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Penggunaan Zeolit A Termodifikasi HDTMA sebagai Slow Release Urea Fertilizer Haditya, Ervan Bagus; Jumaeri, Jumaeri; Sulistyaningsih, Triastuti
Indonesian Journal of Chemical Science Vol 9 No 1 (2020)
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/ijcs.v9i1.28675

Abstract

Abstrak Penggunaan zeolit A-HDTMA sebagai agen pupuk lepas lambat terhadap ketersediaan nitrogen tanah telah dipelajari. Penelitian diawali dengan sintesis zeolit A menggunakan bahan kaolin dengan metode hidrotermal. Zeolit A hasil sintesis dimodifikasi dengan surfaktan HDTMA dengan konsentrasi 2x KTK. Analisis nitrogen dengan menggunakan metode Kjeldahl. Karakterisasi zeolit A dan zeolit A termodifikasi surfaktan ditentukan menggunakan FT-IR, dan XRD. Hasil penelitian menunjukkan bahwa hasil karakteristik XRD dan FT-IR dari zeolit hasil sintesis sesuai dengan karakteristik zeolit A. Zeolit A termodifikasi menunjukkan karakteristik yang berbeda pada analisis FT-IR pada serapan bilangan gelombang 2852 dan 2920 cm-1,sedangkan hasil karakteristik XRD pada zeolit hasil sintesis menunjukkan fase kristal dengan puncak tertinggi pada 2θ = 7,20°, 10,18°, dan 23,99°. Kandungan nitrogen tertinggi pada pot yang berisi tanaman jagung dan SRUF sebesar 1,04%, sedangkan pada pot yang berisi tanaman jagung dan urea 0,99 %, dan pot tanpa penambahan pupuk sebesar 0,49%. Abstract Research has been studied on the effect of zeolite A-HDTMA as a slow release fertilizer agent on availability of soil nitrogen. The study began with synthesis of zeolite using kaolin by hydrothermal method. Synthesis of zeolite A is modified by HDTMA surfactant with concentration of 2x CEC. Nitrogen analysis using the Kjeldahl method. Characterization of zeolite A and modified zeolite A using FT-IR, and XRD. The results showed that the characteristics XRD and FT-IR of the synthetic zeolite according to the characteristics of zeolite A. Zeolite A modification showed different characteristics in FT-IR analysis of wave number absorption 2852 and 2920 cm-1, while result of XRD of synthesis zeolite shows the crystal phase with highest peak at 2θ = 7.20°, 1018°, dan 23.99°. The higest nitrogen content in a pot containing corn plant and slow release fertilizer is 1.04%, where in pot containing corn plant and urea 0.99%, and pot without additions fertilizer is 0.49%.
Penentuan Nilai LoD dan LoQ pada Pengujian Metanol pada Miras Oplosan menggunakan Gas Chromatography dengan Variasi Metode Ainul, Ahmad Akhib; Mahatmanti, F Widhi; Sulistyaningsih, Triastuti
Indonesian Journal of Chemical Science Vol 8 No 3 (2019)
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/ijcs.v8i3.28725

