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Indonesian Journal of Chemistry

ijc
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Published by Universitas Gadjah Mada

ISSN : 14119420 EISSN : 24601578 DOI : -

Core Subject : Science, Engineering,

Chemical Engineering, Chemistry & Bioengineering Chemistry

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).

Arjuna Subject : -

Articles 1,981 Documents

86 87 88 89 90

Equilibrium, Kinetic and Thermodynamic Investigation of Adsorption of Hexavalent Chromium by Activated Carbon Derived from Leucaena leucocephala Seed Pod Yusuff, Adeyinka Sikiru; Nwosu, Chisom Joy
Indonesian Journal of Chemistry Article in press
Publisher : Universitas Gadjah Mada

In the present study, Leucaena leucocephala seed pod, a non-edible plant waste, was utilized to prepare low-cost activated carbon to remove hexavalent chromium [Cr(VI)] from aqueous solution via batch mode adsorption. The activated carbon was prepared by chemical activation with NaOH and characterized by Brunauer-Emmett-Teller (BET) surface area measurement, Scanning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) spectroscopy. The effects of various variables, such as initial Cr(VI) concentration, contact time, adsorbent dosage, temperature, and pH, which influence the adsorption processes, were investigated. Equilibrium adsorption isotherms, the kinetic and thermodynamic behavior of the process were investigated. The obtained results showed that 100 min contact time, 1.0 g adsorbent dose, 45 °C temperature and solution pH of 6.0 resulted in maximum Cr(VI) uptake. The experimental data well fitted to the Langmuir isotherm with monolayer adsorption capacity of 26.94 mg/g. The kinetic analysis showed that the pseudo-second-order model well fitted to the acquired experimental data. The thermodynamic behavior of Cr(VI) adsorption onto activated carbon was found to be spontaneous and endothermic. The L. leucocephala seed pod based activated carbon was found to be efficient for Cr(VI) adsorption.

Angiotensin Converting Enzyme (ACE) Inhibitory Activity of Peptide Fraction of Germinated Pigeon Pea (Cajanus cajan (L.) Millsp.) Ketut Ratnayani; I Ketut Suter; Nyoman Semadi Antara; I Nengah Kencana Putra
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

During the germination process, seeds can release various types of peptides due to the degradation of storage proteins. Some of these peptides can have biological activity (bioactive peptides). The objective of this study was to determine the ACE inhibitory activity of germinated pigeon pea peptide extract at various germination times and to carry out the fractionation to the extract to get the most active peptide fraction. The results showed that the highest activity of peptide extract was found on the 4th-day germination of pigeon pea with an IC50 value of 63.46 μg/mL. The peptide extract was further fractionated by centrifugal ultrafiltration method and it was found that the peptide fraction < 3 kDa had the highest ACE inhibitory activity with an IC50 value of 57.79 μg/mL. The result of identification with the LCMS method to the fraction was able to detect 4 types of the peptide with a molecular weight of 230.304, 294.303, 441.436, and 570.591 Da. These results suggested that the peptide fraction of germinated pigeon pea has the potency as an ACE inhibitory nutraceutical.

Identification and Validation of Synthetic Phenolic Antioxidants in Various Foods Commonly Consumed in Malaysia by HPLC Chen Son Yue; Wai Lun Hong; Sheri-Ann Shu Wei Tan; Khye Er Loh; Yee Chuan Liew; Rosemary Elizabeth Yap; Zi Yi Chong; Jiong Chen Chai
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

This study was conducted in order to identify the presence of four synthetic phenolic antioxidants (SPAs): propyl gallate (PG), tert-butylhydroquinone (TBHQ), butylated hydroxyanisole (BHA), and butylated hydroxytoluene (BHT) in various food stuffs that are commonly consumed in Malaysia. The identification method was optimized and validated before it was applied to the analyses of eighty three food samples which include chewing gum, chili sauce, cereal-based snack food, noodles, potato snack, cereal breakfast, oat, biscuit, cookie, coffee, junk food, seaweed, nut, chocolate, apple juice, orange juice and blackcurrant juice. Twenty nine food samples contained SPAs either singly or in combination. The chromatography conditions such as elution method, flow rate and wavelength were optimized. Good linearity ranges (1–300 mgL–1) were found for all the four phenolic antioxidants. RSD for repeatability and reproducibility ranged from 0.15–0.84% for both precision analyses. LOD and LOQ ranged from 0.02–0.67 and 0.06–2.03 mgL–1, respectively. Recoveries of the four SPAs ranged from 80.4 to 119.0% when selected food items spiked at 10, 50, and 100 mgL–1.

