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Reaktor
Published by Universitas Diponegoro
Reaktor invites contributions of original and novel fundamental research. Reaktor publishes scientific study/ research papers, industrial problem solving related to Chemical Engineering field as well as review papers. The journal presents paper dealing with the topic related to Chemical Engineering including: Transport Phenomena and Chemical Engineering Operating Unit Chemical Reaction Technique, Chemical Kinetics, and Catalysis Designing, Modeling, and Process Optimization Energy and Conversion Technology Thermodynamics Process System Engineering and products Particulate and emulsion technologies Membrane Technology Material Development Food Technology and Bioprocess Waste Treatment Technology
Articles 527 Documents
IN SITU TRANSESTERIFIKASI MINYAK BIJI MAHONI MENJADI METIL ESTER DENGAN CO-SOLVENT THF (TETRAHYDROFURAN) Elvianto Dwi Daryono; Adrianus Chrisantus Rengga; Imaniar Safitri
Reaktor Volume 15, No.1, APRIL 2014
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (22.611 KB) | DOI: 10.14710/reaktor.15.1.51-58

Abstract

Tujuan dari penelitian  adalah untuk mengkaji efektifitas penggunaan co-solvent THF pada reaksi transesterifikasi in situ minyak biji mahoni sebagai solusi proses pembuatan biodiesel yang efektif dan efisien. Variabel dan kondisi operasi  meliputi katalis NaOH, kecepatan pengadukan 450 rpm, suhu reaksi suhu kamar, rasio molar minyak:metanol = 1:101,39, rasio molar katalis:minyak = 0,5:1, % FFA minyak 1,42%, kadar air biji 0,8%, waktu reaksi 3, 8, 13, 18, dan 23 menit serta rasio molar minyak:THF 1:47,15, 1:57,85 dan 1:67,85. Biji mahoni yang telah dikeringkan dan dihaluskan ukuran +20/-30 mesh sebanyak 50 gram dimasukkan dalam labu leher tiga yang dilengkapi pendingin balik dan ditambahkan metanol, THF dan katalis NaOH serta dilakukan reaksi sesuai dengan variabel dan kondisi operasi penelitian. Setelah reaksi selesai dipisahkan antara ampas dan filtratnya. Filtrat didistilasi pada suhu ± 70oC dan residu hasil distilasi dimasukkan dalam corong pemisah dan didiamkan selama ± 12 jam agar terbentuk 2 lapisan. Lapisan atas sebagai metil ester kemudian dianalisis konsentrasi metil oleatnya dengan GC. Dari data hasil penelitian didapatkan hasil terbaik pada rasio molar minyak:THF = 1:67,85 dan waktu reaksi 23 menit dengan  konsentrasi metil oleat 59,10% dan yield metil ester 79,69%. Densitas metil ester 0,8791 g/cm3 memenuhi SNI 04-7182-2006 yaitu 0,85 – 0,89 g/cm3. Kata kunci : biodiesel, co-solvent, minyak biji mahoni, transesterifikasi in situ Abstract The purpose of this research was to assess the effectiveness of the use of co-solvent THF for in situ transesterification reaction mahogany seed oil as a biodiesel manufacturing process solutions that effectively and efficiently. Variables and operating conditions include catalyst NaOH, stirring speed of 450 rpm, room temperature the reaction temperature, molar ratio of oil: methanol = 1: 101.39, the molar ratio of catalyst: oil = 0.5: 1, % FFA oil is 1,42%,  moisture content seed of 0.8%, reaction time is 3, 8, 13, 18, and 23 minutes, and the molar ratio of oil: THF is 1: 47.15, 1: 57.85 and 1: 67.85. Mahogany seeds that have been dried and pulverized size +20/-30 mesh as much as 50 grams included in the three-neck flask equipped condenser and added methanol, THF and catalyst NaOH and the reaction carried out in accordance with the variables and operating conditions. After the reaction is complete, the filtrate and cake was separated. The filtrate is distilled at a temperature of ± 70°C and the residue distilled included in the separating funnel and allowed to stand for ± 12 hours in order to form two layers. The top layer as methyl esters were analyzed by GC to concentrations of methyl oleate. From the research data obtained the best results at a molar ratio of oil: THF = 1: 67.85 and reaction time 23 minutes with methyl oleate concentration of 59.10% and yield methyl ester of 79.69%. Methyl ester density 0.8791 g/cm3 meet SNI 04-7182-2006 from 0.85 to 0.89 g/cm3. Keywords : biodiesel, co-solvent, in situ transesterification, mahogany seed oil  
Penentuan Tetapan Keseimbangan Penjerapan Pada Sistem Koloid Dengan Metode Ekstrapolasi Grafik H. satriadi; I. M. Bendiyasa; Rochmadi rochmadi
Reaktor Volume 6 No. 2 Desember 2002
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (3440.529 KB) | DOI: 10.14710/reaktor.6.2.72-76

