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All Journal Reaktor Journal of Engineering and Technological Sciences JURNAL SELULOSA ASEAN Journal of Chemical Engineering Jurnal Teknologi Bahan dan Barang Teknik Jurnal Teknik Kimia Indonesia Bulletin of Chemical Reaction Engineering & Catalysis Journal of Engineering and Technological Sciences

S. Subagjo

Chemical Engineering Department, Institut Teknologi Bandung

Author-ID : 444851

Aerospace Engineering Automotive Engineering Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Computer Science & IT Control & Systems Engineering Education Electrical & Electronics Engineering Energy Engineering Materials Science & Nanotechnology

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ISOTHERMAL PYROLYSIS OF KRAFT PULP MILL SLUDGE Syamsudin Syamsudin; Herri Susanto; Subagjo Subagjo
Reaktor Volume 14, No. 4, OKTOBER 2013
Publisher : Dept. of Chemical Engineering, Diponegoro University

Kraft pulp mill sludge cake composed of rejected wood fibers and activated sludge microorganisms. With a heating value about 14 MJ/kg (dried basis), this type of biomass had a potential as an alternative energy source. Unfortunately, it had an ash content of 27.6% and a moisture content of 80%. For reducing moisture content with minimum energy consumption, a combination of mechanical dewatering and thermal drying was studied previously. Meanwhile, experiments on isothermal pyrolysis had been carried out for further improvement on ultimate and proximate analysis of solid fuel. Final mass of char obtained from pyrolysis at 500oC was not significantly different from that of 700oC, so pyrolysis was considered to be optimum at 500oC. A char obtained from pyrolysis at temperature of 500oC had a pore surface area of 77.049 m2/g (highest among other temperatures). Kinetic of isothermal pyrolysis was well represented with a first order modified volumetric model with a frequency factor of 0.782 1/s and an activation of 34.050 kJ/mol.

POTENSI KATALIS PADAT ASAM GAMMA ALUMINA TERSULFATASI PADA REAKSI ESTERIFIKASI MINYAK BIJI KARET Maria Ulfah; S Subagjo
Reaktor Volume 16 No.3 September 2016
Publisher : Dept. of Chemical Engineering, Diponegoro University

POTENTIAL OF SULFATET ALUMINA-HETEROGENEOUS ACID CATALYST IN ESTERIFICATION RUBBER SEED OIL. Two tipe of catalysts have been synthesed and evaluated ( free fatty acid conversion) in esterification of rubber seed oil. The first and the second catalyst have content SO3 8,821 % and 40,715 %, respectly. The optimum condition of reaction studied : volume ratio methanol/oil 0,9-1,8 v/v; catalyst concentration 1,67-10 % wt/v; time of reaction 1-7 hours and temperature of reaction 50-70 oC. This study showed, the second catalyst more active than the first catalyst. Maximum conversion from esterification reaction of rubber seed oil of the first and the second catalyst are 75 % and 97 %, respectly. The optimum condition of reaction achieved at volume ratio methanol/oil 1,8 v/v; catalyst concentration 1,67 % wt/v; time of reaction 7 hours and temperature of reaction 70 oC. Keywords: sulfated alumina, free fatty acid, eterification, rubber seed oil.AbstrakDua tipe katalis alumina tersulfatasi telah disintesis dan dievaluasi kinerjanya (berupa konversi Asam Lemak Bebas, ALB) pada reaksi esterifikasi asam lemak bebas minyak biji karet. Katalis tipe 1 dan tipe 2 berturut-turut memiliki kandungan SO3 8,821 % dan 40,715 %. Kondisi optimasi reaksi yang dipelajari: rasio volume metanol/minyak 0,9-1,8 v/v; konsentrasi katalis 1,67-10 % b/v; waktu reaksi 1-7 jam dan temperatur reaksi 50-70 oC. Hasil penelitian menunjukkan katalis tipe 2 lebih aktif dari tipe 1. Konversi ALB maksimum dari reaksi esterifikasi minyak biji karet dengan katalis tipe 1 dan tipe 2 berturut-turut 75 % dan 97 %. Kondisi optimum reaksi tersebut dicapai pada rasio volume metanol/minyak 1,8; konsentrasi katalis/minyak 1,67 % b/v; lama reaksi 7 jam dan temperatur reaksi 70 oC. Kata kunci: alumina tersulfatasi, asam lemak bebas, esterifikasi, minyak biji karet

