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Articles 131 Documents
Potensi Pembuatan Replika Tulang Berpori Menggunakan Template Ampas Tebu Reno Susanto
CHEMPUBLISH JOURNAL Vol. 5 No. 2 (2020): Chempublish Journal
Publisher : Universitas Jambi, Fakultas Sains dan Teknologi, Program Studi Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22437/chp.v5i2.10612

Abstract

Scaffold Hidroksiapatit dengan ukuran pori dari 400 nm sampai 4 mm dan porositas dalam kisaran 20%-97% telah diproduksi dengan menggunakan template alam dengan berbagai metode seperti replica method, direct foaming method, solvent casting katalisis, dan starch consolidation method. Pada artikel ini, kami meninjau pemrosesan natural template yang dapat digunakan untuk pembuatan hidrokdisiapatit dengan mempertimbangkan hasil yang diperoleh berupa ukuran pori, porositas, densitas, kuat tekan, dan hasil analisa uji in vitro serta in vivo. Pada akhirnya kami mengusulkan untuk membuat scaffold HA menggunakan Template Ampas tebu karena memiliki kuat tekan yang baik serta memilki kandungan silica yang cukup tinggi untuk mendukung kegiatan bioaktivitas hidroksiapatit. Kata kunci: Ampas Tebu, Scaffold HA, Template Alam
Nanofikasi Fraksi Tanah Gambut untuk Modifikator Nanomagnetit/AH-Kitosan sebagai Kandidat Penanggulangan Pencemaran Zat Warna Ngatijo Ngatijo; Restina Bemis; Mahya Ihsan; Nurul Gusmaini; Salim Hidayat; Rahmat Basuki
CHEMPUBLISH JOURNAL Vol. 5 No. 2 (2020): Chempublish Journal
Publisher : Universitas Jambi, Fakultas Sains dan Teknologi, Program Studi Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22437/chp.v5i2.11105

Abstract

The nanomagnetite/HA-Chitosan adsorbent has been successfully synthesized by the co-precipitation method. HA was synthesized from the peat soils of Geragai village, Tanjung Jabung Timur, Jambi province and chitosan isolated from marine animal shell waste around the city of Jambi. The results of FT-IR analysis showed that nanomagnetite/AH-chitosan has a spectra which was combination of the characteristic spectra of magnetite, HA and chitosan. Morphological analysis using SEM showed that nanomagnetite/AH-chitosan was in the form of fractal agglomerates. TEM image of magnetite/AH-chitosan showed that magnetite/AH-chitosan has nano scale magnetite core particles with a size between 4-22 nm. Crystallinity analysis showed that magnetite/AH-chitosan has 2θ characteristics of magnetite i.e., 30.1°, 35.4°, 43.1°, 57.0°, 62.68° and 74.5°. The magnetic saturation strength (Ms) decreased from 80.23 (magnetite) to 30.63 (magnetite/AH-chitosan) due to the coating of AH-chitosan on magnetite which was still effectively attracted by the external magnet with 96% effectiveness of adsorption of 25 mL Methylene Blue 10 mg/L.
Mempelajari Senyawa Mirisitrin Dengan Penambahan Substituen NH2, NO2, dan CH3 Sebagai Inhibitor Korosi Menggunakan Metode Density Fuctional Theory (DFT) Azuxe Tullatif
CHEMPUBLISH JOURNAL Vol. 5 No. 2 (2020): Chempublish Journal
Publisher : Universitas Jambi, Fakultas Sains dan Teknologi, Program Studi Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22437/chp.v5i2.11347

Abstract

Corrosion inhibition ability myricitrin compound (M1) with the addition of NH2 (M2), NO2 (M3), and CH3 (M4) on the metal surface has been studied using Fuctional Density Theory (DFT) with a base set of B3LYP / 6-31G (d, p). Parameters obtained from the optimization result are the value EHOMO, ELUMO and dipole moment. Of the value EHOMO and ELUMO obtained and calculated the value of the energy gap (AE), ionization potential (IP), electron affinity (EA), electronegativity (χ), hardness (η), softness (σ), electron transfer (ΔN), and electrophilicity (ω). Computational calculations show that the compound M4 has the best corrosion inhibition ability. Based on the value EHOMO, the energy gap (AE), ionization potential (IP), hardness (η), softness (σ) and electron transfer (ΔN). Keywords: DFT, Corrosion Inhibition, EHOMO, ELUMO
Efek Sinergetik Ekstrak Daun Jambu Bol (Syzygium malaccense) dan Iodida terhadap Korosi Baja dalam Larutan Asam Putri Untari
CHEMPUBLISH JOURNAL Vol. 5 No. 2 (2020): Chempublish Journal
Publisher : Universitas Jambi, Fakultas Sains dan Teknologi, Program Studi Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22437/chp.v5i2.11348

