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Journal : Reaktor

The Use of Natural Zeolite as A Catalyst for Esterification Reaction Between Glycerol and Oleic Acid Anggara Diaz Ramadhan; Nindya Carolina C.S; Nuryoto Nuryoto; Teguh Kurniawan
Reaktor Volume 19 No. 4 December 2019
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (388.938 KB) | DOI: 10.14710/reaktor.19.4.172-179

Abstract

Natural zeolite in Indonesia generally divided into 2 types, which are mordernite and clinoptilolite. As far the use of zeolites is very limited. This experiment tries to use both types of natural zeolites to find out its work. The purpose of this experiment is testing the performance of mordenite natural zeolite from Bayah-Indonesia and clinoptilolite from Lampung- Indonesia in the esterification reaction between glycerol and oleic acid integrated by several variable that affect the reaction. The experiment will be done by using three-neck rounded flask batch reactor. The result showed that modernite zeolite has a better performance compared to clinoptilolite zeolite. To get the oleic acid conversion of 70%, clinoptilolite zeolite needs 4% catalyst of glycerol weight and reactant ratio of 6:1 mole of glycerol/mole of oleic acid, Meanwhile the mordernite zeolite only needs 2% catalyst of glycerol weight with reactant ratio of 4:1 mole of glycerol/mole of oleic acid.Keywords: natural zeolite; glycerol; reaction; diffusion
Effect of Acid Concentration on the Activation of Bayah Natural Zeolite for Palm Kernel Shell Pyrolysis Application Endang Suhendi; Andre Wibowo; Tia Lestari; Teguh Kurniawan
Reaktor Volume 20 No.3 September 2020
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (543.303 KB) | DOI: 10.14710/reaktor.20.3.109-116

Abstract

Biooil is the main product in the pyrolysis process which is expected to be a liquid fuel replacement solution. But the resulting biooil cannot be directly used as a result of high oxygenated compounds, high viscosity, corrosive, and unstable. Addition of activated natural zeolite catalyst to the pyrolysis process is expected to improve the quality of biooil in order to be used as a renewable liquid fuel. The research aims to determine the influence of acid concentrations on zeolite modification to the characteristics of pyrolysis products. Result of catalyst characterization indicates that zeolite activation using acid will increase Si/Al ratio as well as open the surface of previously hindered zeolite. The yield of char produced in this study tends not to undergo significant changes between the catalytic and noncatalytic pyrolysis by 33% wt. Addition of zeolite catalyst in pyrolysis proved to be able to increase the content of phenol and decrease the content of acetic acid in bio-oil by 6% . Meanwhile, yield of CO2 increases by 20% in the use of catalysts due to the release of oxygen in the oxygenate compounds. The results of this study showed that the resulting biooil still does not meet the specifications of liquid fuels but can be utilized as a renewable chemical feedstock.Keywords: pyrolysis; biomass; natural zeolite;modified
Co-Authors Abdul Hadi Abdusattar, Thareqa ACHMAD RIFAI Adian Yoga Pradana Adiwibowo, Muhammad Triyogo Aisyah, Ratna Sari siti Alia Badra Pitaloka Andre Wibowo Anggara Diaz Ramadhan Anita Diyanah Anton Irawan Asep Bayu Dani Nandiyanto Bindar, Yazid Damar Abi Ramadani Darisman Darisman Dhimas Satria Dina Pujianti Endang Suhendi, Endang Erny Listijorini Fajar Gumelar Fauzan, Eka R. Fiandini, Meli Firdaus, Mochamad Adha Frans Romario Panjaitan Ghani Naufal Hafid Alwan Hafid Alwan Hairus Abdullah Handry Shantos Hanif Nur Purnamasari Hesti Prihastuti Ilham, Willy Aulia Imron Rosyadi Indar Kustingsih Indar Kustiningsih Jayanudin Jayanudin Juniafit Bima Saputra Kustiningsih, Indar Makiyi, Muhammad Marta Pramudita Mentari Putri Aprilia Muchamad Ismettulloh Muhammad Roil Bilad Muhammad Saifullah Abu Bakar Murni, Dewi Naibaho, Pipiet P.U. Nik Abdul Hadi Md Nordin Nindya Carolina C.S Nisa Aina Fauziah Novan Prihasa Nurwijayanti Nuryoto Nuryoto, Nuryoto Oki Muraza Putri, Berliana Tristati Putri, Martina Reza Raffli Nurmuhammad Ragadhita, Risti Rahmayetti Rahmayetti Rahmayetty Rahmayetty Ranggaweny Al-Ghani Ranggaweny Al-Ghani Ratna Sari Siti Aisyah Rina Lusiani Rosid Rosid Saepurahman Saepurahman Saepurahman Saepurahman Saepurahman, Saepurahman Saiful Bahri Salman, Nidya Jullanar Sari, Denni Kartika Selfira Arum Andadari Septian Arief Nur Rahman Sjaifuddin Sjaifuddin Slamet, Slamet Sri Agustina Tia Lestari Vicky Zayan Giffari Wahyudi Eko Pratomo Willy Aulia Ilham Yazid Bindar Yazid Bindar Yazid Bindar Yogi Wibisono Budhi Yuhelsa Putra