Abstract

ABSTRAK Penentuan kadar metanol dalam minuman keras oplosan dapat dianalisis menggunakan Gas Chromatography-Flame Ionization Detector (GC-FID). Sebelum dianalisis, sampel minuman keras oplosan dapat dipreparasi menggunakan metode destilasi, ekstraksi cair-cair dan ekstraksi fase padat (SPE). Metode penelitian diawali dengan preparasi minuman keras oplosan menggunkan metode destilasi, ekstraksi cair-cair dan SPE kemudian dianalisis menggunakan GC-FID untuk menentukan nilai LoD dan LoQ masing-masing metode. Hasil penelitian menunjukkan bahwa linieritas kurva standar yang didapatkan sebesar 0,9996 dengan LoD dan LoQ berturut-turut 0,074% dan 0,247%. Perhitungan LoD metanol dalam sampel oplosan hasil dari ketiga metode distilasi, ekstraksi cair-cair, dan ekstraksi fase padat berturut-turut 0,048%, -0,020%, dan -0,018%. Perhitungan LoQ metanol dalam sampel oplosan hasil dari ketiga metode distilasi, ekstraksi cair-cair, dan ekstraksi fase padat berturut-turut 0,072%,-0,024, dan -0,005%. Hasil tersebut menunjukkan bahwa LoD dan LoQ dari metode distilasi lebih baik dibandingkan metode ekstraksi cair-cair dan ekstraksi fase padat, sehingga metode distilasi lebih cocok digunakan untuk menentukan kadar metanol dalam miras oplosan menggunakan GC-FID ABSTRACT Determination of methanol in alcoholic beverage can be analyzed by using Gas Chromatography-Flame Ionization Detector (GC-FID). Alkoholic beverage samples are first prepared with distillation method, liquid-liquid extraction, and solid phase extraction to remove impurities. This study aims to determine the most good preparation based on LoD and LoQ value. The standard curve linearity which was obtained in the amount of 0.9996 with LoD and LoQ respectively 0.0743% and 0.2477%. Calculation of LoD methanol in the beverage results from all three distillation methods, liquid-liquid extraction, and solid phase extraction were respectively 0,048126%, -0,019919%, and -0,018107%. Calculation of LoQ methanol in the beverage results from all three distillation methods, liquid-liquid extraction, and solid phase extraction were respectively 0,072629%,-0,024376, and -0,005351%. Those results indicated that LoD and LoQ distillation method were better than liquid-liquid extraction and solid phase extraction methods. So it can be concluded that the distillation method is more suitable to determine the methanol levels in the alcoholic beverage using GC-FID.
Peningkatan Kadar Etanol dalam Ciu dengan Metode Distilasi Adsorptif Menggunakan Zeolit Alam Rahayu, Anita; Sulistyaningsih, Triastuti; Jumaeri, Jumaeri
Indonesian Journal of Chemical Science Vol 9 No 2 (2020)
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/ijcs.v9i2.28727

Abstract

Abstrak Kebutuhan bahan bakar minyak di Indonesia, khususnya premium semakin meningkat, sedangkan ketersediaannya di alam semakin sedikit. Oleh karena itu, perlu dicari alternatif bahan bakar yang dapat diperbaharui, seperti Etanol. Etanol dengan kadar >96,5% v/v dapat digunakan sebagai campuran bahan bakar. Etanol dengan kadar >96,5% dapat dicapai dengan menggunakan metode distilasi adsorptif. Pada penelitian ini pemurnian etanol dilakukan menggukana dua cara yaitu distilasi sederhana dan distilasi adsorptif. Kadar awal sampel CIU A, CIU B dan CIU C berturut-turut adalah 9,92%, 44,60% dan 47,31% dengan menggunakan metode distilasi sederhana kadar etanol dapat meningkat menjadi 29,37%, 86,96% dan 90,81%. Meskipun metode distilasi sederhana dapat meningkatkan kadar etanol secara signifikan namun tidak dapat melampaui titik azeotropnya sehingga perlu adanya metode lain yaitu distilasi adsorptif dengan adsorben zeolit alam yang sudah teraktivasi. Dengan menggunakan metode distilasi adsorptif diperoleh kadar etanol tertinggi CIU A, CIU B dan CIU C berturut-turut sebesar 33,20%, 98,28% dan 99,22%. Kadar etanol tertinggi diperoleh saat pengambilan distilat ke-3 yaitu pada waktu 45 menit distilasi. Abstract The need for fuel oil in Indonesia, especially premium, is increasing, while its availability in nature is getting smaller. Therefore, it is necessary to look for alternative renewable fuels, such as Ethanol. Ethanol with a level of> 96.5% v / v can be used as a mixture of fuel. Ethanol with a concentration of> 96.5% can be achieved using the adsorptive distillation method. In this study, ethanol purification was carried out using two methods, simple distillation and adsorptive distillation. Initial levels of CIU A, CIU B and CIU C samples were 9.92%, 44.60% and 47.31% respectively using a simple distillation method. Ethanol levels could increase to 29.37%, 86.96% and 98.81%. Although a simple distillation method can significantly increase ethanol levels but cannot exceed its azeotropic point, it is necessary to have another method, namely adsorptive distillation with activated zeolite natural adsorbent. By using the adsorptive distillation method, the highest ethanol levels of CIU A, CIU B and CIU C were 33.20%, 98.28% and 99.22% respectively. The highest ethanol content was obtained when the third distillate was taken at 45 minutes distillation.
Dimethyl Phthalate Adsorption Using a Composite of Activated Carbon from Black Liquor-diatomite Yasmine, Luigy Maurizka; Sari, Ajeng Arum; Sulistyaningsih, Triastuti
Indonesian Journal of Chemical Science Vol 9 No 2 (2020)
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/ijcs.v9i2.33837

