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Journal : Bulletin of Chemical Reaction Engineering

Synthesis of Porous N-doped TiO2 by Using Peroxo Sol-Gel Method for Photocatalytic Reduction of Cd(II) Diana Vanda Wellia; Dina Nofebriani; Nurul Pratiwi; Safni Safni
Bulletin of Chemical Reaction Engineering & Catalysis 2022: BCREC Volume 17 Issue 1 Year 2022 (March 2022)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.17.1.12347.103-112

Abstract

Porous N-doped TiO2 photocatalyst was successfully synthesized by an environmentally friendly peroxo sol-gel method using polyethylene glycol (PEG) as a templating agent. Here, the effect of PEG addition to the aqueous peroxotitanium solutions on the structure, pore properties and photocatalytic activity of the obtained photocatalysts was systematically studied. The prepared photocatalysts were characterized by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), and Brunauer-Emmett-Teller (BET). It was found that the doping of nitrogen narrows the band gap of TiO2 leading to enhance its visible-light response. The BET analysis shows that the prepared photocatalysts have a typical mesoporous structure with pore sizes of 3–6 nm. The photocatalytic activity of the prepared photocatalysts was evaluated by photocatalytic reduction of Cd(II) in an aqueous solution under visible light irradiation. The results show that porous N-doped TiO2 with the optimal PEG addition had the highest Cd(II) reduction of 85.1% after 2.5 h irradiation in neutral aqueous solution. This significant improvement in photocatalytic activity of the prepared photocatalysts was mainly attributed to the synergistic combination of N doping and porous structure, which could actively increase the catalytic active site of this photocatalysts. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Co-Authors -, Maizatisna -, Roswita -, Zulfarman Abinul Hakim Adlis Santoni Admi Admi Aldini, Tasya Amelia, Fitrah Anggraini, Deby Anna Fadhilla Arief Yandra Putra Bhayu Gita Bhernama BUSTANUL ARIFIN Chris Deviarny Deby Anggraini Deliza - Deliza, Deliza Desmiati - Deswati Deswati Dheasy Gustira Dina Nofebriani Dini Hariyati Adam Dytta Fitria Elma Fadrita Rahman Emriadi - Eno Okta Patricia Era, Yuni Fadhilla, Anna Fardila Sari Febi Rahmi Febrina Arfi Fitra Febrianti Fitrah Amelia Fitrah Amelia fitri mairizki Fitri Mairizki, Fitri Fivi Mona Bareno Gustiana, Mega Hakim, Abinul Hamzar Suryani Hamzar Suyani Harza Dipajana Umardi Hazanita Jumiaty Hazanita Jumiaty Henny Lucida Hermansyah Aziz Hermansyah Aziz Hilfi Pardi Ibnu Irawan Imelda Imelda Jarnuzi Gunlazuardi Jihanul Khaira K Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah, Khoiriah Liansari, Oktanora Mai Efdi Mai Efdi Maizatisna - Maizatisna Maizatisna Marniati Salim Matlal Fajri Alif Mechy Rezita Wahyuni Mega Gustiana Muhamad Nasir Muhamad Nasir, Muhamad Neila Yenni Norman Ferdinal Novesar Jamarun Novesar Jamarun Nurul Pratiwi Oktanora Liansari Olly Norita Tetra Putri Arwanda Putri Perdana Roza Putri, Reza Audina Rahmi, Febi Rahmiana Zein Refilda Refilda Refinel - Reza Audina Putri Reza Audina Putri Roswita - Roza, Putri Perdana Sakai, T. Sakai, Tadao Salmariza Sy Sumaryati Syukur Suryati Suryati Syukri - Syukri Arief Syukri Syukri Syukri Syukri Syukri Syukri T. Sakai Tadao Sakai Tommi Hermansyah Trisna Olinovela Trisna Ollinovela Umiati Loekman Umiati Loekman Umiati Loekman Upita Septiani Vanny Yulia Safitri Vepilia Wulanda Wellia, Diana Vanda Willy Cahya Nugraha Willy Cahya Nugraha, Willy Cahya Yefrida - Yefrida Yefrida Yetria Rilda Yuli Okta Fitriyani Yulizar Yusuf Yulizar Yusuf Yuni Era Zaimi Abdullah Zaimi Abdullah Zilfa Zilfa Zulfarman - Zulfarman Zulfarman Zulkarnain Chaidir