Claim Missing Document
Check
Articles

MINI REVIEW : SINTESIS KOMPOSIT Fe3O4/ARANG AKTIF SEBAGAI MEDIA ADSORPSI Laurentha, Nantha; Hindryawati, Noor
PROSIDING SEMINAR KIMIA Vol 3 No 2 (2025): Prosiding SNKT 2024
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Mini review of Fe3O4/activated carbon composite synthesis as adsorption media. The purpose of this mini review is to optimize adsorption efficiency through variations of different types of activated carbon. The Fe3O4/activated carbon composite is used as adsorption media due to its high adsorption capacity, and the magnetic properties of Fe3O4 facilitate the separation of the composite from the solution after the adsorption process. Based on a literature review, the Fe3O4/activated carbon composite can be synthesized using the co-precipitation method, and characterization is performed using Fourier Transform Infrared Spectroscopy (FTIR), and X-Ray Diffraction (XRD). Therefore, this article reviews recent developments regarding the Fe3O4/activated carbon composite as an adsorption medium for dye wastewater. Keywords : Fe3O4, activated carbon, composite, adsorption.
Synthesis of Silver Nanoparticle Using Bio-Reductant from Wuluh Star Fruit (Averrhoa Bilimbi L.) Extract and Their Activity as Sunscreen Hindryawati, Noor; Muhammad Marion Akbar; Eva Marliana; Ratna Kusuma
Jurnal Bahan Alam Terbarukan Vol. 14 No. 1 (2025): June 2025 [Nationally Accredited Sinta 3]
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/jbat.v14i1.16552

Abstract

Synthesis of silver nanoparticles has been carried out using AgNO3 solution as precursor with wuluh star fruit extract as bioreductant and reacted under the sunlight. The synthesized silver nanoparticles were tested for its sunscreen activity. The synthesized has been done with optimation of AgNO3 precursor and bioreductant. Based on absorbances value using UV-Vis Spectrophotometer, it is shown that silver nanoparticles from 1,5 mM AgNO3 and 25% (v/v) extract are more stable than the other variation for 4 days. The characterization of silver nanoparticles using Transmission Electron Microscope (TEM) and Particle Size Analyzer (PSA) instrument result shows the morphology of rounded silver nanoparticles with diverse sizes at range 6,9 – 27,7 nm, and with average particle size of 14,8 nm. Particle Size Analyzer (PSA) instrument shows the distribution of silver nanoparticles at range under 100 nm. Sunscreen activity of silver nanoparticles shows the SPF value of 44,14 with ultra protection type and on high level. The SPF value obtained indicates that silver nanoparticles can be applied as sunscreen.  
Preparation of Fe3O4/TiO2/ZnO Composite as a Photocatalyst for the Degradation of Methylene Blue: Optimization and Light Source Variations Wulandari, Duwi Devi; Hindryawati, Noor; Subagyono, RR Dirgarini Julia Nurlianti
Jurnal Kimia Sains dan Aplikasi Vol 28, No 7 (2025): Volume 28 Issue 7 Year 2025
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/jksa.28.7.374-386