KINETIKA HIDRODESULFURISASI DIBENZOTHIOPHENE (HDS DBT) MENGGUNAKAN KATALIS NiMo/γ-Al2O3 Subagjo Subagjo; Maria Ulfah
Reaktor Volume 14, No. 4, OKTOBER 2013
Publisher : Dept. of Chemical Engineering, Diponegoro University

Evaluasi kinetika reaksi hidrodesulfurisasi (HDS) dibenzothiophene dan simulasi nafta hydrotreater yang berada di PT. PERTAMINA Refinery Unit II Dumai menggunakan katalis NiMo/Al2O3 hasil pengembangan telah dilakukan. Kinetika reaksi HDS DBT dilakukan dalan sistem reaktor batch dengan variasi temperatur 280-320oC dan tekanan 30 bar. Data kinetika diolah dengan persamaan hukum pangkat (law power) dan persamaan kinetik mekanistik (Langmuir Hinshelwood, LH). Berdasarkan model hukum pangkat, kinetika HDS DBT menggunakan NiMo/Al2O3 hasil pengembangan merupakan orde satu terhadap DBT dengan konstanta Arhenius sebesar 165633 detik-1 dan energi aktivasi 69017 J/mol (16,56 kkal/mol). Model LH yang cocok untuk reaksi HDS DBT menggunakan NiMo/Al2O3 hasil pengembangan adalah model LH yang mengilustrasikan adanya kompetisi antara reaktan DBT dan H2 pada tipe pusat aktif yang sama, dengan DBT teradsorb secara kuat sedangkan H2 teradsorpsi secara lemah. Energi aktifasi dan konstanta Arhenius berdasarkan model LH ini ini berturut-turut adalah 81409 J/mol (19,34 kkal/mol) dan 1658133 s-1. Dengan menggunakan persamaan laju reaksi hukum pangkat, model memberikan hasil konversi sulfur yang sama dengan hasil keluaran reaktor nafta hydrotreater RU II-Dumai, yaitu mencapai 98%.

PENGARUH PERBEDAAN SIFAT PENYANGGA ALUMINA TERHADAP SIFAT KATALIS HYDROTREATING BERBASIS NIKEL-MOLIBDENUM Maria Ulfah; Subagjo Subagjo
Reaktor Volume 14, Nomor 2, Oktober 2012
Publisher : Dept. of Chemical Engineering, Diponegoro University

