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Pembuatan Biodiesel Dari Minyak Kapuk Menggunakan Katalis Lempung : Studi Regenerasi Katalis Dalam Proses Produksi Genardus Oktavri Sijabat; Syaiful Bahri; Edy Saputra
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 4, No 2 (2017): Wisuda Oktober Tahun 2017
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Petroleum oil still serves as a primary source of energy and national fuel. Oil reserves in Indonesia are depleting so substitution of fuel that derived from petroleum have to be sought. Recent years, a lot of research has done, whose purpose to find a fuel that can be an alternative source one of that is biodiesel. Raw material for making biodiesel can be from animal fat or vegetable oil. One type of vegetable oil that can be used as a raw material source of energy is kapok wood. This research is aimed to make biodiesel from cotton oil, to study factors which influences production, such as acid-based activated catalyst, the regeneration catalyst, and to determine the physical and chemical properties of biodiesel. The transesterification process was done on a mole ratio of oil: methanol 1: 9, oil mass 50 grams, the weight of the catalyst 1%-wt, temperature of 60°C during 90 minutes, the activation of clay catalysts are in acids and bases, and then recycle and regeneration of catalyst. This study given the biodiesel result having the largest yield of alkaline activation of the catalyst as much as 93.1%. Characterization of physical properties of biodiesel have a density 871 kg/m3, kinematic viscosity 3.5 mm2/s, acid number 0.37 mg KOH/g sample, and the flash point 210oC respectively. The catalyst regeneration cannot restore 100% reactivity of catalyst.Keywords: biodiesel, clay, recycle, regeneration, transesterification
Pemanfaatan Geopolimer Dari Kaolin Sebagai Adsorben Untuk Mengolah Air Gambut Imelda Dewi Agusti; Edy Saputra; Lita Darmayanti
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 1 (2015): Wisuda Februari Tahun 2015
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Basicly peat water is belong to surface water which is found in the wet land, like Riau Province. The characteristic of peat water are high color intensites (yellow or brown red), high organic content and low pH values about 2-5. For use as water source for domestic purposes, it was a process to change peat water toward clean water. One of the process was adsorption way. In this research is required by kaolin based geopolymers as adsorbent.The variable that used in this research is the mass of the adsorbent (1; 1,5; 2; and 2,5 gram, and stirring (time between 30,60 and 90 seconds) then tested of organic content. The best result from this research is that the adsorbent mass of 1 gram and the stirring time of 30s while adsorbent can increase from 51,192 mg/l to 0,63 mg/l on organics content. The results of this research indicated that the peat water treatment in accordance with the Decree of the Minister of the Health No. 416 Year 1990 and could be use kaolin based geopolymer as an alternative to peat water treatment .Keyword : Kaolin, Geopolymer, Adsorption, Peat Water
Degradasi Zat Warna Methylene Blue Dengan Metode Fotofenton Menggunakan Katalis nano-Fe0@CS Rahman Fikri; Panca Setia Utama; Edy Saputra
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 8 (2021): Edisi 1 Januari s/d Juni 2021
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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In this study, nano-Fe0@CS were synthesized by hydrothermal method. Studied Methylene Blue (MB) degradation process and find the best composition of the degradation process. Catalytic performance of nano-Fe0@CS was tested in Phenton process for MB degradation in aqueous solution with H2O2 3%, and MB concentration variant. The best process conditions was observed by 99.99% removal of 30 ppm MB within 90 min with added 0.3 g/l nano-Fe0@CS and 2 ml H2O2 3% in 250 ml solution.Keywords: Degradation, Methylene Blue, nano-Fe0@CS, Phenton Process
Pembuatan Biodiesel Dari Minyak Biji Kapuk (Ceiba Pentandra) Dengan Katalis Lempung Teraktivasi, Pengaruh Rasio Molar : Metanol Nova Dwi Safitir; Syaiful Bahri; Edy Saputra