Abstract

The Fe3O4/TiO2/ZnO (MTZ) composite was synthesized by preparing Fe3O4 via the coprecipitation method, TiO2 via the hydrothermal method, and ZnO via the precipitation method. The three oxides (Fe3O4, TiO2, and ZnO) were composited using the solid-state method with varying mass ratios (1:2:1, 2:1:1, 1:1:2, and 1:1:1) and calcined at 600°C for 4 h to obtain MTZ composites. The composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and particle size analysis (PSA). The results indicated that the Fe3O4/TiO2/ZnO composite with a 1:1:2 ratio (MTZ3) exhibited the most favorable properties. MTZ3 was evaluated as a photocatalyst for methylene blue degradation under UV light, with variations in irradiation time, catalyst mass, and dye concentration. Further tests were conducted under sunlight and dark conditions using both the composite and its individual oxides (Fe3O4, TiO2, and ZnO). Reuse tests assessed the stability of MTZ3 after repeated cycles. Under optimum conditions (catalyst mass 0.4 g, methylene blue concentration 20 ppm, irradiation time 60 min), MTZ3 achieved 80.4% degradation under UV light. Under sunlight, degradation efficiency reached 98.7%, while under dark conditions it was only 4.5%. Reuse tests demonstrated consistent performance over three cycles, maintaining 80.4% degradation, surpassing previous studies on Fe3O4–TiO2 (1:2) composites, which achieved 67.49% degradation over two cycles. These results suggest that the MTZ3 composite is a stable and efficient photocatalyst with excellent potential for dye degradation under various light sources.
SINTESIS DAN KARAKTERISASI NANOPARTIKEL PERAK TERMODIFIKASI GLUTATHIONE MENGGUNAKAN REDUKTOR NaBH4 Aditya, Adrian Maulana; -, Daniel; Hindryawati, Noor
JURNAL ATOMIK Vol 10 No 2 (2025)
Publisher : Jurusan Kimia FMIPA UNMUL

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30872/ja.v10i2.1549

Abstract

Silver nanoparticles (AgNPs) possess remarkable properties that make them suitable for various applications in biomedical, environmental, and catalytic fields. This study focuses on the synthesis and characterization of glutathione-modified silver nanoparticles (AgNPs-GSH) using sodium borohydride (NaBH₄) as a reducing agent. The reduction of AgNO₃ by NaBH₄ produces elemental silver nanoparticles, as indicated by a color change to bright yellow due to the localized surface plasmon resonance (LSPR) phenomenon. The synthesized nanoparticles were stabilized using glutathione (GSH), which binds through thiol (-SH), amine (-NH₂), and carboxyl (-COOH) functional groups, enhancing the stability and biocompatibility of the AgNPs. UV-Vis spectroscopic analysis revealed a maximum absorbance at 408 nm, consistent with the optical properties of silver nanoparticles. Furthermore, particle size analysis indicated an average nanoparticle size of 1.271 nm, with some degree of agglomeration. These findings suggest the successful synthesis and functionalization of AgNPs-GSH with potential applications in nanobiotechnology.
Validasi Metode Penentuan Benzena, Toluena dan Xilena pada Sampel Udara dan Tanah Menggunakan Kromatografi Gas Panggabean, Aman Sentosa; Widyastuti, Tika; Hindryawati, Noor
ALCHEMY Jurnal Penelitian Kimia Vol 15, No 1 (2019): March
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (398.077 KB) | DOI: 10.20961/alchemy.15.1.25522.177-189

