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JURNAL ATOMIK
Published by Universitas Mulawarman
ISSN : 25490052     EISSN : 25490052     DOI : -
Jurnal Atomik (JA) is published twice a year (March and August) by Department of Chemistry, Faculty of Mathematics and Natural Sciences, Mulawarman University. Jurnal Atomik is a media for graduate students of Department of Chemistry to publish their research articles in Chemistry field including Analytical Chemistry, Inorganic Chemistry, Physical Chemistry, Organic Chemistry, and Biochemistry. The research articles that be submitted to Jurnal Atomik have to be approved by Editorial Board and in accordance with the rules of writing approved by Editor of Jurnal Atomik.
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Articles 194 Documents
PEMBUATAN BIOETANOL DARI BIJI LAI (Durio kutejensis) Aditya, Roy; -, Alimuddin; Kartika, Rudi
JURNAL ATOMIK Vol 1 No 1 (2016)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Durian Lai (Durio kutejensis) merupakan buah lokal Kalimantan. Sejauh ini biji buah lai belum dimanfaatkan hanya dibuang begitu saja sebagai limbah, kandungan karbohidrat yang tinggi mencapai 47,6 %. Penelitian ini bertujuan untuk mengetahui konsentrasi amonium sulfat dan waktu fermentasi terbaik terhadap kadar bioetanol yang dihasilkan. Proses hidrolisisi pati dilakukan secara  enzimatis melalui tahap liquifikasi dan sakarifikasi dengan menggunakan enzim alfa-amilase dan glukolase yang akan mengkonversi pati menjadi glukosa. Glukosa hasil hidrolisis ditambahkan amonium sulfat sebagai sumber nutrisi dengan variasi 0,1 %; 0,3 % dan 0,5 % (b/v) kemudian difermentasi menggunakan jamur Saccharomyces cereviceaea dengan variasi waktu 4, 5 dan 6 hari. Pemurnian bioetanol dilakukan dengan proses destilasi. Analisa kadar etanol menggunakan kromatografi gas. Hasil penelitian menunjukkan penambahan nutrisi amonium sulfat yang paling optimum adalah 0,3 % (b/v) dan waktu fermentasi yang optimum adalah 6 hari dengan kadar etanol sebesar 9,403 %. Kata Kunci : Biji lai (Durio kutejensis), ammonium sulfat, fermentasi, bioetanol
Pembuatan dan Karakterisasi Membran Selektif Ion Timbal (II) dengan Menggunakan Etilen Diamin Tetra Asetat (EDTA) sebagai Ionofor Waqifah, Ummul; Panggabean, Aman S.; Akkas, Erwin
JURNAL ATOMIK Vol 2 No 1 (2017)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

A research about preparation and characterization of Plumbum (II) ion selective membrane using a PVC based on ethylene diamine tetraacetate as ionophores have been done. Ethylene diamine tetra acetate (EDTA) was able to coordinate with Pb2+ and increase the conductivity of the membrane. Ethylene diamine tetra acetate (EDTA) as the main ingredient mixed with polyvinylchloride (PVC) as a matrix whose first dissolved using tetrahydrofuran (THF), added dioctyl phat alate (DOP) as a plasticizer. The membrane was soaked with Pb2+ for 2 days and membrane absorption ability of EDTA to the metal dopant Pb2+, and measured using atomic absorption spectrophotometer (AAS). Membrane absorption ability of the dopant metal Pb2+ retrieved the percent absorption was 76.01 % at the optimum composition of the membrane with a ratio of EDTA: PVC: DOP is 60: 30: 10. EDTA membrane characterization results with Fourier transform infrared spectroscopy (FT-IR) showed specific functional groups on the membrane EDTA.
PENGARUH ION PENGGANGGU Pb2+ DAN Fe2+ TERHADAP ELEKTRODEPOSISI LOGAM KADMIUM (Cd) DALAM SAMPEL AIR Miu, Agustinus; -, Alimuddin; Yusuf, Bohari
JURNAL ATOMIK Vol 1 No 1 (2016)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

