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Removal Of Lead (Pb2+) From Aqueous Solutions By Natural Bentonite Wahyu Wilopo; Doni Prakasa Eka Putra; I Wayan Warmada; Tsuyoshi Hirajima
Journal of Applied Geology Vol 4, No 1 (2012)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (745.797 KB) | DOI: 10.22146/jag.7195

Abstract

The aim of the present work is to investigate the ability of natural bentonite (untreated) from Pacitan, East Java to remove lead ions from aqueous solution. The bentonite has specific surface area and cation exchange capacity of 27.52 m2 g−1 and 65.20 meq/100 gr of bentonite, respectively. Towards this aim, batch adsorption experiments were carried out and the effect of various parameters on this removal process has been investigated. The effects of pH, grain size of bentonite, adsorption time and lead ion concentration on the adsorption process were examined. The optimum pH for adsorption was found to be 9, with the finer grain size of bentonite is more effective. In adsorption studies, residual lead ions concentration reached equilibrium in a duration of 24 hours. Adsorption of lead on bentonite appeared to follow Freundlich isotherm. Our results demonstrate that the adsorption process was mostly dominated by ion exchange process. Keywords: Removal, lead, aqueous solution, natural bentonite, adsorption.
Fluid Inclusion Study Of The Polymetallic Epithermal Quartz Veins At Soripesa Prospect Area, Sumbawa Island, Indonesia Win Kant; I Wayan Warmada; Arifudin Idrus; Lucas Donny Setijadji; Koichiro Watanabe
Journal of Applied Geology Vol 4, No 2 (2012)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (3344.355 KB) | DOI: 10.22146/jag.7199

Abstract

The Soripesa prospect area is located at Maria village, Wawo district, Bima region in the eastern part of Sumbawa Island, Indonesia. This area is a part of Cenozoic Calc-alkaline volcanic inner Banda-Sunda Arc. The dominant lithology of Soripesa prospect area are a lithic-crystal tuff of andesitic and dacitic composition and bedded limestone. There have five main polymetallic epithermal quartz veins in the Soripesa prospect area, namely, Rini vein, Jambu air vein, Dollah vein, Merpati vein, and Arif vein. Those quartz veins are hosted mainly in andesitic volcaniclastic rocks. Fluid inclusion study on those quartz veins is vey important to know the condition of hydrothermal fluids and their origin. Fluid inclusion study is conducted at the laboratory of Earth Resources Engineering Department, Kyushu University, Japan. Homogenization temperature, freeze temperature, eutectic temperature, and melting temperature can be known from fluid inclusion study. Based on fluid inclusion study, formation temperatures of all veins are between 250–260◦C. Melting temperature is between -0.2 to -3◦C. Based on the melting temperature, salinity (wt.% NaCl equiv.) of fluid inclusions is calculated by using Bodnar’s equation. Paleodepth of formations and pressure of trapping are also estimated by using formation temperature and salinity. Based on Hass (1971) diagram, estimated paleodepths of formations are 270 m for Merpati vein, 400 m for Dollah vein, 480 m for Rini vein, 570 m for Arif vein, and 680 m for Jambu Air vein, respectively. Pressure of trapping can also be estimated from depth of formation, density of lithostatic overburden, and gravity; 72 bars for Merpati vein, 106 bars for Dollah vein, 127 bars for Rini vein, 151 bars for Arif vien, and 180 bars for Jambu Air vein, respectively. Keywords: Soripesa, polymetallic quartz veins, homogenization temperature, salinity.
HOST ROCKS’ GEOCHEMISTRY AND MINERALIZATION POTENTIAL OF POLYMETALLIC EPITHERMAL QUARTZ VEINS AT SORIPESA PROSPECT AREA, SUMBAWA ISLAND, INDONESIA Win Khant; I Wayan Warmada; Arifudin Idrus; Lucas Donny Setijadji; Koichiro Watanabe
Journal of Applied Geology Vol 5, No 1 (2013)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2935.663 KB) | DOI: 10.22146/jag.7205

