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PEROLEHAN KEMBALI PERAK DARI LIMBAH SISA ANALISIS COD MENGGUNAKAN METODA ELEKTROLISIS Djaenudin Djaenudin; Mindriany Syafila
Purifikasi Vol 10 No 1 (2009): Jurnal Purifikasi
Publisher : Department of Environmental Engineering-Faculty of Civil, Environmental and Geo Engineering. Institut Teknologi Sepuluh Nopember, Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12962/j25983806.v10.i1.163

Abstract

The spent COD test solution has unique characteristics, i.e. small in volume and discontinued in production. However, it contains hazardous elements to environment such as heavy metals, i.e. silver, mercury, iron, and chromium, which could be having an economic value if can be reused. This research was subjected to the recovery of silver element the spent COD test solution using electrolysis method. The anode used was made from platinum sized 1 x 1 cm2, whereas copper was used as the cathode. The optimum silver recovery using the artificial waste of Ag2SO4 was 19.93% and the reaction rate constant value (k) was 0.0363 /minute from initial silver concentration of 199.375 mg/L to became 159.64 mg/L. This result was obtained on the experimental conditions of 5 cm electrode distance, 1 x 3 cm2 cathode surface area and DC supply voltage of 6 volt. The experiment using the spent COD test solution was carried out at electrode distance of 5 cm, cathode surface area of 1 x 3 cm2 and DC supply voltage of 6 volts. The silver recovery was 47.19% from initial silver concentration of 204.375 mg/L to be 107.92 mg/L and the reaction rate constant value (k) was 0.1053 /minute. The results showed that the increasing in DC supply voltage and the reducing in the electrode distance would increase the silver recovery.
PERILAKU SENYAWA POLYCYCLIC AROMATIC HYDROCARBONS (PAH) YANG TERKANDUNG DI DALAM PRODUCED WATER INDUSTRI MINYAK DI KOMPARTEMEN AIR DAN SEDIMEN LINGKUNGAN PERAIRAN ASIN Mindriany Syafila
Purifikasi Vol 10 No 2 (2009): Jurnal Purifikasi
Publisher : Department of Environmental Engineering-Faculty of Civil, Environmental and Geo Engineering. Institut Teknologi Sepuluh Nopember, Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12962/j25983806.v10.i2.178

Abstract

Polycyclic Aromatic Hydrocarbons (PAHs) are ubiquitous pollutants formed from both natural and anthropogenic sources. Produced water of crude oil industries contains PAHs, which in high concentrations could pollute the environment. Saline water environment model used in this research was an aerobic reactor which contains sediment collected from the estuary of Mahakam River. The sediment bacteria were first activated by glucose and toluene before it was exposed to the PAHs compound. Three PAHs compounds observed were naphthalene, anthracene, and phenanthrene. The result showed that it was difficult to determine the PAH degradation rate in the water compartment, because the PAHs were volatile and easily deposited. The degradation rate of naphthalene in the sediment compartment was the highest when compared to anthracene and phenanthrene. Furthermore, phenanthrene was the most undegradable compound.
STUDI KINETIKA PENYISIHAN ORGANIK PADA SEQUENCING BATCH REACTOR (SBR) AEROB DENGAN PARAMETER RASIO WAKTU PENGISIAN TERHADAP WAKTU REAKSI Mindriany Syafila
Purifikasi Vol 5 No 2 (2004): Jurnal Purifikasi
Publisher : Department of Environmental Engineering-Faculty of Civil, Environmental and Geo Engineering. Institut Teknologi Sepuluh Nopember, Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (388.763 KB) | DOI: 10.12962/j25983806.v5.i2.306