Abstract

Percobaan penjerapan pestisida pada sistem koloid air-tanah telah mendapatkan nilai tetapan keseimbangan penjerapan yang selalu berubah dan dipengaruhi perbandingan antara berat penjerap terhadap volum pelarutnya. Hal ini terjadi karena pemisahan antara penjerap dan pelarut sangat sulit dilakukan, dan pelarut selalu masih mengandung butir penjerap. Akibatnya  zat yang terjerap dalam penjerap ikut terbaca ketika menganalisis konsentrasi zat dalam pelarut. Untuk mendapatkan tetapan keseimbangan yang sebenarnya dapat dilakukan dengan modifikasi persamaan keseimbangan dan metode ekstrapolasi secara grafis. Percobaan dilakukan secara batch dengan konsentrasi awal pestisida sumithion 1,1014 ppm, perubahan konsentrasi diamati dengan kromatografi gas yang dilengkapi dengan Flame Photo Detector. Tanah yang digunakan berdiameter  butir 8,066. 10-5 cm, diameter pori 20,443 A, serta mengandung 2,86% bahan organic. Nilai tetapan keseimbangan sebenarnya diperoleh 123,936 ml air/g tanah pada 26,5 0C.Kata kunci : ekstrapolasi grafis, sistem koloid, tetapan keseimbangan penjerapan
UTILIZATION OF PINEAPPLE WASTE AS CARBON SOURCE Abdullah Moch Busairi
Reaktor Volume 12, Nomor 4, Desember 2009
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (101.165 KB) | DOI: 10.14710/reaktor.12.4.268 – 272

Abstract

The liquid pineapple waste contains mainly sucrose, glucose, fructose and other nutrients. It therefore can potentially be used as carbon source for organic acid fermentation.  The objective of this work is to evaluate the use of pineapple waste as substrate for lactic acid fermentation under variables of aerobic, anaerobic condition and pH controlling. Initial results showed that the liquid pineapple waste can be used as carbon source for lactic acid fermentation using Lactobacillus delbrueckii. In the anaerobic condition growth of bacteria and lactic acid production better than aerobic condition. In the anaerobic condition and the controlled pH  the production of lactic acid are found to be 54.79 g/l  (78.27% yield) at  40oC, pH 6, 50 rpm and 70 g/l sugar concentration.  In contrast, only 13.87g/l lactic acid produced if the fermentation pH was not controlled even though the fermentation parameters were kept at the same conditions
Utilization of Crude Intracellular Chitinase Enzyme from Providencia stuartii for Glucosamine Production from Shrimp Shells Hardoko Hardoko; Titri Siratantri Mastuti; Desy Puspasari; Yuniwaty Halim
Reaktor Volume 19 No. 2 June 2019
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (455.841 KB) | DOI: 10.14710/reaktor.19.2.62-67

