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Sintesis Nanokomposit Fe3O4/SiO2/TiO2 dengan Metode Sol-Gel Aisyiah Restutiningsih Putri Utami; Eko Sri Kunarti; M. Sulthon Nurharman Syah Putra
Jurnal Kimia Fullerene Vol 8 No 1 (2023): Fullerene Journal of Chemistry
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37033/fjc.v8i1.498

Abstract

The research was began with the synthesis of magnetite by reacting FeCl3.6H2O and FeSO4.7H2O by co-precipitation and sonication method. Then magnetite covered by silica was sintisized using sonication method by reacting TEOS with magnetit in base condition, and then coated by TiO2 using sol-gel method followed by calcination by using TTIP as a precusor. The X-Ray Diffractometer (XRD) were used to characterize the nanoparticles. The XRD defractofram showed the diffraction pattern 2ÆŸ (o) at 25.38o, 35.881o, 38o, 38,797o, 48.26o, 54.22o, 55,4o, 63.119o, and 69.24o that based on JCPDS data No. 21-1272 that showed TiO2 anatase stucture.
Chemicals Analysis of Drilled Ground Waters in Moa Island, Maluku, Indonesia Putra, M. Sulthon Nurharmansyah; Hermana, Nabila Swarna Puspa; Sumarno, Ari Pitoyo
Indonesian Journal of Chemical Studies Vol. 2 No. 2 (2023): Indones. J. Chem. Stud., December 2023
Publisher : Indonesian Scholar Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55749/ijcs.v2i2.36

Abstract

Moa Island is one of the remote Indonesian Islands that face the difficulty in accessing clean water, especially during the dry season. One way to get clean water is by drilling for groundwater. The drilled groundwater in Kaiwatu Village on Moa Island, Southwest Maluku Regency, Maluku Province, was analyzed for its content to obtain primary data. Primary data related to the quality of drilled groundwater sources includes chemical, physical, and microbiological parameters. The results of chemical parameters obtained from the test results were <0.01 mg/L fluoride, total chromium, nitrite, nitrate, iron, manganese, zinc, cyanide, lead, <0,001 mg/L cadmium, 17.9 mg/L hardness, sulfate 147.55 mg/L, pH 7.50, and organic substances 2.8 mg/L.  The physical parameter analysis showed a turbidity level of 3.71 NTU, a temperature of 26.8 °C, and a color of 5 TCU. The microbiological parameters obtained by the analysis were 0/100 mL. Primary data was then compared with secondary data, namely environmental health quality standards and air health requirements from Minister of Health Regulation No. 32 of 2017 for chemical and physical parameters, as well as water quality requirements and monitoring from Minister of Health Regulation 416/MENKES/IX/1990 for microbiological parameters. The analysis results using a comparison of primary and secondary data showed that all parameters contained in the primary data had values below the safe limits set by the requirements in the secondary data.
Comparative Analysis of FABA Waste Composition in Various Coal-Fired Power Plant Industries in Several Countries and Indonesia: A Review Putra, M. Sulthon Nurharmansyah; Prasojo, Agus Eko; Budiman, Anggito; Anty, Mentari Zikri; Hasnowo, Lutfi Aditya
Indonesian Journal of Chemical Studies Vol. 3 No. 2 (2024): Indones. J. Chem. Stud., December 2024
Publisher : Indonesian Scholar Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55749/ijcs.v3i2.58