Abstract

This kinetic study was done using two kind of variations, namely loading variations (600, 1800, 3400 and 4800 mg/l COD) and fill-react ratio variations (2:2, 2:4, and 2:8) by investigating main parameters, namely COD, VSS and total volatile acid (TVA), beside the other data such as CO2, gas concentration, DO, temperature and pH. And to investigate the role of microorganism, control was conducted with the absence of biomass. During filling period, the yield coefficient was 0,42-0,88 gVSS/gCOD. During reacting period, the yield coefficient was 0,39-0,93 gVSS/gCOD and specific biomass decay rate constant (Kd) 0,021 hour-1.
KINERJA SEQUENCING BATCH REACTOR (SBR) AEROB PADA DEGRADASI GLUKOSA DENGAN VARIASI RASIO WAKTU PENGISIAN TERHADAP WAKTU REAKSI Mindriany Syafila
Purifikasi Vol 4 No 3 (2003): Jurnal Purifikasi
Publisher : Department of Environmental Engineering-Faculty of Civil, Environmental and Geo Engineering. Institut Teknologi Sepuluh Nopember, Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (321.937 KB) | DOI: 10.12962/j25983806.v4.i3.332

Abstract

An aerobic sequencing batch reactor (SBR) was used to investigate the optimum organic concentration and the ratio of fill – react time. The synthetic wastewater used had approximately COD of 10,000 mg/l; 8000 mg/l; 4000 mg/l; and 2000 mg/l, in the room temperature between 23 – 26 °C. The ratio of fill – react time was (2:2) hours, (2:4) hours, and (2:8) hours. The results showed that the optimum COD reduction of 70.62% was achieved in the influent concentration of approx. 4000 mg/l COD with the fill-react ratio of (2:2) hours.
POTENSI PEMBENTUKAN PRODUK HASIL DEGRADASI SENYAWA ORGANIK LIMBAH CAIR TAHU MENGGUNAKAN ANAEROBIC BAFFLED REACTOR LIMA KOMPARTEMEN Puteri Myrasandri; Mindriany Syafila
Jurnal Teknik Lingkungan Vol. 18 No. 1 (2012)
Publisher : ITB Journal Publisher, LPPM ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/jtl.2012.18.1.8

Abstract

Abstrak:  Industri  tahu di Indonesia  kebanyakan  merupakan  industri  skala kecil yang berkembang  dengan  pesat. Penggunaan  air  yang  signifikan  pada  proses  pembuatan  menghasilkan  limbah  cair  yang  jumlahnya  besar  pula. Teknologi pengolahan secara biologi dengan memanfaatkan  bakteri merupakan alternatif   yang potensial  untuk  dikembangkan  karena  teknologinya  sederhana,  dan  hemat  energi.  Salah  satu  contohnya  adalah Anaerobic Baffled Reactor yang merupakan modifikasi dari tangki septik konvensional dengan adanya penambahan sekat-sekat  pada tangki septik. Penelitian  ini bertujuan  untuk mengetahui  proses pengolahan  limbah cair industri Tahu  di  Bandung  Utara  dengan  menggunakan   Anaerobic   Baffled  Reactor  skala  laboratiorium   dengan  lima kompartemen. Pada percobaan ini akan dipelajari degradasi senyawa organik terlarut pada tiap kompartemen. Beban Chemical Oxygen Demand terlarut influen adalah sebesar 8.000 mg/L dan reaktor dioperasikan  pada HRT 96 jam dan 72 jam. Kondisi steady-state diindikasikan dengan nilai Chemical Oxygen Demand terlarut yang stabil, dengan produksi  Total  Asam  Volatil  dan etanol  paling  besar  terjadi  pada  waktu  operasi  jam  ke-48.  Penyisihan  organik tertinggi dihasilkan oleh HRT 96 jam sebesar 53,34%. Biogas berupa gas metan yang terbentuk sebesar 14,0-14,6% (v/v) pada HRT 96 jam dan 29,1-29,6% (v/v) menunjukkan proses asidogenesis yang lebih dominan daripada metanogenesis.Kata kunci: Anaerobic Baffled Reactor, biogas, limbah cair tahu, Chemical Oxygen Demand terlarut, Total Asam Volatil. Abstract: Tofu industry is one of the fast-growing industries among the small-scale industries in Indonesia. In the process of tofu production, the significant usage of water results in tremendous amount of wastewater. Treatment of tofu wastewater has become an obstacle because of the high capital cost and limited resources. Biological treatment using microorganism, more specifically bacteria, is a potential alternative to be developed because the technology is relatively simple and has a low energy usage. An example of this kind of treatment is Anaerobic Baffled Reactor, which is a modification  of conventional  septic tank with the addition of baffles. In this experiment,  a laboratory- scale  Anaerobic  Baffled  Reactor  with  five  compartments  was  used.  The  degradation  of organic  matter  in each compartment was studied. Tofu wastewater used in this experiment was from a tofu industry in North Bandung Area with soluble COD 8.000 mg/L. Reactor was operated at HRT of 96 and 72 hours. Steady-state condition achieved was indicated  by the stabilized  soluble  Chemical  Oxygen  Demand.  The highest  Volatile  Fatty  Acid and ethanol production occur in the 48th  hours of reactor operation. Significant organic removal occur on HRT of 96 hours at 53,34%. The production of biogas as methane was 14,0-14,6% (v/v) at HRT 96 hours and 29,1-29,6% (v/v) at HRT 72 hours showing a dominant acidogenesis process compared to methanogenesis process.Key words: Anaerobic Baffled Reactor, biogas, Soluble Chemical Oxygen Demand, tofu wastewater, Volatile Fatty Acid
REDUKSI UKURAN ADSORBEN UNTUK MEMPERBESAR DIAMETER PORI DALAM UPAYA MENINGKATKAN EFISIENSI ADSORPSI MINYAK JELANTAH Marsen Alimano; Mindriany Syafila
Jurnal Teknik Lingkungan Vol. 20 No. 2 (2014)
Publisher : ITB Journal Publisher, LPPM ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/jtl.2014.20.2.8

