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INDONESIA
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)
Published by Universitas Sriwijaya
ISSN : 25409395     EISSN : 25409409     DOI : -
Core Subject : Science, Social,
Biochemistry, Genetics & Molecular Biology Chemistry Environmental Science
Indonesian Journal of Fundamental and Applied Chemistry (IJFAC) is an international research journal and invites contributions of original research articles as well as review articles in several areas of chemistry. The journal aims to publish refereed, high-quality research papers with significant novelty and short communications in all branches of chemistry. Papers which describe novel theory and its application to practice are welcome, as are those which illustrate the transfer of techniques from other disciplines. IJFAC calls for papers that cover the following fields: Biochemistry Inorganic chemistry Physical chemistry Organic chemistry Analytical chemistry Applied Chemistry All papers are peer reviewed by at least two referees. Papers presented at conferences are peer reviewed and selected with the same standards as individually submitted papers. They therefore have the same archival value. Article should be submitted by the Online Submission Module at www.ijfac.unsri.ac.id or email to ijfac@unsri.ac.id
Arjuna Subject : -
Articles 196 Documents
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Study of Boron Complexation with Pyridoxine: Effect of Interaction Time, Temperature, and Amount of Pyridoxine Nurlisa Hidayati; Ariqah Fianti; Mita Arnela
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 8, No 2 (2023): June 2023
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v8.i2.76

Abstract

Borax is one of the compounds of boron (B), which is widely used as an anti-fungal, wood preservative, and antiseptic in cosmetics. Boron can form complexes with biomolecules such as pyridoxine, so it is interesting to know the interaction between borax and pyridoxine. This study seeks to investigate the complexation of boron, which is obtained from borax, with pyridoxine under various conditions of time, temperature, and the amount of pyridoxine. The resulting complex was characterized by UV-Vis spectrophotometry, Fourier Transform Infrared (FT-IR), and X-Ray diffraction (XRD). The study was initiated by optimizing the complexation of boron and pyridoxine. The maximum wavelengths of pyridoxine were found in the 205 nm and 292 nm regions, while the boron-pyridoxine complex was found in the 237 nm region. The obtained contact time, temperature, and amount of pyridoxine are 40 minutes, 60 °C, and 2 mL respectively. The results of the Fourier transform infrared (FT-IR) analysis of the boron-pyridoxine complex showed that there were OH groups, aromatic C=C groups, aliphatic C-C groups, B-H groups, and B-O groups. The results of the XRD analysis of the boron-pyridoxine complex obtained a diffraction angle of 30.93°.
Synthesis and Characterization of Cellulose Acetate from α-Cellulose of Paper Waste Ristika O Asriza; Nurhadini Nurhadini; Fardhan Arkan
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 8, No 2 (2023): June 2023
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v8.i2.82

Abstract

A cellulose derivative substance called cellulose acetate is frequently used in the manufacturing of photographic film, fiber, membranes, and bioplastics. However, the availability of sources for cellulose acetate's raw material does not support this demand. Paper waste has a high cellulose content. Therefore, the aim of this research is to synthesize cellulose acetate from α-cellulose waste paper. In order to separate alpha cellulose from waste paper in this study, the delignification process with NaOH solvent was used as a first step. After obtaining alpha cellulose, acetic anhydride was used to carry out the acetylation reaction. The yield of α-cellulose from paper waste is 51.8%. α-Cellulose is reacted with acetic anhydride through acetylation reactions and hydrolysis of acetyl groups. From this reaction, functional groups -OH, C=O ester, and C-O acetyl appeared from the FTIR spectra analysis which indicated that cellulose acetate had been successfully synthesized. The type of cellulose acetate produced is a type of cellulose monoacetate with an acetyl groups of 23% and a degree of substitution value of 1.17.
Antibacterial Activity of Triterpenoid from The Leaves of Tahi Ayam (Lantana camara Linn) Kartika MZ; Suryati Suryati; Mai Efdi
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 8, No 3 (2023): October 2023
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v8.i3.110

Abstract

Tahi Ayam (Lantana camara Linn) is known as the herbal plant to cure several diseases and has been used in folk medicine. The result of this study indicates that the isolated compound and the ethyl acetate fraction are components having antibacterial activity. The isolated compound from the ethyl acetate fraction from the leaves of the Lantana camara Linn plant is 9-hydroxy-Lantadene A. The compound includes the triterpenoid compound group, the molecular formula is C35H52O6, and another name is 22-angeloiloxy-9-hydroxy-3-oxo-olean-12-en-28-oat. The antibacterial activity of this compound was determined by looking at the inhibition zone of the test bacteria, namely Staphylococcus aureus as gram-positive and Escherichia coli as gram-negative. The treatment has been using the disc diffusion method and using amoxicillin as a control positive. The result of the antibacterial activity test revealed that both 9-hydroxy-Lantadene A and the ethyl acetate fraction exhibited antibacterial activity. Becouse there are inhibition zones around the discs at concentrations of 10 μg/disk and 5 μg/disk.
Development of a Concentration Cell Potentiometric Method for Fe2+ and Fe3+ Speciation Izzati Izzati; Suheryanto Suheryanto; Poedji Loekitowati Hariani
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 8, No 3 (2023): October 2023
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v8.i3.115