Abstract

Penelitian tentang validasi metode penentuan kadar benzena, toluena dan xilena pada sampel udara dan tanah dengan menggunakan kromatografi gas telah dilakukan. Untuk mendapatkan hasil pengukuran yang valid, beberapa parameter penting yang berpengaruh dalam validasi metode telah ditentukan. Beberapa parameter penting yang dilakukan adalah penentuan besaran dasar kromatografi yang meliputi: waktu retensi, kapasitas (k’), faktor selektivitas (α) dan kinerja analitik yang meliputi: penentuan linearitas (r), limit deteksi (LOD), limit kuantitasi (LOQ), presisi dan akurasi. Hasil penelitian penentuan kinerja analitik sangat baik ditunjukkan oleh nilai presisi sebagai % KV < 2/3 nilai KV Horwitz, LOD untuk masing-masing senyawa benzena, toluena dan xilena adalah 0,02 mg/L; 0,59 mg/L dan 0,08 mg/L serta LOQ untuk masing-masing senyawa benzena, toluena dan xilena adalah 0,07 mg/L; 1,99 mg/L dan 0,27 mg/L. Akurasi  metode ini sangat baik ditunjukkan dengan nilai presentase perolehan kembali masing-masing senyawa benzena, toluena dan xilena untuk sampel tanah sebesar 102,61 ± 4,61%; 101,65 ± 7,41%; 102,15 ± 4,15%, dan untuk sampel udara masing-masing senyawa sebesar 101,69 ± 5,77%; 102,08 ± 5,43% dan 98,55 ± 5,11%. Berdasarkan hasil penelitian ini, metode kromatografi gas dapat digunakan dalam penentuan benzena, toluena dan xilena pada sampel udara dan tanah dengan memberikan hasil yang valid.Validation Method on The Determination of Benzene, Toluene and Xylene in Air and Soil Samples Using Gas Chromatography. The present study investigated the method for the determination of the content of benzene, toluene, and xylene in air and soil samples using gas chromatography. To obtain a valid measurement result, several important parameters that influence the method validation have been determined. The several important parameters carried out are the determination of the basic chromatographic such as retention time, capacity factor (k'), selectivity (α) and analytical performance measurement includes: the determination of linearity (r), limit of detection (LOD), limit of quantitation (LOQ), precision and accuracy. The result of analytical performance of the research are well verified, in which the value of precision was % CV < 2/3 CV Horwitz value, LOD for benzene, toluene, and xylene compound were 0.02 mg/L, 0.59 mg/L, 0.08 mg/L, respectively, and LOQ for benzene, toluene and xylene compounds was 0.07 mg/L, 1.99 mg/L and 0.27 mg/L respectively. This method achieved high accuration, indicated by a percentage of recovery value of benzene, toluene, and xylene for soil samples of 102.61 ± 4.61%; 101.65 ± 7.41%; 102.15 ± 4.15%, and for air samples was 101.69 ± 5.77%, 102.08 ± 5.43%, and 98.55 ± 5.11% respectively. Based on the results of this research, the method presented in this study can be applied for the determination of benzene, toluene, and xylene using gas chromatography in air and soil samples with valid results.
Sintesis Nanopartikel Perak Menggunakan Campuran Reduktor Kimia Trisodium Sitrat dan Bioreduktor Ekstrak Kulit Batang Cempedak (Artocarpus integer (Thunb.) Merr.) Isah Waliah Indriani; Noor Hindryawati; Irfan Ashari Hiyahara
ALCHEMY Jurnal Penelitian Kimia Vol 21, No 2 (2025): September
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.21.2.103484.389-400