Abstract

Abstrak: Pada penelitian yang telah dilakukan, dengan reduksi ukuran partikel hingga dibawah 2 μm dapat menghasilkan diameter pori yang masuk klasifikasi mesopori (2 "“ 50 nm). Uji kemampuan bentonit dan  zeolit  mesopori  sebagai  penjerap  untuk  meningkatkan  kualitas  minyak  jelantah  agar  dapat digunakan kembali telah dilakukan dengan metode batch. Konsep batch dipilih karena tujuan penelitian adalah untuk mengetahui secara pasti parameter yang paling berpengaruh terhadap proses penjerapan dari variabel yang telah ditentukan. Penelitian dilakukan dengan variasi waktu 40, 55, dan 70 menit. Dosis penjerap sebagai variabel utama ditentukan 5, 15, dan 25%. Kecepatan pengadukan merupakan parameter yang berpengaruh terhadap tingkat kesempurnaan perlekatan ditentukan pada skala 3 dan 6 (225 dan 450 RPM). Dari hasil penelitian ditunjukkan bahwa kemampuan penjerapan bentonit dan zeolit mesopori dapat secara sempurna menghasilkan kualitas minyak goreng yang baik dari parameter warna, dimana kondisi optimum tercapai pada waktu proses 70 menit, dosis penjerap sebesar 25%, dan kecepatan pengadukan pada skala 6 (450 RPM) dengan nilai absorbansi sebesar 0,0117 Abs untuk bentonit (efisiensi 88,26%) dan 0,0100 Abs (efisiensi 89,97%) untuk zeolit dengan blanko minyak goreng baru sebesar 0,0000 Abs dan minyak jelantah sebesar 0,0997 Abs yang diukur pada panjang gelombang489,2 nm. Selain itu, hasil percobaan mendapatkan efisiensi penurunan nilai asam lemak bebas optimum mencapai 68,75% (bentonit) dan 62,50% (zeolit), jauh diatas hasil percobaan dengan penetralan basa dan menggunakan adsorben bentonit teraktivasi (31,28%) dan tanah diatomit (43,36%). Dari hasil tersebut maka dapat ditarik kesimpulan bahwa reduksi ukuran adsorben yang akan meningkatkan luas permukaan, volume pori, dan radius pori dapat meningkatkan efisiensi adsorpsi minyak jelantah pada parameter warna dan asam lemak bebas secara signifikan Kata kunci: bentonit, zeolit, mesopori, minyak jelantah, penjerapan Abstract : In the research result, by using particle size reduction to less than 2 μm, it can produce pore diameter were into mesoporous classification (2-50 nm). The ability testing for bentonite and zeolite mesopores as an adsorbent to improve the quality of used cooking oil so it can reuse, has been conducted by using a batch method. The batch concept selected because of research purpose was to determine the proper parameters that most influenced on the adsorbency process from predetermined variables. The research was conducted with the variation of time of 40, 55, and 70 minutes. The adsorbent dose as the main variable determined at 5, 15, and 25%. Stirring speed was a parameter affected the level of adhesion perfection that is determined on a scale of 3 and 6 (225 and 450 RPM). From the study results, indicated that the adsorbent ability of bentonite and zeolite mesopores could produce a good quality of cooking oil perfectly from color parameters, where the optimum condition reached during 70 minutes in process, adsorbent dose by 25%, and stirring speed on a scale of 6 (450 RPM) with the absorbency values of 0.0117 Abs(efficiency 88.26%) for bentonite and 0.0100 Abs (efficiency 89.97%) for zeolite, with a new form of cooking oil at 0.0000 Abs and used cooking oil at 0.0997 Abs. The form used was origin cooking oil before it used for frying, and its wavelength spectrophotometer used at 489.2 nm. In addition, the results of the experiment to get the efficiency of free fatty acid impairment optimum reach 68.75% (bentonite) and 62.50% (zeolite), well above the results of experiments with alkaline neutralization and use of activated bentonite adsorbent (31.28%) and soil diatomite (43.36%). From these results it can be concluded that the reduction in the size of the adsorbent will increase the surface area,  pore  volume  and  pore  radius  can  enhance  the  adsorption  efficiency  of  cooking  oil  on  the parameters of color and free fatty acids significantly. Key words: bentonite, zeolites, mesoporous, used cooking oil, adsorption 
KINETIKA DEGRADASI LIGNIN DARI LIMBAH CAIR INDUSTRI PULP AND PAPER MENGGUNAKAN ADVANCED OXIDATION PROCESS (AOP) DENGAN KOMBINASI OZON DAN HIDROGEN PEROKSIDA Ardhi Ristiawan; Mindriany Syafila
Jurnal Teknik Lingkungan Vol. 21 No. 1 (2015)
Publisher : ITB Journal Publisher, LPPM ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/jtl.2015.21.1.6