Abstract

Fly Ash and Bottom Ash (FABA) is the waste from burning coal in coal-fired power plants and consists of chemical compounds, such as SiO₂, Al₂O₃, Fe₂O₃, and CaO. This waste poses an environmental challenge and an opportunity for the construction industry. This study conducted a comparative analysis of the composition of FABA from several coal-fired power plants in Indonesia and other countries, such as Thailand, China, Malaysia, France, Italy, and Portugal. In particular, this study assessed the XRF data from several other references. The XRF test data showed significant variations in the FABA content, influenced by coal type, combustion method, and emission management technology. The high SiO₂ content in the Cirebon and Teluk Sirih coal-fired power plants showed potential for pozzolanic applications. Meanwhile, the high Fe₂O₃ in Tanjung Enim and Sudimoro had the potential for metallurgical applications. In addition, the high CaO content of Teluk Sirih allowed its use in lime production and soil stabilization. However, high levels of SO₃, especially in Cirebon, required more attention in processing because of its impact on concrete quality and environmental pollution. With proper processing, FABA could be a valuable resource in various industries, reducing reliance on natural raw materials. This study highlighted the potential for the sustainable use of FABA and proposed management measures to address environmental challenges. The optimal use of FABA reduced negative environmental impacts and opened up significant economic opportunities, supporting the circular economy in the energy and construction sectors.
Enriching of society’s understanding of command-oriented leadership through an interactive virtual discussion Mirad Fahri; Elva Stiawan; Dita Ariyanti; Rahmat Basuki; Yusuf Bramastya Apriliyanto; Anggi Khairina Hanum Hasibuan; Tedi Kurniadi; M. Sulthon Nurharmansyah Putra; Dewi Septaningsih; Sekar Ilma Tiarani; Ersha Mayori; Regita Andriani Wiana; Amalia Yunita; Naufan Nurrosyid; Agus Eko Prasojo; Riyanti Putri
Journal of Community Service and Empowerment Vol. 5 No. 2 (2024): August
Publisher : Universitas Muhammadiyah Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22219/jcse.v5i2.27961

Abstract

In the post-pandemic era, many interactive activities have been flexibly generated through virtual conditions. Accordingly, some problems could appear in terms of leadership, such as difficulties in maintaining the audience’s attention during the event. Thus, the utilization of a command-based leadership style that could straightforwardly maintain audience focus ought to be considered to be adopted. However, both the command-based leadership style and its prospective aspects have not been widely understood by society. This community service aims to deliver a proper understanding of the command-based leadership style through interactive virtual discussion between experts in teaching activities of defense-based science and society consisting of Indonesian teachers, high school students as well as academics. Statistical results of pre-test and post-test scores showed enhancement of the participants’ understanding of command-based leadership. Hopefully, some relevant aspects of their new perspective of command-based leadership can be properly adopted and effectively implemented to answer current challenges, such as in terms of managing people in virtual conditions. 
Magnetik spinel ferit: Doping Ni₁₋ₓMnₓFe₂O₄ sebagai radar absrorbing material Yolanda Ferliana Putri; Sulthon Nurharmansyah Putra; Gabriel Radika Prabowo
Papanda Journal of Mathematics and Science Research Vol. 5 No. 1 (2026): Volume 5 Nomor 1 Maret 2026
Publisher : Papanda Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.56916/pjmsr.v5i1.3713

Abstract

This study investigates the synthesis and characterization of radar absorbing material (RAM) of spinel ferrite based (Ni₁₋ₓMnₓFe₂O) has been performed by hydrothermal method using Mn(NO₃)₂·4H₂O, Fe(NO₃)₃·9H₂O, Ni(NO₃)₂·6H₂O, and CTAB as a precursor. The effect of Mn doping on the structural, optical, and magnetic properties was examined by varying the Mn concentration (x=0-1). X-Ray Diffraction (XRD) analysis confirmed a single-phase cubic spinel structure for all samples, with a shift in diffraction peak observed as the Mn concentration increased, attributable to the difference in ionic radii between Ni2+ and Mn2+. The band gap value decreased with increasing Mn doping, which enhanced electron hopping within the lattice and consequently contributed to the observed dielectric loss. Magnetization tests indicated an increase in magnetization at low doping levels (3 wt%), which strengthened the magnetic loss mechanism, while excessive doping led to a reduction in ferrimagnetic properties, approaching paramagnetic behavior. FESEM revealed agglomerated nanoparticles with sizes ranging form 11–27 nm, this nanoscale dimension is advantageous as it increase the specific surface area for enhanced  interaction with electromagnetic waves. Conclusion, Mn doping successfully enhanced the performance of NiFe₂O₄ system as a candidate for new radar-absorbing materials, with the optimum composition achieved at low doping levels. In practical terms, this material can be applied as a lightweight coating in stealth aircraft technology or as electromagnetic interference (EMI) shielding in modern telecommunications devices.
Synthesis and Characterization of SnO and SnO₂ Catalysts for Biodiesel from Crude Palm Oil via Interesterification Amadea Kenyoning Hapsari Subiakto; M. Sulthon Nurharmansyah Putra; Dewi Anggraini Septaningsih; Hanifa Setya Ningrum; Fikriyah Hamidah; Ardine Kusuma Nismarawati; Zaidan Al Fajri; Maura Agnes Erwinda
Indonesian Journal of Chemical Studies Vol. 5 No. 1 (2026): Indones. J. Chem. Stud. June 2026
Publisher : Indonesian Scholar Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55749/ijcs.v5i1.98