Abstract

Chitin hydrolysis using enzyme is one of the methods to produce glucosamine in shorter time compared to using microbial cells, but the ability to produce glucosamine at enzyme’s optimum condition is influenced by substrate concentration and fermentation time. The objective of this research was to determine the optimum substrate concentration and fermentation time of shrimp shells’ chitin to produce glucosamine at the optimum pH and temperature of crude intracellular chitinase enzyme from Providencia stuartii. Method used was experimental method, started by extraction of intracellular enzyme from P. stuartii, followed by determination of optimum pH and temperature of enzyme. The optimum condition was used for experiment of shrimp shells’ chitin fermentation with treatments of chitin substrate concentration (0.5; 1.0; 1.5; 2.0%) and fermentation time (2, 4, 6 and 24 hours). Results showed that optimum enzyme activity occurred at pH of 5.0 and temperature of 40oC, which was about 6.03 U/ml. Concentration of chitin substrate and fermentation time influenced the amount of glucosamine obtained. Fermentation of shrimp shells’ chitin using crude intracellular enzyme was optimum at 1.0% substrate concentration and 6 hours fermentation time, which produced glucosamine about 1680.06±58.49 ppm. Keywords: intracellular chitinase enzyme, glucosamine, shrimp shells’ chitin, P. stuartii
AMOKSIMASI SIKLOHEKSANON DENGAN KATALIS MoO3/TS-1 MENGGUNAKAN HIDROGEN PEROKSIDA SEBAGAI AGEN PENGOKSIDASI Rakhmadi Harsanto; Imroatul Qoniah; Didik Prasetyoko; Ratna Ediati
Reaktor Volume 16 No.1 Maret 2016
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (503.686 KB) | DOI: 10.14710/reaktor.16.1.41-48

Abstract

AMMOXIMATION OF CYCLOHEXANONE OVER Mo-IMPREGNATED TITANIUM SILICALITE USING HYDROGEN PEROXIDE AS AN OXIDANT. Ammoximation of cyclohexanone reaction using 1% MoO3/TS-1 catalyst have been made with hydrogen peroxide as an oxidant. Reaction carried out with the batch method using methanol and acetonitrile as solvent. Reaction products analyzed using gas chromatography. The 1% MoO3/TS-1 catalyst shows the highest activity than the TS-1. The increased of 1% MoO3/TS-1 catalytic activity due to hydrophilicity properties higher than TS-1. Reaction using methanol shows the highest activity compared with reactions using acetonitrile. The optimum calcination temperature for 1% MoO3/TS-1 catalyst to gives the highest activity is 400 ºC.   Keywords: ammoximation of cyclohexanone; TS-1; 1% MoO3/ TS-1 Abstrak Amoksimasi sikloheksanon menggunakan katalis 1% MoO3/TS-1 telah dilakukan dengan menggunakan hidrogen peroksida sebagai agen pengoksidasi. Reaksi dilakukan dengan metode batch menggunakan pelarut metanol dan asetonitril. Produk reaksi dianalisis dengan kromatografi gas. Katalis 1% MoO3/TS-1 menunjukkan aktivitas katalitik yang lebih tinggi daripada katalis TS-1. Peningkatan aktivitas katalitik 1% MoO3/TS-1 dikarenakan sifat hidrofilisitasnya lebih tinggi dibandingkan TS-1. Reaksi katalisis yang menggunakan pelarut metanol memberikan aktivitas katalitik lebih tinggi daripada reaksi yang menggunakan pelarut asetonitril. Suhu kalsinasi paling optimum pada katalis 1% MoO3/TS-1 untuk memberikan aktivitas katalitik tertinggi adalah 400ºC. Kata kunci: amoksimasi sikloheksanon; TS-1; 1 % MoO3/ TS-1 
Etanolisi Olein Sawit Dengan Katalis Potassium Hidroksida J. Utomo; A. R. Ardiyanti; T. Prakoso; A. Fransiska
Reaktor Volume 09 No. 02 Desember 2005
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (4832.195 KB) | DOI: 10.14710/reaktor.9.2.79-85

