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Contact Name
Istadi
Contact Email
istadi@che.undip.ac.id
Phone
+6281316426342
Journal Mail Official
bcrec@live.undip.ac.id
Editorial Address
Editorial Office of Bulletin of Chemical Reaction Engineering & Catalysis Laboratory of Plasma-Catalysis (R3.5), UPT Laboratorium Terpadu, Universitas Diponegoro Jl. Prof. Soedarto, Semarang, Central Java, Indonesia 50275
Location
Kota semarang,
Jawa tengah
INDONESIA
Bulletin of Chemical Reaction Engineering & Catalysis
ISSN : -     EISSN : 19782993     DOI : https://doi.org/10.9767/bcrec
Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in chemical reaction engineering, catalysis science, and engineering, catalyst preparation method and characterization, novel innovation of chemical reactor, kinetic studies, etc. are particularly welcome. However, articles concerned on the general chemical engineering process are not covered and out of the scope of this journal. This journal encompasses Original Research Articles, Review Articles (only selected/invited authors), and Short Communications, including: fundamentals of catalyst and catalysis; materials and nano-materials for catalyst; chemistry of catalyst and catalysis; surface chemistry of catalyst; applied catalysis; applied bio-catalysis; applied chemical reaction engineering; catalyst regeneration; catalyst deactivation; photocatalyst and photocatalysis; electrocatalysis for fuel cell application; applied bio-reactor; membrane bioreactor; fundamentals of chemical reaction engineering; kinetics studies of chemical reaction engineering; chemical reactor design (not process parameter optimization); enzymatic catalytic reaction (not process parameter optimization); kinetic studies of enzymatic reaction (not process parameter optimization); the industrial practice of catalyst; the industrial practice of chemical reactor engineering; application of plasma technology in catalysis and chemical reactor; and advanced technology for chemical reactors design. However, articles concerned about the "General Chemical Engineering Process" are not covered and out of the scope of this journal.
Articles 838 Documents
Synthesis of W-Doped TiO2 Material Ratio Using One-Step Solvothermal Method and Treatment Orientation of Volatile Organic Compounds Chau, Hung Dung; Tuu, Tran Thi; Sy, Phung Chi; Tan, Lam Van; Tran, Thi Kim Ngan
Bulletin of Chemical Reaction Engineering & Catalysis 2023: BCREC Volume 18 Issue 4 Year 2023 (December 2023)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.18198

Abstract

In TiO2 photocatalysts have been interested in the world thanks to many advantages in handling toxic compounds, with great potential for practical application at low cost. However, the electron-hole recombination rate is still high and can not be processed under visible light, which is a major limitation of this material. Modification of TiO2 by W6+ is a possible solution, however there is still little research and the optimal W6+ ratio in small amounts is still low. The material was synthesized by a one-stage solvothermal method at 200 ºC for 10 hours, without using any surfactants or post-reaction calcination with doped W molar ratios of 0.5%, 1%, and 1.5%. The result was that the TiW-1.5% catalyst sample had the highest specific surface area of 175 m2/g, higher than pure TiO2 of 160.0 m2/g. The W6+ ion successfully replaced Ti4+ in the TiO2 crystal lattice, reducing the band gap energy of the catalytic sample to 2.88 eV with the TiW-1.5% sample. For TiW-0%, the formaldehyde decomposition ability is 53.50%. Doping W into TiO2 increased catalytic efficiency, with a material sample with an optimal modified W content of 1.5% mol W having a formaldehyde decomposition efficiency of 71.98%. Research results show that W modification can improve the activity of TiO2 and increase the efficiency of volatile organic compound treatment. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Synthesis of SrO.SiO2 Catalyst and Its Application in the Transesterification Reactions of Soybean Oil Nuni Widiarti; Lisa Amalia Suryana; Nanik Wijayati; Endah Fitriani Rahayu; Harjito Harjito; Samuel Budi Wardhana; Didik Prasetyoko; Suprapto Suprapto
Bulletin of Chemical Reaction Engineering & Catalysis 2017: BCREC Volume 12 Issue 2 Year 2017 (August 2017)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.12.2.804.299-305