Abstract

This study reports the synthesis and characterization of SnO and SnO₂ catalysts for biodiesel production from crude palm oil (CPO) via interesterification. SnO was synthesized using the hydrothermal method, while SnO₂ was prepared through the sol–gel route. The catalysts were applied in the interesterification of refined bleached palm oil with methyl acetate at an oil : methyl acetate molar ratio of 1:9, catalyst loading of 0.25 wt%, reaction temperature of 65 °C, and reaction time of 3 h. X-ray diffraction (XRD) analysis confirmed the formation of tetragonal SnO and rutile tetragonal SnO₂ phases. Biodiesel quality was evaluated according to SNI 7182:2015 parameters. Biodiesel produced using SnO showed density of 861 kg/m³, viscosity of 3.09 cSt, water content of 0.25%, free fatty acid (FFA) of 0.66%, and iodine value of 44.04. Meanwhile, SnO₂-catalyzed biodiesel exhibited density of 886 kg/m³, viscosity of 3.12 cSt, water content of 0.22%, FFA of 0.56%, and iodine value of 36.03. GC–MS analysis identified methyl oleate as the dominant compound in SnO-catalyzed biodiesel, while methyl palmitate was dominant in SnO₂-catalyzed biodiesel. These results indicate that both catalysts have potential as alternative heterogeneous catalysts for biodiesel production from palm oil via interesterification.
Alkali Activation of Coal Fly Ash: Characterization and Potential for Oil Remediation Ayu Fahimah Diniyah Wathi; Aisyiah Restutiningsih Putri Utami; Teguh Pambudi; Meiyanti Ratna Kumalasari; M. Sulthon Nurharman Syah Putra; Sri Setyaningsih; Dola Suciana
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 11, No 2 (2026): June 2026
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v11.i2.146

Abstract

Fly ash, a byproduct of coal combustion, has attracted increasing attention as a low-cost adsorbent for environmental remediation. This study aims to investigate the effect of alkali activation on the structural and surface characteristics of fly ash and to evaluate its potential for oil remediation. In this work, fly ash was activated using sodium hydroxide (NaOH) followed by thermal treatment at 250 C. The structural and surface properties of the materials before and after activation were characterized using Fourier Transform Infrared spectroscopy (FTIR), X-ray Diffraction (XRD), and Brunauer–Emmett–Teller (BET) surface area analysis. FTIR analysis indicated changes in the surface functional groups of fly ash after alkali activation, while hydrocarbon-related bands observed after contact with used oil suggested the presence of oil-derived compounds on the adsorbent surface. XRD results showed that the activated fly ash retained a predominantly amorphous phase with slight changes in crystallinity. BET analysis revealed only a slight increase in specific surface area from 22.71 to 23.53 m2g-1, accompanied by a small increase in average pore diameter from 5.49 to 5.77 nm, indicating limited modification of the mesoporous structure after alkali activation. These structural modifications suggest that alkali activation alters the surface characteristics of fly ash and may support its potential use in oil remediation. The findings indicate that alkali-activated fly ash has potential as an economical and sustainable adsorbent for environmental remediation applications, particularly for the treatment of oil-contaminated waste.Keywords: alkaline activation, adsorbent, BET, FTIR, XRD
Penerapan Teknologi Instalasi Pengelolaan Air Limbah di Muara Angke dan Analisis Pasca Pengoperasian M. Sulthon Nurharmansyah Putra; Tedi Kurniadi; Mitro Prihantoro; Gunaryo; Dea Dwi Ananda; Latisa Stefi Alivia; Arya Rafif Rabbani; Gabriel Prabowo
Babakti: Journal of Community Engangement Vol 3 No 1 (2026): April
Publisher : Fakultas Teknik, Universitas Singaperbangsa Karawang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35706/babakti.v3i1.13199