Abstract

The speciation of Fe2+ and Fe3+ iron ions using the concentration cell potentiometric method has been developed. The determination and speciation of metals that have been used include potentiometry using comparison electrodes, selective ion electrodes, and voltammetry. The concentration cell potentiometric method has the advantages of simple equipment, the use of common metal electrodes, high selectivity, and relatively low detection limits. The method validation results for Fe2+ and Fe3+ ion speciation were LOD: Fe2+ 0.22 mg/L Fe3+ 0.29, LOQ: Fe2+ 0,92 mg/L ; Fe3+ 0,01 mg/L, precision (1.17%; 1.2%) and accuracy (95.57%; 93.15%) based on CV Horwtz.  This method has been well applied for Fe2+ and Fe3+ speciation in natural water samples. The concentrations of Fe2+ and Fe3+ species in Sekanak river water were (1.88 mg/L; 2.07 mg/L). Concentration of Fe2+ and Fe3+ species in well water samples (0.5 mg/L; 1.32 mg/L).
Integration of Internet of Things (IoT) on Web-based Chemistry Learning Annisa Filantropie; Suheryanto Suheryanto; Poedji Loekitowati Hariani
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 8, No 3 (2023): October 2023
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v8.i3.120

Abstract

The development of science and technology, especially the development of the internet is very rapid today. The world of education, needs to develop learning innovations involving the internet. Internet of Things is one of the innovative technologies that can connect a device or object into a large data base so as to speed up the information process through the power of the internet network. The application of the Internet of Things in high school chemistry learning, especially in the concentration cell potentiometry method, can be used in practicum in school laboratories. The results showed that the combined method of concentration cell potentiometry integrated with the Internet of Things (Pot-IoT) has been proven effective (n-gain = 0.7208) to be used as a learning medium for the practicum of measuring Pb metal in water samples at school.
Adsorption and Photocatalytic Activity of Bentonite–Titanium Dioxide on The Degradation of Methylene Blue Dyes Muhammad Said; Niko Erlangga; Daniel Alfarado; Suheryanto Suheryanto; Elisa Nurnawati
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 8, No 3 (2023): October 2023
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v8.i3.126

Abstract

The aim of this research is to determine the effect of bentonite-Titanium dioxide (Benonite-TiO2) composite on the degradation process of methylene blue. It was carried out by synthesizing the composite through the impregnation of Titanium dioxide (TiO2) on bentonite and then characterizing the obtained compound using XRD and SEM-EDX. The results of the XRD characterization showed that there was a shift in the diffraction angle (2θ), which indicated the success of the impregnation procedure. The morphology of the composite showed that the bentonite surface had been filled with TiO2, as evidenced by the results of the EDX analysis, which showed a 7.03% increase in Titanium. Furthermore, the degradation process was carried out using various variables, including contact time, the ratio of composite weight to dye, and by irradiation with a UV lamp at a wavelength of 352 nm UV. It was discovered that the best degradation in the concentration of methylene blue occurred at a maximum contact time of 90 minutes and at a maximum weight of 10 mg of benonite-TiO2, with an effectiveness of 99.91% after irradiation and 92.26% without irradiation.
Chitosan-ZnO Composite for Removal of Methylene Blue Desnelli Desnelli; Leidya Yulinda; David Fernando; Fatma Fatma; Ady Mara
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 8, No 3 (2023): October 2023
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v8.i3.133

Abstract

This study aims to determine the effectiveness and increase in absorption of the chitosan-ZnO composite in the process of removing methylene blue when using the photodegradation method with the help of a UV lamp. Chitosan was synthesized from shrimp shell waste composite with metal oxide ZnO. The results of the characterization using XRD obtained the diffraction peak for chitosan at an angle of 2θ, namely 19.85°; 29.43°; 34.76° and chitosan-ZnO composite at an angle of 20.18°; 28.93°; 33.57° The SEM-EDX characterization shows that chitosan-ZnO has small, light-colored grains and more gaps and contains elements of chitosan and Zn. In the FTIR characterization, there was a decrease in intensity at a peak of around 3360 cm-1 which was caused by the chitosan-ZnO composite producing OH groups which reacted with methylene blue dye. In testing the effect of contact time using a UV lamp, there was an increase in the percentage of degraded methylene blue compared to without using a UV lamp. The maximum contact time is obtained at 60 minutes. While testing the effect of methylene blue dye concentration, the maximum absorption concentration was 45 ppm at 60 minutes of contact time. The adsorption capacity of the composite against methylene blue dye without UV light was 18.91 mg/g while using a UV lamp it increased to 20.145 mg/g. Based on this research, the chitosan/ZnO composite can be used quite well as a methylene blue dye remover.Keywords: Chitosan, Chitosan-ZnO, Photodegradation, Adsorption, Methylene blue.
Sweet flag (Acorus calamus L.) rhizomes chromatography column isolates potential as rich antioxidant compounds Amalia, Suci; Hasibuan, Lili Sunarti; Arianti, Ninit Arinda; Fasya, A Ghanaim; Dewi, Diana Chandra; Kadarani, Deva Krisna
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 9, No 2 (2024): June 2024
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v9.i2.66

