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CONVERSION OF (±)-CITRONELLAL AND ITS DERIVATIVES TO (-)-MENTHOL USING BIFUNCTIONAL NICKEL ZEOLITE CATALYSTS Adilina, Indri Badria; Pertiwi, Ralentri; Sulaswatty, Anny
Biopropal Industri Vol 6, No 1 (2015)
Publisher : Balai Riset dan Standardisasi Industri Pontianak

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Abstract

(±)-Citronellal and its derivatives were converted to (-)-menthol by a one-pot reaction system using zeolite based nickel catalysts. The catalysts were prepared by immobilization of nickel on natural zeolite (NZ) or synthetic zeolite (ZSM-5) by a simple cation exchange method. Calcination and hydrogen treatment procedures were able to significantly increase the surface area and pore volume of NZ based catalysts whereas negligible changes in the properties were observed for that of ZSM-5. Catalytic reactions were carried out at 70ºC by stirring the mixture in the air for cyclization of (±)-citronellal to (±)-isopulegol followed by hydrogenation towards the desired (-)-menthol at 2 Mpa of H2 pressure. The Ni/NZ catalyst was able to convert a (±)-citronellal derivative yielding 9% (-)-menthol (36% selectivity) with conversion up to 24%, whereas Ni/ZSM5 catalyst directly converted 65% (±)-citronellal to give 4% menthol (6% selectivity). These zeolite based catalysts are therefore potential materials for the conversion of biomass feed stock to value-added chemicals.
Patchouli Oil Production for Fixative Aromatheraphy: A Case Study Design of Condenser for Steam Distillation Agustian, Egi; Sulaswatty, Anny
Biopropal Industri Vol 6, No 1 (2015)
Publisher : Balai Riset dan Standardisasi Industri Pontianak

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Abstract

Patchouli oil is an important material for aromatherapy industries and made from patchouli leaves by steam distillation. The important parts of steam distillation is condenser. The problem is process of farmers patchouli based on experience not used chemical process of steam distillation cause not effective and efficient. The study was designed of condensers on steam distillation for patchouli leaves. Specification of condenser type is shell and tube, stainless steel material and water as coolant. Tubing sized is ¼ inch with 500 mm of length and 24 pieces. Shell measuring 2.5 inch and 600 mm of length. The performance of condenser gave the efficiency at 94.51%. The process condition of ratio stems to leaves is 5:6 and 4.5 hours was considered ideal for steam distillation. The used of energy is lowest cause the efficiency condenser and yield will be higher. Patchouli oil yield of 2.39% and patchouli alcohol content is 35.65%.
Modeling Social, Health, and Vaccines Intervention in Time of Covid-19 Pandemic Impacted in Jakarta - Indonesia Setiawan, Arief Ameir Rahman; Susanto, Heru; Adjie, Firman Tri; Prasetiya, Hafiizh; Laksmono, Joddy Arya; Sulaswatty, Anny; Wiloso, Edi Iswanto; Hidayat, Dudi
Unnes Journal of Public Health Vol 10 No 1 (2021): Unnes Journal of Public Health
Publisher : Universitas Negeri Semarang (UNNES) in cooperation with Association of Indonesian Public Health Experts (Ikatan Ahli Kesehatan Masyarakat Indonesia (IAKMI))

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/ujph.v10i1.43065

Abstract

Since the first outbreak of SARS-CoV-2 worldwide, research on modeling and simulation has grown, particularly to estimate the peak and end time of the pandemic which has been exceeded in some cases. This study aims to model the current virus spread with discrete event simulation, using the case of Jakarta. About 2 million of Jakarta's susceptible population was used for the the model's input which ran for a year. The data was obtained from past records and were divided into three main timelines (i.e. initial stage, large scale restriction and new normal) in order to validate the model with real cases step by step. Scenario analysis was then performed by evaluating five possible interventions such as: existing scenarios, social and health intervention, mass vaccination and hybrid intervention. The results show that the model represents real cases with a variation of less than 5% during the timeline. Furthermore, scenario analysis showed that mass vaccination, hybrid and social intervention provide the least positive cases in the system. This study recommends that hybrid intervention should be used while the vaccine is being mass produced, and the implementation of social intervention should be highlighted.
Molar Ratio Comparison of Ti-Zr as Catalyst Support of Bentonite in Esterification Reaction Firmansyah, Sanji; Agustian, Egi; Rinaldi, Nino; Widiarti, Nuni; Hanifah, Yuliza; Maisaroh, Maisaroh; Sulaswatty, Anny
Bulletin of Chemical Reaction Engineering & Catalysis 2025: BCREC Volume 20 Issue 1 Year 2025 (April 2025)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20258

Abstract

Natural bentonite from Pacitan - Indonesia as a support in the preparation of Ti and Zr-pillared metal catalysts (Ti-Zr/bent) for esterification reaction were studied. The preparation of Ti-Zr/bent catalyst was prepared to find out the effect of molar ratios (Ti:Zr) where an investigation was performed in the esterification of waste cooking oil. The catalyst was varied as follows: 0.5:1 (Ti-Zr-1/bent), 1:1 (Ti-Zr-2/bent), 1.5:1 (Ti-Zr-3/bent), 2:1 (Ti-Zr-4/bent), and 5:1 (Ti-Zr-5/bent) were used to determine the yield. The reaction was carried out for 3 hours at 150°C and a pressure of 40 bar N2 gasses. The result of the Ti-Zr/bent catalyst was given increasing significantly for surface area of 133–147 m²/g compares to bentonite 27 m²/g and 10 times of acidity. The best catalyst was shown in 2:1 of ratio Ti:Zr (molar) on esterification reaction with succesfuly performed about 80.40% of yield. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
The Significant Process Variable of Tea Powder Production Based On Spray Dry Method Fitriady, Muhammad Arifuddin; Rohmah, Alfissyahriyah Nur; RINALDI, NINO; Agustian; SULASWATTY, ANNY; Shabri, Shabri
Jurnal Sains Materi Indonesia Vol. 26 No. 1 (2024): Jurnal Sains dan Materi Indonesia
Publisher : BRIN Publishing (Penerbit BRIN)