The research was performed about interferes between of ion Pb2+ and Fe2+ on electrodeposition of ion Cadmium (Cd) in the water sample with electrode Al-Al. Electrolysis on solution 3CdSO4. 8H2O with three parameters, like time variation of electrolysis, influence variation of concentration Pb2+ ions and  influence of mix variation concentration of ions Pb2+ and Fe2+. The results showed that the longer electrolysis, more metal deposition on the electrode. Based on observation, variation the number level of metals Cadmium (Cd) that deposition on the electrode was up 83.62 % on 120 minutes. The variations of addition of ion Pb2+ (2, 4, 6, 8 and 10 mg/L) obtained percent decrease in the level of disruption to in a solution of ion Cadmium (Cd) with average 21.53 % with every addition concentration of disruptor ion Pb2+ give influence 0.21 %. The variations of the addition disruptor ion Pb2+ and Fe2+ (2, 4, 6, 8 and 10 mg/L) obtained percent decrease of disruption in solution of ion Cadmium (Cd) with result 18.46 %, with each addition of ion Pb2+ and Fe2+ obtained 0.96 %. This showed that the addition of the ion disruptor on proccess electrodeposition  given influence on Cadmium (Cd) electrodeposition itself, but for every addition of concentration given less significant effects. Keywords: Electrodeposition, electrode Al-Al and decrease percentace.
PENGEMBANGAN METODE RAPID TEST DALAM PENENTUAN ASH CONTENT DAN CALORIFIC VALUE BATUBARA DI LABORATORIUM PT JASA MUTU MINERAL INDONESIA Kumalasari, Anisa; Panggabean, Aman Sentosa; Akkas, Erwin
JURNAL ATOMIK Vol 2 No 1 (2017)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

A research on development of rapid test methods for two parameters, calorific value and ash content, based on the needs of minimum time analysis has been conducted. This study aims to determine whether the analytical performance of rapid test methods is comparable with the standard methods. The results showed that the standard and the rapid test method have good analytical performance. Accuracy results which is expressed as recovery percentage show that the calorific values of both methods were in the range of 99.75 % - 100.40 % and the ash content values ​​with both methods were in the range of 93.33 % - 103.70 %. Precision results by CV percentage showed that the calorific value were 0.21 % and 0.23 %, and the value of ash content were 4.03% and 4.28%. For the ruggedness parameter test, the success rate was almost for the entire parameter, excepts for precision test where the ash content value obtained has CV percentage ≥ 5 %. Nevertheless, the overall parameters of the test and the analytical performance analysis are extremely good and acceptable according to the references and a rapid test method can be used as an alternative method.
VALIDASI METODE RAPID TEST DALAM PENENTUAN TOTAL MOISTURE, ASH CONTENT, CALORIFIC VALUE (AR) PADA BATUBARA TERHADAP STANDAR ISO UKURAN 3 MM PT. KALTIM PRIMA COAL Sari, Ermalia Lintang; Panggabean, Aman Sentosa; Hindryawati, Noor
JURNAL ATOMIK Vol 1 No 2 (2016)
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Abstract

Penelitian validasi metode rapid test dalam penentuan total moisture, ash content, calorific value (as received) pada batubara terhadap standar ISO (International Organization for Standardizations) dengan ukuran 3 mm (studi kasus di PT. Kaltim Prima Coal) telah dilakukan. Tujuan penelitian ini adalah mengetahui perbedaan pada total moisture, ash content, calorific value jika dilakukan dalam basis (ar) dan mengetahui hasil jika batubara yang digunakan dalam operasional berukuran 3 mm. Berdasarkan penelitian yang telah dilakukan dengan menggunakan batubara ukuran 3 mm diperoleh hasil pada total moisture dan ash content untuk batubara ini tidak terdapat perbedaan dan dapat digunakan dalam operasional laboratorium, sedangkan pada calorific value terdapat perbedaan pada batubara ini. Dalam penentuan ini harus tetap memperhatikan range varian dari nilai reproducibility pada setiap parameter batubara.
UJI FITOKIMIA DAN PENENTUAN AKTIVITAS ANTIOKSIDAN DARI MADU Trigona incisa Gunawan, Rio; -, Erwin; -, Syafrizal
JURNAL ATOMIK Vol 3 No 1 (2018)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Trigona Incisa honey is flower nectar and pollen are known to have properties that are very good for health used as ingredients or cosmetic. This study aims to determine the content of secondary metabolites and determination of antioxidant activity of honey Trigona incisa which is a natural product that is found. Do fractionation using ethanol, n-hexane and ethyl acetate determination of the content of secondary metabolites was conducted using harbone and antioxidant activity was determined by testing against DPPH free radicals by measuring the absorbance of DPPH (diphenyl -1- using 2,2- picrylhidrazyl) at a wavelength of 517 nm. Phytochemical test results to the fraction of ethanol, ethyl acetate and n-hexane of Honey Trigona incisa. Showed that the alkaloid compounds, Triterpenoid and Flavonoids present in fractions of ethanol and ethyl acetate fraction. Alkaloid contained in n-hexane fraction. The results showed the ethanol and ethyl acetate fractions thought to contain flavonoid, while the antioxidant activity of the ethyl acetate fraction larger than the fraction of n-hexane and ethanol role in this case amounted to 97.00 ppm, 249 ppm and 233.85 ppm. This shows that the ethyl acetate fraction contains more antioxidant components.
ISOLASI DAN KARAKTERISASI LIPASE DARI KECAMBAH BIJI ALPUKAT (Persea americana Mill) Sya'bani, Nurillah; Astuti, Winni; Pratiwi, Djihan Ryn
JURNAL ATOMIK Vol 2 No 2 (2017)
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Abstract