Effect of Molar Ratio on Structural and Size of ZnO/C Nanocomposite Synthesized Using a Colloidal Method at Low Temperature Siham Lhimr; Saidati Bouhlassa; Bouchaib Ammary
Indonesian Journal of Chemistry Vol 19, No 2 (2019)
Publisher : Universitas Gadjah Mada

In this paper we study the effects of different molar ratio R of Zn2+ to OH– (R= nOH–/nZn(II) of the precursor was investigated by varying the amount of NaOH. Samples have been synthesized by the colloidal method at room temperature using (ZnCl2), citric acid (C6H8O9·H2O) and sodium hydroxide (NaOH). The formation of ZnO/C composite was characterized by The X-ray diffraction patterns indicated a high crystallinity and nanocrystalline size of ZnO with hexagonal wurtzite structure. The morphologies of the particles have been studied with a scanning electronic microscopy (SEM). The existence of carbon into the composite was detected by FTIR and EDS. The optical band gap of various ZnO/C composite was calculated from UV-Visible absorption measurement varied in the range 3.301 to 3.282 eV according to R values.

Alginate-Graphene Oxide Biocomposite Sorbent for Rapid and Selective Extraction of Non-Steroidal Anti-Inflammatory Drugs Using Micro-Solid Phase Extraction Mohammad Salim Tabish; Nor Suhaila Mohamad Hanapi; Wan Nazihah Wan Ibrahim; Nor’ashikin Saim; Noorfatimah Yahaya
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

In this work, a bio-composite sorbent, alginate incorporated graphene oxide (Alg/GO) is prepared for the micro solid phase extraction of non-steroidal anti-inflammatory drugs (NSAIDs) from water samples. The sorbent was prepared in a suspended solution form at a ratio of 0.3:1 (w/v %) of graphene oxide (GO) and alginate (Alg). The chemical structure, morphology and surface area of the composite beads were characterized using Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and Brunauer–Emmett–Teller (BET). GO showed good miscibility and well dispersion through intermolecular hydrogen bonds and electrostatic interactions within the Alg matrix. The synthesized sorbent was applied for the determination of the selected drugs in a tap water sample using micro-solid phase extraction technique and was analyzed by high-performance liquid chromatography-ultraviolet detector (HPLC-UV). The results showed good linearity in the range of 10–1000 µg L–1 with correlation coefficients (r ≥ 0.9979), low detection limits (LOD) between 3.1–4.6 µg L–1, excellent relative recoveries in the range of 99.6–102.1% and good reproducibility (RSD ≤ 3.9%). Thus, these validated results showed that Alg/GO could be potential and useful as a bio-composite sorbent for micro-solid phase extraction for the analysis of targeted drugs from aqueous matrices.

Analytical Approach of Laser-Induced Breakdown Spectroscopy to Detect Elemental Profile of Medicinal Plants Leaves Abdul Jabbar; Mahmood Akhtar; Shaukat Mehmood; Koo Hendrick Kurniawan; Rinda Hedwig; Muhammad Aslam Baig
Indonesian Journal of Chemistry Vol 19, No 2 (2019)
Publisher : Universitas Gadjah Mada

Laser ablation chemical and spectroscopic studies of Calotropis procera, Chenopodium ambrosioides, and Nerium indicum leaves was performed using 1064 nm Nd: YAG laser in air at different pressure and time delay. These medicinal plant’s leaves are used by local people for different diseases. The knowledge of medicinal and toxic metals in these plants is very important. We have presented time-resolved studies of different elements and how their lives change with different delay time. C, H, Si, Al, Fe, Cu, Ca, Mg, Na, K, N, O, Sr and Ba have been detected in all the three samples with a molecular form of Carbon and Nitrogen band. We have detected C, H, N, and O as a major element while, Fe, Cu, Mg, K and Ca as essential medicinal metals with other trace elements such as Si, Sr, Al and Ba in all the three plants leaves. We present 1 µs delay time is the best time for elements lifetime in time resolved studies. The behaviour of intensity with different pressures was also studied and it was concluded that 7 torr was the best pressure for the maximum value of intensity. In particular, the electron density and the temperatures of the plasma were reported. The temperature was calculated from the well-known Boltzmann plot method and electron density was estimated from the stark broadened profile of the Hα line.

