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INDONESIA
Communications in Science and Technology
Published by Komunitas Ilmuwan dan Profesional Muslim Indonesia
ISSN : 25029258     EISSN : 25029266     DOI : -
Core Subject : Engineering,
Engineering
Communication in Science and Technology [p-ISSN 2502-9258 | e-ISSN 2502-9266] is an international open access journal devoted to various disciplines including social science, natural science, medicine, technology and engineering. CST publishes research articles, reviews and letters in all areas of aforementioned disciplines. The journal aims to provide comprehensive source of information on recent developments in the field. The emphasis will be on publishing quality articles rapidly and making them freely available to researchers worldwide. All articles will be indexed by Google Scholar, DOAJ, PubMed, Google Metric, Ebsco and also to be indexed by Scopus and Thomson Reuters in the near future therefore providing the maximum exposure to the articles. The journal will be important reading for scientists and researchers who wish to keep up with the latest developments in the field.
Arjuna Subject : -
Articles 209 Documents
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Evaluation of stirring rate and pH on phenolic compounds recovery from palm kernel shell heavy phase bio-oil Wijayanti, Hesti; Mardina, Primata; Tuhuloula, Abubakar; Tri Ananda, Lidya; Aulia Rauf, Zahwa Syafa; Lutfi, Auliyani; Fadil Riyadi, Syahril
Communications in Science and Technology Vol 8 No 1 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.1.2023.1119

Abstract

This study aims to develop an efficient separation method for phenolic compounds derived from the heavy phase of bio-oil produced by the pyrolysis of palm kernel shell. Two variables were investigated during phenolic compound extraction using dichloromethane, i.e., stirring rate and pH of the solution. In both variables, the composition, yield, and distribution coefficient of the extracted phase were investigated. The results showed that the phenolic compounds' extraction favors high stirring rate and it obtained more results at more acidic conditions (lower pH). The best conditions for phenolic compounds were at 300 rpm of stirring rate and pH 4, which resulted in 77.88 % of yield and a 1.13 distribution of coefficient for the total phenols. The findings of this research will contribute to the better separation of phenolic compounds in bio-oil for improving its fuel characteristics as well as producing value-added chemicals.
Synthesis of mesogen-nanoparticle composites by doping 4-decyloxybenzoic acid with substrate-functionalized ZnO nanoparticle Paul, Saurav; Chakraborty, Bimal Bhushan; Deb, Kuheli; Choudhury, Sudip
Communications in Science and Technology Vol 8 No 1 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.1.2023.1125

Abstract

Nanomaterials and Mesogenic materials are two important pillars of today’s science and technology, in the fields of both material and biological applications. Mesogens or liquid crystals (LC) are self-aggregated anisotropic fluids with long range order, and the nature of self-aggregation largely controls their physical and material properties. Doping of nanomaterials over liquid crystalline matrix can provide valuable tools for development of materials with new or improved properties. In the present work 4-decyloxybenzoic acid is taken as the mesogenic matrix. It is observed that, composite prepared by doping of 4-decyloxybenzoic acid mesogen matrix by ZnO nanoparticle pre-functionalized with the same mesogen, caused a marked alteration in the mesogenic behavior. With 3% doping of matrix pre-functionalized ZnO NP on 4- decyloxy benzoic acid, we could achieve a shift of about 31ºC in the N-Iso transition temperature and, a decrease of >10ºC for the onset of liquid crystallinity by this method without quenching any of the mesophases exhibited by the pure mesogen. The synthesized materials have been characterized by variable temperature Polarised optical microscopy (POM), DSC, FTIR, XRD, EDX, and TEM This process may be considered for preparation other nanoparticle-mesogen composites as well. It was observed that, the effect of doping on the transition temperature and enthalpy of 4-Decyloxybenzoic Acid can be significantly enhanced by pre-functionalizing the dopant (ZnO NP) with the substrate molecules and then mixing this substrate functionalized ZnO nanoparticle with the bulk substrate.
Effect of microwave and ultrasonic irradiation on the enzymatic hydrolysis of water hyacinth biomass in the presence of surfactants Rokhati, Nur; Ratnawati; Prasetyaningrum, Aji; Anggraini, Widyah; Nugroho, Akbar; Novita, Nasyriyatul Hana; Andarani, Pertiwi; Riyanto, Teguh
Communications in Science and Technology Vol 8 No 1 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.1.2023.1143