Abstract

Dimethyl phthalate is one of the main chemicals in the manufacture of plastics which is harmful to human health because it can be easily absorbed in the body through the skin and is toxic so it is necessary to do a waste treatment process. Adsorption is an alternative method for reducing the levels of dimethyl phthalate in liquid waste. The purpose of this study was to determine the effect of adsorption efficiency on dimethyl phthalate using a composite activated carbon from black liquor-diatomite. A composite activated carbon from black liquor-diatomite were contacted with dimethyl phthalate using the batch method at 120 minutes contact time at 30°C and pH 5, the variations tested were the concentration and dosage adsorbent. Testing samples using GC-MS. The results showed optimum dimethyl phthalate adsorption at a concentration of 1 ppm with a contact time of 120 minutes, an adsorbent dose of 0.05 gram and a pH of 5 at 64.2%.
Iron Extraction from Coal Fly Ash Using HCl Solution Setyo, Slamet Budi; Sulistyaningsih, Triastuti; Prasetya, Agung Tri; Kusumastuti, Ella
Indonesian Journal of Chemical Science Vol 10 No 2 (2021)
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/ijcs.v10i2.47881

Abstract

About 780 million tonnes of fly ash are produced annually worldwide. The use of fly ash is still minimal, causing fly ash piles to increase. Based on this, a study was conducted on the extraction of iron from coal fly ash using HCl as a solvent. This study aims to determine the Fe content in fly ash extracted using HCl with variations in HCl concentration and extraction time. This research begins with the preparation of fly ash samples using an oven. Fly ash that has been prepared and extracted using HCl added with MIBK and EDTA was then characterized using XRF, FTIR and AAS. The results showed that the highest Fe content (11.48%) was obtained from the extraction using 9N HCl for 1 minute. The greater the concentration of HCl and the faster the extraction time, the more Fe extracted.
The Effectiveness of Problem Based Learning on Acid-Base Materials to Improve Scientific Attitude and Creativity of SMA N 1 Comal Students Dirmanto, Agus; Cahyono, Edy; Sulistyaningsih, Triastuti
Journal of Innovative Science Education Vol 10 No 2 (2021): August 2021
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/jise.v9i3.43051