Abstract

The Soripesa prospect area is located at Maria village, Wawo district, Bima region in the eastern part of Sumbawa Island, Indonesia. This area is a part of Cenozoic Calc-alkaline volcanic inner Banda- Sunda Arc. There are five main polymetallic epithermal quartz veins in the Soripesa prospect area, namely, Rini vein, Jambu air vein, Dollah vein,Merpati vein, and Arif vein. The dominant lithology is a lithic-crystal tuff of andesitic and dacitic composition and bedded limestone. Major oxides and trace elements were analyzed by using X-Ray Fluorescence (XRF) to identify the host rock geochemistry. The main veins are hosted by andesitic and andesitic/ basaltic volcanic host rocks. Major elements compositions are affected by alteration. Based on the trace element data, host rocks of all veins were formed in the volcanic arc basalt (VAB) and island arc basalt (IAB) tectonic settings. Host rocks of Rini vein contain higher amount of precious and base metal elements (Zn, Cu, Pb, and Ag.etc.) than those of other host rocks. Keywords: Soripesa prospect area, lithology, tectonic setting, mineralization.
HIGH SULFIDATION EPITHERMAL MINERALIZATION AND ORE MINERAL ASSEMBLAGES OF CIJULANG PROSPECT, WEST JAVA, INDONESIA Myo Min Tun; I Wayan Warmada; Arifudin Idrus; Agung Harijoko; Okki Verdiansyah; Koichiro Watanabe
Journal of Applied Geology Vol 6, No 1 (2014)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (4446.559 KB) | DOI: 10.22146/jag.7215

Abstract

Cijulang is a high-sulfidation epithermal system hosted in the calc-alkaline rocks of andesite lava and lapilli tuff. Mineralization in the prospect is characterized by pyrite-enargite-gold and associated acid sulfate alteration. Studies on ore and gangue mineral assemblages and their mutual textural relationships were carried out in order to explore the paragenetic sequence of mineralization. Hypogene mineralization primarily occurs in the silicic core and the advanced argillic zone in the form of massive replacement, fracture-filling veinlets, vug-filling, patches and dissemination. Mineralization is apparently controlled by both lithology and structures. Common ore minerals include pyrite, enargite, luzonite, tennantite, chalcopyrite, covellite, galena, emplectite and Te-bearing minerals. The paragenetic study indicates that the epithermal prospect evolved from an early stage of intense acid leaching resulting in the formation of vuggy silica and advantage argillic mineral assemblage which was followed by the sulfides deposition. Two metal stages were identified during ore deposition: an early Fe-As-S stage and the later Cu-Fe-As-S stage. The former stage is char- acterized high-sulfidation state sulfides such as enargite/ luzonite+covellite whereas a later stage of Cu- Fe-As–S is represented by intermediate sulfidation state sulfides assemblage of tennantite+chalcopyrite. Gold is probably introduced in the early stage within the ore system and more abundant in the late stage. Keywords: Cijulang, high-sulfidation, acid sulfate, mineralization, enargite, paragenetic, metal stages
FLUID INCLUSION STUDIES OF THE EPITHERMAL QUARTZ VEINS FROM SUALAN PROSPECT, WEST JAVA, INDONESIA Myo Min Tun; I Wayan Warmada; Arifudin Idrus; Agung Harijoko; Okki Verdiansyah; Koichiro Watanabe
Journal of Applied Geology Vol 6, No 2 (2014)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (952.327 KB) | DOI: 10.22146/jag.7218

Abstract

Sualan prospect is located at Talegong Sub-district of Garut Regency, West Java, Indonesia. The area constitutes calc-alkaline volcanic and volcaniclastic rocks of Tertiary age. The rocks have experienced regional propylitic and argillic alteration. Fluid inclusions from quartz veins were studied in order to constrain the nature, characteristics and evolution of fluids. Microthermometric measurements on fluid inclusion were carried out by freezing and heating experiment. Temperatures of homogenization (Th) and final melting of ice (Tm) were measured for primary, liquid-dominated, two-phase inclusions. The values of Th range from 160°C to 210°C and salinities range from 0.35 to 4.96 wt.% NaCl equiv. Formation temperature of the quartz veins are estimated at 180°C and 190°C and paleo-depth of formation are at 80m and 140m, respectively. Microthermometric data indicates that fluid mixing and dilution were important processes during the evolution of hydrothermal system. Based on fluid inclusion types, microthermometric data, trapping temperature, paleo-depth, texture of quartz and hydrothermal alteration types, quartz veins from prospect were developed under epithermal environment. Keywords: Quartz vein, fluid inclusions, microthermometry, salinities, formation temperature, paleo-depth, epithermal, Sualan prospect.
MODIFIED NATURAL ZEOLITE AND BENTONITE AS ADSORBENTS OF HEAVY METAL IONS FROM POLLUTED GROUNDWATER IN YOGYAKARTA URBAN ARE, INDONESIA Bunchoeun Pich; I Wayan Warmada; Heru Hendrayana; Tetsuro Yoneda
Journal of Applied Geology Vol 2, No 1 (2010)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (327.01 KB) | DOI: 10.22146/jag.7229