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 4, No 2 (2017): Wisuda Oktober Tahun 2017
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Biodiesel is a renewable alternative fuel that can be made from vegetable oils. One was from the kapok seed oil by using an activated clay catalyst. The purpose of this study is to determine the characteristics of the clay catalysts for the synthesis of biodiesel, making biodiesel from kapok seed oil, determine the effect of the molar ratio of oil-methanol to yield biodiesel, and determines the physical properties and chemical properties of biodiesel produced. Activated clay as acids and bases using H2SO4 and NaOH. Biodiesel is made by reacting kapok seed oil and methanol at 60°C, the reaction time of 1.5 hours, and a catalyst concentration of 0.5% w/w. Treatment variations molar ratio of reactants affect the yield of biodiesel, as well as variations in the concentration of acids and bases for the activation of the catalyst on the clay affect the yield of biodiesel. The result of physical charactearization density 884 kg/m3, viscosity 3.28 mm2/s, acid number of 0.49 mg-KOH/g biodiesel and flash point 200°C meet the SNI standards (SNI 7182-2015).Keywords: activation, biodiesel, clay, molar ratio, yield
Pembuatan Biodiesel Dari Minyak Nyamplung (Calophyllum Inophyllum) Menggunakan Katalis Basa Heterogen Naca-Geopolimer Mustapa Ardi; Zuchra Helwani; Edy Saputra
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 6 (2019): Edisi 1 Januari s/d Juni 2019
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

Biodiesel is a product of transesterification reaction fat/oil and methanol with the aid of catalyst. Catalysts is commonly used in the production of biodiesel is strong base catalysts such as NaOH and KOH which is difficult to separate from the product of the reaction because it has the same phase as the reactant. Therefore, it is necessary to develop catalyst technology in order to get the production process becomes more economical, applicable and environmentally friendly, one of the catalyst is geopolymer. Geopolymers are synthesized by reacting sodium silicate, metakaolin, and bottom ash. Geopolymers is used in transesterification reaction. The process variables are weight of oil 50 grams, stirring rate 400 rpm, reaction time 120 minutes, and temperature of 65 oC, with catalyst 2% (w/w) and mole ratio of methanol:oil 1:12. The yield of biodiesel 88.04% with density 875 kg/m3, viscosity 4.27 mm2/s, the acid number of 0.29 mg-KOH/g biodiesel, the flash point 140 °C and alkyl ester level of 99,91% comply with the SNI standards (SNI 7182: 2015). Keywords: biodiesel, calophyllum inophyllum oil, geopolymer, transesterification, yield
Adsorpsi Zat Warna Methylene Blue Menggunakan Spent Bleaching Earth Sebagai Adsorben Tejo Yulandi; Edy Saputra; Syarfi Daud
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 3, No 2 (2016): Wisuda Oktober Tahun 2016
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The industrial waste especiallytextile waste is one of the causes of environmental problems that require effective and efficient processing. Adsorption is a separation method that is simple, easy to operate, flexible, affordable cost and does not produce toxic products. The purpose of this study calculates the efficiency of decreasing the concentration of the colors contained in metyhlene blue dye and studying the adsorption capacity to variations in pH, adsorbent mass and stirring time. The maximum wavelength of the dye methylene blue 660 nm. The efficiency of 99.973 % decline in the highest concentration. Isotherm corresponding to methylene blue dye adsorption by spent bleaching earth is Langmuir isotherm with adsorption capacity to variations in pH of 0.5035 mg/g, the adsorbent mass variation of 0.3816 mg/g, the stirring time variation of 0.5012 mg/g.Keywords : Adsorption, Methylene Blue, Spent Bleaching Earth, EfficiencyDecreased Concentration, Adsorption Capacity
Pembuatan Biodiesel Dari Minyak Biji Kapuk (Ceiba Pentandra) Dengan Katalis Lempung Teraktivasi; Pengaruh Konsentrasi Katalis Dan Aktivasi Katalis Nurhasanah Nurhasanah; Syaiful Bahri; Edy Saputra
