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All Journal Reaktor TEKNIK METANA JURNAL TEKNOLOGI KIMIA DAN INDUSTRI Bulletin of Chemical Reaction Engineering & Catalysis Seminar Nasional Teknik Kimia Kejuangan Majalah Ilmiah MOMENTUM Indonesian Journal of Chemistry Jurnal Pasopati : Pengabdian Masyarakat dan Inovasi Pengembangan Teknologi International Journal of Renewable Energy Development Bulletin of Chemical Reaction Engineering & Catalysis JURNAL REKAYASA KIMIA & LINGKUNGAN

Bakti Jos

Departemen Teknik Kimia, Fakultas Teknik, Universitas Diponegoro, Kampus Undip Tembalang Jl. Prof. Soedarto, SH, Semarang, Indonesia 50275

Author-ID : 292934

Aerospace Engineering Automotive Engineering Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Computer Science & IT Control & Systems Engineering Earth & Planetary Sciences Education Electrical & Electronics Engineering Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology

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Application of Glyoxal Acrylamide Modified Κ-Carrageenan as A Superabsorbent Polymer in Drug Delivery System Aji Prasetyaningrum; Al Farrel A. Raemas; Nur Rokhati; Bakti Jos
Reaktor Volume 20 No.3 September 2020
Publisher : Dept. of Chemical Engineering, Diponegoro University

The hydrogel is superabsorbent polymers (SAP) that are biodegradable and can be obtained from polysaccharides, lipids, and proteins. Polysaccharides include cellulose, starch and their derivatives, seaweed extracts such as carrageenan, alginate, pectin, and chitosan. Carrageenan is the result of the extraction of red seaweed sap with an alkaline solution. The main objective of this study was to simultaneously increase the strength and properties of κ-carrageenan SAP film with the addition of glyoxal and acrylamide as crosslinkers. The addition of acrylamide (variated from 1 to 7 % b/v) into the k-Carrageenan based SAP hydrogel compound and the presence of glyoxal as crosslink agent (variated from 0 to 1,0 % v/v). The physical properties of the SAP films were analyze using swelling degree and tensile strength. The structural and morphological properties of composite films were analyzed using Fourier Transform Infrared (FTIR) and Scanning Electron Microscopy (SEM). In addition, the effect of pHs on the releasing drug Poly(vinylpyrrolidone)-Iodine was investigated. This research shows that the addition of acrylamide and glyoxal can improve the physical properties of the modified κ-carrageenan film. Characterization using SEM shows that the addition of glyoxal causes the formation of tissue fibers in SAP. FTIR spectra indicated the formation of cross bonds in modified SAP film at 3294.42 cm-1 (carboxylic acid). The treatment under alkaline conditions will increase drug release ability.Keywords: κ-carrageenan; hydrogels; acrylamide; glyoxal; drug delivery

Effect of Esterification on Cassava Starch: Physicochemical Properties and Expansion Ability Siswo Sumardiono; Listiyana Riska; Bakti Jos; Isti Pudjiastuti
Reaktor Volume 19 No. 1 March 2019
Publisher : Dept. of Chemical Engineering, Diponegoro University

In this study, the characteristic of cassava starch have been developed through esterification reaction using ethyl lactate. Commercial cassava starch was modified by using (0.5; 0.75; 1.00; 1.25; 1.50 % v/v) ethyl lactate solution with pH 6, 7, 8, 9 for 15, 25, 35, 45, 55 minutes and the drained starch was dried with sun drying. The cassava starch which has been esterified with 1.5% ethyl lactate for 15 minutes pH 6 gave highest volume expansion of 2,438.9 %. For swelling power, the highest value was 19.32 swelling power at variable concentrations of 1.5% ester, esterification period of 15 minutes, and pH 6. The lowest amylose content was 15.68 % in ester concentration of 1.5 %. From the scanning electron micrograph, shows that the cassava starch after and before modification has not changed since the modifications performed under the gelatinization temperature. FTIR spectra of native cassava starch and ester cassava starch shown shift of the carboxyl group of starch from 1072.37 to 1087.80 cm-1 and a decrease in the OH group is from 3452.53 to 3417.81 cm-1. Bond formed indicates that the esterification reaction occurs between cassava starch with ethyl lactate esters. Keywords: volume expansion, cassava starch, ester starch, ethyle lactate, modified starch

EKSTRAKSI OLEORESIN DARI KAYU MANIS BERBANTU ULTRASONIK DENGAN MENGGUNAKAN PELARUT ALKOHOL Bakti Jos; Bambang Pramudono; Aprianto Aprianto
Reaktor Volume 13, Nomor 4, Desember 2011
Publisher : Dept. of Chemical Engineering, Diponegoro University