Abstract

Sintesis nanopartikel perak (AgNPs) telah dilakukan menggunakan reduktor kimia trisodium sitrat (Na3C6H5O7) dan bioreduktor dari ekstrak kulit batang cempedak (Artocarpus integer (Thunb.) Merr.) serta campuran keduanya. AgNPs hasil sintesis dianalisis menggunakan spektrofotometer UV-Vis, PSA (Particle Size Analyzer) dan TEM (Transmission Electron Microscope). AgNPs berhasil disintesis dapat dilihat dari perubahan warna medium reaksi menjadi kuning kecokelatan. AgNPs tetap stabil dipengukuran hari ke 5, ditunjukkan dari data spektrofotometer UV-Vis. Panjang gelombang maksimum muncul berturut turut untuk AgNPs dengan reduktor Na3C6H5O7 pada 426 – 430 nm;  AgNPs dengan bioreduktor dari ekstrak kulit batang cempedak pada 426 – 428 nm;  dan AgNPs dengan bioreduktor campuran pada 428 – 432 nm. Kondisi optimum sintesis AgNPs diperoleh dengan reduktor campuran pada konsentrasi AgNO3 4,5 mM;  perbandingan volume Na3C6H5O7:ekstrak kulit batang cempedak 2:1. Hasil karakterisasi dari PSA menunjukkan nanopartikel perak memiliki distribusi ukuran rata-rata 78,2 nm. Morfologi nanopartikel perak dari TEM menunjukkan AgNPs berbentuk bulat dengan rata-rata ukuran partikel sebesar 93,49 nm. Silver Nanoparticles Synthesis using a Mixture of Chemical Reductors of Trisodium Citrate and Bioreductors of Cempedak Stem Bark Extract (Artocarpus integer (Thunb.) Merr. The synthesis of silver nanoparticles (AgNPs) has been carried out using the chemical reductant trisodium citrate (Na3C6H5O7) and bioreductant prepared from the extract of cempedak bark (Artocarpus integer (Thunb.) Merr.) and a mixture of both. The synthesized AgNPs were analyzed using a UV-Vis Spectrophotometer, PSA (Particle Size Analyzer), and TEM (Transmission Electron Microscope). The successful synthesis of AgNPs can be identified from the change in color of the reaction medium to brownish yellow. AgNPs remained stable on the 5th day of measurement, as shown by the UV-Vis spectrophotometer data. The maximum wavelengths appeared successively for AgNPs with Na3C6H5O7 reductant at 426 – 430 nm; AgNPs with bioreductant from cempedak bark extract at 426 – 428 nm; and AgNPs with mixed bioreductant at 428 – 432 nm. The conditions for AgNPs synthesis are optimum with a mixed reducing agent at a concentration of AgNO3 of 4.5 mM; the volume ratio of Na3C6H5O7:cempedak bark extract of 2:1. The characterization results from PSA showed that silver nanoparticles had an average size distribution of 78.2 nm. The morphology of silver nanoparticles from TEM showed that AgNPs were spherical with an average particle size of 93.49 nm. 
Co-Authors -, Rahayuningsih Abdul Aziz Adhaina, Karina Aditya, Adrian Maulana Ahmad, Atika Aulia Akbar, Muhammad Marion Alimuddin Alimuddin Aman Sentosa Panggabean Apriliana, Nina Arief, M. Syaiful Ashari, Irfan Audi Zahid Iswaradi Az Zahra, Upi Fathimah Bergita, Angela Br Ginting, Survina Osalia Corebima, Damianus Develistur Daniel -, Daniel Daniel Daniel Duratulhikmah, Nur Fadhilah Duwi Devi Wulandari Elean, Samuel Erwin Erwin Eva Marliana, Eva Gaanty Pragas Maniam, Gaanty Pragas Hariati, Hariati Hariati, Hariati Helbianurramdan, Helbianurramdan Hiyahara, Irfan Ashari Husna Syaima Indriani, Isah Waliah Irfan Ashari Hiyahara Isah Waliah Indriani Ishak Wiradikara Az Kusmiaty, Prilianda Laksono, Annuary Larasati, Zarra Udyani Laurentha, Nantha Mid, Arsy Aprilia Muhammad Marion Akbar N. S, R. R. Dirgarini Julia N., R.R. Dirgarini N., R.R. Dirgarini Julia Nanang Tri Widodo Octavianus, Riyan Octavianus, Riyan Oktaviani, Reka Palentin, Ersa Rizkita Pasuluran, Nirwanto Prastiwi, Mela puah, Siti Mar Putra, Narundana Perdana Putri, Rinda Anisyah Putriani, Elsa Avrilia Rahayuningsih Rahayuningsih, Rahayuningsih Rahmat Gunawan RAHMAT GUNAWAN Rakhmad, Rakhmad Ratna Kusuma Ronaldy, Igo Marsat Rudi Kartika, Rudi Saleh, Chairul Saputra, Herdian Sari, Ermalia Lintang Sari, Helbyarti Mawar Setiawan, M. Pratsojo Soerja Koesnarpadi Soerja Koesnarpadi Subagyono, Dirgarini Julia Nurlianti Subagyono, R.R. Dirgarini Julia Nurlianti Subagyono, R.R. Dirgarini Julia Nurlianti Subagyono, RR Dirgarini Julia Nurlianti Subagyono, RR Dirgarini Julia Nurlianti Sukanadi, I Putu Sumarni Sumarni Syukri, Irma Syukri, Irma Tandirerung, Edman Tanjung, Faisal Teguh Wirawan Teguh Wirawan Teguh Wirawan, Teguh Wahyuni Ramadhani Widyastuti, Tika Wilsoma, Wilsoma Winanti, Renita Anggun Winni Astuti, Winni Wulandari, Duwi Devi Wulandari, Siti Aprilia Yuli Yana