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Nurul Hidayat Aprilita
Department Of Chemistry, Faculty Of Mathematics And Natural Sciences, Universitas Gadjah Mada Sekip Utara, Yogyakarta 55281
Agriculture, Biological Sciences & Forestry Humanities Astronomy Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Earth & Planetary Sciences Education Energy Engineering Environmental Science Immunology & microbiology Materials Science & Nanotechnology Neuroscience Physics Social Sciences

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ADSORPTION CHARACTERISTIC OF IRON ONTO POLY[EUGENOL-CO-(DIVINYL BENZENE)] FROM AQUEOUS SOLUTION Fitrilia Silvianti; Dwi Siswanta; Nurul Hidayat Aprilita; Agung Abadi Kiswandono
Jurnal Natural Volume 17, Number 2, September 2017
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (561.316 KB) | DOI: 10.24815/jn.v17i2.8076

Abstract

A study on the adsorption characteristic of Iron onto Poly[eugenol-co-(divinyl benzene)] (EDVB) from aqueous solution has been conducted. EDVB was produced and characterized by using FTIR spectroscopy. The adsorption was studied by a batch method by considering the factors affecting the adsorption such as initial metal ion concentration, adsorption selectivity, and mechanism of adsorption using a sequential desorption method. The adsorption of Iron onto EDVB followed a pseudo-2 order kinetics model with the rate constant of 0,144 L2 mmol-1 min-1. The adsorption isotherm was studied with Tempkin, Langmuir and Freundlich models. The adsorption capacity (Qmax) obtained by Langmuir isotherms was 250mg.L-1 while the equilibrium value was 0.8 Lmg-1. A competitive adsorption study showed that EDVB is adsorbed selectively towards Iron rather than Chromium, Coppers and Cadmium ions. The interaction type of Iron onto EDVB was determined by a sequential desorption.Keywords: Polyeugenol; divinyl benzene (DVB); adsorption; Iron; FeReferencesAbasi, C. Y.; Abia, A.A.; Igwe, J.C. Adsorption of Iron (III), Lead (II) and Cadmium (II) Ions by Unmodified Raphia Palm (Raphia hookeri) Fruit Endocarp. Environ. Res. 2011, 5 (3), 104-113, ISSN: 1994-5396, Medwell Journals. DOI: 10.3923/erj.2011.104.113Baes, F. C.; Mesmer, R. E. The Hydrolisis of Cations; John Wiley: New York, 1976Bakatula, E.N.; Cukrowska, E.M.; Weiersbye, L.; Mihali-Cozmuta, L.;Tutu, H. Removal of toxic elements from aqueous solution using bentonite modified with L-histidine. Water Sci. Technol.2014, 70 (12),2022-2030, DOI: 10.2166/wst.2014.450Bhattacharyya, K.G.; Gupta, S.S. Adsorption of Fe(III) from Water by Natural and Acid Activated Clays: Studies on equilibrium isotherm, kinetics and thermodynamics of interactions. Adsorption. 2006, 12 (3), 185-204,DOI : 10.1007/s10450-006-0145-0Carmona, M..; Lucas, A.D.; Valverde, J.L.; Velasco, B.; Rodriguez, J.F. Combined adsorption and ion exchange equilibrium of phenol on Amberlite IRA-420.Chem. Eng. J.2006, 117, 155-160, Doi : 10.1016/j.cej.2005.12.013Debnath, S.; Ghosh, U.C. Kinetics, isotherm and thermodynamics for Cr(III) and Cr(VI) adsorption from aqueous solutions by crystalline hydrous titanium oxide. J. Chem. Thermodin. 2008, 40: 67-77, DOI: 10.1016/j.jct.2007.05.014Djunaidi, M.C.; Jumina; Siswanta, D.; Ulbricht, M. Selective Transport of Fe(III) Using Polyeugenol as Functional Polymer with Ionic Imprinted Polymer Membrane Method. Asian J. Chem. 2015, 27 (12): 4553-4562, DOI : 10.14233/ajchem.2015.19228Febriasari, A.; Siswanta, D.; Kiswandono, A.A.; Aprilita, N.H. Evaluation of Phenol Transport Using Polymer Inclusion Membrane (PIM) with Polyeugenol as a Carrier. Jurnal Rekayasa Kimia dan Lingkungan. 