Abstract

Permasalahan sanitasi lingkungan di kawasan pesisir Muara Angke, Jakarta Utara, khususnya terkait pengelolaan air limbah domestik yang dibuang langsung ke badan air tampa pengolahan, telah menyebabkan penurunan kualitas air serta meningkatkan resiko penyakit bebasis lingkungan. Kegiatan pengabdian masyarakat ini bertujuan untuk menerapkan teknologi Instalasi Pengolahan Air Limbah (IPAL), serta melakukan analisis pasca pengoprasian guna mengevaluasi kinerja dan efektivitas sistem yang telah dibangun. Metode yang digunakan survei awal, perancangan IPAL dan untuk mengetahui kondisi pengelolaan sarana tersebut dilakukan dengan metode pendekatan deskriptif kualitatif yakni dengan mendeskripsikan kondisi pengelolaan sarana sanitasi berdasarkan hasil kuisioner masyarakat yang terkena dampak IPAL Muara Angke. Tingkat kepuasan meliputi pengetahuan, kebermanfaatan, hasil kualitas air, dampak, dan penerapan IPAL. Hasil pengabdian ditunjukkan dengan teknologi IPAL yang telah terpasang di Muara Angke dan hasil analisis menunjukkan bahwa tipologi pengelolaan IPAL adalah : Aspek hasil pengelolaan air yang berada pada posisi pertama dengan nilai 95%, aspek kebermanfaatan dan dampak positif yang pada posisi kedua dengan nilai 90%, aspek pengetahuan dan kemudahan penerapan yang berada pada posisi terakhir dengan nilai 87,5%. Berdasarkan data yang diperoleh didapatkan hasil yang baik mengenai tingkat kepuasan masyarakat terhadap IPAL. Kegiatan ini diharapkan menjadi model replikasi pengelolan air limbah di wilayah pesisir perkotaan.
Hubungan Antara Beban Kerja dan Kelelahan Kerja dengan Kejadian Stres Akibat Kerja pada Pengrajin Kayu di Dusun Rejosari, Desa Jatimulyo, Kabupaten Bantul, Yogyakarta Imaniar Intan Harmawati; M. Sulthon Nurharmansyah Putra
PubHealth Jurnal Kesehatan Masyarakat Vol. 5 No. 1 (2026): Edisi Juli
Publisher : Ilmu Bersama Center