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 4, No 2 (2017): Wisuda Oktober Tahun 2017
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Biodiesel is a methyl ester transesterification reaction products of triglycerides derived from vegetable oils or animal fats. One among of vegetable oils that can produce biodiesel is kapok seed oil. Kapok seed oil had higher levels of unsaturated fatty acids are high that they could be made to produce biodiesel. This research is aim to make biodiesel from kapok seed oil, studying the effect of concentration of activated clay catalyst to the amount of biodiesel produced, determine the characteristics of biodiesel from kapok seed oil and determine the best catalyst activation of the activation of acid or base. The transesterification process occured at a temperature of 60oC, the weight of oil 50 grams, the reaction time 1,5 hours, mole ratio of oil to methanol 1 : 9, variation of the catalyst concentration 0,1%, 0,5%, and 1%-weight of oil, and variations of acid solution (0,47%, 0,62%, dan 0,78%) and alkaline solution (0,33%, 0,44%, 0,66%) for activation of catalyst. From the result is obtained the highest biodiesel of 1% catalyst concentration of acid activation 0,78%, methanol mole ratio of 1: 9 for 1,5 hours as much as to 92,62 %. Characterization of physical properties of biodiesel is density of 871 kg/m3, 3,11 mm2/s kinematic viscosity, acid number 0.36 mg KOH / g sample, and the flash point 200oC respectivity.Keywords: biodiesel, catalysts, clay, activation of acids, activation of bases, transesterification
Transesterifikasi Minyak Sawit Off-Grade Menjadi Biodiesel Menggunakan Katalis CaO Yang Diimpregnasi Dengan Limbah Serbuk Besi Muhammad Rahman; Zuchra Helwani; Edy Saputra
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 3, No 1 (2016): Wisuda Februari Tahun 2016
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Off-grade oil is a raw material for biodiesel that has ALB levels> 2% so that the production of biodiesel made by two stage reaction, the esterification and transesterification. In general, biodiesel is produced using homogeneous catalysts. Homogeneous catalysts can be replaced by a heterogeneous catalyst. CaO catalyst has a high alkalinity but has shortcomings in the process of separation of the reaction products. Waste iron powder can be used as a support and to provide a catalyst Ca2Fe2O5 metal forming properties. This study aims to create a catalyst that has a high alkalinity and metallic, and study the performance of the catalyst in the transesterification reaction of palm oil off-grade. Esterification process were reacted at 60°C with a mole ratio of oil: methanol of 1:12 and 1% H2SO4 catalyst -b. The esterification reaction can reduce levels of ALB from 12.47% to 0.36%. Transesterification is done by varying the mole ratio of oil: methanol in a row is 1: 6, 1: 8 and 1:10, the amount of catalyst modification 1% -b, -b 2%, 3% -b, a reaction temperature of 50°C, 60°C, 70°C, and the reaction time 2 hours. Processing data using Response Surface Area (RSM), the amount of attack using Central Composite Design (CCD). The resulting yield ranging from 23.19% to 52.34%. The highest yield obtained at 70°C with a mole ratio of oil: methanol of 1:10 and the amount of catalyst Ca2Fe2O5 1%-b. Biodiesel characteristics such as density, kinematic viscosity, acid number and flash point are in accordance with the standards of Indonesian biodiesel. The most significant process conditions to yield biodiesel is the ratio of the mole ratio of oil: methanol and the amount of catalyst.Keywords : Biodiesel, Catalyst, Off-grade Palm Oi, Transesterification, Wasted Iron
Pengolahan Limbah Tekstil Artifisial (Zat Warna Reaktif) Dengan Proses Oksidasi Katalitik Menggunakan Nano-Mn/Carbon Sphere Sri Meilani; Edy Saputra; Chairul Chairul
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 4, No 1 (2017): Wisuda Februari Tahun 2017