Abstract

Research on the synergistic effect of jambu bol leaves extract and iodide on the corrosion of mild steel in acid solution has been carried out by weight loss, potentiodynamic polarization measurements, Fourier transform infrared (FTIR), scanning electron microscopy (SEM) analysis, and X-Ray Diffraction (XRD) characterization. The inhibition efficiency increased with increasing iodide concentration and temperature. The highest inhibition efficiency was 92.05% in inhibitor of 5 g / L jambu bol leaves extract with the addition of 0.08 g / L of iodide. Adsorption of jambu bol leaves extract and iodide following the Langmuir isotherm adsorption. Potentiodynamic polarization measurements show the combination of jambu bol leaves inhibitor and iodide was a type of mixture inhibitor in hydrochloric acid solution. The synergistic effect of guava bol extract and potassium iodide was studied using thermodynamic and kinetic parameters. Keywords: Jambu bol leaves, corrosion inhibitor, weight loss, synergistic effect, Langmuir isotherm
Pengaruh konsentrasi PEG 400 sebagai kosurfaktan pada formulasi nanoemulsi minyak kepayang Maharini; Rismarika; Yusnelti
CHEMPUBLISH JOURNAL Vol. 5 No. 1 (2020): Chempublish Journal
Publisher : Universitas Jambi, Fakultas Sains dan Teknologi, Program Studi Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22437/chp.v5i1.7604

Abstract

Kepayang oil has a high content of linoleic and oleic acids. Linoleic and oleic acids act as emollients in the cosmetic field. Nanotechnology is one of the latestinnovations that can be used in cosmetics preparation delivery systems because it can improve the drug delivery process. This study aims to examine the effect of PEG 400 on the formulation of Kepayang oil nanoemulsion. The concentrations of tween 80 and variation concentrations of PEG 400 used in F1, F2, and F3 are 36%: 0%, 36%: 24% and 36%: 14% using the SNEDDS method. The characteristics of nanoemulsion preparations include organoleptic, particle size, polydispersity index, and zeta potential. The result of nanoemulsion production has the organoleptic form in bright yellow color and has a distinctive odor, the particle size in F1, F2 and F3 are 11.8, 13.2 and 11.3 with a polydispersity index of 0.315, 0.147 and 0.121 and zeta potential -16.2, 13.4 and 1.8. The effect of variations in surfactant concentration in the nanoemulsion formulations of kepayang oil is that the higher the level of PEG 400, it will reduce the pH and viscosity of the preparation, increase the particle size, the uniformity of droplet size uniformity, but does not affect the potential zeta value. The best formula is F2.
Pengolahan limbah cair industri pelapisan logam dengan proses elektrokoagulasi secara kontinyu Idral Amri; Febri Awalsya; Irdoni
CHEMPUBLISH JOURNAL Vol. 5 No. 1 (2020): Chempublish Journal
Publisher : Universitas Jambi, Fakultas Sains dan Teknologi, Program Studi Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22437/chp.v5i1.7650

Abstract

Limbah cair industri pelapisan logam berasal dari hasil pembilasan pada proses pelapisan dengan Chrome, masih banyak terkandung zat berbahaya apabila langsung dibuang kelingkungan. Untuk itu perlu dilakukan pengolahan lebih lanjut dengan menggunakan elektrokoagulasi. Metode ini memiliki potensi penjernihan limbah cair pelapisan logam dan penurunan kandungan logam yang terkandung tanpa adanya penambahan koagulan. Tujuan dari penelitian ini untuk mengetahui penerapan metoda elektrokoagulasi untuk menetralkan pH, serta menurunkan kadar TSS dan Cr pada limbah dan untuk mengetahui pengaruh perubahan laju alir dan kuat arus untuk menetralkan pH, serta menurunkan kadar TSS dan Cr pada limbah. Parameter yang diuji meliputi pH, TSS (Total Suspended Solid), dan Cr. Proses elektrokoagulasi menggunakan listrik searah melalui elektroda. Reaktor elektrokoagulasi yang dipasangkan kabel ke power suplay kemudian disambungkan ke arus listrik dengan variasi kuat arus (1,2 ; 1,6 ; dan 2 A) dan variasi laju alir (0,78 ; 1,32 ; 2,7 L/menit). Hasil penelitian didapat kondisi optimum pada kuat arus 2 A dan laju alir 0,78 L/menit dengan kenaikan pH dari 4,5 menjadi 6,6, penurunan TSS dari 3,2 menjadi 1,2 mg/L, penurunan Cr sebesar 82,4 % dari 1,5 mg/L menjadi 0,263 mg/L.
Pengolahan limbah cair tahu menjadi air bersih dengan metode elektrokoagulasi secara kontinyu Idral Amri; Pratiwi Destinefa; Zultiniar
CHEMPUBLISH JOURNAL Vol. 5 No. 1 (2020): Chempublish Journal
Publisher : Universitas Jambi, Fakultas Sains dan Teknologi, Program Studi Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22437/chp.v5i1.7651