EFFECT OF ALUMINA SUPPORT PROPERTIES ON THE NICKEL-MOLIBDENUM BASE HYDROTREATING CATALYST. Effect of surface characteristics of three species of synthesized γ-alumina (alumina-1, alumina-2 and alumina-3) on characteristics NiMo catalysts has been studied. Those aluminas are derived from boehmite Catapal B by varying rasio mol nitric acid to boehmite. A sol-gel method is used to synthesize γ-Al2O3 support. The Nitrogen adsorption, X-ray diffraction (XRD), Temperature Programmed Reduction (TPR) of H2, Temperature Programmed Desorption (TPD) of NH3, and mechanical strength are used to characterize the supports and catalysts. The results showed that the surface area alumina affects the formation of crystalline MoO3 in the NiMo catalyst, while γ-Al2O3-3 support which has the highest surface area (about 195 m2/g) compared to the other two types of alumina (>195 m2/g) does not have a crystalline MoO3. The formation of crystalline MoO3 is not influenced by the acidity alumina. Based on the results of XRD, it is indicated that the supported alumina-3 NiMo catalyst (having the highest acid strength) shows that there is no presence of crystalline MoO3. Pore size distribution of support did not change significantly after the deposition of Ni and Mo oxides. Mechanical strength of support also affects the strength NiMo catalyst. Support alumina-3 which has the highest mechanical strength gives the mechanical strength of the highest NiMo catalyst. Pengaruh sifat penyangga γ-alumina hasil pengembangan (alumina-1, alumina-2 dan alumina-3) pada karakter katalis hydrotreating nikel-molibdenum (NiMo) telah dipelajari. Ketiga jenis γ-alumina diturunkan dari boehmite “Catapal B” dengan menvariasikan nisbah mol asam nitrat terhadap boehmite. Pembuatan γ-alumina menggunakan metoda sol-gel. Adsorpsi Nitrogen, X-ray difraksi (XRD), Temperature Programmed Reduction (TPR) H2, Temperature Programmed Desorption (TPD) NH3, dan kekuatan mekanik digunakan untuk mengkarakterisasi penyangga dan katalis. Hasil penelitian menunjukan bahwa luas permukaan alumina mempengaruhi pembentukan kristalin MoO3 dalam katalis NiMo. Pada penyangga alumina-3 yang memiliki luas permukaan yang paling tinggi (sekitar 195 m2/g) di banding dua jenis alumina lainnya (>195 m2/g) tidak memiliki kristalin MoO3. Pembentukan kristalin MoO3 tidak dipengaruhi oleh sifat keasaman alumina. Berdasarkan hasil XRD ditunjukan bahwa pada katalis NiMo berpenyangga alumina-3 (memiliki kekuatan asam yang paling tinggi) tidak terdapat adanya kristalin MoO3. Distribusi ukuran pori peyangga tidak berubah signifikan setelah deposisi oksida Ni dan Mo. Kekuatan mekanik penyangga mempengaruhi pula kekuatan katalis NiMo. Penyangga γ Al2O3-3 yang memiliki kekuatan mekanik yang paling tinggi memberikan kekuatan mekanik katalis NiMo yang tertinggi.

Co-Authors Achmad Syamsul Arief Adnanta Rio Agus Subekti Ahlul Hafizan Resha Anita K. Wardani Anita K. Wardani, Anita K. Candra Lutfi Widikrama Carolus Borromeus Rasrendra Danu Ariono David Bahrin Deviana Pramitasari Endang Sri Rahayu Endar Puspawiningtiyas Farhansyah Yusuf Putra Hudaya Fitri Rumiani Galang Putra Persada Grandprix T.M. Kadja Hendra Suherman Herri Susanto I G. B. N. Makertihartha I Gede Wenten I.G.B Ngurah Makertihartha IGBN Makertihartha IGBN Makertihartha IGBN Makertihartha Kevin R. Lismana Kevin R. Lismana Khasin Fuadi Khasin Fuadi Lita Marina Nisa M. Effendy M. Effendy M. Effendy M. Effendy M. Effendy Maria Ulfah Meiti Pratiwi Melia L. Gunawan Melia Laniwati Melia Laniwati Gunawan Melia Laniwati Gunawan Melia Laniwati Gunawan Melia Laniwati Gunawan Melia Laniwati Gunawan Mohammad Effendy Mohammad Effendy P.T.P. Aryanti P.T.P. Aryanti, P.T.P. Praharso Paharso Praharso Praharso Pratama Istiadi Rino R. Mukti Rizky Gilang Kurniawan Shelli R. Joscarita Shelli R. Joscarita, Shelli R. Syamsudin Syamsudin Syamsudin Syamsudin T. Walmiki Samadhi Tatang Hernas Soerawidjaja Temy Nurfahmiawati Tirto Prakoso Tjokorde Walmiki Samadhi Tjokorde Walmiki Samadhi Tjokorde Walmiki Samadhi Tobias Richards Ulfah, Maria Vita Wonoputri Vita Wonoputri Widdy Andya Fanny Winny Wulandari, Winny Yazid Bindar Yazid Bindar Yazid Bindar Yazid Bindar Yogi W. Budhi Yogi W. Budhi Yogi Wibisono Budhi Zaky Al Fatony

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