Abstract

The synthesis and characterization of SrO.SiO2 were carried out. The rice hull ash was utilized as a source for SiO2. The SrO.SiO2 was prepared by sol-gel technique, and the ratios of SrO:SiO2 were      varied as 0:1, 1:0, 3:2, 2:4, and 2:7. The sol-gel was calcined at 800 oC for 4 hours. The result was    characterized using XRD and FTIR. The diffraction pattern shows that the diffraction angle was shifted, and the intensity of the main peaks was increased. This research indicated that the            crystallinity of SrO was improved at the higher SiO content. Further, a new peak was observed in the IR spectra at a wavenumber of 900 cm-1 indicating the appearance of new functional groups of the SrO.SiO2. The catalytic activity of SrO.SiO2 on transesterification reaction was optimized. The optimum condition was obtained at SrO.SiO2 of 2:7, reaction time of 30 minutes, reaction temperature of 65 oC, the amount of catalyst of 1 % w/v of reactants, and the biodiesel yield of 96.66 %. 
Operating Conditions and Composition Effect on the Hydrogenation of Carbon Dioxide Performed over CuO/ZnO/Al2O3 Catalysts Djaouida Allam; Salem Cheknoun; Smain Hocine
Bulletin of Chemical Reaction Engineering & Catalysis 2019: BCREC Volume 14 Issue 3 Year 2019 (December 2019)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.14.3.3451.604-613

Abstract

A series of catalysts constituted of mixed copper and zinc oxides supported on alumina were prepared by co-precipitation method. The cooper content was in the 10-90 wt.% range. Their catalytic behavior in the hydrogenation of carbon dioxide to methanol was investigated at high pressure (up to 75 bars). The catalysts were characterized by elemental analysis, N2-adsorption, N2O-chemisorptions, and X-ray diffraction (XRD). The catalysts showed a clear activity in the hydrogenation reaction that could be correlated to the surface area of the metallic copper and to the reaction pressure. The CuO/ZnO/Al2O3 catalyst with a Cu/Zn/Al weight ratio of 60/30/10, exhibits the highest carbon dioxide conversion and methanol selectivity. Finally, a mechanism pathway has been proposed on copper active sites of (Cu0/CuI) oxidation state. 
Production of Biodiesel from Oleic Acid and Methanol by Reactive Distillation Kusmiyati Kusmiyati; Agung Sugiharto
Bulletin of Chemical Reaction Engineering & Catalysis 2010: BCREC Volume 5 Issue 1 Year 2010 (June 2010)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.5.1.7103.1-6

Abstract

Biodiesel is an alternative diesel fuel that is produced from vegetable oils and animal fats. Generally, it is formed by transesterification reaction of triglycerides in the vegetable oil or animal fat with an alcohol. In this work, esterification reaction was carried out using oleic acid, methanol and sulphuric acid as a catalyst by reactive distillation method. In order to determine the best conditions for biodiesel production by reactive distillation, the experiments were carried out at different temperature (100 0C, 120 0C, 150 0C and 180 0C) using methanol/oleic acid molar ratios (1:1, 5:1, 6:1, 7:1, 8:1), catalyst/ oleic acid molar ratios (0.5%wt, 1%wt, 1.5%wt and 2%wt) and reaction times (15, 30, 45, 60, 75 and 90 minutes). Results at temperature 180 0C, methanol/ oleic acid molar ratio of 8:1, amount of catalyst 1% for 90 minute reaction time gives the highest conversion of oleic acid above 0.9571. Biodiesel product from oleic acid was analysed by ASTM (American Standard for Testing Material). The results show that the biodiesel produced has the quality required to be a diesel substitute. © 2010 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)
Electrochemical Generation of Hydrogen and Methanol using ITO Sheet Decorated with Modified-Titania as Electrode Tariq Abbas; Muhammad Tahir; Nor Aishah Saidina Amin
Bulletin of Chemical Reaction Engineering & Catalysis 2021: BCREC Volume 16 Issue 2 Year 2021 (June 2021)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.16.2.10514.430-439