Abstract

The liquid waste of the tofu industry contains high organic contaminants, such as proteins and amino acids. These organic compounds causes liquid waste of tofu industry to contain high BOD, COD, and TSS so that it can pollute the environment. Therefore, tofu liquid should be removed first by electrocoagulation method. This method has the potential to purify tofu liquid waste and decrease the content of COD, BOD, TSS, and pH contained without the addition of coagulants. The purpose of this study was to determine the effect of voltage and flow rate to neutralize pH, and reduce levels of COD, BOD, and TSS in tofu liquid waste. The parameters tested included COD, BOD, TSS, and pH. The electrocoagulation process uses electrical power that flows in the direction of the electrode. The electrocoagulation reactor was paired with a cable connected to the power supply then connected to an electric current with voltage and flow rate variations. The results of this study found that optimum conditions were obtained at current of 12 V and flow rate of 0.087 L/min with increasing pH from pH from 3.5 to 6.7, percent removal of COD 72.17%, percent removal BOD 71.53% , and percent removal TSS 90.90%.
Analisis pewarna Rhodamin B pada kerupuk merah di Payakumbuh Linda Hevira; Desmi Alwinda; Najmi Hilaliyati
CHEMPUBLISH JOURNAL Vol. 5 No. 1 (2020): Chempublish Journal
Publisher : Universitas Jambi, Fakultas Sains dan Teknologi, Program Studi Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22437/chp.v5i1.7912

Abstract

Rhodamine B adalah pewarna sintetis yang digunakan sebagai zat pewarna untuk tekstil, cat, dan kertas tetapi banyak disalahgunakan dalam makanan, salah satunya adalah kerupuk merah. Rhodamine B dapat mengiritasi saluran pernapasan, kulit, mata, saluran pencernaan, keracunan, dan gangguan hati, dan dalam jangka panjang, dapat menyebabkan kanker dan tumor. Secara kualitatif dan kuantitatif kandungan pewarna Rhodamine B dalam kerupuk merah ditentukan menggunakan TLC dan UV-Vis Spectrophotometry. Tujuh sampel dari produsen menunjukkan bahwa Rhodamine B atau negatif tidak ditemukan pada kerupuk merah. Itu artinya kerupuk merah yang diproduksi oleh industri rumah tangga di Payakumbuh aman untuk dikonsumsi.
Analisis GC-MS ekstrak tanaman terfermentasi (ETT) dari kulit buah jengkol (Pithecellobium jiringa Prain) Refilda Suhaili; Lucy Prima Ardi; Emil Salim; Mai Efdi
CHEMPUBLISH JOURNAL Vol. 5 No. 1 (2020): Chempublish Journal
Publisher : Universitas Jambi, Fakultas Sains dan Teknologi, Program Studi Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22437/chp.v5i1.7957

Abstract

Analysis of active compounds in fermented plant extract (FPE) from the ngapi nut peel using Effective Microorganism-4 (EM-4) has been done by Gas Chromatography-Mass Spectroscopy (GC-MS). There were 88 compounds found in fermented plant extract, the major content with the area above 1% were 7 compounds such as succinic acid; ethyl hydrogen succinate; 1,2,3-benzetriol; 3,3-dimethylhexanal; L-proline, 1-methyl-5-oxo-methyl ester; 3-methoxycinnamic acid and hexadecanoic acid. Based GC-MS analysis, fermented plant extract indicated that several compounds that have potential as biopesticides.
Sintesis kalsium pirofospat (Ca2P2O7) dari limbah cangkang telur dengan metode solvothermal Ihsanul Huda; Retno Kusumaningrum; Mi'raj Shabrin Jamil; Wahyu Bambang Widayatno; Agus Sukarto Wismogroho; Nurul Taufiqu Rochman; Alfian Noviyanto
CHEMPUBLISH JOURNAL Vol. 5 No. 1 (2020): Chempublish Journal
Publisher : Universitas Jambi, Fakultas Sains dan Teknologi, Program Studi Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22437/chp.v5i1.8669

Abstract

Kalsium pirofospat telah berhasil disintesis dengan menggunakan metode solvothermal. Bahan dasar yang digunakan adalah limbah cangkang telur ayam dan bebek. Cangkang telur ayam dan bebek dibersihkan dan digerus, kemudian dikalsinasi pada temperatur 1000°C selama 2 jam untuk mendapatkan serbuk CaO. Serbuk CaO kemudian dicampurkan dengan H3PO4 dan dimasukkan ke dalam bejana solvothermal. Proses solvothermal dilakukan pada temperatur 130°C selama 16 jam. Fasa tunggal CaHPO4 diperoleh setelah proses solvothermal. Kalsinasi serbuk CaHPO4 dilakukan pada tungku muffle dengan temperatur 800°C selama 2 jam dan kondisi atmosfir biasa. Hasil analisa fasa menunjukkan terbentuknya fasa tunggal kalsium pirofospat (Ca2P2O7) tanpa adanya fasa pengotor lainnya. Hasil ini menunjukkan perbandingan Ca dan P adalah 1. Mikrostruktur kalsium pirofospat yang terbentuk agak kasar dengan ukuran partikel rata-rata 590 ± 43 nm untuk cangkang telur ayam dan 455 ± 32 nm untuk cangkang telur bebek. Studi lebih lanjut diperlukan untuk mendapatkan kondisi optimum dari proses solvothermal limbah cangkang telur sehingga bisa didapatkan kalsium pirofospat yang mempunyai ukuran lebih halus dan seragam.

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