Abstract

Biodiesel merupakab sumber energy alternatif yang ramah lingkungan dan dapt diperbarui, hasil reaksi transesterifikasi atau alkoholisis. Etanol digunakan sebagai bahan baku reaksi transesterifikasi. Minyak nabati yang digunakan adalah olein kelapa sawit. Etanolisis dilangsungkan dalam reaktor batch berpengaduk dengan memvariasikan temperatur  (40 0C dan 60 0C), perbandingan molar etanol terhadap minyak (3:1 dan 9:1), dan konsentrasi katalis KOH (0,5% b/b minyak dan 1,5% b/b minyak). Pengaruh setiap parameter terhadap konversi dianalisis  dengan rancangan percobaan factorial 23 dengan center point. Konversi reaksi dihitung berdasarkan analisis kadar gliserol total dan bebas menurut metode AOCS Ca 14-56. Variabel yang paling berpengaruh terhadap konversi adalah jumlah etanol yang diumpankan. Analisis varian menunjukkan adanya interaksi antar masing-masing parameter. Konversi maksimum sebesar 96,82% tercapai saat 60 0C, rasio molar 3:1, dan konsentrasi KOH 1,5% b/b minyak. Densitas etil ester yang dihasilkan dari percobaan adalah 0,852-0,894 gr/cm3 serta viskositas kinematik sebesar 1,64-5,09 mm2/s.Kata kunci : biodiesel, etanolisis, konversi, transesterifikasi
Pre-treatment dan Fermentasi Hidrolisat Kulit Buah Kakao menjadi Asam Laktat menggunakan Lactobacillus Plantarum Dodi Irwanto; Wiratni Wiratni; Rochmadi Rochmadi; Siti Syamsiah
Reaktor Volume 16 No.3 September 2016
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (350.831 KB) | DOI: 10.14710/reaktor.16.3.123-127

Abstract

Abstract COCOA POD HUSK PRE-TREATMENT AND HYDROLYZATE FERMENTATION INTO LACTIC ACID USING LACTOBACILLUS PLANTARUM. Lactic acid is a raw material that is widely used in food industry as preservatives in meat, vegetables or canned fish. In the pharmaceutical industry is used as raw material for the manufacture of drugs. Lactic acid can be made from natural materials such as lignocellulosic waste one of them is cocoa shell waste. Indonesia is number three cocoa-producing country in the world. 70% cacao fruit components such as pod husk are composed of cellulose, hemicellulose and lignin, so it has the potential to be converted into lactic acid. In this study been the conventional method to determine the overall process in order to know what parts need to be further developed to become a method more effective and efficient. The conventional method is done through several processes, namely the delignification, hydrolysis and fermentation using microorganisms. This study aims to determine the extent of the potential for cocoa pod husk waste to be converted into lactic acid. The results showed that the pod husks delignification with sodium hydroxide solution reaches optimum at a concentration of 6% which results in lower levels of lignin from 30.46 to 24.64%. The process of acid hydrolysis of the pod husks achieve optimum conditions at a concentration of 2.0%, a temperature of 120°C and a 30 minute production of glucose at 32g/L. Glucose is the result of acid hydrolysis produces lactic acid by 13.268g/L. Keywords: lactic acid; delignification; fermentation; hydrolysis; cocoa pod husks   Abstrak Asam laktat adalah salah satu bahan baku yang banyak dimanfaatkan pada industri makanan sebagai bahan pengawet daging, sayuran atau ikan kalengan. Dalam industri farmasi digunakan sebagai bahan baku pembutan obat-obatan. Asam laktat dapat dibuat dari bahan alam berupa limbah lignoselulosa yang salah satunya adalah limbah kulit kakao. Indonesia merupakan negara penghasil kakao nomor tiga di dunia. Komponen buah kakao 70% berupa kulit buah yang terdiri dari selulosa, hemiselulosa dan lignin, sehingga berpotensi untuk dikonversi menjadi asam laktat. Pada penelitian ini dipilih metode konvensional untuk mengetahui proses secara keseluruhan sehingga diketahui bagian mana yang perlu dikembangkan lebih lanjut untuk menjadi metode yang lebih efektif dan efisien. Metode konvensional dilakukan melalui beberapa proses, yakni delignifikasi, hidrolisis, dan fermentasi menggunakan mikroorganisme. Penelitian ini bertujuan untuk mengetahui sejauh mana potensi limbah kulit buah kakao untuk dikonversi menjadi asam laktat. Hasil penelitian menunjukkan bahwa delignifikasi kulit buah kakao dengan larutan sodium hidroksida mencapai kondisi optimum pada konsentrasi 6% yang menyebabkan penurunan kadar lignin dari 30,46% menjadi 24,64%. Proses hidrolisis asam terhadap kulit buah kakao terdelignifikasi mencapai kondisi optimum pada konsentrasi 2,0%, suhu 120°C dan waktu 30 menit yang menghasilkan glukosa sebesar 32g/L. Glukosa hasil hidrolisis asam menghasilkan asam laktat sebesar 13,268g/L. Kata kunci: asam laktat; delignifikasi; fermentasi; hidrolisis; kulit buah kakao 
EFFECTS OF ADMIXTURES ON THE CRYSTALLISATION RATE OF GYPSUM A BATCH CRYSTALLISATION STUDY S. Muryanto; H. M. Ang
Reaktor Volume 08 No.2 Desember 2004
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (7364.772 KB) | DOI: 10.14710/reaktor.8.2.85-93