Abstract

Groundwater quality in Yogyakarta city has become the major concern due to the presence of heavy metals originated from batik home industries, slaughterhouses, and leather factories, especially in shallow groundwater. In response to the above problems, the naturally abundant zeolite and bentonite in Sidomulyo and Bandung areas were respectively sampled along with the metal-containing groundwater in Yogyakarta urban area for batch adsorption experiment. Before put into experiment, the zeolite and bentonite were characteristically investigated by means of XRD, SEM, chemical composition, and physical property analyses. Also, they were thermally activated to improve their qualities in terms of increase in CEC, whereas the groundwater was analyzed for heavy metal concentrations (Cd, Cr, Cu, Fe, Zn) and its physical property. Five logarithmic amounts of this modified zeolite or bentonite were separately and incrementally introduced into the same three solutions of heavy metals. After the experiment, all the solutions were re-analyzed for the rest of heavy metals to figure out the optimum adsorption capacity of zeolite and bentonite. The outcomes of this experiment will be beneficial in enhancing the groundwater quality for consumptions in Yogyakarta city as well as other places in Indonesia, and will also imply the zeolite and bentonite in commercialization. Keywords: zeolite, bentonite, groundwater, heavy metal, adsorption
MERCURY AND ARSENIC CONTAMINATION FROM SMALL SCALE GOLD MINING ACTIVITIES AT SELOGIRI AREA, CENTRAL JAVA, INDONESIA Agung Harijoko; Tin May Htun; Rodhie Saputra; I Wayan Warmada; Lucas Donny Setijadji; Akira Imai; Koichiro Watanabe
Journal of Applied Geology Vol 2, No 1 (2010)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1689.074 KB) | DOI: 10.22146/jag.7235

Abstract

Small scale gold mines discussed here are located at Selogiri area, Central Java, Indonesia which was mined by local community mainly during gold rush in 1990s. This Selogiri gold deposit genetically is characterized by porphyry mineralization overprinted by epithermal system. The ore minerals assemblage consists of pyrite, sphalerite, chalcopyrite, galena, chalcocite and rare arsenopyrite. Chemical analysis of soil and stream sediment sampled over 1.5 km across at the Selogiri gold extraction site indicates that the site has been contaminated with mercury due to mining activities. The mercury concentrations in soil and stream sediments collected during dry season range from 0.01 to 481 ppm and 0.01 to 139 ppm, respectively, higher than background value of 0.05 ppm. In contrast, mercury concentration in stream sediments collected during rainy season from the same location as dry season sampling ranges from 0.01 to 13.42 ppm, and one sample has anomalous value of 331 ppm. This result show that rain water may disperse and decrease mercury concentration in stream sediments. In case of arsenic, although the ore contains rare arsenic minerals, arsenic concentration in bulk rock and ore is high ranging from 8 to 59 ppm, while the arsenic concentration in tailing is much higher ranging from 5.8 to 385 ppm. Chemical analyses on pyrite reveal that the pyrite grains contain arsenic and might be the source of arsenic in Selogiri mine site. However, analysis of dug-well water demonstrates that the mercury and arsenic content is still lower than the maximum allowable concentration. Keywords: Mercury, arsenic, contamination, Selogiri, gold mine
CHATODOLUMINESCENCE MICROSCOPIC ANALYSIS TO INTERPRET THE REDOX CONDITION DURING THE FORMATION OF CARBONATE VEIN I Wayan Warmada; Retno Hartati
Journal of Applied Geology Vol 2, No 1 (2010)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (126.97 KB) | DOI: 10.22146/jag.7236

