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Contact Name
Agung Abadi Kiswandono
Contact Email
agung.abadi@fmipa.unila.ac.id
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+6281329121722
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agung.abadi@fmipa.unila.ac.id
Editorial Address
Bandar Lampung
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Lampung
INDONESIA
Analit: Analytical And Environmental Chemistry
Published by Universitas Lampung
ISSN : 25408224     EISSN : 25408267     DOI : 10.47352/analit
Core Subject :
Analit is a scientific journal that contains research results and reviews in the field of analytics and the environment. Fields of research studies or review articles that can be published in this journal include analytical chemistry, biosensor, chemical sensor, synthesis and characterization of materials, renewable-energy-related functional materials, environmental chemistry, remediation and waste treatment technologies, green chemistry and sustainability, as well as applied chemistry for environmental health and industrial processes.
Arjuna Subject : -
Articles 173 Documents
REMOVAL OF NAPTHOL DYE FROM BATIK WASTEWATER USING CHITOSAN FROM BLACK SOLDIER FLY PUPAL EXUVIAE Putri Rayhani Rahmania; Arseto Yekti Bagastyo
Analit : Analytical and Environmental Chemistry Vol. 9, No. 01 April (2024) Analit : Analytical and Environmental Chemistry
Publisher : Jurusan Kimia FMIPA Universitas Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/analit.v9i01.191

Abstract

This research discussed about the application of chitosan from black soldier fly (BSF) pupal exuviae as an adsorbent in the adsorption of napthol dyes in batik wastewater. The adsorption process was carried out in batch process with the aim of analyzing the dye removal efficiency and adsorption capacity as affected by solution pH and adsorbent dosage, as well as determining the appropriate adsorption kinetics model to be applied. Changes in dye concentration were analyzed for absorbance using a spectrophotometer. The results of the adsorption process research showed that the optimal pH and adsorbent dose were at pH 4 and 0.4 g/L with removal efficiency reaching 92%. The removal efficiency decreased with increasing pH. The increasing amount of adsorbent, the removal efficiency decreased. However, after reaching the optimal dose, the addition of chitosan mass no longer gave a significant increase in the removal efficiency, indicating that the saturation point had been reached. The adsorption process tends to follow a pseudo second-order kinetics model with a maximum adsorption capacity of 344.82 mg/g.
METHYLENE BLUE DYE REMOVAL BY ADSORPTION ONTO NATURAL GAMALAMA VOLCANIC SOIL Indra Cipta; Nur Jannah Baturante; Khusna Arif Rakhman; Ilham Mauraji; Dini Hadiarti
Analit : Analytical and Environmental Chemistry Vol. 10, No. 01 April (2025) Analit : Analytical and Environmental Chemistry
Publisher : Jurusan Kimia FMIPA Universitas Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/analit.v10i01.194

Abstract

The adsorption of Methylene Blue (MB) dye from aqueous solutions using natural adsorbents derived from Gamalama volcanic soil was investigated in this study. The adsorbent materials were characterized by FTIR, X-ray Diffraction (XRD), and Scanning Electron Microscopy (SEM) analyses, confirming the presence of allophane, halloysite, and kaolinite, which exhibit different morphologies and surface properties. Batch adsorption experiments were conducted to evaluate the effects of pH, contact time, and adsorbent mass on the removal efficiency of Methylene Blue. The results demonstrated that Gamalama volcanic soil adsorbents have a high affinity for Methylene Blue, achieving significant removal rates under optimal conditions. The findings suggest that Gamalama volcanic soil is a promising, low-cost, and environmentally friendly adsorbent for treating dye-contaminated wastewater. This study highlights the potential application of natural volcanic soil as an effective adsorbent in environmental remediation. The optimum MB removal was performed by adsorption condition with pH 6, 20 minutes contact time and 30 mg adsorbent.    
PYROLYSIS OF PALM OIL MILL EFFLUENT (POME) USING MODIFIED LAMPUNG NATURAL ZEOLITE WITH THE SI/AL RATIO OF 1 AS CATALYST Kamisah Delilawati Pandiangan; Frangky Gom Gom; Nurul Fajriyati; Muhammad Sabil; Tasyadinia Tasyadinia; Hanna Luthfia; Qori Hikmah Faranida; Ilim Ilim; Wasinton Simanjuntak
Analit : Analytical and Environmental Chemistry Vol. 9, No. 02 October (2024) Analit : Analytical and Environmental Chemistry
Publisher : Jurusan Kimia FMIPA Universitas Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/analit.v9i02.199