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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The latest innovations in the processing of textile waste is using advanced oxidation processes (AOPs) by oxidant capable of generating a radical sulphate (SO4*). The purpose of this research is to determine catalyst activity of Nano-Mn/CS in oxidation process, reduce the dye on using peroxymonosulfate and Nano-Mn/CS, and determine the optimum conditions for reducing the dye in water. Catalytic synthesis process carried out by the hydrothermal process at temperature of 180o C for 18 hours in an autoclave to produce black carbon from D-glucose solution and then it will be impregnated with a variation of 3% and 5% Mn. Then it calcined with N2 at temperature of 500o C for 4 hours. The optimum condition for degradation of methylene blue (artificial wastes) 25 ppm carried out for 120 minutes with 0,2 gr/L catalysts Nano-Mn/CS and 4 gr/L oxone with efficiency of 91.07%.Keywords: AOPs, Methylene blue, Nano-Mn/CS, Peroxymonosulfate
Degradasi Zat Warna Tekstil (Rhodamin B) Dengan Teknologi Aop (Advanced Oxidation Process) Metode Fotokatalitik Menggunakan Katalis Nanokomposit Znfe2o4/SBE Affananda Taufik; Zultiniar Zultiniar; Edy Saputra
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5 (2018): Edisi 2 Juli s/d Desember 2018
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Dyestuffs which the result of the textile industry are non-biodegradable organic compounds, can cause environmental pollution especially the aquatic environment. One alternative to processing textile waste is to use the photocatalytic. Photocatalytic is a process of combination of catalyst and light. This study aims to synthesize ZnFe2O4 / SBE catalysts with microwave methods and characterization, study the influence of process conditions in degradation and determine the best process conditions in dye degradation. Nanocomposites from ZnFe2O4 / SBE have been successfully synthesized using the microwave method. The catalyst synthesis process is carried out by microwave for 20 minutes and followed by calcination at 500oC for 5 hours. Photocatalytic degradation lasted 120 minutes, stirring speed 350 rpm and volume of 250 ml solution. The variation of ZnFe2O4 / SBE concentration was 1.5 g / L, 1 g / L, 0.5 g / L and 0.25 g / L and the showed the maximum results from the best photocatalytic process obtained from variations in the catalyst concentration of 1.5 g / LKeywords: photocatalytic, rhodamine b, znfe2o4/sbe
Co-Authors Abdullah Syafi’i Ade Anggriawan Affananda Taufik Agustinus Lamhot Viraro Ahmad Fadli Ahmad Zaki Al Qarni Putra Aldi Okta Priyatna Amin Fitra Amir Awaluddin Andes Sagita Arbhy Indera Ikhwansyah Arif Kurnia Arosyidin Arosyidin Bahruddin Chairul Chairul Charismayani Charismayani David Andrio Delvi Yolanda Denny Elisabet Situmeang Desly Fadilla Simbolon Eka Putri Sriandriani Eka Trisnawati Ekadian Lestari Simatupang Ekky Wahyudi Enang Vovilya Eri Kaiyul Erlisa Yanuari Putri Evelyn Evelyn Farhiz Lagan Febrian Adhitya Fenny Lasma Hilde S Fitriani Fitriani Fitry Rahmah Ganis Kharisma Wiranti Genardus Oktavri Sijabat Gusti Ayu Nurjanah Hade Karimata Hafizah Hasrul Hasrul Heru Kristianto Hery Fiza Simarmata Ilok Dianggoni Imelda Dewi Agusti Inget Yester Yunanda Irdoni Irdoni Ismeddyanto, Ismeddiyanto Ismi Siska Rahmayani Jhon Armedi Pinem Jhon Fery Marihot Tua S Kartika Pratama Syafitri Khairat Khairat Kiki Farida Ferine Komalasari Komalasari Lita Darmayanti Lora Mona Tambunan M Arief Riandy M. Isa Indrawan M. Wahyu Nugraha Magfirah Marihot Danield Vyendri Simatupang Miguel Felix Wijaya Mohd Fajri Amrullah Monita Olivia Moses O. Tadé Muhammad Rahman Mustapa Ardi Nani Agustina Nazily Haryati Niko Rizaldi Nissa Aqhilla Nova Dwi Safitir Novi Purnama Nuraina Siregar Nurhasanah Nurhasanah Nurlis Nurlis Nurul Afifah Peji Nopeles Rahman Fikri Redol Sianturi Reno Susanto Rianti Ratna Dewi Rio Akbar Rio Saputra Rizaldi Riski Irawan Rozanna Sri Irianty Shaobin Wang Shaobin Wang Sitanggang, Ronal Rius Solly Aryza Sri Meilani Sri Ulina Beru Ginting Subangkit Julio Jaya SYAIFUL BAHRI Syaiful Bahri Syaifullah Muhammad Syaifullah Muhammad Syarfi Daud Syarfi Syarfi Syelvia Putri Utami Tarsensius Wabady Happy Limbong Tejo Yulandi Tresia Monika Natalia Sinaga Trisuciati Syahwardini Utama, Panca Setia Viqrie Wahyudi Wahyu Muhammad Firdaus Wahyuni Zumara Wali Ara Widya Yoesepha Windy Nila Hakim Yelmida Azis Yudhi Salman Dwi Satya Yuliati Eka Putri Yunita Selonika Zuchra Helwani Zultiniar Zultiniar