2016, Vol. 11, No. 2, 99-106, DOI: 10.23955/rkl.v11i2.5112Foldesova, M.; Dillinger, P.; Luckac, P. Sorption and Desorption of Fe(III) on Natural and chemically modified zeolite. J. Radioanal. Nucl. Chem. 1999, Vol. 242, No. 1 (1999), 227-230, DOI: 10.1007/BF02345926Gupta, V.K.;Sharma, S. Removal of cadmium and zinc from aqueous solutions using mud.Environ. Sci. Technol. 2002, 36: 3612-3617, DOI: 10.1021/es020010vHandayani, D.S. Sintesis kopoli(eugenol-DVB) sulfonat dari Eugenol Komponen Utama Minyak Cengkeh Szygium aromaticum (Synthesis of copoly(eugenol-DVB) sulfonic from main components of eugenol clove oil Szygium aromaticum). Biopharmacy Journal of Pharmacological and Biological Sciences. 2004, 2 (2): 53-57 ISSN: 1693-2242. url : https://eprints.uns.ac.id/id/eprint/856Harimu, L.; Matsjeh, S.; Siswanta, D.; Santosa, S.J. Synthesis of Polyeugenyl Oxyacetic Acid as Carrier to Separate Heavy Metal Ion Fe(III), Cr(III), Cu(II), Ni(II), Co(II), and Pb(II) that Using Solvent Extraction Mehod. Indo. J. Chem. 2009, 9 (2): 261-266.Ho, Y.S.; McKay, G. Pseudo-second Order Model for Sorption Processes. Process. Biochem. 1999, 34, 451-465, DOI: 10.1016/S0032-9592(98)00112-5Ho, Y.S.; McKay, G.; Wase, D.A.J.;Forster, C.F. Study of Sorption Divalent Metal Ions on to Peat. Adsorpt. Sci. Technol. 2000, 18: 639-650. DOI : 10.1260/0263617001493693Indah, S.; Helard, D.;Sasmita, A. Utilization of maize husk (Zea mays L.) as low-cost adsorbent in removal of iron from aqueous solution. Water Sci. Technol. 2016, 73 (12), 2929-2935, DOI: 10.2166/wst.2016.154Kiswandono, A.A.; Siswanta, D.; Aprilita, N.H.; Santosa, S.J. Transport of Phenol through inclusion polymer membrane (PIM) using copoly(Eugenol-DVB) as membrane carries. Indo .J. Chem. 2012, 12 (2): 105-112. Doi : 10.22146/ijc.667Kousalya, N.; Gandhi, M.R.; Sundaram, C.S.; Meenakshi, S. Synthesis of nano-hydroxyapatite chitin/chitosan hybrid bio-composites for the removal of Fe(III).Carbohyd. Polym. 2010, 82: 594-599, DOI:10.1016/j.carbpol.2010.05.013Kumar, K.V.; Porkodi, K.;Rocha, F. Langmuir-Hinshelwood kinetics – A theoretical study, Catalysis Communications. 2008, 9: 82-84, DOI:10.1016/j.catcom.2007.05.019Masel, R.I. Principles Adsorption and Reaction on Solid Surface; John Wiley Sons: Canada, 1996Moore, J. W.; Pearson, R.G. Kinetics and Mechanism Third Edition; John Wiley Sons: Canada, 1981.Ngah, W.S.W.; Ghani, S.A.; Kamari, A. Adsorption Behaviour of Fe(II) and Fe(III) Ions in Aqueous Solution on Chitosan and Cross-linked Chitosan Beads. Bioresource. Technol. 2005, 96: 443-450. DOI:10.1016/j.biortech.2004.05.022Rahim, E.A.; Sanda, F.; Masuda, T. Synthesis and Properties of Novel Eugenol-Based Polymers. Polymer Bulletin. 2004, Vol. 5, 93-100, DOI: 10.1007/s00289-004-0272-2Samarghandi, M.R.; Hadi. M.; Moayedi, M.; Askari, F.B. 2009. Two Parameter Isotherms of Methyl Orange Sorption by Pinecone Derived Activated Carbon. Iran. J. Environ. Health Sci. Eng., 6 (4): 285-294.Setyowati, L. 1998. Pengaruh Penambahan Divinil Benzena (DVB) pada Kopolimerisasi Kationik Poli[eugenol-co-(divinil benzena)] dan Sifat Pertukaran Kation Kopoligaramnya (The Effect of divinylbenzene (DVB) Addition to Eugenol-DVB Cationic Copolymerization and Its Use As Cation-Exchanger), Thesis, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta, Indonesia.Shi, T.; Jia, S.; Chen, Y.; Wen, Y.; Du, C.; Guo, H.; Wang, Z. Adsorption of Pb(II), Cr(III), Cu(II), Cd(II) and Ni(II) onto a vanadium mine tailing from aqueous solution. J. Hazard. Mater. 