Abstract

In this research, palm oil mill effluent (POME), was pyrolized using a modified Lampung natural zeolite (LNZ) catalyst. Modification was conducted by reducing the Si/Al molar ratio to 1 by mixing certain mass of food grade aluminum food dissolved in 1.0 M NaOH solution and certain mass of LNZ. The mixture was homogenized using a magnetic stirrer, left at room temperature for 12 hours, and finally subjected to hydrothermal crystallization at 100 ºC for 72 hours. The solid sample produced was dried and calcined at 600 °C for 6 hours then characterized using X-ray diffraction (XRD) and Scanning Electron Microscope (SEM) techniques to evaluate the formation of zeolite-A. The BCO produced from the pyrolysis experiment was analyzed using gas chromatography-mass spectrometry (GC-MS), revealing the presence of hydrocarbon as the main components (70%), suggesting the promising potential of the catalyst for further investigation.
CHOLINE CHLORIDE BASED DEEP EUTECTIC SOLVENTS: PHYSICOCHEMICAL PROPERTIES AND SPECTROSCOPIC INSIGHTS Indah Puspita Sari; Annisaa Siti Zulaicha; Sinta Bella Triyanti
Analit : Analytical and Environmental Chemistry Vol. 9, No. 02 October (2024) Analit : Analytical and Environmental Chemistry
Publisher : Jurusan Kimia FMIPA Universitas Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/analit.v9i02.200

Abstract

This study focuses on the synthesis and characterization of Choline Chloride-based Deep Eutectic Solvents (DES) using Citric Acid (ChCl+CA) and Malic Acid (ChCl+MA) as hydrogen bond donors. The DES were prepared at various molar ratios, and their physicochemical properties, including viscosity, density, pH, water content, and molecular interactions, were comprehensively analyzed. The FTIR spectroscopic analysis revealed key shifts in the functional groups, indicating strong hydrogen bonding between the DES components. While ChCl+CA and ChCl+MA successfully formed stable eutectic solvents at a 1:1 molar ratio, synthesis with higher molar ratios (1:2 and 1:3) and ChCl+Ethylene Glycol (ChCl+EG) were unsuccessful, highlighting the importance of component compatibility and molar ratios. The density and viscosity measurements showed the potential applicability of these DES in extraction processes. This research contributes to the development of DES as green solvents, with future applications in pigment extraction for cosmetic purposes.   Keywords: Deep Eutectic Solvents, Choline Chloride, Citric Acid, Malic Acid, Pigment Extraction, Cosmetic Applications
SPECTROSCOPIC INSIGHTS AND PHYSICOCHEMICAL PROPERTIES OF DEEP EUTECTIC SOLVENTS FORMED FROM CHOLINE CHLORIDE AND ORGANIC HYDROGEN BOND DONORS Indah Puspita Sari; Eti Artiningsih Octaviani; Shefia Dhiya Khansa; Ganjar Fadillah
Analit : Analytical and Environmental Chemistry Vol. 9, No. 02 October (2024) Analit : Analytical and Environmental Chemistry
Publisher : Jurusan Kimia FMIPA Universitas Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/analit.v9i02.202

Abstract

This study investigates the physicochemical properties and molecular insights of Deep Eutectic Solvents (DES) formed with choline chloride as the hydrogen bond acceptor (HBA) and various organic hydrogen bond donors (HBDs), such as citric acid, glycerol, and glycolic acid. DES were assessed for bioactive compound extraction using Fourier Transform Infrared (FTIR) spectroscopy to analyze hydrogen bonding interactions and by measuring viscosity, density, and water content. Results showed viscosity ranging from 100 to 300 mPa-s and density from 1.05 to 1.45 g/cm ³, depending on the specific HBD. DES formed with glycerol and sorbitol exhibited higher viscosity due to stronger hydrogen bonding, while DES with lactic acid and glycolic acid showed lower viscosity, enhancing fluidity. FTIR spectra revealed shifts in the O—H and C=O stretching bands, indicating complex hydrogen bonding networks. These findings highlight the potential of DES to optimize bioactive compound extraction and their application in the cosmetics industry.  
EFEK PENAMBAHAN BUBUK DAUN KENIKIR (COSMOS CAUDATUS KUNTH) TERHADAP KADAR PROTEIN MINUMAN FUNGSIONAL BERBASIS SUSU KAMBING BUBUK Candra Saka Nusantari; Annisaa Siti Zulaicha
Analit : Analytical and Environmental Chemistry Vol. 9, No. 02 October (2024) Analit : Analytical and Environmental Chemistry
Publisher : Jurusan Kimia FMIPA Universitas Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/analit.v9i02.203

