analisis GC-MS diperoleh yield biodiesel sebesar 54% dengan konversi sebesar 49%.
Characterization of Zeolite ZSM-5 Synthesized from Kaolin and TPABr Using X-Ray Diffraction and Infrared Spectroscopy Abdul Hamid; Faizatur Rohmah; Tri Esti Purbaningtias; Mohammad Abdullah
Indonesian Journal of Chemical Analysis (IJCA) Vol. 6 No. 1 (2023): Indonesian Journal of Chemical Analysis
Publisher : Universitas Islam Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/ijca.vol6.iss1.art5

Abstract

Kaolin with alumina and silica content is used as the main material in this research to study the synthesis of ZSM-5 zeolite. The hydrothermal process was carried out through different aging times, namely 12, 24 and 36 hours. Tetrapropyl ammonium bromide (TPABr) was used as a template for the Mobile Five-1 (MFI) structure guide. X-ray diffraction (XRD) and infrared spectroscopy (FTIR) instruments were used to characterize the ZSM-5 zeolite formed from the synthesis results. This was done to identify the phase change from kaolin to zeolite ZSM-5. The results of the analysis using XRD for all samples showed a characteristic peak of the ZSM-5 zeolite at 2θ around 7.88°; 8.72° ;23.09°; 23.84° and 24.32°. However, samples with an aging time of 12 hours also showed peaks at 2θ around 15.84° and 26.03° which indicated an analsim phase. The absorption bands from the FTIR characterization for all samples are seen at wave numbers around 453, 542, 793, 1088 and 1221 cm−1 which are the characteristic peak points of ZSM-5 zeolite. The longer the aging time indicates that the crystallinity of the ZSM-5 zeolite is increasing. The highest crystallinity was obtained from ZSM-5 zeolite samples which were aged for 36 hours. This indicates an increasing number of ZSM-5 crystal nuclei with high purity because there is no other phase besides the ZSM-5 phase.
Transesterification of Waste Cooking Oil using CaO Catalyst Derived from Madura Limestone for Biodiesel Production and Its Application in Diesel Engine Abdul Hamid; Amin Jakfar; Sirly Bifadilatur Romaniyah; Ike Dayi Febriana; Mohammad Abdullah; Zeni Rahmawati; Didik Prasetyoko
Automotive Experiences Vol 6 No 1 (2023)
Publisher : Automotive Laboratory of Universitas Muhammadiyah Magelang in collaboration with Association of Indonesian Vocational Educators (AIVE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31603/ae.7879

Abstract

In this study, we report biodiesel production from waste cooking oil using CaO catalyst derived from Madura limestone through a transesterification reaction. Many limestone quarries in Madura can be used as heterogeneous catalysts because they are cheap, easy to separate, and have high basicity. Conversion of limestone into CaO catalyst through calcination at 900°C for 3 hours. The CaO catalyst formed was characterized using X-Ray Diffraction (XRD), Fourier Transform Infra-Red (FTIR), and Scanning Electron Microscopy-Energy Dispersive X-Ray (SEM-EDX) instruments. Biodiesel formed through the transesterification reaction was analyzed using GC-MS. Furthermore, biodiesel blends from waste cooking oil and pure diesel were prepared in volume percentages (B-10, B-20, B-30, B-40, and B-100) for testing on diesel engine performance. The results of testing the highest torque and brake horsepower (BHP) were obtained on pure diesel fuel (S-100) at 2.49 Nm and 381.12 watts, respectively. The lowest fuel consumption at 1500 rpm is produced on the B-20 at 0.186 kg/h. Overall, the emission characteristics of carbon monoxide (CO), nitrogen oxides (NOx), and nitrogen monoxide (NO) with the lowest concentration resulted from biodiesel blends rather than pure diesel.
Rancang Bangun Desain Aquatec Hybrid Berbasis Ecoblue Guna Peningkatan Hasil Tangkap Ikan di Pesisir Madura Anauta Lungiding Angga Risdianto; Triyanti Irmiyana; Astri Rino Okvitasari; Mohammad Abdullah
G-Tech: Jurnal Teknologi Terapan Vol 7 No 3 (2023): G-Tech, Vol. 7 No. 3 Juli 2023
Publisher : Universitas Islam Raden Rahmat, Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33379/gtech.v7i3.2930

