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All Journal Indonesian Journal of Chemical Studies (Indones. J. Chem. Stud.) JPM-AKA Sorption Studies
Ananda, Dea Dwi
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Chemical Engineering, Chemistry & Bioengineering Chemistry Materials Science & Nanotechnology Social Sciences

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Brief Virtual Observation Revealed the Possibility of Trade in Organophosphate-based Pesticides through E-commerce Stiawan, Elva; Nurhalimah, Siti; Ananda, Dea Dwi; MS, M. Adrian Rezki Anggara; Tayon, Felix
Jurnal Pengabdian Masyarakat AKA Vol 4, No 1 (2024): Juni 2024
Publisher : Politeknik AKA Bogor

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55075/jpm-aka.v4i1.225

Abstract

Reactive organophosphates (OPs) could be utilized as deadly pesticides due to their nerve agent properties for several organisms. Although the utilization of these compounds has been strictly regulated, monitoring its trading activities, particularly through e-commerce, could be quite challenging. There is a lack of information on whether the pesticide products containing OPs or slightly featured with similar phosphates groups exist or are un-existed in the online stores in Indonesia. This community service aims to briefly report the possibility of trade in phosphorous-based pesticides through online stores in Indonesia. We demonstrated virtual observation to obtain the list of phosphorous-based pesticides from several e-commerce in Indonesia. We detected 24 pesticides displayed on some popular e-commerce with particular phosphate groups in the active substance, i.e., Acephate, Chlorpyrifos, Dimethoate, Diazinon, Profenofos, and Triazofos. The finding could provide insight for those online stores to establish particular rules to monitor and control trading activities of agrochemicals that could be illegally used or further processed for any activities related to Chemical, Biological, Radiological, and Nuclear and Explosives (CBRN-E) threats.
Reflection Loss Improvement by Cerium Addition in Chitosan-Hydroxyapatite Film as Stealth Drone Candidate Putri, Riyanti; Prasojo, Agus Eko; Lazuardy, Ardyan; Anitasari, Reza; Salsabila, Fidela Aurellia; Sasongko, Nugroho Adi; Apriliyanto, Yusuf Bramastya; Hasibuan, Anggi Khairina Hanum; Ananda, Dea Dwi
Indonesian Journal of Chemical Studies Vol. 4 No. 1 (2025): Indones. J. Chem. Stud., June 2025
Publisher : Indonesian Scholar Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55749/ijcs.v4i1.53

Abstract

Radar is a detection and tracking technology commonly applied to monitor environmental conditions. Its ever-growing capabilities pose a serious challenge to military operations because they increase the risk of being detected by the enemy. On the other hand, unmanned aircraft (drones) are increasingly widespread in gathering information. However, the effectiveness of this technology can be reduced due to exposure to radar waves that allow detection. Therefore, developing coating materials that can absorb radar waves is an urgent need to increase the effectiveness of military equipment. The composites developed were derived from chitosan obtained from crustacean waste, hydroxyapatite from eggshell waste, and the rare earth metal cerium obtained from Lapindo Mud. Composites containing cerium metal (Ce) have higher radar signal absorption capabilities than samples without Ce, as evidenced by VNA measurements showing increased absorbance in the 100 MHz - 8.5 GHz frequency range. SEM tests indicate that cerium particles increase the density and homogeneity of the pore structure, with a size range of 17–24 µm. FTIR characterization revealed that Ce was physically bound to the chitosan-HAp composite. Mechanically, the composite with Ce had a maximum tensile stress of 9.512 MPa and a strain of 9.512%, while without the addition of Ce, a stress of 9.529 MPa and a strain of 25.512% was obtained. These findings indicate that integrating rare earth metals in chitosan-HAp composites can improve the material's capability to absorb radar waves, thus having broad prospects for applications in defence technology.
Radar Absorber Composite Graphene Oxide/Magnetite/Zinc Oxide in Polypyrole Matrix Xaviera, Allodya Nadra; Nareswari, Vania Agatha; Ananda, Dea Dwi; Azzahra, Hazzha; Tarigan, Thessa Ocatvia Joyetta; Yulita, Tiara Rizki; Sasongko, Nugroho Adi; Basuki, Rahmat
Sorption Studies Vol. 1 No. 1 (2025): Sorption Studies, Vol. 1 No. 1 June 2025
Publisher : Indonesian Scholar Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55749/ss.v1i1.80

Abstract

The development of stealth technology in modern defense systems demands superior radar absorbing material (RAM) innovation. This study aims to synthesize and characterize Fe₃O₄/ZnO modified carbon-based RAM composites in a polypyrrole (PPy) matrix using graphite oxide (GiO). The composites were synthesized via a modified Hummer method as well as a one-pot technique, and characterized using FTIR, XRD, SEM-EDX, and VNA. The FTIR characterization results showed that the C=C peak decreased in intensity after the oxidation process, indicating the breaking of the aromatic double bond and the formation of new functional groups such as C–O and C=O. This change was detected in both pGiO and kGiO samples. XRD data showed a shift in the main peaks to 2θ = 11.25° and 42.20° for pGiO and 2θ = 11.56° and 42.40° for GiO-k, respectively. This shift indicates the formation of a more amorphous graphite oxide structure compared to the original graphite.The results show that GiO/Fe₃O₄/ZnO has the highest reflection loss value of -9.20 dB at 10.91 GHz (GiO-p/Fe₃O₄/ZnO 66%-PPy) with an absorption value of 88.03% and rGO/Fe₃O₄/ZnO/PPy the highest RL value reached -7.51 dB at 11.57 GHz (rGO-k/Fe₃O₄/ZnO 66%-PPy) with an absorption value of 82.21%. This research proves that Fe3O4/ZnO modified carbon-based composites in a polypyrrole matrix have high potential as an efficient radar absorbing material and can support the needs of domestic defense technology.
Effect of Different Temperatures in Magnetite Synthesis on Methylene Blue Adsorption Ananda, Dea Dwi; Napoleon, Sultan; Tarigan, Thessa Octavia Joyetta; Yulita, Tiara Rizki; Alivia, Latisa Stefi; Kusuma, Bagas; Fajri, M. Rizki; Putri, Kayla Sophia; Artdero, Nayantaka Virsa; Nurwanto; Hartono, Rudi; Rahmat Basuki
Sorption Studies Vol. 1 No. 2 (2025): Sorption Studies, December 2025
Publisher : Indonesian Scholar Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55749/ss.v1i2.84

