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Journal : Jurnal Teknik Kimia dan Lingkungan

Aplikasi Response Surface Methodology pada Optimasi Penambahan Blast Furnace Slag Terhadap Waktu Pengikatan dan Kuat Tekan Semen Hardjono Hardjono; Cucuk Evi Lusiani; Agung Ari Wibowo; Mochammad Agung Indra Iswara
Jurnal Teknik Kimia dan Lingkungan Vol. 4 No. 1 (2020): April 2020
Publisher : Politeknik Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (642.64 KB) | DOI: 10.33795/jtkl.v4i1.150

Abstract

The production of clinker consumes high energy and causes high production cost of cement industry. It can be reduced by adding blast furnace slag as a mixture in cement production. The blast furnace slag - clinker mixture can produce cement with setting time and compressive strength according to SNI. The effect of the addition of blast furnace slag as a clinker mixture to the setting time and compressive strength of cement can be optimized by response surface methodology (RSM) using Central Composite Design (CCD). Optimization by using RSM aims to determine the optimum condition of the blast furnace slag – clinker mixture to the initial setting time, final setting time, and compressive strength. ANOVA test results and response surface analysis show that the addition of blast furnace slag into the cement mixture has a significant influence on the initial setting time, final setting time, and compressive strength. The addition of 5% blast furnace slag with 92.5% clinker in the mixture of clinker and gypsum is the optimum condition which gives a significant effect on the response variable.
Simulasi CHEMCAD: Studi Kasus Distilasi Ekstraktif pada Campuran Terner n-Propil Asetat/n-Propanol/Air Agung Ari Wibowo; Cucuk Evi Lusiani; Rizqy Romadhona Ginting; Dhoni Hartanto
Jurnal Teknik Kimia dan Lingkungan Vol. 2 No. 2 (2018): October 2018
Publisher : Politeknik Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (743.916 KB) | DOI: 10.33795/jtkl.v2i2.75

Abstract

Pemisahan n-propil asetat dari campuran terner n-propil asetat/n-propanol/air merupakan salah satu proses yang tidak dapat dilakukan dengan distilasi sederhana. Adanya azeotrop terner minimum dari campuran tersebut menyebabkan n-propil asetat hanya dapat dipisahkan dari campuran n-propanol dan air salah satunya dengan metode distilasi ekstraktif. Distilasi ekstraktif merupakan proses vaporisasi parsial dengan menambahkan suatu agen pemisah non-volatil yang disebut sebagai sovent atau agen ekstraktif. Solvent yang digunakan dalam simulasi proses ini adalah campuran DMSO (Dimetil Sulfoksida) dan Gliserol dengan komposisi 50 % massa dengan perbandingan 1:2 untuk massa umpan kolom : solvent. Feed yang digunakan adalah n-propanol (10 kmol/jam) dan asam asetat (13 kmol/jam) masing-masing pada suhu 25°C dan tekanan 101,3 kPa. Hasil n-propil asetat terbaik diperoleh saat solvent diumpankan pada stage 5 dengan fraksi mol n-propil asetat pada distilat 0,9975 disertai dengan minimumnya energi reboiler yang digunakan pada konfigurasi kolom ini. n-Propyl acetate separation of the n-propyl acetate /n-propanol/water mixture composition can't be done by simple distillation. The existence of minimum ternary azeotrope on the mixture causes n-propyl acetate can be separated only by extractive distillation method. Extractive distillation is a partial vaporization process in the presence of a non-volatile separating agent called as solvent or extractive agent. Solvent used in the simulation process is DMSO (Dimethyl Sulfoxide)-Glycerol mixture (50% mass) with a ratio of 1: 2 for column feed : solvent. n-Propanol (10 kmol/hour) and acetic acid (13 kmol/hour) are fed into reactor (before extractive distillation process) at 25°C and 101.3 kPa, respectively. The best results of n-propyl acetate were obtained when the solvent was fed to stage 5 in which mole fraction of n-propyl acetate in distillate 0.9975 accompanied by the minimum reboiler energy used in this column configuration.