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.56211/pubhealth.v5i1.1648

Abstract

Stres kerja merupakan kondisi yang muncul dari interaksi antara manusia dan pekerjaannya serta dikarakteristikkan oleh perubahan manusia yang memaksa mereka untuk menyimpang dari fungsi normal mereka. Stres merupakan respon tubuh yang sifatnya non spesifik terhadap setiap tuntutan beban atasnya, penyebab dari stres kerja salah satunya yaitu karena kelelahan kerja dan beban kerja. Kelelahan kerja banyak dirasakan di akhir kerja terutama bagi pengrajin kayu yang sedang banyak pesanan di mana pekerja harus kerja lembur sampai pekerjaan tersebut selesai. Beban kerja yang terkadang tinggi dan terkadang rendah juga dapat menyebabkan kelelahan kerja dan berujung pada stres kerja.  Tujuan dari penelitian ini untuk mengetahui apakah ada hubungan antara beban kerja dan kelelahan kerja dengan kejadian stres akibat kerja pada pengrajin kayu di Dusun Rejosari, Desa Jatimulyo, Kabupaten Bantul, Yogyakarta. Penelitian ini merupakan penelitian analitik, dengan cross sectional sebagai rancangan sampelnya. Sampel dalam penelitian ini adalah pengrajin kayu di Desa Jatimulyo, Kecamatan Dlingo, Kabupaten Bantul, Provinsi Yogyakarta yaitu sebanyak 100 orang. Instrumen yang digunakan untuk mengetahui beban kerja menggunakan stopwatch dengan metode palpasi, yaitu mengukur denyut nadi responden per menit, sedangkan pengukuran terkait perasaan kelelahan kerja menggunakan metode subjective self rating test, dan untuk mengetahui permasalahan terkait stres kerja menggunakan kuesioner industrial fatigue research Committee (IFRC). Data dianalisis dengan menggunakan uji chi square. Berdasarkan hasil analisis data menunjukkan bahwa tidak ada hubungan antara beban kerja dengan kejadian stres akibat kerja karena P value: 0,338>0,05 dengan OR = 1,52, dan tidak ada hubungan antara kelelahan kerja dengan kejadian stres akibat kerja karena P value: 0,872>0,05 dengan OR = 0,92. Dari hasil tersebut dapat disimpulkan bahwa tidak ada hubungan antara beban kerja dan kelelahan kerja dengan kejadian stres akibat kerja di Desa Jatimulyo, Kecamatan Dlingo, Kabupaten Bantul, Provinsi Yogyakarta.
Peningkatan Pengetahuan Petani tentang Ketahanan Pangan dan Paparan Bahan Kimia Pertanian di Desa Cimuncang, Sumedang Yosephine Liliana Intan Danar Saputri; Gunaryo Gunaryo; Minandre Wiratama; Fitria Rahma Dewi; Riana Zevanisa Arsyi; Sari Purbaya; Mentari Zikri Anty; Rahmat Basuki; Azimatur Rahmi; Anggi Khairina Hanum Hasibuan; Yusuf Bramastya Apriliyanto; Tedi Kurniadi; M. Sulthon Nurharmansyah Putra; Dewi Anggraini Septianingsih; Rudi Hartono; Nurwanto Nurwanto; Mirad Fahri
Jurnal SOLMA Vol. 15 No. 2 (2026)
Publisher : Universitas Muhammadiyah Prof. DR. Hamka (UHAMKA Press)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22236/solma.v15i2.21122

Abstract

Background: Ketahanan pangan dan keamanan bahan kimia merupakan aspek penting dalam pertanian berkelanjutan. Petani di Desa Cimuncang, Kabupaten Sumedang, masih memiliki pemahaman yang terbatas mengenai risiko penggunaan pupuk dan pestisida kimia serta alternatif ramah lingkungan. Kegiatan pengabdian kepada masyarakat ini bertujuan untuk meningkatkan wawasan dan pengetahuan petani mengenai ketahanan pangan, risiko paparan bahan kimia pertanian, dan alternatif pupuk organik berbasis senyawa humat di Desa Cimuncang. Metode: Sebanyak 40 petani mengikuti rangkaian kegiatan yang terdiri atas pre-test, penyuluhan, diskusi interaktif, dan post-test. Data dianalisis menggunakan uji t berpasangan untuk menilai perubahan pengetahuan peserta. Hasil: Peningkatan rata-rata skor dari 37% pada pre-test menjadi 82% pada post-test, dengan perbedaan yang bermakna secara statistik (p < 0,001) dan nilai effect size yang sangat besar (Cohen’s d = 4,51). Kegiatan penyuluhan efektif dalam meningkatkan pengetahuan dan kesadaran awal petani mengenai praktik pertanian yang lebih aman dan berkelanjutan. Kesimpulan: Kegiatan ini berhasil meningkatkan pengetahuan dan kesadaran petani terhadap pertanian ramah lingkungan. Kegiatan lanjutan berupa pendampingan lapangan diperlukan untuk memastikan penerapan pengetahuan tersebut dalam praktik pertanian sehari-hari