Abstract

This paper presents the effect of microwave and ultrasound irradiation on the enzymatic hydrolysis of water hyacinth biomass in the presence of surfactants. Prior to hydrolyzing, the water hyacinth was treated utilizing alkali with and without microwave assistance. It was revealed that the microwave improved the removal of lignin and hemicellulose. The treated water hyacinth biomass was also characterized using Scanning Electron Microscope (SEM), X-ray Diffraction (XRD), and Fourier-Transform Infrared (FT-IR) Spectroscopy. The effect of surfactant and the assistance of microwave and ultrasound were comprehensively studied. Some parameters varied, including stirring speed, surfactant type, concentration, and reaction time. The results indicated that microwave and ultrasound could enhance the reaction rate. Tween 80 here could improve conventional, microwave-assisted, and ultrasound-assisted hydrolysis of water hyacinth biomass. It was found that the ultrasound-assisted hydrolysis was better than that of others. The results of this research can be used as the groundwork for further developing the lignocellulosic biomass hydrolysis process, especially in an advanced enzymatic hydrolysis process.
Fabrication of glutathione-modified gold nanoparticles as 3-chloropropane-1,2-diol sensor Faramitha, Yora; Barori, Fadhlurrahman Rafi; Dimawarnita, Firda; Siswanto; Aqoma, Havid; Nugraha, Adam F; Ferdiansyah, Alfian
Communications in Science and Technology Vol 8 No 1 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.1.2023.1167

Abstract

Refined palm oil products may contain a harmful substance called as 3-monochloropropane-1,2-diol (3-MCPD), which can potentially be carcinogenic if consumed in excess. The determination of 3-MCPD depends on the sophisticated machine and highly skilled technicians but it is time-consuming. A simple method that proposes rapid detection remains a challenge. Hence, this research aims to develop a colorimetric-based rapid detection sensor using gold nanoparticles functionalized with a ligand, glutathione (GSH) to be bound to 3-MCPD. Varied concentrations of GSH were evaluated to obtain stable GSH-AuNPs. The characterization results showed that the composition of the stable GSH-AuNPs has been achieved by 250 µL of 0.02 M GSH addition. A stable GSH-AuNPs was ruby red with surface plasmon resonance (SPR) band at 520 nm and an average nanoparticle size of 30 nm. The indication for detection of 3-MCPD was marked by the decrease in the absorbance intensity. Thus, GSH-AuNPs have potential to be developed for the 3-MCPD sensor application.
Photocatalytic of anionic dyes on Congo red with M2+/Al (M2+=Ni, Mg, and Zn) layered double hydroxide intercalated polyoxometalate Hanifah, Yulizah; Mohadi, Risfidian; Mardianto; Nur Ahmad; Suheryanto; Lesbani, Aldes
Communications in Science and Technology Vol 8 No 1 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.1.2023.1170

Abstract

The modification catalysts of layered double hydroxide (LDH) with polyoxometalate based on Keggin type were prepared and characterized using X-Ray, FTIR, and SEM to confirm the layered double hydroxide structure. Intercalation was successfully synthesized and showed a heterogeneous aggregate resulted from SEM analysis. The degradation parameters of LDH pristine and LDH composite were determined by observing a number of factors such as pH, catalyst weight, and degradation time. The modification material resulted by preparation material LDH and polyoxometalate (POM) successfully resulted in the lower band gap value compared to material pristine LDH allowing LDH polyoxometalate as photocatalysts to show good photocatalytic activities. The NiAl-SiW12O40 material had the highest percentage of degradation removing Congo Red up to 86% degradation when compared to another composite material, yet it was still significantly better than LDH pristine. The result showed that the LDH composite presented excellent photocatalytic activity in reducing Congo Red.
Synthesis of cellulose acetate (CA) from algae Gracilaria sp. composited with nickel oxide (NiO) as a supercapacitor base material Risdianto, I Wayan; Ahmad, Ahyar; Ermawar, Riksfardini Annisa
Communications in Science and Technology Vol 8 No 1 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.1.2023.1176

