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Yessi Permana
1Inorganic & Physical Chemistry Research Division, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung, Jawa Barat 40132, Indonesia
Engineering

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One pot two-step borylation/fluorination reaction of dysobinin from Chisocheton macrophyllus and its cytotoxicity against cancer cell Huda, Muhammad Badrul; Nurlelasari; Safriansyah, Wahyu; Fajar, Mohamad; Widiyowati, Iis Intan; Supratman, Unang; Permana, Yessi; Budiman, Yudha P.
Communications in Science and Technology Vol 9 No 2 (2024)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.9.2.2024.1514

Abstract

Dysobinin is a naturally occurred limonoid, which is a specific form of triterpenoid, mostly found in certain plants, particularly the Meliaceae family. Overall, it has been found that limonoids have a wide range of biological functions. Typically, the compound comprises anticancer, antimicrobial, and anti-inflammatory properties. Even though dysobinin has shown some effectiveness, its potential in pharmacology, so far, is found limited. This study, therefore, aims to enhance the pharmacological properties of dysobinin through the addition of fluorine. To do this, a one-pot, two-step reaction comprising C-H borylation and selectfluor was used to turn dysobinin into two new compounds: 1,2-dihydro-6?-acetoxyazadirone (5) and 1?-fluorodysobinin (6). After the transformation, various spectroscopic methods, including UV (Ultraviolet), IR (infrared), MS (mass spectra), as well as NMR (1D and 2D) were applied to figure out the structures of the new compounds. Accordingly, of the derived compounds, 1?-fluorodysobinin showed significantly higher cytotoxicity against A549 lung cancer cells when compared to dysobinin.
Hydrogenolysis of furfuryl alcohol to 1,2-pentanediol catalyzed by first row transition metal salts Pratama, Muhammad Rafi; Irnanda, Istifhamy; Situmorang, Hendra Julius; Permana, Yessi; Qurbayni, Siti Hartinah; Wijaya, Husni Wahyu; Arrozi, Ubed Sonai Fahruddin
Communications in Science and Technology Vol 9 No 2 (2024)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.9.2.2024.1549

Abstract

The growing and relatively large market share of 1,2-pentanediol (1,2-PeD) has attracted attention of researchers to find effective and economically viable catalysts. One type of catalyst that can be used for synthesizing this compound is transition-metal-based catalysts, employed in the hydrogenolysis of furfuryl alcohol (FOL). In this study, the hydrogenolysis of furfuryl alcohol were performed with 2-propanol as the hydrogen source and transition metal salts as the catalysts. The used catalysts include first-row early and late transition metals, i.e., ZrOCl2·8H2O, VOSO4·H2O, FeSO4·7H2O, CuSO4·5H2O, NiCl2, Al(NO3)3·H2O, CoCl2, FeCl3·6H2O, and Zn(NO3)2·6H2O. It was found that ZrOCl2·8H2O, VOSO4·H2O, and FeCl3·6H2O demonstrated superior catalytic activity compared to the other catalysts. Optimal reaction conditions for these three catalysts were achieved at 150 °C for 1 hour, using 2-propanol as the hydrogen source. Under these reaction conditions, the ZrOCl?·8H?O catalyst achieved 95.5% conversion of FOL and 30.3% yield of 1,2-PeD, while the VOSO?·H?O catalyst attained 80.5% conversion of FOL and 36.9% yield of 1,2-PeD. Both results were obtained with a low catalyst concentration of 0.6 mmol%. Meanwhile, the FeCl3·6H2O catalyst converted 94.9% of FOL and yielded 30.9% of 1,2-PeD, using a lower catalyst concentration of 0.4 mmol%. Kinetic studies suggested that the reactions likely follow pseudo-first-order kinetics with experimental activation energies (Ea) of 65 kJ/mol, 55 kJ/mol, and 37 kJ/mol for ZrOCl?·8H?O, VOSO?·H?O, and FeCl?·6H?O catalysts, respectively. These findings highlight the potential of transition-metal-based catalysts in achieving high efficiency with low loading, emphasizing their suitability for industrial applications.
Synergetic effect of ZnO/NiO nanocomposite on the enhancement of photocatalytic degradation efficiency of dyes molecules Iasya, Yurin Karunia Apsha Albaina; Khoerunnisa, Fitri; Dwi, Sadina Sahitya; Putri, Restiani Alia; Nurhayati, Mita; Arrozi , Ubed Sonai Fahruddin; Permana, Yessi; Handayani, Murni; Astuti, Wijayanti Dwi; Da, Oh Wen; Irnanda, Istifhamy
Communications in Science and Technology Vol 10 No 1 (2025)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.10.1.2025.1583