ULTRASOUND ASSISTED EXTRACTION OF CINNAMON OLEORESIN FROM CINNAMON BARK USING ALCOHOLS AS SOLVENTS. Cinnamon oleoresin is a complex mixture of resin and essential oil extracted from cinnamon burmanii by using organic solvent, and is primarily used as a coloring and flavoring in food products. Major component in essential oil is cinnamic aldehyde. Extraction was usually performed by percolation or soxhlet with various solvents. Several studies on the extraction of oleoresin have been completed by using polar organic solvents. Generally Recognized as Safe (GRAS) solvents, which are safe to use in food, were considered as alternative extraction solvents. Hildebrand solubility parameter concept was also used to choose the solvent. In this research, oleoresin from cinnamon was extracted by using ultrasound assisted extraction. Methanol, ethanol and isopropyl alcohol were used as the solvent to determine the extraction time, extraction rate and the kinetic model correspond to the yield of oleoresin. The result showed that the optimal time and extraction intensity are 66 minutes and 20% respectively, oleoresin yield by using solvent extraction of methanol, ethanol, and isopropyl alcohol were 22.86%, 17.87%, and 14.64% respectively. The results were similar compared to conventional extraction. Kinetic study confirmed that the second-order kinetic model is suitable for this research and the extraction rate constant for the second-order kinetic model of these solvents were 0.098, 0.057, and 0.089 respectively. Abstrak Oleoresin kayu manis merupakan campuran komplek antara resin dan minyak atsiri sebagai hasil ekstraksi kayu manis dengan menggunakan pelarut organik. Oleoresin banyak digunakan sebagai pewarna dan flavor dalam industri makanan. Komponen utama dalam minyak atsiri kayu manis adalah cinnamic aldehyde. Pada umumnya ekstraksi kayu manis menggunakan cara perkolasi atau soxhlet dengan berbagai pelarut. Beberapa studi ekstraksi oleoresin yang telah dilakukan, menunjukkan bahwa penggunaan pelarut polar lebih baik dibandingkan pelarut non polar. Pemilihan pelarut yang digunakan untuk ekstraksi harus mempertimbangkan pelarut GRAS (Generally Recognized as Safe) dan juga parameter kelarutan Hildebrand. Penelitian ini menggunakan metanol, etanol, dan isopropil alkohol sebagai pelarut untuk mengekstraksi oleoresin dari kayu manis yang menggunakan ultrasonik. Tujuan penelitian ini adalah menentukan pengaruh waktu dan intensitas ekstraksi berbantu ultrasonik dan juga menentukan model laju ekstraksi. Hasil penelitian menunjukkan bahwa waktu optimal dan intensitas optimal masing-masing adalah 66 menit dan 20%, sedangkan kadar oleoresin yang dihasilkan dengan pelarut metanol, etanol, dan isopropil alkohol berturut-turut sebesar 22,86%, 17,87%, dan 14,64%, dimana hasil ini relatif sama dengan hasil ekstraksi dengan menggunakan metode konvensional. Studi kinetika menunjukkan bahwa model laju ekstraksi orde dua lebih sesuai untuk penelitian ini dan dari hasil penelitian diperoleh nilai konstanta laju ekstraksi, k berturut-turut 0,098; 0,057; dan 0,089

Encapsulation of Lemongrass Extract (Cymbopogon citratus) Coated Alginate/Chitosan Using Gelation Method Aji Prasetyaningrum; Sadam Arrois; Fitri Lafifa; Aat Zaki Mubarok; Fadlillah Fani; Noer Abyor Handayani; Ratnawati Ratnawati; Bakti Jos
Reaktor Volume 21 No. 3 September 2021
Publisher : Dept. of Chemical Engineering, Diponegoro University