Abstract

This study aims to synthesize magnetite (Fe₃O₄) particles using the coprecipitation method, with variations in temperature (70°C and 90°C) and reaction system (open and closed) to evaluate their effects on product quality. Characterization was conducted using FTIR, XRD, and organoleptic observation to confirm the formation of Fe₃O₄. Additional tests included magnetic attraction measurements through mass response and adsorption capacity (Q) analysis using methylene blue. FTIR analysis showed absorption bands at 3417.00 cm⁻¹, 1627 cm⁻¹, 1404 cm⁻¹, and 578 cm⁻¹, indicating the presence of O–H, C=O, and Fe–O functional groups. XRD patterns revealed diffraction peaks at 2θ values of 30.27°, 35.23°, 43.22°, 53.71°, 57.43°, and 62.11°, confirming the spinel crystal structure of Fe₃O₄. The sample synthesized at 90°C under closed conditions exhibited a darker black color and higher mass yield, suggesting improved crystallinity and phase purity. The closed system also showed higher adsorption capacities of 0.0008 mmol·g⁻¹ at 70°C and 0.0018 mmol·g⁻¹ at 90°C, along with stronger magnetic response. The open system produced a black precipitate with lower yield and weaker magnetic response, suggesting oxidation of Fe²⁺ to Fe³⁺ due to direct contact with oxygen, leading to the formation of compounds such as hematite or maghemite with lower magnetic properties. These results confirm that higher reaction temperatures and closed conditions optimally enhance the quality and stability of magnetite.
Recent Advances in Nickel Ferrite-Polymer Nanocomposites for Radar Absorbing Material Applications Panjaitan, Thesalonika Br; Hijrianisa, Alya; Apriliyanto, Yusuf Bramastya; Ananda, Dea Dwi; Basuki, Rahmat; Renta, Hotma
Sorption Studies Vol. 1 No. 2 (2025): Sorption Studies, December 2025
Publisher : Indonesian Scholar Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55749/ss.v1i2.125

Abstract

Nickel ferrite (NiFe₂O₄) and its polymer-based composites have emerged as promising candidates for radar absorbing materials (RAMs) due to their unique combination of magnetic and dielectric loss mechanisms. This review highlights recent advances in synthesis strategies, including sol–gel, hydrothermal, co-precipitation, and microwave-assisted methods, which enable precise control of particle size, morphology, and crystallographic defects. Such control supports flexible structural design of nickel ferrite spinel structures, allowing dopant incorporation to tailor magnetic anisotropy and saturation magnetization. These structural features directly affect electromagnetic performance. Magnetic loss is mainly governed by natural resonance and, to a lesser extent, eddy current effects, while dielectric loss arises from dipole polarization, interfacial polarization, and conduction loss. The synergistic balance of magnetic and dielectric losses makes nickel ferrite–polymer nanocomposites promising broadband radar absorbing materials. The discussion emphasizes the role of cation substitution, polymer matrices, and hybridization with carbon-based materials in enhancing microwave absorption bandwidth and impedance matching. Various synthesis approaches, including sol–gel, hydrothermal, and in-situ polymerization, are compared with respect to their influence on particle size, morphology, and absorption efficiency. Challenges such as limited bandwidth, thermal and mechanical stability, and scalability are highlighted, along with potential solutions through advanced nanostructuring, multifunctional design, and sustainable synthesis. Future research directions are also outlined to support the development of next-generation stealth and electromagnetic interference shielding technologies.
Co-Authors Alivia, Latisa Stefi ANGGI KHAIRINA HANUM HASIBUAN Anitasari, Reza Artdero, Nayantaka Virsa Azzahra, Hazzha Elva Stiawan Fajri, M. Rizki Hartono, Rudi Hijrianisa, Alya Kusuma, Bagas Lazuardy, Ardyan MS, M. Adrian Rezki Anggara Napoleon, Sultan Nareswari, Vania Agatha Nugroho Sasongko Jati, Nugroho Sasongko Nurwanto Panjaitan, Thesalonika Br Prasojo, Agus Eko Putri, Kayla Sophia Putri, Riyanti Rahmat Basuki Renta, Hotma Salsabila, Fidela Aurellia Siti Nurhalimah Tarigan, Thessa Ocatvia Joyetta Tarigan, Thessa Octavia Joyetta Tayon, Felix Xaviera, Allodya Nadra Yulita, Tiara Rizki Yusuf Bramastya Apriliyanto