2009, 169: 838-846, DOI: 10.1016/j.jhazmat.2009.04.020Sun, S.;Wang, A. Adsorption Kinetics of Cu(II) Ions Using N,O-Carboxymethyl-Chitosan. J. Hazard. Mater. 2006, B131: 103-111, DOI: 10.1016/j.jhazmat.2005.09.012Sun, S.; Wang, L.;Wang, A. Adsorption Properties of Crosslinked Carboxymethyl-chitosan Resin With Pb(II) as Template Ions. J. Hazard. Mater. 2006, B136: 930-937, DOI: 10.1016/j.jhazmat.2006.01.033Uzun, I.; Guzel, F. Adsorption of Some Heavy Metal Ions from Aqueous Solution by Activated Carbon and Comparison of Percent Adsorption Result of Activated Carbon with those of Some Other Adsorbents. Turk. J. Chem. 2000, 24: 291-297.Zou, X.; Pan, J.; Ou, H.; Wang, X.;Guan, W.; Li, C.; Yan, Y.; Duan, Y. Adsorptive removal of Cr(III) and Fe(III) from aqueous solution by chitosan/attapulgite composites: Equilibrium, thermodynamics and kinetics. Chem. Eng. J. 2011, 167: 112-121, DOI: 10.1016/j.cej.2010.12.009 
ADSORPTION CHARACTERISTIC OF IRON ONTO POLY[EUGENOL-CO-(DIVINYL BENZENE)] FROM AQUEOUS SOLUTION Fitrilia Silvianti; Dwi Siswanta; Nurul Hidayat Aprilita; Agung Abadi Kiswandono
Jurnal Natural Volume 17, Number 2, September 2017
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24815/jn.v17i2.8076

Abstract

A study on the adsorption characteristic of Iron onto Poly[eugenol-co-(divinyl benzene)] (EDVB) from aqueous solution has been conducted. EDVB was produced and characterized by using FTIR spectroscopy. The adsorption was studied by a batch method by considering the factors affecting the adsorption such as initial metal ion concentration, adsorption selectivity, and mechanism of adsorption using a sequential desorption method. The adsorption of Iron onto EDVB followed a pseudo-2 order kinetics model with the rate constant of 0,144 L2 mmol-1 min-1. The adsorption isotherm was studied with Tempkin, Langmuir and Freundlich models. The adsorption capacity (Qmax) obtained by Langmuir isotherms was 250mg.L-1 while the equilibrium value was 0.8 Lmg-1. A competitive adsorption study showed that EDVB is adsorbed selectively towards Iron rather than Chromium, Coppers and Cadmium ions. The interaction type of Iron onto EDVB was determined by a sequential desorption.Keywords: Polyeugenol; divinyl benzene (DVB); adsorption; Iron; FeReferencesAbasi, C. Y.; Abia, A.A.; Igwe, J.C. Adsorption of Iron (III), Lead (II) and Cadmium (II) Ions by Unmodified Raphia Palm (Raphia hookeri) Fruit Endocarp. Environ. Res. 2011, 5 (3), 104-113, ISSN: 1994-5396, Medwell Journals. DOI: 10.3923/erj.2011.104.113Baes, F. C.; Mesmer, R. E. The Hydrolisis of Cations; John Wiley: New York, 1976Bakatula, E.N.; Cukrowska, E.M.; Weiersbye, L.; Mihali-Cozmuta, L.;Tutu, H. Removal of toxic elements from aqueous solution using bentonite modified with L-histidine. Water Sci. Technol.2014, 70 (12),2022-2030, DOI: 10.2166/wst.2014.450Bhattacharyya, K.G.; Gupta, S.S. Adsorption of Fe(III) from Water by Natural and Acid Activated Clays: Studies on equilibrium isotherm, kinetics and thermodynamics of interactions. Adsorption. 