Abstract

Abstrak: Secara umum, air limbah industri pulp and paper mengandung produk ekstraktif, karbohidrat, dan lignin. Lignin dan senyawa chlorinated organic merupakan senyawa utama yang menjadi concern dalam potensi pencemaran lingkungan. Pengolahan biologi secara konvensional hanya dapat mengolah sebagian senyawa organik yang terkandung dalam air limbah karena beberapa senyawa dalam air limbah industri pulp and paper merupakan senyawa persisten. Advanced oxidation process (AOP) merupakan alternatif dalam mendegradasi senyawa resistan yang terdapat dalam limbah cair industry pulp and paper. Prinsip pada proses AOP adalah pembentukan hidroksil radikal (OH*) yang merupakan molekul dengan kemampuan oksidasi yang sangat kuat sehingga dapat mendegradasi senyawa organik kompleks menjadi CO2 dan H2O. Salah satu teknologi AOP adalah O3/H2O2 (peroxone). Penggunaan metode ini lebih efektif jika dibandingkan dengan penggunaan O3 atau H2O2 secara sendiri-sendiri Pada penelitian ini akan dilakukan proses AOP menggunakan O3/H2O2 untuk mendegradasi lignin. Variasi feeding rate ozon, H2O2, dan waktu dilakukan pada sampel limbah cair untuk mengetahui kondisi optimal. Hasil menunjukkan bahwa penambahan dosis H2O2 pada proses ozonasi dapat meningkatkan efisiensi proses. Namun pada konsentrasi H2O2 berlebih dapat menjadi scavenger sehingga menurunkan efisiensi proses. Kondisi optimum diperoleh pada feeding rate ozon 26,7 ppm/dtk dan dosis H2O2 selama 2 jam pada pH asli limbah (7-8). Penyisihan COD pada kondisi tersebut sebesar 28% dan penyisihan lignin sebesar 88%. Biodegradabilitas air limbah menunjukkan peningkatan. Rasio BOD/COD meningkat dari 0,11 menjadi 0,33. Kata kunci: Advanced Oxidation Process (AOP), ozon, hidrogen peroksida, lignin Abstract: In general, pulp and paper wastewater contain extractive products, carbohydrates and lignin. Lignin and chlorinated lignin are the main compounds that could be potentially pollute environment. Conventional biological treatments only treat organic compounds partially because some organic compounds in pulp and paper wastewater are persistent organic compounds. Advanced oxidation process (AOP) is an alternative to degrade resistant compounds that contained in wastewater from pulp and paper industry. The principle of AOP is formation of hydroxyl radicals (OH*) which is a molecule with a very strong oxidizing ability that can degrade complex organic compounds to CO2 and H2O. O3/H2O2 (peroxone) is one of AOP's technologies. This method is more effective then uses O3 or H2O2 alone. This study conducted AOP process using O3/H2O2 for lignin removal. Variations of ozone feeding rate, H2O2, and reaction time conducted to determine the optimal condition. Results showed that the addition of H2O2 doses on ozonation process can improve the efficiency of the process. But the excedd concentration of H2O2 could be a scavenger thus reducing the efficiency of the process. The optimum condition obtained in the ozone feeding rate of 26.7 ppm/sec and 100 mg/l dose of H2O2 for 2 hours at the original pH of wastewater (7-8) with 28% COD removal and 88% lignin removal. Ozonation combined by H2O2 increased biodegradability of wastewater. BOD/COD ratio increased from 0.11 to 0.33. Keywords: Advanced Oxidation Process (AOP), ozone, hydrogen peroxide, lignin
PENGARUH PLAT GRAFIT DAN TEMBAGA TERHADAP KINERJA PROSES PENGOLAHAN LIMBAH CAIR INDUSTRI BATIK YANG MENGANDUNG LOGAM ZN MENGGUNAKAN METODE ELEKTROLISIS Robby Hermawan; Mindriany Syafila
Jurnal Teknik Lingkungan Vol. 23 No. 1 (2017)
