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Journal : International Journal of Renewable Energy Development

Characteristics of all organic redox flow battery (AORFB) active species TEMPO-methyl viologen at different electrolyte solution Ariyanti, Dessy; Purbasari, Aprilina; Hapsari, Farida Diyah; Saputra, Erwan Adi; Hamzah, Fazlena
International Journal of Renewable Energy Development Vol 13, No 5 (2024): September 2024
Publisher : Center of Biomass & Renewable Energy (CBIORE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/ijred.2024.60155

Abstract

The practice of using wind and solar energy to generate electricity represents a solution that would be beneficial for the environment and ought to be explored. However, in order to ensure users' stability and continuous access to electricity, the increasing usage of renewable energy needs to align with the advancement of energy storage technologies. Redox flow batteries, which use an organic solution as the electrolyte and a proton exchange membrane as an ion exchange layer, are currently the subject of extensive research as one of the alternative renewable energy storage systems with the benefit of a techno economy. This study investigated the solubility of organic solution, namely 2,2,6,6-Tetramethylpiperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl (TEMPO) and methyl viologen (MV) in various essential electrolyte solutions such as NaCl, KCl, KOH, and H2SO4 that can be used as electrolytes of all organic redox flow battery (AORFB) system to produce high energy density and charging and discharging capacity. The result shows the optimum condition for effective charge transfer in AORFB is TEMPO catholyte and MV anolytes in the 0.08 M H2SO4electrolyte solution. Additionally, a correlation between the acquisition of electrolyte solutions on TEMPO catalyst and MV anolytes was discovered by the data. Electrolyte solution can improve electrical conductivity in TEMPO solution, which in turn can improve the efficiency of AORFB charging and discharging. Contrarily, MV anolytes exhibit a different pattern where the addition of electrolyte solutions reduces their electrical conductivity. RFBs systems with the aforementioned catholyte and anolyte can be used to store solar energy with a maximum current of 0.6 A for 35 minutes. Storage effectiveness is characterized by a change in colour in the catholyte and anolyte. The findings firming the possibility of using AORFB as one of the alternative energy storage systems that can accommodate the intermittence of the renewable energy input resource. 
Co-Authors . Suherman Afiatin Afiatin Afri Yenni Agnesia Permatasari Alice Pramashinta Andri Cahyo Kumoro Anissa Ardanti Wulandari Ariestya Meta Devi Arif Fajar Utomo Aulia Beta Safira Ayyubi, Shalahudin Nur Budi Ismadi Budiyono Budiyono Darmaji, Timothius Adrian Christantyo Dessy Ariyanti Dessy Ariyanti Didi Dwi Anggoro Ekky Febri Ariani Erwan Adi Saputro Faleh Setia Budi Fikri Mudzakir Marasabessy Hafsah Fajrin Aprilianti Hamzah, Fazlena Hapsari, Farida Diyah Hargono Hargono Heny Kusumayanti Heny Kusumayanti Herry Santosa Heru Susanto Kristinah Haryani Laeli Kurniasari Lesdantina, Dina Lukman Atmaja Lulluil Mahsunnah Luqman Buchori M. Djaeni Machmud Lutfi H Margaretha Praba Aulia Mira Amalia Hapsari Muhammad Adi Irawan Muslim, Aristianto Nita Aryanti Nita Aryanti Noer Abyor Handayani Noer Abyor Handayani Nungki Primastuti Pratama, Pambudi Pajar Pratiwi, Wahyu Zuli Purwanto Purwanto Purwanto Purwanto Pury Diana Shintawati Raizka Kharisma Mediani Ratnawati Ratnawati Restu Kusumawardani Rini Kusumawati Samadhi, T Walmiki Saputra, Erwan Adi Sary, Cindy Nella Setia Budi Sasongko Shalahudin Nur Ayyubi Silviana Silviana Silviana Silviana Siswo Sumardiono Slamet Priyanto Sri Rukiyawati Suherman Suherman Titik Istirokhatun Tjokorde Walmiki Samadhi Tjokorde Walmiki Samadhi Tjokorde Walmiki Samadhi Tkokorde Walmiki Samadhi Tutuk Djoko Kusworo Vitus Dwi Yunianto Vitus Dwi Yunianto Budi Ismadi Wei Gao Wisnu Jati N Wulandari Dharsono Y. Saptiana Oktari Yazid Bindar Yazid Bindar Yustina Linasari