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All Journal VALENSI International Journal of Renewable Energy Development JURNAL KIMIA SAINS DAN APLIKASI Jurnal Sains Materi Indonesia Bulletin of Chemical Reaction Engineering & Catalysis Journal of Engineering and Technological Sciences EduChemia: Jurnal Kimia dan Pendidikan Chimica et Natura Acta Indonesian Journal of Chemistry Chemistry Indonesian Journal of Chemical Research Jurnal Kartika Kimia EKOLOGIA : Jurnal Ilmiah Ilmu Dasar dan Lingkungan Hidup Jurnal Teknologi dan Manajemen Makara Journal of Science Molekul: Jurnal Ilmiah Kimia Environmental and Materials International Journal of Renewable Energy Development Bulletin of Chemical Reaction Engineering & Catalysis
Jarnuzi Gunlazuardi
Department Of Chemistry, Faculty Of Mathematics And Natural Sciences, University Of Indonesia, Depok 16424, West Java
Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Computer Science & IT Control & Systems Engineering Decision Sciences, Operations Research & Management Earth & Planetary Sciences Economics, Econometrics & Finance Education Electrical & Electronics Engineering Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Mathematics Physics

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Photocatalytic Degradation of Commercial Diazinon Pesticide Using C,N-codoped TiO2 as Photocatalyst Khoiriah Khoiriah; Diana Vanda Wellia; Jarnuzi Gunlazuardi; Safni Safni
Indonesian Journal of Chemistry Vol 20, No 3 (2020)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (340.666 KB) | DOI: 10.22146/ijc.43982

Abstract

Diazinon (C12H21N2O3PS) is an effective pest controller that has been frequently used by farmers in agriculture. It is a nonspecific and highly toxic pesticide having low persistence in the environment and categorized as moderately hazardous class II. The degradation of commercial diazinon in aqueous solution was investigated by photocatalysis using low-energy activated C,N-codoped TiO2 as catalyst under visible-light. The influence of some parameters, i.e., catalyst concentration, the initial concentration of diazinon, initial pH of diazinon, and irradiation time on the diazinon degradation was studied. The amount of diazinon degradation was strongly influenced by all the above parameters. The results show that titania-modified enhanced the degradation percentage of diazinon, from 44.08% without a catalyst to 86.93% by adding 12 mg C,N-codoped TiO2 catalyst after 30 minutes visible-light irradiation. UV-visible spectrophotometer, HPLC, and COD analysis verified that diazinon was successfully degraded under photocatalysis visible.
Electrogenerated Chemiluminescence for Immunoassay Applications Isnaini Rahmawati; Irkham Irkham; Rahmat Wibowo; Jarnuzi Gunlazuardi; Yasuaki Einaga; Tribidasari Anggraningrum Ivandini
Indonesian Journal of Chemistry Vol 21, No 6 (2021)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.64596

Abstract

Electrogenerated chemiluminescence (ECL) has recently become one of the most prominent and well-established transducers for immunoassay techniques. ECL relates a luminophore concentration in solution with the emission of light triggered by an electrochemical stimulus. ECL immunoassay (ECLIA) performance depends on the parameters of its light generation, including the luminophore, the species that emit light called labels in ECLIA; co-reactants, which are added reagents that support the luminophore to undergo the excited state; electrodes, which are the place for the ECL reactions to take place; and the format of the immunoassay. This review discusses the behaviour of ECLIA parameters, the required instrumentations, and some important examples of detections based on ECLIA.
SINTESIS DAN KARAKTERISASI N DOPED TiO2 (N/TiO2) NANOTUBE SERTA UJI AKTIVITAS FOTOKATALISIS TERHADAP ZAT WARNA RHODAMIN B Ida Nur Apriani Apriani; Jarnuzi Gunlazuardi
Jurnal Teknologi dan Manajemen Vol. 19 No. 1 (2021): JURNAL TEKNOLOGI DAN MANAJEMEN
Publisher : Politeknik STMI Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (612.956 KB) | DOI: 10.52330/jtm.v19i1.21