Publisher : ITB Journal Publisher, LPPM ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.tl.2017.23.1.2

Abstract

Abstrak: Batik merupakan salah satu budaya warisan dunia yang telah ditetapkan UNESCO. Semenjak saat itu permintaan produksi batik meningkat. Limbah cair batik telah banyak diolah dengan berbagai macam proses biologi. Namun pada penelitian ini akan mengolah limbah cair batik dengan pengolahan secara fisika-kimia. Elektrolisis akan memecah molekul air limbah dengan aliran arus listrik searah dan bantuan senyawa elektrolit seperti NaCl sehingga dihasilkan reaksi redoks. Limbah cair berasal dari industri batik rumahan yang terletak di kawasan lembang. Limbah cair diolah menggunakan dua macam variasi elektrolisis yaitu, tegangan dan jenis elektroda. Variasi pertama elektroda yang digunakan adalah grafit pada anoda maupun katoda dan akan dialirkan tegangan yang bervariasi mulai dari 5 volt, 15 volt dan terakhir 48 volt. Variasi yang kedua adalah penggunaan grafit pada anoda dan tembaga pada katoda dengan tegangan yang dialirkan sebesar 5 volt, 15 volt dan 48 volt. Berdasarkan uji karakteristik awal limbah ditemukan bahwa Zn sebesar 340,76 mg/l. Dengan pengolahan elektrolisis variasi pertama menggunakan elektroda grafit-grafit dihasilkan penyisihan Zn optimum pada tegangan 48 volt selama 8 jam sebesar 89,74% dan variasi dengan grafit-tembaga optimum pada tegangan 48 volt selama 48 jam sebesar 90,26%. Variasi menggunakan pH dan NaCl pada elektroda grafit-grafit dihasilkan 92,73% penyisihan pada pH 10 dan NaCl 0 gr/l. pada elektroda grafit-tembaga penyisihan sebesar 94,7% dengan pH 10 dan NaCl 5 gr/l. Kata kunci: elektrolisis, anoda, katoda, grafit, tembaga Abstract: Batik is one of the world's cultural heritage that has been designated by UNESCO. Since that time the demand for batik production increases. Batik wastewater has been treated with a variety of biological processes. In this study, Batik wastewater will treat with physico-chemical process. Electrolysis will break down the wastewater molecules to flow electric current direction and assistance electrolyte compounds such as NaCl so that the resulting redox reactions. Home industrial wastewater which located in the lembang. Wastewater is processed using two kinds of electrolysis variations, those are voltage and type of electrodes. First variation electrode used is graphite on the anode or cathode and will be streamed voltages ranging from 5 volts, 15 volt and 48 volt. The second variation is the use of graphite in the anode and copper cathode supplied with the voltage of 5 volts, 15 volts and 48 volts. Based on preliminary detected metal is Zn amounted to 340,76 mg/L. With the first variation electrolysis process using graphite-graphite electrodes most optimum Zn removal at 8 th hour with 48 volt is 89,74% and using graphite-copper electrodes most optimum zn removal at 48 th hour and 48 volt is 90,26%. Variation using pH and NaCl with graphite-graphite electrodes resulted 92,73% zn removal at pH 10 and NaCl 0 gr/l.Using graphite-copper electrodes resulted 94,7% zn removal at pH 10 and NaCl 5 gr/l. Keywords: electrolysis, anode, catode, graphite, copper
Adsorption of Dyes Using Graphene Oxide-Based Nano-Adsorbent: A Review Danar Arifka Rahman; Qomarudin Helmy; Mindriany Syafila; Andri Gumilar
Jurnal Presipitasi : Media Komunikasi dan Pengembangan Teknik Lingkungan Vol 19, No 2 (2022): July 2022
Publisher : Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (915.863 KB) | DOI: 10.14710/presipitasi.v19i2.384-397