Abstract

The learning model is fundamental to increase the effectiveness of the teaching and learning process in the classroom. Learning models that make students more active in the chemistry teaching and learning process in class XI SMA N 1 Comal are rarely used. As a result, students become passive and scientific attitudes and student creativity have not developed. This study aims to determine : the process of implementing problem-based learning (PBL), the effectiveness of PBL on acid-base material in high school, increasing the scientific attitude and creativity of class XI SMA students. The research design used was a pretest-postest control group with a quasi experimental design. This study’s population was all students of class XI SMA N 1 Comal in the academic year 2020/2021. The sample was taken using simple random sampling technique and selected class XI MIPA 5 as the control class and XI MIPA 6 as the experimental class. Data collection techniques used documentation in the form of pretest and postest scores, scientific attitude observation sheets and questionnaires to measure student creativity. The data analysis technique used is the t-test. The results showed that the average posttest score of students in the experimental class were higher than the average posttest score of students in the control class. The percentage of students with a high scientific attitude in the experimental class is also more remarkable than the control class. The creativity category with a very creative category in the experimental class shows a more significant percentage than the control class. From the analysis results, it can be concluded that first, the application of PBL starts from problem orientation, group organizing, conducting experiments, presenting work results, and evaluating. The second is the problem based learning model provides excellent results and is quite effective compared to conventional methods. Third, PBL models can improve student’s scientific attitudes and creativity compared to conventional methods.
Laboratory Course During Pandemic Covid-19: Do Lab at Home to Promote Creative Thinking Skill Dewi, Siti Herlina; Sudarmin, Sudarmin; Haryani, Sri; Sulistyaningsih, Triastuti
International Journal of Active Learning Vol 7, No 1 (2022): April 2022
Publisher : International Journal of Active Learning

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

During online learning, students are generally asked to study practicum procedures that have been provided by the lecturer, then they are given raw data from practicum results in the previous semester for analysis and preparation of practicum reports. Another method used is to provide demonstration videos or use digital applications such as virtual labs. In general, students can attend lectures smoothly and well, but many also say that this method is boring because there is almost no difference with theoretical classes. The object of the research is second semester chemistry students, which consists of 1 class of chemistry program and 1 class of chemistry education program. The research begins with a pretest, then students carry out the planned learning, then ends with a posttest and filling out a questionnaire. The project in the do lab at home practicum is specified to titrate a solution of vinegar with a solution of baking soda or vice versa. Each student prepares a buffer solution with various pH according to the instructions of sub-project 1, makes an acid-base indicator solution from natural materials according to the instructions of sub-project 3, and determines the RGB ratio of a buffer solution that has been given a natural acid-base indicator using the instructions of the sub-project.  In quantity, all students upload practicum videos, with a duration ranging from 8-15 minutes.  Based on the results of the practicum videos uploaded by students, the first creativity that can be seen immediately is the composition of video editing, such as sound quality, image quality, and the addition of information in the video. In this study, in general, it can be said that students are in the development stage for the fluency-brainstorming indicator.  Just like fluency indicators, flexibility indicators are also generally still in the developing stage, they still need help in taking new perspectives. Making videos, although not the main product, can train students' skills, including creative thinking. In detail, risk taking indicators are further divided into 2, namely risk taking-1 and risk taking-2. Most of the students are at the developing level for the risk taking-1 indicator.
PENERAPAN MODEL TALKING CHIPS UNTUK MENGUKUR HASIL BELAJAR DAN KECERDASAN INTERPERSONAL Sarifa, Zakiyatu; Wardani, Sri; Sulistyaningsih, Triastuti; Purniawati, Henny
Jurnal Inovasi Pendidikan Kimia Vol 15, No 2 (2021): July 2021
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/jipk.v15i2.17464

Abstract

The aims of research is to find out the analysis of student learning result and interpersonal intelligence through talking chips learning model. The methods of this research is using experiment. The sample used was XI IPA 1 class and XI IPA 2 at SMA N 2 Kudus with sampling technique based on the consideration of the teacher concerned. The data taking is done using validation sheets, cognitive test instruments, observation sheets, student response questionnaires and documentation. The cognitive analysis results of the experimental class 1 pre-test score was 70 and the post-test was 100 while the experimental class 2 the pre-test score was 70 and the post-test was 95. The results of the affective analysis is the highest aspect of the experimental class 1 were aspects of cooperation while for the experimental class 2 is the aspect of curiosity. The indicators of empathetic processing, team building and listening to other owned by the experimental class students are very good, but the indicators for giving feedback and inquiry and questioning are still not enough and need to be improved. It can be concluded that talking chips learning can improve student learning result and interpersonal intelligence and make students more interested and active during the learning process.
INOVASI PEMURNIAN GARAM (NATRIUM KLORIDA) MENGGUNAKAN ZEOLIT ALAM SEBAGAI PENGIKAT IMPURITAS DALAM PROSE KRISTALISASI Jumaeri, Jumaeri; Sulistyaningsih, Triastuti; Sunarto, Wisnu
Sainteknol : Jurnal Sains dan Teknologi Vol 15, No 2 (2017): December 2017
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/sainteknol.v15i2.12403