Synthesis of Iron-Doped Zirconium Titanate as a Potential Visible-Light Responsive Photocatalyst Rian Kurniawan; Sri Sudiono; Wega Trisunaryanti; Akhmad Syoufian
Indonesian Journal of Chemistry Vol 19, No 2 (2019)
Publisher : Universitas Gadjah Mada

Synthesis and properties of iron-doped zirconium titanate (ZrTiO4) as a potential visible-light-responsive photocatalyst had been conducted. Various iron dopant concentration and calcination temperature were investigated toward the properties of Fe-doped ZrTiO4. The photocatalyst material was synthesized by sol-gel and impregnation method. Titanium tetraisopropoxide (TTIP) was used as a precursor, embedded on zirconia fine powder. A certain amount of iron (1, 3, 5, 7 and 9 wt.%) was introduced into the photocatalyst system from iron(II) sulfate heptahydrate (FeSO4·7H2O). Photocatalyst with various iron concentration calcined at 500 °C. ZrTiO4 with 5% iron additionally was calcined at 700 and 900 °C. Characterization was performed by using XRD, FT-IR, SR-UV, and SEM-EDX. The presence of iron on the surface of ZrTiO4 was proved by EDX analysis. Fe-doped ZrTiO4 with the lowest bandgap (2.83 eV) is 7% of iron content after calcination at 500 °C.

Methyl-3-(2-hydroxy-5-nitrophenyl amino)-3-phenylpropanoate Based Colorimetric Sensor for Oxyanions Venty Suryanti; Fajar Rakhman Wibowo; Sekar Handayani
Indonesian Journal of Chemistry Vol 20, No 2 (2020)
Publisher : Universitas Gadjah Mada

A colorimetric anion sensor of methyl-3-(2-hydroxy-5-nitrophenyl amino)-3-phenylpropanoate bearing –OH and –NH groups as binding sites and nitrophenyl as a signaling unit, has been successfully accomplished. The compound functioned as a colorimetric chemosensor for H2PO4– and AcO–, in particular, the sensor showed significant naked-eye detectable color change from colorless to light yellow. In contrast, no color change was detected upon addition of other anions such as SO42–, NO3–, and CIO4–. The anion sensing ability of the sensor was further investigated by UV-Vis absorption spectroscopy in acetone. Characteristic UV-Vis spectra changes were revealed upon addition of H2PO4– and AcO–.

Hydrogen Bond Stability of Quinazoline Derivatives Compounds in Complex against EGFR using Molecular Dynamics Simulation Herlina Rasyid; Bambang Purwono; Thomas S Hofer; Harno Dwi Pranowo
Indonesian Journal of Chemistry Vol 19, No 2 (2019)
Publisher : Universitas Gadjah Mada

Lung cancer was a second common cancer case due to the high cigarette smoking activity both in men and women. One of protein receptor which plays an important role in the growth of the tumor is Epidermal Growth Factor Receptor (EGFR). EGFR protein is the most frequent protein mutation in cancer and promising target to inhibit the cancer growth. In this work, the stability of the hydrogen bond as the main interaction in the inhibition mechanism of cancer will be evaluated using molecular dynamics simulation. There were two compounds (A1 and A2) as new potential inhibitors that were complexed against the EGFR protein. The dynamic properties of each complexed were compared with respect to erlotinib against EGFR. The result revealed that both compounds had an interaction in the main catalytic area of protein receptor which is at methionine residue. Inhibitor A1 showed additional interactions during simulation time but the interactions tend to be weak. Inhibitor A2 displayed a more stable interaction. Following dynamics simulation, binding free energy calculation was performed by two scoring techniques MM/GB(PB)SA method and gave a good correlation with the stability of the complex. Furthermore, potential inhibitor A2 had a lower binding free energy as a direct consequence of the stability of hydrogen bond interaction.

Yield Optimization and Supercritical CO2 Extraction of Essential Oil from Jasmine Flower Hesham Hussein Rassem; Abdurahman Hamid Nour; Rosli Mohammad Yunus; Yasmeen Hafiz Zaki; Hybat Salih Mohamed Abdlrhman
Indonesian Journal of Chemistry Vol 19, No 2 (2019)
Publisher : Universitas Gadjah Mada

Supercritical fluid extraction (SFE) is an innovation that permits extraction of an extensive variety of different chemical composition from the plant grids. Extraction of essential oil from Jasmine flower was tentatively carried out using the supercritical CO2 technique. The effect of extraction parameters which include pressure (100–300 bar) and temperature (300–350 K) on the oil recovery was explored. The extraction process was optimized using the response surface methodology (RSM). At the SFE optimal conditions, the chemical compositions of the extracted oil were examined using gas chromatography-mass spectrometry (GC-MS) analysis. The obtained result reflected that the optimal yield of oil from Jasmine flower was 12.18% mg oil extracted/100 g dry flower, which was achieved through an SFE optimal conditions of pressure at 200 bar and extraction temperature at 325 K. A total number of six chemical compounds were tentatively identified in the Jasmine flower extracted oil at the optimal SFE conditions.

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