Abstract

One variation of functional beverages that is beneficial for the body is powdered goat milk with the addition of kenikir leaf powder (Cosmos caudatus Kunth). Kenikir leaves not only contain bioactive compounds that act as antioxidants, anti-inflammatory agents, and antimicrobials, but they also have high levels of protein, phenolic compounds, carbohydrates, vitamins, and minerals. Therefore, kenikir leaves are utilized as a component to enhance the protein content in functional beverages. The effect of adding kenikir leaf powder to functional beverages on protein content was assessed using the Kjeldahl method, with sample formulations labeled MF(F0), MF(F1), and MF(F2). The results from the Kjeldahl method showed that the highest protein content was found in the MF(F2) sample at 3.58%, while the MF(F1) sample had a protein content of 3.07%, and the MF(F0) sample had 2.49%. This demonstrates that the addition of kenikir leaves increases the protein content in functional beverages. Keywords: kenikir leaves, functional beverages, protein, goat milk.
FUNCTIONALIZATION MAGNETITE ACTIVATED CARBON COATINNG WITH SILANE AGENT AS ADSORBENT FOR CRYSTAL VIOLET AND METHYL ORANGE DYES Annisaa Siti Zulaicha; Candra Saka Nusantari; Arif Setiajaya
Analit : Analytical and Environmental Chemistry Vol. 9, No. 02 October (2024) Analit : Analytical and Environmental Chemistry
Publisher : Jurusan Kimia FMIPA Universitas Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/analit.v9i02.209

Abstract

Indonesia, the largest palm oil producer, produces a very large of palm kernel shell waste. This study aims to optimize utilization of this waste by converting it into activated carbon which has high potential adsorbent. Process   making activated carbon involves carbonization and activation of palm kernel shells, followed by surface modification using   magnetic particles and organosilane triethoxyiphenylsilane (TEPS). Addition of Fe3O4 particles can increase adsorption capacity and facilitate the separation of the adsorbent from the solution after adsorption process. Meanwhile, addition of TEPS compounds increases the number of functional groups on the surface of activated carbon so   can interact more strongly with dye molecules. Characterization using various techniques such as UV-Vis, FTIR, XRD, SEM-EDX, and BET was carried out to analyze changes structure and surface properties of activated carbon after modification. The results of the study can contribute to   development of waste processing technology and production of value-added adsorbent materials.  
ASSESSMENT OF BENGAWAN SOLO RIVER RAW WATER QUALITY USING THE POLLUTION INDEX Intan Ayu Pebiola; Heri Mulyanti; Laily Agustina Rahmawati
Analit : Analytical and Environmental Chemistry Vol. 10, No. 01 April (2025) Analit : Analytical and Environmental Chemistry
Publisher : Jurusan Kimia FMIPA Universitas Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/analit.v10i01.215

Abstract

The Bengawan Solo River is a primary water resource in Central and East Java. Human activities along the Watershed (DAS) have affected water quality. This study evaluates the water quality of the Bengawan Solo River during the dry and rainy seasons from 2019 to 2023 using the Pollution Index (IP) method, based on secondary data from Perum Jasa Tirta I at four locations: upstream, middle, downstream 1, and downstream 2. The analyzed parameters include physical (temperature, TDS, TSS), chemical (pH, DO, BOD, nitrate), and biological (Total coliform) aspects. The results indicate that pH, TDS, and nitrate remain within quality standards, whereas temperature, BOD, DO, and TSS often exceed the limits, especially during the rainy season. The Pollution Index (Pij) suggests better water quality in the dry season, predominantly classified as "Lightly Polluted." However, in the 2021 rainy season, two locations reached the "Moderately Polluted" category, indicating that rainfall contributes to increased pollution.
EFFECTIVENESS OF USING ACTIVATED CARBON TO REDUCE POLLUTANTS IN LEACHATE Nindy Callista Elvania; Oktavianus Cahya Anggara; Narafa Nur Khairiyyah; Regina Widya Putri L
Analit : Analytical and Environmental Chemistry Vol. 10, No. 01 April (2025) Analit : Analytical and Environmental Chemistry
Publisher : Jurusan Kimia FMIPA Universitas Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/analit.v10i01.217