Abstract

Garam  merupakan salah satu komuditas strategis yang diprioritaskan untuk  dikembangkan oleh Kementrian Perindustrian.  Kebutuhan garam berkualitas tinggi, utamanya garam industri, masih diimpor dari luar negeri. Penelitian inovasi proses pemurnian garam menggunakan filter zeolit alam sebagai bahan pengikat impuritas dalam proses kristalisasi telah dilakukan. Penelitian bertujuan untuk  mengetahui efektifitas dan kondisi optimal proses  pemurnian garam (natrium klorida) menggunakan zeolit alam dalam proses kristalisasi dan model proses pembuatan uapan air laut. Penelitian ini dimulai dengan pengambilan sampel garam krosok dan karakterisasinya. Sampel garam krosok selanjutnya dimurnikan dengan menggunakan zeolit alam sebagai pengikat impuritas dalam proses kristalisasi. Efektifitas proses pemurnian ditetukan berdasarkan kualitas garam hasil pemurnian yang diperoleh. Kualitas produk garam hasil pemurnian ditentukan berdasarkan standar kualitas garam baku sesuai SNI Garam 2000, yang meliputi kadar NaCl, air, logam berat, Ca, Mg dan sifat fisik garam (warna, rasa dan bentuk kristal). Kemurnian produk garam juga diuji menggunakan XRD dan hasilnya dibadingkan dengan NaCl standar. Hasil penelitian menunjukkan bahwa garam krosok dengan kadar NaCl 82,37% setelah proses pemurnian kadar NaCl meningkat menjadi 92,64, 92,49 dan  91,80% masing-masing untuk kepekatan awal  larutan garam 17, 15 dan 12o Be. Kadar air garam hasil kristalisisasi untuk ketiga larutan garam adalah 1,25, 1,52 dan 1,68%.  Hasil penelitian ini menunjukkan bahwa zeolit alam dapat digunakan secara efektif dalam pemurnian garam dapur melalui proses kristalisasi. Aktivasi zeolit dengan larutan HCl 0,1 M dapat meningkatkan kualitas garam hasil rekristalisasi. Garam hasil kristalisasi mempunyai kadar NaCl tertinggi (98,73%) diperoleh dengan menggunakan zeolit lolos ayakan 10/20 mesh yang teraktivasi HCl 0,1 M
PENINGKATAN KUALITAS GULA AREN TRADISIONAL PRODUKSI DESA JAWISARI KABUPATEN KENDAL Astuti, Widi; Sulistyaningsih, Triastuti; Prastiyanto, Dhidik
Jurnal Puruhita Vol 1 No 1 (2019): February 2019
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/puruhita.v1i1.28647