Abstract

Cathodoluminescence (CL) is generated by an electron gun coupled to an optical microscope. There are two types of chatodoluminescence, i.e., cold CL and hot CL. In the cold cathode microscopic equipment, the electrons are generated by an electric discharge between two electrodes under a low gas pressure, whereas in the hot CL microscope, the electrons are generated by heating a filament (2000–3000°C). In this paper we utilize cold CL combine with electron microprobe analysis (EMPA). The CL microscopy of carbonate shows at least three carbonate generations, i.e., rhodochrosite with dull or no luminescence, Mg-rich calcite with dark red luminescence, manganese-bearing calcite with up to 0.04 wt.% Mn with bright orange luminescence, and pure calcite and Mn-rich calcite (> 0.15 wt.% Mn) with dull or no luminescence. The result also suggests that the luminescence pattern of calcite is controlled by the amount of Mn2+. Sectoral zoning and chevron-shape growth zoning exist in some coarse-grained calcite aggregates. The sectorial zoning of calcite as reflected by dull to bright CL color indicated that slightly to more reducing environment during calcite deposition. Keywords: Chatodoluminescence, rhodochrosite, calcite, sectorial zoning
COPPER (Cu2+) REMOVAL FROM WATER USING NATURAL ZEOLITE FROM GEDANGSARI, GUNUNGKIDUL, YOGYAKARTA Wahyu Wilopo; Septiawan Nur Haryono; Doni Prakasa Eka Putra; I Wayan Warmada; Tsuyoshi Hirajima
Journal of Applied Geology Vol 2, No 2 (2010)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (449.767 KB) | DOI: 10.22146/jag.7253

Abstract

Development of indusrialization and urbanization not only increase economic growth but also contribute to the environmental degradation, especially contamination of heavy metals in water. In other side, there are many geological materials have capability to immobilize heavy metals. Therefore, the objective of this research is to know the maximum capacity of natural zeolite from Trembono area, Gunung Kidul regency to immobilize copper (Cu2+) from water and to understand their mechanism. This experiment was carry out by a batch test. The result showed that the maximum capacity of zeolite to immobilize Cu (qmax) is 63,69 mmolCu/kg Zeolite according to Langmuir adsorption equilibrium model. In addition, the capability to immobilize Cu will increases due to decreasing the grain size. The result of this research can be used as an alternative for waste water treatment, especially Cu. Keywords: Removal, copper (Cu2+), natural zeolite, Langmuir isotherm
Characteristics Of Hydrothermal Alteration In Cijulang Area, West Java, Indonesia Myo Min Tun; I Wayan Warmada; Agung Harijoko; Reza Al-Furqan; Koichiro Watanabe
Journal of Applied Geology Vol 7, No 1 (2015)
Publisher : Geological Engineering Department Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (11802.161 KB) | DOI: 10.22146/jag.16917