Abstract

Madura merupakan bagian dari provinsi Jawa Timur. Salah satu kabupaten yang memiliki potensi perikanan yaitu Sampang. Dengan luas wialayah 1233 , dimana 75% penduduk bekerja sebagai nelayan. Saat ini permasalahan yang dihadapi oleh nelayan berupa sarana alat tangkap ikan yang belum efektif. Melihat permasalahan yang ada perlu adanya suatu inovasi berupa desain sarana guna peningkatan hasil tangkap ikan. Metode pada penelitian ini berupa kualitatif dimana dengan mengumpulkan data melalui kegiatan survey untuk pembuatan konseptual desain agar sesuai dengan kondisi yang ada dengan bantuan aplikasi Autocad. Hasil dari penelitian ini berupa desain rencana umum dengan ukuran utama kapal loa: 9,22 m; B: 1,8; H: 0,8; T: 0,42. Serta kebutuhan panel surya untuk hybrid budidaya ikan yaitu 8 panel surya(200 wp) dan 1 baterai kering (12V/100 Ah).
Pelatihan Pembuatan Miniatur Kapal pada Siswa dan Siswi di SMAN 3 dan 4 Pamekasan Sebagai Upaya Peningkatan Minat Kewirausahaan Generasi Muda terhadap Produk Kemaritiman Aurista Miftahatul Ilmah; Arief Syarifuddin; Taufan Prasetyo; Desta Rifky Aldara; Arisessy Maharani Mulananda; Retno Syahriawati Dewi; Mohammad Abdullah; Fadlilatin Nailah
I-Com: Indonesian Community Journal Vol 3 No 4 (2023): I-Com: Indonesian Community Journal (Desember 2023)
Publisher : Fakultas Sains Dan Teknologi, Universitas Raden Rahmat Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33379/icom.v3i4.3435

Abstract

Data BAPPEDA Jawa Timur pada bulan Februari 2023 menunjukkan bahwa permasalahan pengangguran pada lulusan SMA/SMK adalah yang tertinggi, sehingga perlu pembekalan agar para siswa bisa menciptakan lapangan pekerjaan sendiri. Jurusan Teknologi Kemaritiman di Politeknik Negeri Madura turut mempunyai tanggung jawab dalam memberikan pembekalan pada siswa SMA khususnya di Pamekasan untuk bisa mempunyai pengetahuan dalam bidang kewirausahaan dengan memberikan pelatihan pembuatan miniatur kapal sebagai lahan berwirausaha dalam penjualan cinderamata atau kesenian. Pelatihan pembuatan miniatur kapal dilaksanakan dengan total peserta 47 siswa dari 2 (dua) sekolah di Pamekasan yaitu SMAN 3 dan 4 Pamekasan. Pelaksanaan pelatihan pembuatan miniatur kapal diawali dengan koordinasi internal dan eksternal, pembuatan modul pelatihan. Pada hari pertama pelatihan diawali dengan pelaksanaan pre-test, penyampaian materi tentang kewirausahaan, e-commerce, dan miniatur kapal serta ditutup dengan post-test. Pada hari kedua pelatihan fokus kepada cara pembuatan miniatur kapal sebagai produk yang akan dijadikan dijual. Berdasarkan hasil pre-test dan post-test dapat diketahui bahwa siswa dan siswi di SMAN 3 dan 4 mengalami peningkatan secara pemahaman terhadap kewirausahaan, e-commerce, dan pembuatan miniatur kapal.
Pelatihan Pengelasan dan Inspeksi kepada Siswa SMAN 3 Sampang sebagai Upaya Penguatan Indeks Pembangunan Manusia (IPM) Arief Syarifuddin; Aurista M. Ilmah; Taufan Prasetyo; Desta Rifky Aldara; Mohammad Abdullah
I-Com: Indonesian Community Journal Vol 4 No 3 (2024): I-Com: Indonesian Community Journal (September 2024)
Publisher : Fakultas Sains Dan Teknologi, Universitas Raden Rahmat Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33379/icom.v4i3.5327

Abstract

Madura Island is part of the province of East Java which has a lot of potential, starting from tourism, natural resource potential, such as oil, natural gas, and salt, as well as cultural potential. Until now, the large potential possessed by the island of Madura has not been managed optimally; this is partly due to the low interest of the Madurese people in studying as much as possible. Welding and inspection training for SMAN 3 Sampang students as an effort to strengthen the Human Development Index (HDI) in the sector of improving the quality of human resources is one of the efforts that will be taken by the Maritime Technology Department of the Madura State Polytechnic to be able to improve the quality of high school graduates. Hence, they are ready to compete in the world of work. Overall, the training resulted in a good understanding for participants, as evidenced by the improvement in post-test results. The training participant satisfaction questionnaire showed poor and poor results for several aspects of resource persons, training materials, and consumption.