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KONSENTRASI LOGAM Pb DAN Cd DALAM BUAH JERUK SERTA BIOAVAILABILITASNYA DALAM TANAH PERKEBUNAN JERUK DI DAERAH KINTAMANI I M. Siaka; N. K. Ermin; M. Manurung
Jurnal Kimia (Journal of Chemistry) Vol. 17, No.1, Januari 2023
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24843/JCHEM.2023.v17.i01.p02

Abstract

Kintamani dikenal sebagai pusat penghasil buah jeruk siam di Bali. Berbagai usaha dilakukan oleh para petani untuk meningkatkan produksi buah jeruk siam tersebut, salah satunya adalah dengan mengaplikasikan agrokimia. Akan tetapi, penggunaan agrokimia secara intensif tanpa kontrol yang memadai, dapat meningkatkan kandungan logam-logam berat dalam tanah pertanian, seperti yang telah dilaporkan oleh beberapa peneliti. Keadaan ini tentu dapat juga terjadi pada tanah perkebunan jeruk di Daerah Kintamani-Bali. Penelitian ini bertujuan untuk menentukan konsentrasi logam Pb dan Cd total dalam tanah dan buah jeruk siam serta tingkat bioavailabilitas logam berat tersebut dalam tanah perkebunan jeruk di Daerah Kintamani. Metode ekstraksi bertahap digunakan untuk penentuan konsentrasi logam total Pb dan Cd serta bioavailabilitasnya. Hasil penelitian menunjukkan bahwa konsentrasi Pb dan Cd total dalam tanah sebelum tanaman jeruk berbunga berturut-turut pada kisaran 344,0007-381,4229 mg/kg dan 3,6400-5,3236 mg/kg. Akan tetapi, konsentrasi logam Pb dalam tanah saat panen jeruk mengalami kenaikan menjadi 498,8548-514,3733 mg/kg, sedangkan logam Cd mengalami penurunan menjadi 2,7658-3,4094 mg/kg. Dalam buah jeruk ditemukan bahwa konsentrasi logam Pb dan Cd berturut-turut: 18,3048-24,2205 mg/kg dan 12,3983-15,9922 mg/kg. Konsentrasi ini melebihi ambang batas menurut Peraturan BPOM No. 5 Tahun 2018. Bioavailabilitas logam Pb pada tanah sebelum tanaman jeruk berbunga di setiap lahan sebagian besar berpotensi bioavailable dengan persentase rata-rata sebesar 49,35%. Berbeda dengan Pb, bioavailabilitas logam Cd yang ditemukan dalam tanah di lahan 1 dan 3 adalah Cd yang bioavailable yaitu sebesar 43,57% dan 39,09%, sedangkan di lahan 2 adalah non bioavailable dengan persentase sebesar 41,33%. Kata Kunci: bioavailabilitas, jeruk siam, logam berat. ABSTRACT Kintamani is known as the center of Siamese citrus production in Bali. Various efforts have been made by farmers to increase the production of Siamese citrus fruits, one of which is by applying agrochemicals. However, intensive use of agrochemicals without adequate control can increase the content of heavy metals in agricultural soils, as has been reported by several researchers. This situation can certainly also occur in the soil of citrus plantations in the area of Kintamani-Bali. This study aimed to determine the concentration of total Pb and Cd metals in the soil and citrus fruits as well as the level of bioavailability of these heavy metals in the soil. The sequential extraction method was used to determine the total metal concentrations of Pb and Cd and their bioavailability. The results showed that the total Pb and Cd concentrations in the soil before flowering citrus plants were in the range of 344,0007-381,4229 mg/kg and 3,6400-5,3236 mg/kg, respectively. However, the concentration of Pb in the soil during citrus harvest increased to 498,8548-514,3733 mg/kg, while Cd decreased to 2,7658-3,4094 mg/kg. In citrus fruits, it was found that the concentrations of Pb and Cd were 18,3048-24,2205 mg/kg and 12,3983-15,9922 mg/kg, respectively. This concentration exceeds the maximum allowed according to BPOM Regulation No. 5 of 2018. The bioavailability of Pb in the soil before the citrus plants flowered in each field was potentially bioavailable with an average percentage of 49,35%. In contrast to Pb, the bioavailability of Cd found in the soil of fields 1 and 3 was Cd which was bioavailable, with an average of 43,57% and 39,09%, while in field 2 it was non-bioavailable with a percentage of 41,33%. Keywords: bioavailability, heavy metals, siamese citrus.
Activated Bamboo Charcoal by ZnCl2 as Remazol Yellow FG Adsorbent: Isotherm, Kinetic, and Thermodynamic Studies Manurung, Manuntun; Suaniti, Ni Made; Ratnayani, Oka
The Journal of Pure and Applied Chemistry Research Vol. 13 No. 2 (2024): Edition May-August 2024
Publisher : Chemistry Department, The University of Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21776/ub.jpacr.2024.013.02.3311