Abstract

This paper descripbes a study on the effects of admixtures on the crystallization rate of gypsum. Two different types of biodegradable admixtures commonly used as flotation agent in copper/zinc concentrate production, namely, sodium isopropyl xanthate (=SIPX) and isopropyl thionocarbamate were investigated in this study. A laboratory batch crystallizer was used in this study, and the experiments were run using seeded method. The rate of desupersaturation or the time required to reach the equilibrium concentration was  compared for varying admixture oncentrations. It was discovered that the added seed crystals started growing imediately upon addition into the supersaturated solution, i.e. there  was no induction time.Results of this batch crystallizationstudy suggest that addition of admixtures individually or in combination, significantly affects the crystallization kinetics and in particular, reduces the rate of crystallization of gypsum. Activation energies were determined using three different temperatures, and the values obtained  mostly agreed with other published values, i.e. 60.00 ± 3.00, 57.39 ± 2.87, and 37.65 ±1.88 kj/mol, for pure gypsum, isopropyl yhionocarbamate, and SIPX, respectively.Keywords : activation energy; admixtures; CaSO4.2H2O; crystallization, gypsum; reaction rate
UPAYA PENINGKATAN MUTU DAN EFISIENSI PROSES PENGERINGAN JAGUNG DENGAN MIXED-ADSORPTION DRYER Luqman Buchori; Mohamad Djaeni; Laeli Kurniasari
Reaktor Volume 14, No. 3, APRIL 2013
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (420.285 KB) | DOI: 10.14710/reaktor.14.3.193-198