Abstract

the unavailability of local materials in purposing of independently manufacturing pharmaceutical products. One of plants which can be used for raw materials in the biopharmaceuticals, sweet flag (Acorus calamus L.) that is rich in bioactive compounds such as flavonoids, alkaloids, phenolic compounds, tannins, steroids, saponins, glycosides and terpenoids. Flavonoids are the majority bioactive compounds in sweet flag rhizomes, which leads this study to isolate the flavonoids to identify as antioxidant agent for biopharmaceutical products development later. This study determined the antioxidant activity of sweet flag rhizomes as its crude extract, ethyl acetate fraction, and column isolate. Decreasing range of phytochemical compounds was remained only flavonoid that was in the column isolate.  Liquid chromatography Mass Spectrometry (LC-MS) in column isolates was identified isorhamnetin, quercetin, kaempferol, genistein, and glycitein. Additionally, this study aims the data that column isolate has the highest purity level with the least inhibitory concentration 50%  (IC50) and the strongest antioxidant activity.Keywords: Jeringau Rhizome, Acorus calamus, Column Isolate, Flavonoids, Antioxidants 
Integrated Process of Palm Oil Mill Effluent using Electrocoagulation, Active Carbon Filter, Zeolite and Membrane Separation Technology Alqorni, Kemas Uwais; Dahlan, Hatta; Arita, Susila
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 9, No 1 (2024): February 2024
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v9.i1.9

Abstract

Palm Oil Mill Effluent (POME) is a type of agro-industrial organic originating from the by-products of the processing of fresh fruit bunches (FFB) of oil palm. Palm oil waste pollution decreases environmental quality which will indirectly be harmful to the environment and human health. This research aims to treat palm oil liquid waste using electrocoagulation process, activated carbon filter, zeolite and membrane separation technology in an integrated manner. The combination of palm ash and zeolite was found to be the most effective in reducing pH, TSS, COD, BOD, and fatty oils. The electrocoagulation method best conditions are at a voltage of 15 Volts and an operating time of 90 minutes. The system of integration of the electrocoagulation process, activated carbon filters, zeolite and membrane separation technology has proven to be very effective for processing palm oil mill wastewater. The treatment results meet the quality standards based on Governor of South Sumatra Regulation No. 8 of 2012 concerning Liquid Waste Quality Standards for Industrial, Hotel, Hospital, Domestic and Coal Mining Activities and based on Government Regulation no. 22 of 2021 concerning Implementation and Management of the Environment (Annex 6 National Water Quality Standards) with average results: pH 7.02 TSS 44.6 mg/L, COD 24 mg/L, BOD 2.89 mg/L and fatty oils 1.2 mg/LKeywords: Palm Oil Mill Effluent, Electrocoagulation, Zeolite, UF Membrane, Fatty Oil
Production of CO Gas as Fuel Through The Utilization of CO2 Greenhouse Gas and Fine Coal Solid Waste Yazila, Syukran; Faisal, Muhammad; Bahrin, David; Novia, Novia; Said, Muhammad
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 9, No 2 (2024): June 2024
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v9.i2.117

Abstract

Utilization of Fine coal gasified with CO2 (Carbon dioxide) gas to produce CO (Carbon Monoxide) fuel is one effort to utilize coal waste and utilize CO2 greenhouse gas emissions. Testing was carried out at the Sriwijaya University Laboratory in Palembang with the aim of analyzing the production process of CO gas as fuel by utilizing the greenhouse gas CO2 through the gasification of fine coal solid waste and knowing and analyzing the influence of temperature, reaction time and CO2 gas debid on the Boundouard reaction on gas yields. CO and CO2. So we get the variable that produces the expected CO gas. The initial stage is to prepare 2.3 kg of fine coal and the grain size has been filtered to a size of <3mm or or mesh 8 – 18 then heated to a temperature of 500˚C with a time of 68 minutes 48 seconds for the carbonization process. Fine coal that has been carbonized is then reacted with CO2 gas in a heating furnace at variable temperatures of 300 ˚C, 400 ˚C, 450 ˚C and 500˚C and at a flow rate of 2.5 L/min, 5 L/min, 7.5 L/min, 10 L/min, 15 L/min. From 26 test samples, it shows that the best variable for producing CO gas is heating at a temperature of 500˚C with a CO2 reactor gas discharge of 5 L/min which can produce CO gas with a concentration of 208,586 ppm and CO2 gas is 357,703 ppm with CO & CO2 ratio is 0.583.

Page 15 of 20 | Total Record : 196

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