2006, 12 (3), 185-204,DOI : 10.1007/s10450-006-0145-0Carmona, M..; Lucas, A.D.; Valverde, J.L.; Velasco, B.; Rodriguez, J.F. Combined adsorption and ion exchange equilibrium of phenol on Amberlite IRA-420.Chem. Eng. J.2006, 117, 155-160, Doi : 10.1016/j.cej.2005.12.013Debnath, S.; Ghosh, U.C. Kinetics, isotherm and thermodynamics for Cr(III) and Cr(VI) adsorption from aqueous solutions by crystalline hydrous titanium oxide. J. Chem. Thermodin. 2008, 40: 67-77, DOI: 10.1016/j.jct.2007.05.014Djunaidi, M.C.; Jumina; Siswanta, D.; Ulbricht, M. Selective Transport of Fe(III) Using Polyeugenol as Functional Polymer with Ionic Imprinted Polymer Membrane Method. Asian J. Chem. 2015, 27 (12): 4553-4562, DOI : 10.14233/ajchem.2015.19228Febriasari, A.; Siswanta, D.; Kiswandono, A.A.; Aprilita, N.H. Evaluation of Phenol Transport Using Polymer Inclusion Membrane (PIM) with Polyeugenol as a Carrier. Jurnal Rekayasa Kimia dan Lingkungan. 2016, Vol. 11, No. 2, 99-106, DOI: 10.23955/rkl.v11i2.5112Foldesova, M.; Dillinger, P.; Luckac, P. Sorption and Desorption of Fe(III) on Natural and chemically modified zeolite. J. Radioanal. Nucl. Chem. 1999, Vol. 242, No. 1 (1999), 227-230, DOI: 10.1007/BF02345926Gupta, V.K.;Sharma, S. Removal of cadmium and zinc from aqueous solutions using mud.Environ. Sci. Technol. 2002, 36: 3612-3617, DOI: 10.1021/es020010vHandayani, D.S. Sintesis kopoli(eugenol-DVB) sulfonat dari Eugenol Komponen Utama Minyak Cengkeh Szygium aromaticum (Synthesis of copoly(eugenol-DVB) sulfonic from main components of eugenol clove oil Szygium aromaticum). Biopharmacy Journal of Pharmacological and Biological Sciences. 2004, 2 (2): 53-57 ISSN: 1693-2242. url : https://eprints.uns.ac.id/id/eprint/856Harimu, L.; Matsjeh, S.; Siswanta, D.; Santosa, S.J. Synthesis of Polyeugenyl Oxyacetic Acid as Carrier to Separate Heavy Metal Ion Fe(III), Cr(III), Cu(II), Ni(II), Co(II), and Pb(II) that Using Solvent Extraction Mehod. Indo. J. Chem. 2009, 9 (2): 261-266.Ho, Y.S.; McKay, G. Pseudo-second Order Model for Sorption Processes. Process. Biochem. 1999, 34, 451-465, DOI: 10.1016/S0032-9592(98)00112-5Ho, Y.S.; McKay, G.; Wase, D.A.J.;Forster, C.F. Study of Sorption Divalent Metal Ions on to Peat. Adsorpt. Sci. Technol. 2000, 18: 639-650. DOI : 10.1260/0263617001493693Indah, S.; Helard, D.;Sasmita, A. Utilization of maize husk (Zea mays L.) as low-cost adsorbent in removal of iron from aqueous solution. Water Sci. Technol. 2016, 73 (12), 2929-2935, DOI: 10.2166/wst.2016.154Kiswandono, A.A.; Siswanta, D.; Aprilita, N.H.; Santosa, S.J. Transport of Phenol through inclusion polymer membrane (PIM) using copoly(Eugenol-DVB) as membrane carries. Indo .J. Chem. 2012, 12 (2): 105-112. Doi : 10.22146/ijc.667Kousalya, N.; Gandhi, M.R.; Sundaram, C.S.; Meenakshi, S. Synthesis of nano-hydroxyapatite chitin/chitosan hybrid bio-composites for the removal of Fe(III).Carbohyd. Polym. 2010, 82: 594-599, DOI:10.1016/j.carbpol.2010.05.013Kumar, K.V.; Porkodi, K.;Rocha, F. Langmuir-Hinshelwood kinetics – A theoretical study, Catalysis Communications. 2008, 9: 82-84, DOI:10.1016/j.catcom.2007.05.019Masel, R.I. Principles Adsorption and Reaction on Solid Surface; John Wiley Sons: Canada, 1996Moore, J. W.; Pearson, R.G. Kinetics and Mechanism Third Edition; John Wiley Sons: Canada, 1981.Ngah, W.S.W.; Ghani, S.A.; Kamari, A. Adsorption Behaviour of Fe(II) and Fe(III) Ions in Aqueous Solution on Chitosan and Cross-linked Chitosan Beads. Bioresource. Technol. 