Abstract

Telah dilakukan sintesis fotokatalis N/TiO2 bermofologi nanotube dengan metode anodisasi menggunakan ammonium nitrat (NH4NO3) sebagai sumber dopan pada berbagai variasi konsentrasi (0,5M , 1M, 2M), dilanjutkan dengan kalisinasi pada suhu 4500C selama 2 jam untuk mendapatkan fasa kristal anatase. Karakterisasi dilakukan menggunakan Scanning Electron Miscroscopy (SEM), Fourier Transform Infra Red (FT-IR), X-ray Diffraction (XRD), dan DRS (Diffused Reflectant Spectrometry) UV-Vis. Pengujian Linear Sweep Voltametri dan Multi Pulse Anperiometri pada fotokatalis­ N/TiO2 telah berhasil diterapkan untuk degradasi senyawa Rhodamin B menggunakan sinar UV maupun sinar tampak. Aplikasi dari uji fotoelektrokatalisis menggunakan sinar tampak untuk N/TiO2-NT memberikan hasil eliminasi sebesar 47,86%, sedangkan bila menggunakan TiO2 nanotube tanpa dopan eleminasi hanya sebesar 25,49%. Hal ini menunjukkan bahwa proses doping yang dilakukan telah berhasil menyisipkan nitrogen kedalam matrik TiO2 nanotube dan memperbaiki kinerja fotokatalisis nya di daerah sinar tampak.
Electrochemical Detection of Neuraminidase Based on Zanamivir Inhibition Reaction at Platinum and Platinum-Modified Boron-Doped Diamond Electrodes Ivandini, Tribidasari Anggraningrum; Ariani, Jenny; Jiwanti, Prastika Krisma; Gunlazuardi, Jarnuzi; Saepudin, Endang; Einaga, Yasuaki
Makara Journal of Science Vol. 21, No. 1
Publisher : UI Scholars Hub

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Abstract

Neuraminidase sensors have been developed using platinum (Pt) and platinum-modified boron-doped diamond (Pt-BDD) electrodes based on the difference of electrochemical responses of zanamivir in the absence and in presence of neuraminidase. Cyclic voltammetry of zanamivir showed that the presence of zanamivir decreases the oxidation-reduction peak currents of Pt. The responses were found to be linear in the zanamivir concentration range of 7.5-150 μM. Comparison between Pt-BDD and Pt bulk electrodes showed that Pt-BDD offers approximately two times higher sensitivity of zanamivir responses than Pt bulk. Further comparison to gold-based electrodes showed that Pt-based electrodes provided about one order higher sensitivity of zanamivir responses. In the presence of neuraminidase, the oxidation-reduction currents of Pt again increase. Observation on the oxidation currents in the system with 2 x 10-5 M zanamivir showed that the responses were linear in the neuraminidase concentration range of 5-20 mU. Good reproducibility with an RSD < 3 (n = 10) was achieved even when the measurements were performed in a mucin matrix,suggesting that Pt-based electrodes are suitable to be applied for the detection method of neuraminidase.
Grass-Like Structured Mesoporous Carbon as an Acid Red 119 Dye Adsorbent Krisnandi, Yuni Krisyuningsih; Priantini, Tania; Faisal, Muhammad; Yunarti, Rika Tri; Saragi, Indah Revita; Gunlazuardi, Jarnuzi
Makara Journal of Science Vol. 23, No. 4
Publisher : UI Scholars Hub

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Abstract

Grass-like structured mesoporous carbon was prepared by the soft-template method using triblock copolymer Pluronic F127, affording an organic–organic composite structure between phloroglucinol and formaldehyde. Thermogravimetric analysis revealed that the as-synthesized mesoporous carbon is stable to 900 °C, and X-Ray Diffraction (XRD) analysis confirmed the presence of carbon material structures at 2θ values of 22.020° and 42.420°. A hysteresis loop at relative partial pressures (P/Po) between 0.45 and 0.85 was observed in the N2 adsorption isotherm, indicating that the solid material exhibits mesoporous characteristics, with a homogeneous pore size distribution of 8.863 nm. Scanning Electron Microscope (SEM) images revealed that the bulk carbon surface exhibits a uniform grass-like structure. Furthermore, the as-synthesized mesoporous carbon was investigated for the adsorption of a diazo dye Acid Red 119, and it exhibited an adsorption capacity of 217.7389 mg/g; this capacity is 1.53 times greater than that of commercial activated carbon. Therefore, this mesoporous carbon is a potential adsorbent for the treatment of synthetic coloring waste.
Magnetically Separable Fe3O4/SiO2/TiO2 Photocatalyst Composites Prepared through Hetero Agglomeration for the Photocatalytic Degradation of Paraquat Gunlazuardi, Jarnuzi; Fisli, Adel; Ridwan, Ridwan; Krisnandi, Yuni Krisyuningsih; Robert, Didier
Makara Journal of Science Vol. 25, No. 4
Publisher : UI Scholars Hub