Abstract

Leachate pollution resulting from dissolution process organic and inorganic materials in open landfills is a serious environmental problem. Leachate contains various pollutants, such as heavy metals, organic compounds, and hazardous compounds that can damage water and soil quality not managed properly. This study aims assess the effectiveness activated carbon in reducing pollutants in leachate and factors that affect the performance of activated carbon in leachate treatment. The method used in study is leachate treatment using activated carbon as an adsorbent medium. Testing was carried out with variations in contact time and activated carbon concentration to determine the optimal conditions for pollutant absorption. Water quality parameters tested included COD, BOD, Fe and Zn. The results of  study showed that activated carbon is very effective in reducing pollutant content in leachate. This can be seen from results of the effectiveness calculation where it was found that activated carbon can reduce COD 63.96%, BOD 44.89%, Fe 83.33%, and Zn 83.33%.
EFFECT OF BEVERAGE CAN WASTE–KOH RATIO ON ALUM PRODUCTION AS A COAGULANT FOR WATER TREATMENT Nina Arlofa; Shohifah Annur; Angga Tri Prasetyo; Ali Hotman Dzulfathi; Achyar Abdullah
Analit : Analytical and Environmental Chemistry Vol. 10, No. 02 October (2025) Analit : Analytical and Environmental Chemistry
Publisher : Jurusan Kimia FMIPA Universitas Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/analit.v10i02.219

Abstract

  ABSTRAK  Proses daur ulang limbah dapat menghemat energi, mengurangi eksploitasi sumber daya alam, serta meningkatkan nilai ekonomis limbah, salah satunya limbah kaleng minuman. Penelitian ini bertujuan untuk menentukan rasio optimum antara limbah kaleng minuman dan kalium hidroksida (KOH) dalam pembuatan tawas (aluminium sulfat) sebagai koagulan penjernih air. Metode yang digunakan terdiri dari lima tahap, yaitu preparasi, pelarutan, pengendapan alum, pencucian, dan pengeringan. Variabel rasio limbah kaleng terhadap larutan KOH 30% divariasikan sebesar 1%, 2%, 3%, 4%, dan 5%. Parameter yang dianalisis meliputi kadar aluminium dalam tawas, rendemen, dan efektivitas tawas dalam menurunkan kekeruhan air. Hasil menunjukkan bahwa tawas mampu menurunkan kekeruhan air limbah industri dari 55,6 NTU menjadi 16,4 NTU. Rendemen optimum diperoleh pada rasio 3% sebesar 68,91% dengan kadar aluminium 33,80% dan susut pengeringan 9,97%. Efektivitas penurunan kekeruhan ini mengacu pada standar turbiditas menurut SNI 6989.57:2008 dan Permenkes No. 32 Tahun 2017, di mana air bersih non-konsumsi idealnya memiliki kekeruhan di bawah 50 NTU. Dengan demikian, tawas hasil daur ulang ini menunjukkan potensi sebagai koagulan alternatif dalam pengolahan air limbah.   Kata kunci: Tawas, limbah kaleng minuman, koagulan, penjernih air   ABSTRACT Recycling aluminum-based beverage can waste offers a sustainable approach to reducing energy consumption, conserving natural resources, and increasing waste valorization. This study aimed to determine the optimum ratio of beverage can waste to potassium hydroxide (KOH) in synthesizing alum (aluminum sulfate) as an alternative coagulant for wastewater treatment from a petrochemical industry in Anyer, Banten Province, Indonesia. Alum was synthesized through preparation, alkaline dissolution, precipitation, washing, and drying using beverage can waste to 30% KOH ratios of 1–5%. Performance evaluation included yield, aluminum content, drying loss, and coagulation effectiveness based on turbidity, pH, color, and odor.The results showed that recycled alum reduced turbidity from 55.6 NTU to 16.4 NTU, decreased pH from 7.39 to 7.22, and eliminated color and odor. The optimum condition was achieved at a 3% ratio, yielding 68.91% alum with 33.80% aluminum content and 9.97% drying loss. All treated water parameters met Indonesian non-potable clean water standards according to SNI 6989.57:2008 and Ministry of Health Regulation No. 32/2017, demonstrating the potential of recycled alum as a sustainable alternative coagulant.   Keywords: alum, aluminum recycling, beverage can waste, coagulant, wastewater treatment.

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