Abstract

Current issues of global warming and environmental pollution due to extensive use of fossil fuels has been reached to an alarming position. Being CO2 as main byproduct of fossil fuel consumption and water as abundantly available on earth surface has great potential to replace fossil fuels as energy source. Herein, electrocatalytic CO2 reduction with water for methanol and hydrogen gas (H2) production over ITO sheet decorated with modified-Titanium nanorods (TiO2 NR), has been investigated. The performance comparison of electrocatalytic activity of hydrothermally modified-titania with commercial TiO2 microparticles (MP) were further investigated. Electrochemical reactor containing KHCO3 aqueous solution with CO2 as an electrolyte and modified TiO2 nanorods (NR) as working electrodes offer an eco-friendly system to produce clean and sustainable energy system. The typical rates of product, i.e. methanol and H2 generation from the ITO sheet decorated with modified TiO2 NR layer recorded higher than those for the ITO sheet with commercial TiO2 microparticle. At 2.0V applied potential vs Ag/AgCl as reference electrode, the modified TiO2 NR electrocatalyst yielded methanol at a rate of 3.32 µmol.cm−2.L−1 and H2 at a rate of 6 µmol.cm−2.L−1 which was higher than that of commercial TiO2 MP electrocatalyst (methanol = 1.5 µmol.cm−2.L−1 and H2 = 3.7 µmol.cm−2.L−1). The enhancement in product yields of methanol and H2 was mainly due to the notable improvements and modification in texture of TiO2 working electrode interface. Hence, it is concluded that the modified TiO2 NR can be considered as a competent candidate for sustainable energy conversion applications. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Chemical and Structural Changes of Ozonated Empty Fruit Bunch (EFB) in a Ribbon-Mixer Reactor Nurul Suhada Abdur Rasid; Amnani Shamjuddin; Nor Aishah Saidina Amin
Bulletin of Chemical Reaction Engineering & Catalysis 2021: BCREC Volume 16 Issue 2 Year 2021 (June 2021)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.16.2.10506.383-395

Abstract

Agricultural wastes especially empty fruit bunch (EFB) are abundantly available to be utilized as a feedstock for biochemical synthesis or biofuel production. The components of the waste include lignin, hemicellulose and cellulose. Cellulose, the polymer of glucose, is the active component for producing bio-based chemicals. However, it is difficult to isolate cellulose since lignin, the most outer layer in the waste is recalcitrant. Therefore, the agricultural wastes need to be pre-treated prior to downstream processing. The aim of this study was to investigate the effect of ozone pretreatment on lignin degradation and total reducing sugar (TRS) yield. EFB was pre-treated using ozone gas in a ribbon-mixer reactor. The chemical and structural changes of ozonated EFB were analysed. The highest delignification obtained were 95.7 wt.% and TRS yield was enhanced to 84.9% at a moisture content of 40 wt.% with 60 g/m3 ozone concentration within one hour of reaction time. Both NMR and FTIR spectra conferred major peaks inferring higher lignin degradation could be achieved using ozonolysis. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Highly Efficient Catalytic Oxidative Desulfurization of Dibenzothiophene using Layered Double Hydroxide Modified Polyoxometalate Catalyst Nur Ahmad; Muhammad Badaruddin; Nova Yuliasari; Fitri Suryani Arsyad; Aldes Lesbani
Bulletin of Chemical Reaction Engineering & Catalysis 2022: BCREC Volume 17 Issue 4 Year 2022 (December 2022)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.17.4.16373.821-830

Abstract

Layered double hydroxide-modified polyoxometalate (ZnAl-PW) was prepared and used for the oxidative desulfurization of dibenzothiophene. XRD patterns of ZnAl-LDH and PW are still present in ZnAl-PW. The bands of ZnAl-PW in wavenumber 3276, 1637, 1363, 1050, 952, 887, and 667 cm-1. The typical surface of ZnAl-LDH and ZnAl-PW can be observed not smooth in different sized with irregular shapes. The average diameter distribution of ZnAl-LDH and ZnAl-PW is 14 nm and 47 nm, respectively. For dibenzothiophene with 500 ppm, conversion on ZnAl-LDH, PW, and ZnAl-PW was 94.71%, 95.88%, and 99.16%, respectively. Conversion of dibenzothiophene in line with the acidity of ZnAl-LDH, PW, and ZnAl-PW were 0.399, 1.635, and 3.023 mmol/gram, respectively. The most effective catalyst dosage for the desulfurization of dibenzothiophene on ZnAl-LDH, PW, and ZnAl-PW is 0.25 g. The unchanged dibenzothiophene concentration indicates a heterogeneous system. ZnAl-LDH, PW, and ZnAl-PW are truly heterogeneous catalysts. After 3 cycles of oxidative desulfurization, the percentage conversion of dibenzothiophene on ZnAl-LDH, PW, and ZnAl-PW were 77.42 %, 65.98%, and 86.38%, respectively. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Selective Hydrogenation of Biomass-derived Furfural over Supported Ni3Sn2 Alloy: Role of Supports Rodiansono Rodiansono; Maria Dewi Astuti; Syahrul Khairi; Shogo Shimazu
Bulletin of Chemical Reaction Engineering & Catalysis 2016: BCREC Volume 11 Issue 1 Year 2016 (April 2016)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.11.1.393.1-9