Abstract

Characterization of hydrothermal alteration in theCijulang area (West Java, Indonesia) was carriedout using shortwave infrared spectroscopy. Hydrothermal alteration in the Cijulang area occurs in the calc-alkaline volcanic and volcaniclastic rocks. Shortwave infrared spectroscopic measurements of reflectance for altered rocks and minerals were carried out by ASD-FieldSpec and the laboratory spectra acquired were then analysed with “The Spectral Geologist” software program. Shortwave infrared spectroscopy is capable of detecting most finegrained alteration minerals from different hydrothermal alteration zones. Characteristic alteration minerals identified from the SWIR technique include pyrophyllite, alunite, kaolinite, dickite, illite, montmorillonite, polygorskite, gypsum, epidote, paragonite, and muscovite. Most of the spectra show mixture ofalteration minerals and only a few display pure spectra of single mineral. The crystallinity of kaolinite from the samples was also determined from the reflectance spectra and show moderately to high crystallinity. Alteration system of the Cijulang prospectis similar to others documented high-sulfidation epithermal deposits, such as Rodalquilar (Spain), Summitville (Colorado), and Lepanto (Philippines). A characteristic alteration sequence and zonation of advanced argillic, argillic and propylitic alterationoutward from the silica core has resulted from the progressive cooling and neutralization of hot acidic magmatic fluid with the host rocks.Keywords: Cijulang, High-sulfidation, Alteration minerals, Shortwave Infrared Spectroscopy
Co-Authors A. Harijoko A. Imai A. Imai A. M. Imran A. W. Yogatama Agung Harijoko Agus Prasetya Ahmad Aminuddin, Muhammad Irman Khalif bin Akira Imai Al-Furqan, Reza Aldian Fahrialam Alvian Rizky Yanuardian Anastasia Dewi Titisari Anita Yuliyanti Anita Yuliyanti Ariffin, Kamar Shah Arifudin Idrus Arifudin Idrus Arifudin Idrus Arifudin Idrus Atmaja, Ammar Dwi Aulia Rahmah Karunianti Aung Tay Zar Aung Tay Zar, Aung Tay Bhakti H. Harahap Bhakti H. Harahap Bunchoeun Pich Chusni Ansori Denizar Rahman Deviana Shinta Maulana Dian Novia Sartika Dian Yesy Fatimah Diyan Aditya Putra Pratama Doni Prakasa Eka Putra Ega Gita Prasastia Endah Retnaningrum Endah Retnaningrum Endang Tri Wahyuni F. Pratiwi Fadlin Fadlin Fadlin Fadlin Fadlin Fadlin Fadlin, Fadlin Franz Michael Meyer Franz Michael Meyer Franz Michael Meyer, Franz Michael Gevor, Even Hakim, Fahmi Haryono, Septiawan Nur Hasria Hasria Hasria Hasria Hasria Hasria, Hasria Herry Yogaswara Heru Hendrayana Hideki, Ohta Himawan Tri Bayu Murti Petrus Hirajima, Tsuyoshi Htun, Tin May I Gde Budi Indrawan I. G. Sukadana I. Nur I. Nur I. Nur Imai, A. Imai, Akira Irzal Nur Irzal Nur, Irzal Iwan Setiawan Jochen Kolb Johan Syafri Mahathir Ahmad Kaharuddin Kaharuddin Kaharuddin, Kaharuddin Kamar Shah Ariffin Kant, Win Kha Yay Oo Khant, Win Koichiro Watanabe Koichiro Watanabe Koichiro Watanabe Koichiro Watanabe Koichiro Watanabe Koichiro Watanabe, Koichiro Kolb, Jochen Kotaro Yonezu Kusumaningrum, Serafica Btari Christiyani Kyaw Linn Zaw Leonardo Anthony Wijaya Lestari Sutra Simamora Linn Zaw, Kyaw Lucas Donny Setijadji Makruf Nurudin Martadiastuti, Vanadia Maulana, Deviana Shinta Mochammad Aziz Mochammad Aziz, Mochammad Mudinillah, Adam Muhamad Ilham Muhammad Irman Khalif bin Ahmad Aminuddin Muhammad Zulfikrie Mutiara Selvina Myo Min Tun Myo Min Tun Myo Min Tun Naing Oo, Toe Nugroho Imam Setiawan Nur, I. Nur, I. Okki Verdiansyah Okki Verdiansyah Okki Verdiansyah Oo, Than Than Pich, Bunchoeun Pramumijoyo, Pranayoga Pramumijoyo, S. Pranayoga Pramumijoyo Prasastia, Ega Gita Putra Pratama, Diyan Aditya Rahman, Denizar Retno Hartati Reza Al-Furqan Riana Listiyastuti Riyadi, Hasan Rodhie Saputra S. Pramumijoyo S. Pramumijoyo Salafudin Salafudin, Salafudin Sang Kompiang Wirawan Saputra, Rodhie Sartika, Dian Novia Seang Sirisokha Septiawan Nur Haryono Sirisokha, Seang Soewondo, Widiasmoro Subagyo Pramumijoyo Subagyo Pramumijoyo, Subagyo Sufriadin, Sufriadin Sukmandaru Prihatmoko Sukmandaru Prihatmoko Syafruddin Maula Syafruddin Maula T. B. Adimedha Takemura, Jiro Tetsuro Yoneda Than Than Oo Tin May Htun Toe Naing Oo Tsuyoshi Hirajima Tsuyoshi Hirajima Tun, Myo Min Ubaidillah, Aji Syailendra Vanadia Martadiastuti Wahyu Wilopo Wawan Budianta Widiasmoro Soewondo Win Kant Win Khant Yoneda, Tetsuro Yonezu, Kotaro Yonezu, Kotaro