Abstract

Desa Jawisari, yang merupakan salah satu desa diantara 16 desa yang berada di wilayah Kecamatan Limbangan Kabupaten Kendal, merupakan sentra penghasil gula aren tradisional. Namun, jumlah pengrajin yang cukup banyak ini ternyata belum mampu membawa gula aren menjadi salah satu komoditas utama Kabupaten Kendal karena sistem pengelolannya yang masih sangat tradisional. Kesalahan dalam proses pemanasan menyebabkan rendahnya kualitas gula aren yang dihasilkan, dimana intensitas warna yang tidak konsisten dan seringkali bahkan terlalu gelap. Selain itu, bentuk gula juga tidak rapi dengan ukuran yang tidak seragam. Oleh karena itu, dalam kegiatan pengabdian kepada masyarakat masyarakat ini akan dilakukan perbaikan proses pemanasan. Namun demikian, kegiatan pengabdian ini tidak hanya fokus pada perbaikan proses pemanasan nira saja, tetapi juga dilengkapi dengan penyuluhan dan pelatihan teknik penyadapan serta penyimpanan nira serta teknik pengemasan dan pemasaran. Kegiatan ini akan dilakukan secara sinergi antara mitra, Universitas Negeri Semarang selaku lembaga akademisi serta Pemerintah Daerah Kabupaten Kendal melalui Dinas Perindustrian, Koperasi, Usaha Kecil dan Menengah. Hal ini mengingat peran Pemerintah Daerah sebagai fasilitator terhadap keberlangsungan program ini sangat diperlukan, terutama untuk pemasaran gula aren. Harapannya, gula aren dapat menjadi salah satu produk unggulan Kabupaten Kendal, jika kualitasnya dapat ditingkatkan melalui kegiatan pengabdian kepada masyarakat ini.
Co-Authors - Jumaeri Agung Tri Prasetya Agustina Dwi Rahmawati Ainul, Ahmad Akhib Al Muttaqii, Muhammad Alawiyah, Nur Amanda Shinta Maylani, Amanda Shinta Anita Rahayu Annisa Nurul Syakina Bambang Rusdiarso Budi Hastuti Danang Subarkah Hadikawuryan Darmadinata, Mariyanti Darmadinata, Mariyanti Dewi, Siti Herlina Dhidik Prastiyanto Dirmanto, Agus Dwi Siswanta Edy Cahyono Eisdiantoro, Sunarko Eko Budi Susatyo Ella Kusumastuti Ella Kusumastuti, Ella Endang Susilaningsih Endang Susilaningsih Erik Prasetyo F Widhi Mahatmanti Ghaefira Tasya Azany Haditya, Ervan Bagus Hidayah, Miftachul Hidayah, Miftachul Isnaeni, Diana Isnaeni, Diana Kasmadi Imam Supardi Khrisna Khrisna M. Furqon Adli Marbun, Maja Pranata MARIA BINTANG Maryani, Tri Maya Rahmayanti Mochamad Hafiz Ghozali Rusmana Mulyasari, Mursalina Mulyasari, Mursalina Murbangun Nuswowati Natasya Viona Alexandra Nugraha, Muhammad Septian Nugraha, Muhammad Septian Nuni Widiarti Nur Imaniah, Nur Prasasti, Hesti Pratomo, Sigit Wahyu Pratomo, Sigit Wahyu PUJI LESTARI Purniawati, Henny Radenrara Dewi Artanti Putri Rahmawati, Lidia Reni Ainun Jannah Ria Saputri Riza Alviany Rochmah, Vinny Rochmah, Vinny Rusadi, Eka Rusadi, Eka S Mursiti Safitri, Tsania Safitri, Tsania Samuel Budi Wardhana Kusuma Sari, Ajeng Arum Sarifa, Zakiyatu Selli Renata Sari, Selli Renata Setyo, Slamet Budi Sibuea, Andreas Silalahi Raja, Havier Samuel Huttur Sintia Ayu Dewi Siti Herlina Dewi Siti Kholipuk, Siti Sri Haryani Sri Haryani Sri Juari Santosa Sri Mantini Rahayu Sedyawati, Sri Mantini Rahayu Sri Martini Rahayu Sedyawati Sri Mursiti SRI WARDANI Subiyanto Hadisaputro, Subiyanto Sudarmin Sudarmin Sugeng Priyanto, Sugeng Syafaat AM, Fuad Tri Utami Kusuma Putri Umayah, Isponi Umayah, Isponi Ummi Kulsum Wahyu Rahmawati, Aliftia Wahyu Rahmawati, Aliftia Warlan Sugiyo Wasinton Simanjuntak Widi Astuti Widi Astuti Wismaningati, Putri Wisnu Sunarto Wulandari, Ari Vitri Wulandari, Ari Vitri Yasmine, Luigy Maurizka yati, indri Yunita, Anfi'na Ilma Zulfa Ajrina Fitri