Lemongrass (Cymbopogon citratus) is a medicinal plant with various biological activities such as antibacterial, antifungal, antiprotozoal, anti-inflammatory, and antioxidant. This study aimed to encapsulate lemongrass bioactive in alginate/chitosan complex by enhancing the properties of CaCl2 crosslinked incorporated with tween 80 by ionic gelation method. The hydrogel was prepared by mixing alginate solution (2% w/v) and chitosan solution (1% w/v) with a ratio (1:1 v/v). Tween 80 (2% v/v) was added as a dissolution enhancer and CaCl2 as a crosslinker agent. The formulation varying by concentration of CaCl2 (0.1M to 0.3M) and lemongrass extract (2% to 12%). Encapsulation lemongrass with alginate-chitosan beads is characterized to determine encapsulation efficiency, swelling study, morphology, functional groups, and release study. The results showed that encapsulation efficiency ranged from 74.81% to 83.07%. Encapsulation efficiency increased with the addition of CaCl2 and lemongrass extract concentration. The swelling ratio ranged from 27.29 to 37.81, it will decrease with the addition of CaCl2 and lemongrass extract concentration. The Scanning Electron Microscopy (SEM) analysis of hydrogel beads shows a polyhedral shape, porous, and rough surface which indicates bioactive of lemongrass trapped on the beads. The Fourier Transform Infrared Spectroscopy (FTIR) results show new peaks at 1734 cm-1 as carbonyl stretch vibrations in ketones, aldehydes, and carboxylic acids, indicating the addition of lemongrass extract. Bioactive of lemongrass extract loaded alginate-chitosan beads was successfully released as much as 87.12% at pH 6.8. This study suggested the strong potential alginate-chitosan beads as an encapsulating agent for lemongrass extract using the ionic gelation method, and it has potential as a drug delivery system.Keywords: encapsulation; lemongrass; alginate; chitosan; CaCl2

Optimasi Proses Ozonasi pada Depolimerisasi κ-Karagenan dengan Metode Respon Permukaan Aji Prasetyaningrum; Ratnawati Ratnawati; Bakti Jos
Reaktor Volume 17 No.1 Maret 2017
Publisher : Dept. of Chemical Engineering, Diponegoro University

Abstract OPTIMIZATION OF OZONATION PROCESS FOR κ-CARRAGEENAN DEPOLYMERIZATION USING RESPONSE SURFACE METHODOLOGY. The objective of this research is to optimize the operating parameters in depolymerization of κ-carrageenan by ozone treatment. The optimization is done by using Box-Bhenken Design (BBD) model with ozonation time (5-15 minute), pH (3-11) and temperature (20-40oC) as the independent variables.The response of ozonation process is the degree of depolymerization of κ-carrageenan (DP). The initial molecular weight of refined κ-karagenan was 271 kDa. The κ-carrageenans powder was completely dissolved in distilled water to form 1% (weight/volume). The experiments were carried out in a 2000 ml of a glass reactor with an ozone gas sparger. The inlet ozone concentration was 80±2 ppm. The result shows that ozonation time, pH and temperature have significant effects during ozonation process (p< 0.05). Analysis of variance shows that the experimental data fit the model very well with the R2 value of 0.98. The optimum conditions during ozonation process are achieved at the reaction time of 15 min, ozonation pH of 3 and reaction temperature of 25oC. Under these optimum conditions the DP of κ-carrageenan is 91.513%. Keywords: depolymerization; κ-carrageenan;optimization; ozonation process Abstrak Tujuan penelitian ini adalah menentukan kondisi optimum parameter operasi depolimerisasi κ-karagenan dengan perlakuan ozonasi. Optimasi dilakukan dengan menggunakan model statistika Box-Bhenken Design (BBD) dengan variabel yang digunakan yaitu waktu ozonasi (5-15 menit), pH (3-11), dan suhu (20-40oC). Respon dari proses ozonasi adalah derajat depolimerisasi κ-karagenan (DP). Berat molekul awal refined κ-karagenan adalah 271 kDa. Sampel κ-karagenan dilarutkan secara sempurna dalam air distilasi dan konsentrasi diatur 1% (berat/volume). Percobaan dilakukan dalam reaktor gelas volume 2000 ml yang dilengkapi dengan sparger gas ozon. Konsentrasi gas ozon yang masuk adalah 80±2 ppm. Hasil penelitian menunjukkan bahwa waktu ozonasi, pH, dan suhu berpengaruh secara signifikan terhadap proses ozonasi (p<0,05). Analisis varian menghasilkan ketelitian yang tinggi antara data eksperimen dan prediksi, dengan nilai koefisien R2 = 0,98. Kondisi optimum diperoleh pada waktu ozonasi 15 menit, pH ozonasi 3 dan temperatur reaksi 25oC. Pada kondisi optimum ini diperoleh DP κ-karagenan sebesar 91,513%. Kata kunci:depolimerisasi; κ-carrageenan;optimasi; proses ozonasi

Kinetics and equilibriums adsorption of Cu (II) ion by chitosan and cross-linked chitosan-bentonite Hargono Hargono; Angga Mei Sarah; Feninda Nevrita; Bakti Jos
Reaktor Volume 19 No. 3 September 2019
Publisher : Dept. of Chemical Engineering, Diponegoro University