Abstract

A highly active and selective hydrogenation of biomass-derived furfural into furfuryl alcohol was achieved using supported single phase Ni3Sn2 alloy catalysts. Various supports such as active carbon (AC), g-Al2O3, Al(OH)3, ZnO, TiO2, ZrO2, MgO, Li-TN, and SiO2 have been employed in order to understand the role of the support on the formation of Ni3Sn2 alloy phase and its catalytic performance. Supported Ni3Sn2 alloy catalysts were synthesised via a simple hydrothermal treatment of the mixture of aqueous solution of nickel chloride hexahydrate and ethanol solution of tin(II) chloride dihydrate in presence of ethylene glycol at 423 K for 24 h followed by H2 treatment at 673 K for 1.5 h, then characterised by using ICP-AES, XRD, H2- and N2-adsorption. XRD profiles of samples showed that the Ni3Sn2 alloy phases are readily formed during hydrothermal processes and become clearly observed at 2θ = 43-44o after H2 treatment. The presence of Ni3Sn2 alloy species that dispersed on the supports is believed to play a key role in highly active and selective hydrogenation of biomass-derived furfural towards furfuryl alcohol. Ni3Sn2 on TiO2 and ZnO supports exhibited much lower reaction temperature to achieved >99% yield of furfuryl alcohol product compared with other supports. The effects of loading amount of Ni-Sn, reaction conditions (temperature and time profile) on the activity and selectivity towards the desired product are systematically discussed. 
Synthesis and Evaluation of ABO3 Perovskites (A=La and B=Mn, Co) with Stoichiometric and Over-stoichiometric Ratios of B/A for Catalytic Oxidation of Trichloroethylene Razieh Alagheband; Sarah Maghsoodi; Amirhossein Shahbazi Kootenaei; Hassan Kianmanesh
Bulletin of Chemical Reaction Engineering & Catalysis 2018: BCREC Volume 13 Issue 1 Year 2018 (April 2018)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.13.1.1188.47-56

Abstract

In this contribution, perovskite catalysts (ABO3) were probed that site A and site B were occupied by lanthanum and transition metals of manganese or cobalt, respectively, with stoichiometric ratios as well as 20 % over-stoichiometric ratios of B/A. The perovskite samples were synthesized using a gel-combustion method and characterized by BET, XRD, SEM and O2-TPD analyses. After mounting in a fixed bed reactor, the catalysts were examined in atmospheric pressure conditions at different temperatures for oxidation of 1000 ppm trichloroethylene in the air. Evaluation of over-stoichiometric catalysts activity showed that the increased ratio of B/A in the catalysts compared to the stoichiometric one led to BET surface area, oxygen mobility, and consequently catalytic performance improvement. The lanthanum manganite perovskite with 20 % excess manganese yielded the best catalytic performance among the probed perovskites. 
Kinetics of Starch Degradation during Extrusion Cooking of Steady State Flow Konjac (Amorphophallus oncophyllus) Tuber Flour in a Single Screw Extruder Andri Cahyo Kumoro; Diah Susetyo Retnowati; Ratnawati Ratnawati
Bulletin of Chemical Reaction Engineering & Catalysis 2020: BCREC Volume 15 Issue 2 Year 2020 (August 2020)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.15.2.8125.591-602

Abstract

The presence of glucomannan in Konjac (Amorphophallus oncophyllus) tuber flour has promoted its various applications, especially in the food, drink, drug delivery and cosmetics. Starch is the main impurity of Konjac tuber flour. Although the common wet refining method may result in a high purity Konjac tuber flour, it is very tedious, time consuming and costly. This research aimed to study the kinetics of starch degradation in the extrusion cooking process of dry refining method to produce high quality Konjac tuber flour. In this research, Konjac tuber flour with 20% (w/w) moisture was extruded in a single screw extruder by varying screw speeds (50, 75, 100, 125, 150 and 175 rpm) and barrel temperatures (353, 373, 393, 413 and 433 K). The results showed that the starch extrusion cooking obeys the first reaction order. The reaction rate constant could be satisfactorily fitted by Arrhenius correlation with total activation energy of 6191 J.mol−1 and pre-exponential factor of 2.8728×10−1 s−1. Accordingly, thermal degradation was found to be the primary cause of starch degradation, which shared more than 99% of the energy used for starch degradation. Based on mass Biot number and Thiele modulus evaluations, chemical reaction was the controlling mechanism of the process. The results of this research offer potential application in Konjac tuber flour refining process to obtain high quality flour product. Copyright © 2020 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).  

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