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Abstract

A photocatalyst supported on magnetic material allows the simple technique by using an external magnetic material to separate photocatalyst from the treated water. Thus, it is a magnetically separable nanoparticles photocatalyst (MSNP). The use of superparamagnetic nanoparticles that do not pose spontaneous magnetic moment thus could be dispersed in water and can be recollected easily by an external magnetic bar. We prepare Fe3O4/SiO2/TiO2 composite by hetero agglomeration of Fe3O4/SiO2 and TiO2 at a pH range of 3 to 6.2 in an aqueous slurry.The Fe3O4/SiO2 was prepared via co-precipitation of iron (II) and iron (III) ionic solution containing ammonium hydroxide and sodium silicate. The prepared composites were characterized by XRD, TEM, FTIR, and VSM, while the photocatalytic activities were tested toward paraquat in water. Based on zeta potential values, the Fe3O4/SiO2and TiO2 were being hetero agglomerated at pH 5 to obtain Fe3O4/SiO­2/TiO2 composite. The XRD characterization confirmed the presence of anatase, rutile, and magnetite crystal phases. TEM images showed that the Fe3O4 was covered by SiO2 and randomly attached to TiO2. The observed FTIR peak at 940-960 cm-1 attributed to -Si-O-Ti- bonding mode, ensuring photocatalyst (TiO2) adherence to the Fe3O4/SiO2 cluster. The prepared Fe3O4/SiO2/TiO2 composite showed good photocatalytic activity for the paraquat removal and showed a good magnetic property (VSM measurement)
A Comparative Study of Pt Depositing Methods (Chemical Reduction vs Photo-Assisted Deposition) onto TiO2 Nanoparticles for Hydrogen Photo-Production Ratnawati Ratnawati; Slamet Slamet; Viona Wongso; Jarnuzi Gunlazuardi; Muhammad Ibadurrohman
Journal of Engineering and Technological Sciences Vol. 54 No. 6 (2022)
Publisher : Directorate for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2022.54.6.12

Abstract

In this paper, we report a comparative study on two methods (chemical reduction and photo-assisted deposition) of incorporating Pt onto TiO2 nanoparticles (TNP) for H2 generation. The phase structure of the photocatalysts was scrutinized utilizing TEM and XRD. The degree of dispersion of Pt on the TNP was calculated by a pulse chemisorption technique using TPDRO equipment. The results provided by TEM imagery, EDX spectra, elemental mapping, and AAS confirmed the successful deposition of Pt on TNP. XRD patterns confirmed an anatase and rutile crystallite structure, while UV-Vis spectra showed reduction of the bandgap from a typical value of 3.2 eV to ca. 2.9 eV. It was found that there is a correlation between the deposited Pt and dispersed Pt on the TNP with H2 generation. The chemical reduction method offered a higher degree of Pt deposition, resulting in a 2.75 times larger amount of deposited Pt compared to photodeposition. This feature is perceived to contribute a higher H2 yield (3,283 µmol) at 1 w% of Pt loading.
Dye-Sensitized Solar Cell Photoelectrochemical Tandem System Performance Study: TiO2 Nanotube/N719, BiVO4/TiO2 Nanotube, Ti3+/TiO2 Nanotube for Nitrogen Reduction Reaction to Ammonia Suharyadi Suharyadi; Muhammad Iqbal Syauqi; Prita Amelia; Yunita Yunita; Jarnuzi Gunlazuardi
Indonesian Journal of Chemistry Vol 23, No 3 (2023)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.76270

Abstract

Ammonia is commonly synthesized through the Haber-Bosch process, which produces large amounts of CO2 emissions as it is carried out at extreme temperatures and pressures. An alternative technology is needed to synthesize ammonia which consumes less energy and is environmentally friendly. In this research, a Dye-Sensitized Solar Cell Photoelectrochemical tandem system (DSSC-PEC) was developed for the nitrogen reduction reaction (NRR) into ammonia. PEC cells utilized BiVO4/TiO2 Nanotube (BiVO4/TiO2NT) as a photoanode for water oxidation. BiVO4/TiO2NT was synthesized by the successive ionic layer adsorption and reaction (SILAR) with the cycles variation of 10, 15, and 20 cycles. The optimization method for 20 cycles (20s) gave the highest photocurrent of 0.352 mA/cm2. As a cathode where the nitrogen reduction reaction to ammonia takes place, Ti3+/TiO2NT was used. DSSC based on TiO2NT/N719 with an efficiency of 1.13% was used as an energy booster in the reaction. Using this system with an electrodes area of 3 cm2, under visible light irradiation on photoanode and DSSC while dark at the cathode, the rate of ammonia production, analyzed using the phenate method was 0.022 µmol.h−1.cm−2 with solar to chemical conversion (SCC) efficiency of 0.003%.
Development of BiOBr/TiO2 nanotubes electrode for conversion of nitrogen to ammonia in a tandem photoelectrochemical cell under visible light Prita Amelia; Jarnuzi Gunlazuardi
International Journal of Renewable Energy Development Vol 12, No 4 (2023): July 2023
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.2023.51314