Isolation and determination of optimum lipase conditions from Avocado seeds germination (Persea americana Mill) have been done. The purpose of this study is to determine the optimum working conditions and lipase specific activity of avocado seeds germination. Lipase was isolated using homogenization and centrifugation techniques. The crude extract of the enzyme containing the lipase produced from avocado seeds germination was used for the determination of total protein concentration and tested its activity on the pH conditions, temperature, and optimum substrate concentration with different with various variations. Determination of total concentration was done by Bradford method, while the determination of optimum working conditions and lipase specific activity was performed by titrimetric method. The results showed that total protein concentration in avocado seeds germination was 458 μg / mL. The optimum working conditions on avocado seed sprouts are the degree of acidity (pH) 6, temperature 35 oC, and 1.5% v/v substrate concentration. The lipase specific activity of avocado seeds germination is 144,1 U / mg.
EKSTRAKSI DAN UJI STABILITAS ZAT WARNA DARI KULIT BUAH ALPUKAT (Persea americana Mill) DENGAN METODE SPEKTROSKOPI UV-VIS Fauziah, Nadiya Ayu; Saleh, Chairul; -, Erwin
JURNAL ATOMIK Vol 1 No 1 (2016)
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Abstract

The avocado skin fruit (Persea americana Mill) is one of species of Lauraceae family that had many benefits and efficiacy for human. Avocado is a woody plant, the life cycle can reach decades and were known to have potential as pigmen. The purpose of this study is to extract and determine the stability of pigmen from avocado skin fruit (Persea americana Mill) with UV-Vis Specroscopy methode. The extraction was done with soxhlet method using ethanol. The result of soxhlet was 142,13 gr avocado skin fruit dried powder was gained 88,85 gr ethanol extract. The ethanol extract of avocado skin dried powder was concentrated using rotary avoporator was gained 47,93 gr. The result phytochemical study, shown that ethanol coarse contained of Tannin compound, flavonoids and antosianin. The study stability of pigmen from avocado skin fruit (Persea americana Mill) extract was done to temperature effect were 40oC, 50oC, 60oC, 70oC and 80oC, pH effect were 3, 4, 5 and 6 and long storage effect were 1, 2, 3, 4 and 5 days at wave length 200-400 nm. The observational data were analyzed by ANOVA followed by Duncan test..Keywords: Persea americana Mill, Phytochemical , Stability of Pigmen
Penentuan Derajat Esterifikasi Dengan Metode Base Line Pada Sintesis Aldimin Kitosan Asetat Melalui Reaksi Esterifikasi Dari Aldimin Kitosan Dengan Asetat Anhidrida Churohma, Mifta; Tarigan, Daniel; Akkas, Erwin
JURNAL ATOMIK Vol 2 No 1 (2017)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Determination degree of esterification with the baseline on the synthesis method aldimine chitosan acetate by esterification of aldimine chitosan with acetic anhydride has done. In this research, chitosan modified by chemical being aldimine chitosan acetate. Synthesis aldimine chitosan acetate produced by the esterification reaction between aldimine chitosan with acetic anhydride. The result of FT-IR analysis of aldimine chitosan acetate showed in wavenumbers 3448.72 cm-1, which indicated stretching vibration hydroxyl group -OH. Vibration absorption wave numbers 1735.93 cm-1 indicated carbonyl group C = O, ester and backed group C-O-C with wavenumbers 1033.85 cm-1. vibration absorption in wavenumbers 1651.07 cm-1 indicated the presence of C = N. Degree of esterification or degree of acetylation (DA) in aldimine chitosan acetate assign value 82.85%.
PENGGUNAAN ELEKTRODA BESI (Fe), TEMBAGA (Cu) DAN STAINLESS STELL PADA PROSES ELEKTROKOAGULASI LIMBAH SAUS SAMBAL UNTUK MENURUNKAN PARAMETER BOD DAN TSS Purwati, Dewi; -, Alimuddin; -, Erwin
JURNAL ATOMIK Vol 3 No 1 (2018)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Research on the decline in BOD and TSS from waste chili sauce with electrocoagulation method using electrodes Fe, Cu and stainless stell in decreased amount of BOD and TSS. Conducted to determine the optimum point of each parameter based on the reaction of the electrocoagulation process on waste samples of chili sauce by using a variation of time and variation of voltage. The results obtained show that the effect of time is obtained optimum time of 120 minutes with vigorous optimum voltage of 12 volts to the decreased amount of BOD and TSS, respectively for 10.7577 mg/L and 18 mg/L with the results of successive allowance for 99.17% and 98.36% for electrode Fe and stainless stell. And decreased amount of BOD and TSS respectively for 8.2482 mg/L and 296 mg/L with the preliminary results of a row of 99.36% and 73.09% for the electrode Fe and Cu. With initial values of BOD and TSS each of 1301.4010 mg/L and 1100 mg/L.

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