Abstract

In this research, electrodes were made from cellulose acetate (CA) synthesized from algae Gracilaria sp. and then composited with nickel oxide (NiO), the concentration of which varied from 0, 0.2, 0.4, and 0.6 grams. Furthermore, FT-IR characterized cellulose acetate, and the CA-NiOn electrode was characterized by XRD, SEM, and cyclic voltammetry (CV). The results showed that CA was successfully synthesized from Gracilaria sp. Increasing the concentration of NiO added to CA as an electrode could increase the specific capacity, energy density, and power density of the electrode with the highest degree of 83.27 F/g, energy density of 4 Wh/kg, and a power density of 0.4 W/kg at a concentration of 0.6 gram NiO. The effect of the addition of NiO on the characteristics of the CA-NiOn electrode was also studied such as crystallinity, crystal size, and porosity. The presentation of CA doped with NiO has the promising prospects as a supercapacitor base material.
Exploring the impact of co-fermentation Saccharomyces cerevisiae and Lactobacillus sp. on stingless bee-honey cider fermentation Thipraksa, Junjira; Michu, Panisa; Kongthong, Alisa; Chaijak, Pimprapa
Communications in Science and Technology Vol 8 No 1 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.1.2023.1185

Abstract

Stingless bee honey is a nutritious food that contains a variety of vitamins, minerals, enzymes, and antioxidants. It is known to have higher nutritional and medicinal properties compared to honey produced by other bee species. Cider is a well-known functional drink that contains high antioxidants, which can help protect against cellular damage caused by free radicals. This study aimed to investigate the potential of co-fermentation with yeast (Saccharomyces cerevisiae) and bacterium (Lactobacillus sp.) in producing high-antioxidant honey cider when compare with standard antioxidant. The results showed that honey cider co-fermented with both microorganisms for 14 days had significantly higher antioxidant activity (145.27 ± 0.20 µg TE/mL) compared to single culture fermentation (p < 0.05). Gas chromatography-mass spectrometry (GC-MS) analysis revealed the presence of several bioactive compounds in the stingless bee honey cider. These compounds include methylenecyclopropanecarboxylic acid, 2(5H)-furanone, 2-methylbicyclo[4.3.0]non-1(6)-ene, bicyclo[3.1.0]hex-2-ene, 4-methyl-1-(1-methylethyl), D-limonene, benzene, 1-(1-butenyl)-4-methoxy, and phytol. These compounds possess various beneficial activities, such as antioxidant, anti-inflammatory, antimicrobial, and anticancer properties. The identification of these compounds in the stingless bee honey cider suggests that it may have potential health benefits beyond its nutritional value. The co-fermentation approach using S. cerevisiae and Lactobacillus sp. could be considered a promising strategy for developing antioxidant-enriched honey cider with potential health benefits.
Investigating the impact of nanoparticle geothermal silica loading on the mechanical properties and vulcanization characteristics of rubber composites Syabani, Muh Wahyu; Rochmadi; Perdana, Indra; Prasetya, Agus
Communications in Science and Technology Vol 8 No 1 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.1.2023.1190

Abstract

The present study investigates the effects of nanoparticle geothermal silica (NGS) on the mechanical properties and vulcanization characteristics of rubber compounds with various filler loadings. The rubber compounds were filled with 0, 20, 30, and 40 phr of silica. The properties of NGS were analyzed using transmission electron microscopy, particle size analyzer, and BET surface area analysis to examine its morphology, size distribution, and surface area. The mechanical properties and vulcanization characteristics of the rubber compounds reinforced with NGS were evaluated using a universal testing machine and moving die rheometer. The results showed that NGS possessed the primary particle sizes below 20 nm and a surface area of 168.35 m2/g. The interaction between silica and rubber determined the modulus of the rubber composites and the vulcanization characteristics. The tensile strength of the rubber compounds, meanwhile, showed a significant increase more than threefold as the filler loading increased from 0 phr to 30 phr, followed by a slight decline at 40 phr loading. The addition of 20 phr of silica led to a prolonged scorch time compared to the filler-free compound due to the adsorption of activators and accelerators. However, the scorch time decreased after reaching 30 phr of silica loading, which could be attributed to the higher amount of bound rubber covering a portion of the silica surface, thereby reducing its ability to adsorb the activator. The presence of silica with good thermal conductivity enabled a better heat transfer during the vulcanization process, resulting in shorter curing times for higher loading. Rubber compounds with an NGS loading of 30 phr demonstrated a favorable balance between filler-rubber interactions, vulcanization characteristics, and mechanical properties in the rubber compounds.
Effect of multi-walled CNTs polyurethane mats lamination with basalt fabrics reinforced-epoxy composites reviewed on tension and bending properties Sugiarti, N. W.; Adi Atmika, K.; Ary Subagia, I. D. G.
Communications in Science and Technology Vol 8 No 1 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.1.2023.1195