The sorption of Cu (II) particle from aqueous solution onto chitosan and cross-connected chitosan-bentonite (CTS-BTN) as adsorbent were conducted in batch conditions. The impact of different test parameters: starting pH, sorption time was assessed. Equilibrium studies have been completed to decide the limit of chitosan and CTS-BTN for Cu (II) particle. The Langmuir and Freundlich isotherm models were used in the examination of the trial information as linearized conditions. It was discovered that the isotherm information were all around portrayed by the Langmuir isotherm. Chitosan and CTS-BTN showed an adsorption capacity of 125 mg/g and 142.86 mg/g, respectively. The constant of adsorption rate was investigation utilizing a pseudo first order and a pseudo second order model. The pseudo second order model brought about the best fit with test information (R2= 0,991 for CTS and R2= 0,995 for CTS-BTN), additionally giving a constant rate k2, ads= 8.85 x 10-5 g/mg min for CTS and 3.72 x 10-4 g/mg min for CTS-BTN. Recommending that this model could be used in design and applications.Keywords: adsorption; Cu(II) ion; chitosan; cross-linked; isotherm; kinetics

Adsorption Photocatalytic Removal of Rhodamine B using Dodecyl Dimethyl Betaine (BS12) Intercalated Silver Tetratungstate-Bentonite composites: Effect of Ag and Surfactant Loading, pH, and its Subsequent Economic Feasibility Sumardiono, Siswo; Setiawan, Fajar Kasih; Jos, Bakti; Cahyono, Heri
Reaktor Volume 25 No.1 April 2025
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.25.1.%p

The potential of silver tetratungstate-doped bentonite intercalated with zwitterionic surfactant for removing Rhodamine B (RhB) was evaluated by comparing three composites, namely, AB (acid-activated bentonite), AB impregnated with Ag8W4O16 photocatalyst (Ag@AB), and Ag@AB intercalated with dodecyl dimethyl betaine (BS12) surfactant (Ag@OAB) with respect to their photocatalytic adsorption performance. The AB composite was prepared by treating natural bentonite with hydrochloric acid (HCl). Next, Ag@AB was synthesized by wet impregnation of Ag₈W₄O₁₆ onto AB. Lastly, the Ag@OAB was formed by intercalating the BS12 surfactant onto the Ag@AB composite. The morphology of the composite structures was characterized using Scanning Electron Microscopy (SEM). The addition of 4% Ag (w/w) tetratungstate W4O16 and 50% CEC BS12 to AB produced RhB removal percentages of 66% and 59%, respectively, compared to 65% for AB. The maximum removal percentage was achieved at pH 4 for the AB, Ag@AB, and Ag@OAB composites with RhB removal percentages of 67%, 71%, and 44%, respectively. The AB composite showed the highest regenerative ability compared to Ag@AB and Ag@OAB, with AB maintaining RhB removal at 70% after five regeneration cycles, while Ag@AB and Ag@OAB only reached four and three regeneration cycles. The total production cost of AB is fourteen to sixteen times lower than that of Ag@AB and Ag@OAB composites. In summary, the impregnation of the Ag₈W₄O₁₆ photocatalyst onto AB, resulting in the Ag@AB composite, increases the RhB removal efficiency compared to pristine AB. In contrast, the intercalation of the BS12 surfactant in Ag@OAB composite led to a decrease in RhB removal efficiency, resulting in the lowest performance among the three composites.

Co-Authors . Widayat A Abdullah Aat Zaki Mubarok Abdullah Abdullah Abdullah Abdullah Aji Prasetyaningrum Al Farrel A. Raemas Andri Cahyo Kumoro Angga Mei Sarah Aprianto Aprianto Bambang Pramudono Dessy Ariyanti Dessy Ariyanti Diah Susetyo Retnowati Dyah Hesti Wardhani Fadlillah Fani Feninda Nevrita Fitri Lafifa Gian Restu Prinanda Hantoro Satriadi Hargono Hargono Hargono Hargono Hargono Hargono Hargono Hargono Hargono Hargono Hargono Hargono Heri Cahyono Heri Cahyono Heru Susanto Isti Pudjiastuti Jonathan Ginting Listiyana Riska Muchlis Riki Darmawan Noer Abyor Handayani Nur Rokhati Patrick Andreas Praditya Nugraha Prayudi Eko Setyawan Prayudi Eko Setyawan Ratnawati Ratnawati Sadam Arrois Salsabila, Unik Hanifah Satrio Kuntolaksono Setiawan, Fajar Kasih Siswo Sumardiono Suherman Suherman Suherman, Suherman Sukaryo Sukaryo Teguh Riyanto Widayat Widayat Y Yufidani Yanuar Ariyanto Yudha Satria Yudha Satria Yudhy Dharmawan Zakaria, Muhammad Fahmi

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