Abstract

The aim of this study was to determine the isotherm, kinetics, and thermodynamics of remazol yellow FG dye adsorption by ZnCl2-activated bamboo charcoal. The research was started by making charcoal from bamboo stems, then the quality was checked against SNI. Adsorption isotherms were tested against Langmuir and Freundlich models. The adsorption kinetics were examined against pseudo-1st and pseudo-2nd orders and thermodynamic parameters were determined by measuring the values of enthalpy (∆Ho), entropy (∆So), and free energy (∆Go). The values of ∆Ho, ∆So, and ∆Go are -29.747 KJ/mol, -93.798 J/mol, and -1.327 KJ/mol respectively. The adsorption of remazol yellow FG by activated bamboo charcoal was spontaneous. Keywords: adsorption, kinetics, chromium, bamboo charcoal, thermodynamics
Karbon dari Bahan Alam sebagai Adsorben Ramah Lingkungan: Potensi, Tantangan, dan Aplikasinya Manurung, Manuntun; Ratnayani, Oka; Ciawi, Yenni
Nata Palemahan: Journal of Environmental Engineering Innovations Vol. 2 No. 1 (2025)
Publisher : Universitas Pendidikan Nasional

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.38043/natapalemahan.v2i1.6577

Abstract

Karbon dari bahan alam muncul sebagai solusi berkelanjutan untuk mengatasi berbagai jenis polutan dalam air dan udara. Tulisan ini mengulas berbagai aspek penting dari karbon dari bahan alam, mulai dari sumber bahan baku seperti limbah pertanian dan industri pangan, proses pembuatan melalui karbonisasi dan aktivasi, hingga fungsionalisasi untuk meningkatkan afinitas terhadap polutan spesifik. Berbagai aplikasi juga dibahas, termasuk penanganan logam berat, senyawa organik, zat warna sintetis, serta polutan baru seperti obat-obatan dan pestisida. Studi kasus menunjukkan adsorben ini sangat efektif dalam mengolah air limbah industri dan domestik. Namun, implementasi secara luas menghadapi tantangan seperti variabilitas bahan baku, kebutuhan proses aktivasi yang efisien, dan keterbatasan infrastruktur. Dengan pendekatan teknologi hibrida, desentralisasi produksi, dan integrasi dalam ekonomi sirkular, karbon dari bahan alam memiliki potensi besar sebagai alternatif karbon aktif konvensional. Tinjauan ini juga membahas pentingnya penelitian lanjutan dan kebijakan pendukung untuk mendorong pemanfaatan karbon alami sebagai adsorben ramah lingkungan di berbagai skala aplikasi.
Modification of Carbon Paste Electrode with Crown Ether (Dibenzo-18-Crown-6) for Ascorbic Acid Analysis Using Differential Pulse Voltammetry Method Irdhawati Irdhawati; Manuntun Manurung; Anisha Maulinasari
ALCHEMY Jurnal Penelitian Kimia Vol 11, No 2 (2015): September
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.11.2.728.175-191

Abstract

In this research, the modified carbon paste electrode with crown ether (dibenzo-18-crown-6) has been prepared, for determination of ascorbic acid. Some of parameters observed were optimization of crown ether composition in carbon paste, pH of solution, linear concentration range, limit of detection, reproducibility, and recovery. The optimum performance of the prepared electrode was applied for determination of commercialsampleswhich contain of ascorbic acid. The result of this research showsthat the optimum composition of crown ether in carbon paste is 0.6 % at pH 4. Linear range of concentration obtained is from 2 - 200 μM. The detection limit and percentage of recovery are 1.243 μM and 101.31 %, respectively. The modified electrode has HorRat value less than 2, it indicates a good reproducibility. Analysis of 4 commercial samples which contain of ascorbic acid were in agreement with the content listed in the label with the suitability of 94 - 100 %.