Abstract

Material technology continues to develop with various innovations and engineering to improve weaknesses in both mechanical and physical properties. In this study, electrospun fibres containing a multi-wall blend of CNT and Polyurethane (PU) with or without surfactant that laminated into a basalt fibre-reinforced composite were uniquely demonstrated. Multi-wall CNT 3wt% was added to the PU/MEK/DMF solution and produced using an electrospinning process. PU fibre mat containing 3wt% CNT was made without and with surfactants. Also, Basalt fibre reinforced epoxy composite as a control sample was produced. In addition, vacuum-assisted resin transfer printing has been used in the manufacture of composite panels containing both fibres. The aim of combining basalt fibre and PU CNT spun mats was to investigate their effect on the tensile and flexural mechanical properties. Tensile and flexural tests were carried out on a universal testing machine (UTM) in accordance to ASTM D 638 and ASTM D790 standards. FESEM and TEM on composite morphology test were done after testing. The results indicated that the basal matting fibre-reinforced epoxy composites stacked by PU mats with or without surfactants were affected by CNT inclusions. Nanofiber spun mats laminated in a basalt fibre composite lead to a considerable increase in both loads (i.e. tensile and flexural properties). The highest tensile and flexural load values occurred in the BF+PU-mat-2 sample with triton-x 100 surfactants compared to BFRP. The increase in tensile and flexural modulus values was at 13% and 17.3%, respectively. On the other hand, there was a decrease in shear failure due to tensile and bending loads due to the brittleness of the composite reinforcement. In conclusion, this CNF-mat lamination is highly suitable to be used to improve the strength properties of BFRP composites. It is highly recommended for automotive parts, marine compartments and storage insulation.
Study of green and sustainable heterogeneous catalyst produced from Javanese Moringa oleifera leaf ash for the transesterification of Calophyllum inophyllum seed oil Ramdhani, Destania Ayu; Wega Trisunaryanti; Triyono
Communications in Science and Technology Vol 8 No 2 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.2.2023.1202

Abstract

The transesterification of Calophyllum inophyllum seed oil into biodiesel using Javanese Moringa oleifera leaf ash catalyst with various reaction conditions has been completed. MA-500 (Moringa ash at 500°C for 3 h) and MA-900 (Moringa ash at 900°C for 3 h) catalysts were obtained by grinding Javanese old Moringa oleifera leaf (MP) and then calcined for 3 h at 500 and 900°C. The crude Calophyllum inophyllum seed oil was degummed (OD) prior to continue the esterification process (ODE). The MA-500 and MA-900 catalysts were tested for their activity and selectivity through the ODE transesterification with various catalyst weights (3, 6, and 9% (w/w)), reaction temperature (55, 60, and 65°C), oil: methanol mole ratio (1:3, 1:6, and 1:9), and reaction time (60, 90, 120, and 150 minutes). The results showed that the MA-500 and MA-900 catalysts contained 18.17% and 52.91% Ca respectively. The esterification reaction could reduce FFA levels to 89.82%, from 19.46% to 1.98%. ODE transesterification with MA-900 catalyst optimum reaction conditions with a catalyst weight of 3%, reaction temperature of 60°C, oil: methanol mole ratio of 1:9, and reaction time of 120 min, 76.17% FAME yield was observed. The MA-900 catalyst has the potential to be an effective green catalyst.

Page 12 of 21 | Total Record : 209

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