Abstract

Ammonia (NH3) is one of the important chemicals for human life. The demand for ammonia is expected to increase every year. Conventionally, the fixation process of N2 to produce NH3 in the industrial sector is carried out through the Haber−Bosch process, which requires extreme temperature and pressure conditions that consume a high amount of energy and emit a considerable amount of CO2. Therefore, it is necessary to develop alternative technology to produce ammonia using environmentally friendly methods. Many studies have developed the photo-electrochemical conversion of nitrogen to ammonia in the presence of semiconductor materials, but the resulting efficiency is still not as expected. In this research, the development of the tandem system of Dye-Sensitized Solar Cell - Photoelectrochemistry (DSSC - PEC) was carried out for the conversion of nitrogen to ammonia. The DSSC cell was prepared using N719/TiO2 nanotubes as photoanode, Pt/FTO as cathode, and electrolyte I-/I3-. The DSSC efficiency produced in this research was 1.49%. PEC cell at the cathode and anode were prepared using BiOBr/TiO2 nanotubes synthesized by the SILAR (Successive Ionic Layer Adsorption and Reaction) method. The resulting ammonia levels were analyzed using the phenate method. In this study, ammonia levels were obtained at 0.1272 µmol for 6 hours of irradiation with an SCC (Solar to Chemical Conversion) percentage of 0.0021%.
FABRIKASI SEL SURYA TERSENSITASI ZAT WARNA ALIZARIN RED S BERBASIS TIO2 - NANOTUBE BERBENTUK SERBUK YANG DIPEROLEH DARI TEKNIK RAPID BREAKDOWN ANODIZATION (RBA) Linda J Kusumawardani; Jarnuzi Gunlazuardi
Ekologia: Jurnal Ilmiah Ilmu Dasar dan Lingkungan Hidup Vol 16, No 2 (2016): Ekologia : Jurnal Ilmiah Ilmu Dasar dan Lingkungan Hidup
Publisher : Universitas Pakuan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33751/ekol.v16i2.733

Abstract

TiO2 semiconductor is a material that can be expected to play an important role to solve the energy crisis problem through the utilization of solar energy based on photovoltaic devices. Dye sensitized Solar Cells (DSSC) is a cheaper alternative to silicon-based photovoltaic cells. In this study, TiO2 nanotube powder is using for the DSSC fabrication process which is produced by Rapid Breakdown Anodization (RBA) technique. Alizarin red S is also used as a sensitizer and the counter electrode is prepared from a deposition of 5 mM H2PtCl­6 solution as a Pt particle on a fluorine-doped tin oxide (FTO) glass substrate. TiO2 / FTO in DSSC system characterized by FESEM, obtained TiO­2 film thickness about 1,6-1,7 μm and UV-Vis Spectrophotometer. Testing the efficiency value is measured by linear method Sweep Voltametry using potentiostat. The efficiency of converting light energy to electric current obtained is 2.63% and open circuit voltage is 361 mV. Key words : DSSC, Rapid Breakdown Anodization (RBA), Anodization, TiO2 , TiO2 Nanotube-Powder
Co-Authors Abdul Wahid Wahab Adawiah Adawiah adawiah adawiah, adawiah Adel Fisli Agustino Zulys Andri Hermansyah Arda, Hany Dwi Ariani, Jenny Damayanti, Elok Defania, Mella Einaga, Yasuaki Eko Martin Sinaga Endang Saepudin, Endang Fatah, Fadhlir Rahman Aufar Al Harry Budiman Hedi Surahman Hedi Surahman Ida Nur Apriani Apriani Irkham Irkham Isnaini Rahmawati Ivandini Tribidasari Anggraningrum Jin Seog Kim Khoiriah Khoiriah Linda Jati Kusumawardani Madiabu, Mohammad Jihad Maemonah, Maemonah Misriyani Misriyani Misriyani Misriyani Muhammad Derry Luthfi Yudhi Muhammad Faisal Muhammad Fathurrahman Muhammad Ibadurrohman Muhammad Iqbal Syauqi Muhammad Iqbal Syauqi Munawar Khalil Neil V. Rees Oman Zuas Oman Zuas Paulina Taba Prastika Krisma Jiwanti Priantini, Tania Prita Amelia Prita Amelia RAHMAT WIBOWO Rahmat Wibowo Rahmat Wibowo Rahmat Wibowo Rahmawati, Isnaini Ratnawati Ratnawati Ridwan, Ridwan Robert, Didier Safni Safni Sanjaya, Afiten Rahmin Saragi, Indah Revita Sherly Kasuma Warda Ningsih Slamet Slamet Solly Aryza Suharyadi Suharyadi Supriyono Supriyono Supriyono Supriyono Syauqi, Muhammad Iqbal Utami, Chichi Amne Viona Wongso Wellia, Diana Vanda Wijaya, Lany Yasuaki Einaga Yunarti, Rika Tri Yuni K Krisnandi Yuni Krisyuningsih Krisnandi, Yuni Krisyuningsih Yunita Yunita Yunita Yunita