2005, 96: 443-450. DOI:10.1016/j.biortech.2004.05.022Rahim, E.A.; Sanda, F.; Masuda, T. Synthesis and Properties of Novel Eugenol-Based Polymers. Polymer Bulletin. 2004, Vol. 5, 93-100, DOI: 10.1007/s00289-004-0272-2Samarghandi, M.R.; Hadi. M.; Moayedi, M.; Askari, F.B. 2009. Two Parameter Isotherms of Methyl Orange Sorption by Pinecone Derived Activated Carbon. Iran. J. Environ. Health Sci. Eng., 6 (4): 285-294.Setyowati, L. 1998. Pengaruh Penambahan Divinil Benzena (DVB) pada Kopolimerisasi Kationik Poli[eugenol-co-(divinil benzena)] dan Sifat Pertukaran Kation Kopoligaramnya (The Effect of divinylbenzene (DVB) Addition to Eugenol-DVB Cationic Copolymerization and Its Use As Cation-Exchanger), Thesis, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta, Indonesia.Shi, T.; Jia, S.; Chen, Y.; Wen, Y.; Du, C.; Guo, H.; Wang, Z. Adsorption of Pb(II), Cr(III), Cu(II), Cd(II) and Ni(II) onto a vanadium mine tailing from aqueous solution. J. Hazard. Mater. 2009, 169: 838-846, DOI: 10.1016/j.jhazmat.2009.04.020Sun, S.;Wang, A. Adsorption Kinetics of Cu(II) Ions Using N,O-Carboxymethyl-Chitosan. J. Hazard. Mater. 2006, B131: 103-111, DOI: 10.1016/j.jhazmat.2005.09.012Sun, S.; Wang, L.;Wang, A. Adsorption Properties of Crosslinked Carboxymethyl-chitosan Resin With Pb(II) as Template Ions. J. Hazard. Mater. 2006, B136: 930-937, DOI: 10.1016/j.jhazmat.2006.01.033Uzun, I.; Guzel, F. Adsorption of Some Heavy Metal Ions from Aqueous Solution by Activated Carbon and Comparison of Percent Adsorption Result of Activated Carbon with those of Some Other Adsorbents. Turk. J. Chem. 2000, 24: 291-297.Zou, X.; Pan, J.; Ou, H.; Wang, X.;Guan, W.; Li, C.; Yan, Y.; Duan, Y. Adsorptive removal of Cr(III) and Fe(III) from aqueous solution by chitosan/attapulgite composites: Equilibrium, thermodynamics and kinetics. Chem. Eng. J. 2011, 167: 112-121, DOI: 10.1016/j.cej.2010.12.009 
Co-Authors Adhitasari Suratman Agung Abadi Kiswandono Ahmad Nasir Pulungan An Nissa F. Hayu An Nissa F. Hayu, An Nissa F. Bambang Rusdiarso Bambang Sutriyanto Bella Mellisani Beti Wulandari Candra Purnawan Christian W Huck Christian W Huck Dhian Nuri Bawani Dwi Siswanta Dwi Siswanta Dwi Siswanta Dwi Siswanta Eko Sri Kunarti Eko Suguharto Endang Tri Wahyuni Endang Tri Wahyuni Endang Tri Wahyuni Endang Tri Wahyuni Endang Tri Wahyuni Febriasari, Arifina Febriasari, Arifina Firda Ainun Nissa Fitrilia Silvianti Girsang, Ermi Guenther K Bonn Guenther K Bonn Hani Prima Rasydta Hasri Hasri Indriana Kartini Indriana Kartini Indriana Kartini Indriana Kartini Indriana Kartini Isna Nurhidayati Juniva Laila Sihombing, Juniva Laila Khusna Arif Rakhman, Khusna Arif Kinichi Morita Kuntari Kuntari Kusuma Putri Suwondo Mai Anugrahwati Marcelina Marcelina Mardiyah Kurniasih Mudasir Mudasir Mudasir Mudasir Mudasir Mudasir Mudasir Mudasir Muhammad Syahrir Nindya Tri Muliawati Nuryono Nuryono Pamungkas, Alam Reformasi Putra Rambat Rambat Rambat, Rambat Rania Bakry Rania Bakry Romadhona, Miftakhul Roto Roto Roto Roto Sarwendah Ratnawati Hermanto Satriyo Krido Wahono Satriyo Krido Wahono Siti Nurhayati Siti Nurhayati Sofy Herawati Ratnaningtyas Sri Juari Santosa Sri Juari Santosa Sri Juari Santosa Suherman Suherman Suherman, Suherman Sunarti Sunarti Suratno Suratno Suratno Suratno Takashi Hayashita Takashi Hayashita Taufik Abdillah Natsir Tri Joko Raharjo Wina Akmarina Wulandari Sutiawan Yuniar Yuniar