Abstract

The discharge of organic dyes into water systems poses severe risks to human health and aquatic ecosystems. A remarkable technique that is increasingly recognized for dyes degradation is photocatalysis. This work aims to investigate the role of zinc oxide/nickel oxide (ZnO/NiO) nanocomposites in enhancing photocatalytic degradation efficiency of dyes molecules. The nanocomposites were prepared using a simple ultrasonication technique and analyzed through X-ray diffraction (XRD), scanning electron microscopy (SEM), and electrochemical impedance spectroscopy (EIS). The XRD pattern of the ZnO/NiO nanocomposites exhibited characteristic peaks aligned with the ZnO and NiO phases, referring to JCPDS standards. The SEM images of nanocomposites featured the rod and irregular flake-like structures with the average size of 80 nm. The nanocomposites showed the highest dye photodegradation efficiency (RB 93.65% and MO 94.82%) in view of a larger semicircular diameter and lowest band gap energy as verified by Nyquist plot and DFT calculation. These results emphasized the synergistic effect of ZnO/NiO nanocomposites in promoting dye photocatalytic degradation.
HKUST-1-Catalyzed Chan–Evans–Lam C–O Coupling Under Mild Conditions with Catalyst Reusability Sidik, Muhamad R. S.; Kurnia, Irwan; Permana, Yessi; Arrozi, Ubed S.F.; Ciptonugroho, Wirawan; Lestari, Witri Wahyu; Budiman, Yudha Prawira
Communications in Science and Technology Vol 10 No 2 (2025)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.10.2.2025.1837

Abstract

The Chan–Evans–Lam coupling refers to a valuable method for constructing C–O and C–N bonds under mild conditions. Nevertheless, the development of efficient and reusable heterogeneous catalysts remains limited. In this study, we investigated copper-based metal–organic frameworks as catalysts for C–O bond formation between 4-methoxyphenylboronic acid and phenol. The study revealed that HKUST-1 exhibited a significant enhancement in performance when compared to Cu-BDC, yielding up to 86% at room temperature and demonstrating superior accessibility of Cu2+ active sites. A systematic optimization of reaction parameters identified NEt3 as the most effective base, DCM as the optimal solvent, and a mild temperature increase to 40 °C as the key factor enabling a maximum yield of 94%. Studies on recyclability demonstrated that HKUST-1 exhibited high catalytic performance over multiple cycles without significant structural degradation, as confirmed by PXRD analysis. Overall, this work highlights HKUST-1 as an efficient, robust, and reusable heterogeneous catalyst for Chan–Evans–Lam C–O coupling, thus demonstrating its potential for sustainable synthetic applications.
Co-Authors Arrozi , Ubed Sonai Fahruddin Arrozi, Ubed S.F. Astuti, Wijayanti Dwi Budiman, Yudha P. Budiman, Yudha Prawira Ciptonugroho, Wirawan Da, Oh Wen Dwi, Sadina Sahitya Fajar, Mohamad Fitri Khoerunnisa Huda, Muhammad Badrul Husni Wahyu Wijaya Iasya, Yurin Karunia Apsha Albaina Iis Intan Widiyowati Irnanda, Istifhamy Kurnia, Irwan Lestari, Witri Wahyu Murni Handayani Nurhayati, Mita Nurlelasari Pratama, Muhammad Rafi Putri, Restiani Alia Qurbayni, Siti Hartinah Safriansyah, Wahyu Sidik, Muhamad R. S. Situmorang, Hendra Julius Ubed Sonai Fahruddin Arrozi Unang Supratman