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Abstract

Polyphenol, which is very beneficial to the human body, especially as an obesity inhibitor, is one of the leading nutrient content in green tea leaves. To increase popularity as well as practicability, product development needs to be conducted, one of which is to produce an effervescent instant tea. However, a high-density instant tea powder is required in this product development. This study was conducted to predict the significant process variables which affect the density as well as the yield of the instant tea powder. The exploration of significant process variables was conducted based on the Design of the Experiment, while the tea extract was produced using maceration techniques. Maltodextrin was added to the tea extract based on the concentration filler variable. The instant tea powder was produced by the spray drying method, which variable includes the concentration of maltodextrin (filler), the pump flow rate (feed pump), the outlet temperature (Tout), the fan speed, and the atomization air pressure (nozzle). The tapped density of the instant tea powder was analysed and the yield was calculated for each condition. Based on the Pareto graph, it was found that the atomization air pressure (nozzle) is the most significant variable in the spray dry process of instant tea powder.
Bio-briquettes from tea fluff biochar: a response surface methodology study on particle size, resin gum-adhesive, and used cooking oil immersion time Suryajaya, Suryajaya; Agustian, Egi; Haryanti, Ninis Hadi; Prasetia, Hafiizh; Rahmah, Siti; Kurniawan, Hendris Hendarsyah; Wianto, Totok; Ramadhoni, Benni F; Manik, Tetti Novalina; Annisa, Nova; Rezamela, Erdiansyah; Sulaswatty, Anny
International Journal of Renewable Energy Development Vol 14, No 5 (2025): September 2025
Publisher : Center of Biomass & Renewable Energy (CBIORE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/ijred.2025.60877

Abstract

Fluff tea is the residual solid waste generated in the green tea industry and holds the potential for development as a solid fuel in bio-briquettes. This study transformed fluff tea into bio-briquettes utilizing biochar produced through slow pyrolysis. The study aimed to optimize bio-briquettes production from fluff tea using the Response Surface Methodology (RSM) approach through proximate analysis. The cylindrical bio-briquettes were produced using biochar particle sizes of 850, 500, and 150 μm, resin gum adhesive concentrations of 10%, 15%, and 20%, and immersion times in cooking oil of 0, 3, and 6 minutes. The results showed that the overall response by the p-value was <0.05, and the lack of fit was insignificant (p-value >0.05). The findings indicated that the calorific value of tea fluff rose from 4,482.56 cal/g to 6,374.98 cal/g after conversion to biochar. The optimum conditions for producing tea fluff bio-briquettes were a particle size of 850 μm, adhesive concentration of 11%, and immersion time of 5 minutes. The bio-briquettes exhibited a moisture content of 3.53%, ash content of 5.65%, volatile matter of 14.75%, fixed carbon of 76.14%, calorific value of 7,796.37 cal/g, combustion rate of 0.11 g/min, density of 1.22 g/cm3, and compressive strength of 35.57 N/cm2. Most tea fluff briquettes' properties had met Indonesia's briquettes standard. The production of bio-briquettes from tea fluff waste is a viable alternative fuel for both industrial and domestic applications.
EFFECT OF GINGER OLEORESIN CONCENTRATION ON THE ENCAPSULATION PROCESS USING IONIC GELATION Permana, Asep Wawan; Mardiyyah, Annisah; Wiguna, Bangkit; Laksono, Hendrawan; Aji, Galih Kusuma; Mufti, Ayi; Atmaji, Priyo; Muhamaludin; Budiyanto; Kusumasmarawati, Ambar Dwi; Prasetyo, Wegik Dwi; Sulaswatty, Anny; Nasori, Achmad Sofian
Jurnal Teknologi Industri Pertanian Vol. 34 No. 3 (2024): Jurnal Teknologi Industri Pertanian
Publisher : Department of Agroindustrial Technology, Bogor Agricultural University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24961/j.tek.ind.pert.2024.34.3.279

Abstract

The primary active components in ginger oleoresin are gingerol and shogaol, with gingerol exhibiting significant pharmacological activities such as anti-inflammatory, antioxidant, and analgesic effects. However, gingerol is heat-sensitive and degrades at elevated temperatures, limiting its functional efficacy when consumed. To overcome this limitation, encapsulation of ginger oleoresin was performed to enhance its physical and functional properties and improve its bioavailability. This study utilized the ionotropic gelation method to encapsulate ginger oleoresin, resulting in the formation of beads. Alginate was employed as the encapsulation matrix. The dried beads were characterized using FTIR, SEM, disintegration tests, and encapsulation efficiency was assessed via UV-Vis spectrophotometry. Results demonstrated that alginate beads containing ginger oleoresin could be successfully synthesized using the ionotropic gelation technique, with alginate as the polymer and CaCl2 as the cross-linking agent. Ginger oleoresin concentrations of 0.9%, 0.7%, 0.5%, and 0.3% were tested. The highest encapsulation efficiency, 72.48%, was obtained with a ginger oleoresin concentration of 0.7%. Surface morphology analysis revealed that the alginate beads exhibited a rough, porous texture with visible folds. Furthermore, the dry beads disintegrated within 30 minutes. Keywords: alginate, beads, encapsulation, ginger oleoresin, ionic gelation method