Abstract

Graphene Oxide (GO) based adsorbents have attracted much attention from researchers because there have been many reports that they are effective for removing dyes from aqueous environments. That is because GO has good mechanical, electrical, optical and chemical properties, so graphene and its derivatives, such as graphene oxide, have been used in various applications in the field of environmental management. Modifying GO into nano size is an effort to improve its performance in removing dyes. This review uses a database from Science Direct, Google Scholar and Springer, which was screened using graphene oxide, pigments, adsorption and nano adsorbent. The performance of the nano adsorbent showed quite good results in the removal of dyes. The isotherm model suitable for adsorption varies between Langmuir, Freundlich and Redlich-Peterson isotherms. Pseudo-second-order (PSO) is the best model to explain the adsorption process kinetics. Nano-adsorbent modification can be reused at least five times with a reduced adsorption capacity of 4-8%. Studies related to adsorption with GO-based nano adsorbents show promising results in pollutant removal. Still, aspects such as synthesis method, surface functional groups interaction and dye ions and the stability of synthesis products need to be investigated further.
Methylene Blue Adsorption by Activated Carbon and Nano–Activated Carbon from Biomass Waste: A Review Mindriany Syafila; Qomarudin Helmy; Akhmad Masykur Hadi Musthofa
Jurnal Presipitasi : Media Komunikasi dan Pengembangan Teknik Lingkungan Vol 19, No 3 (2022): November 2022
Publisher : Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (887.568 KB) | DOI: 10.14710/presipitasi.v19i3.553-565

Abstract

Dyes are becoming increasingly prevalent in wastewater, and their presence caused serious threats to the environment. One of the most widely used dyes is methylene blue which has been used in the textile industry to dye cotton, wool, and silk. As a solution to this problem, using biomass (usually considered agricultural or plantation waste) as activated carbon is an important issue. Because based on previous studies, these materials are not only abundant and affordable but also have high efficiency in removing dye. Therefore, this paper will provide a further review of the latest research on the use of activated carbon from biomass as an adsorbent for methylene blue, which includes the conversion process of biomass into activated carbon, the mechanism of methylene blue adsorption, the factors that influence adsorption process, and the characteristics of activated carbon. In addition, it also reviewed the implementation of nanotechnology on activated carbon from biomass to adsorb with methylene blue.