Abstract

THE EFFORT OF EFFICIENCY AND QUALITY IMPROVEMENT ON CORN DRYING PROCESS USING MIXED-ADSORPTION DRYER. The main problem in corn drying process is the low of energy efficiency (50%) and quality products. Consequently, operating costs in large for fuel consumption and the short shelf life of corn. Zeolite adsorption dryers have the potential to overcome this problem. This research aims to study composition of corn-zeolite and the effect of temperature on drying speed and protein and fat content in corn. Research variables are the ratio of corn and zeolite (1:0, 1:3, 1:1, 3:1) and intake air temperature (room temperature, 30oC, 40oC, 50oC). Sampling for moisture testing performed every 15 minutes. For energy purposes also calculated the energy efficiency (h) based on the amount of heat used to evaporate water from the corn (Qevap) divided by the total heat requirement to regenerate the zeolite and raising the air temperature (Qintr). Profiles of temperature and water in the mixed adsorption dryer are also studied. The results showed that the greater number of zeolite used, the water content of the final outcome a little more drying, protein and fat content of the final result of drying is relatively constant. The larger intake air temperature, the water content of the less drying results, protein content decreases, and the fat content does not change/relatively constant. The best variable was a ratio of corn: zeolite is 1:3 and air temperature was 50oC. While the variables that are suitable and in accordance with ISO standards for dry foods (14%) are air temperature of between 40oC and 50oC with a ratio of corn:zeolite is 1:3. The energy efficiency of 81.23% is obtained. Modeling done with FEMLAB (COMSOL) can describe the moisture content and temperature profiles in the corn and zeolite. Keywords: corn; drying; energy efficiency; mixed adsorption dryer; zeolite Abstrak Masalah utama proses pengeringan jagung adalah rendahnya efisiensi energi (50%) dan mutu produk sehingga beban biaya operasi besar untuk konsumsi bahan bakar. Pengering adsorpsi dengan zeolite berpotensi untuk mengatasi permasalahan ini. Penelitian ini bertujuan untuk mempelajari pengaruh komposisi jagung-zeolite dan suhu terhadap kecepatan pengeringan dan kandungan protein dan lemak di dalam jagung. Penelitian dilakukan dengan variabel berubah yaitu rasio antara jagung dan zeolit (1:0, 1:3, 1:1, 3:1) dan suhu udara masuk (suhu kamar, 30oC, 40oC, 50oC). Pengambilan sampel untuk pengujian kadar air dilakukan setiap 15 menit. Untuk keperluan energi dihitung pula efisiensi energi (h) berdasarkan jumlah panas yang digunakan untuk menguapkan air dari jagung (Qevap) dibagi dengan kebutuhan panas total untuk meregenerasi zeolit dan menaikkan suhu udara (Qintr). Profil temperatur dan air di dalam mixed adsorption dryer juga dipelajari. Hasil penelitian menunjukkan bahwa semakin banyak jumlah zeolit yang digunakan, kadar air hasil akhir pengeringan makin sedikit, kadar protein dan lemak hasil akhir pengeringan relatif konstan. Semakin besar suhu udara masuk pengering, kadar air hasil pengeringan makin sedikit, kadar protein semakin menurun, dan kadar lemak tidak berubah/relatif konstan. Variabel yang terbaik adalah variabel dengan rasio jagung:zeolit yaitu 1:3 dan menggunakan suhu udara pengering 50oC. Sedangkan variabel yang cocok dan sesuai dengan standar SNI untuk makanan kering (14%) adalah variabel dengan menggunakan suhu udara pengering antara 40oC dan 50oC dengan rasio berat jagung : zeolit adalah 1:3. Efisiensi energi diperoleh sebesar 81,23%. Pemodelan yang dilakukan dengan Femlab (COMSOL) dapat menggambarkan profil kandungan air dan suhu di dalam jagung dan zeolit. Kata kunci : jagung; pengeringan; efisiensi energi; mixed adsorption dryer; zeolit
Distribusi Aliran Dalam Reactor Berkanal Mikro Y. W. Budhi; E. Restiawaty; subagjo Subagjo
Reaktor Volume 11, Nomor 1, Juni 2007
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (4758.051 KB) | DOI: 10.14710/reaktor.11.1.1-7

Abstract

Reactor mikro telah menempatkan diri pada posisi yang diminati dalam pengembangan teknologi reactor modern yang memiliki karakteristik pokok dalam hal  percepatan laju perpindahan massa dan panas yang berlipat ganda. Dengan dimensi yang berskala mikron, distribusi aliran dari pipa induk menuju masing-masing kanal merupaka salah satu persoalan penting untuk menjamin keseragaman aliran di setiap kanal. Makalah ini mengkaji distribusi aliran dalam lima model reactor dan shift converter yang mengkonversi CO menjadi CO2 agar tidak meracuni katalis dalam sel bahan bakar. Selanjutnya pada model reactor dengan distribusi terbaik, karakteristik cold start up ditelaah lebih mendalam melalui teknik reaksi kimia tak tunak. Hasil studi menunjukkan bahwa start up pada shift converter dapat dilakukan dalam waktu yang sangat singkat yang menunjukkan bahwa secara praktis unit reactor mikro ini dapat diterapkan.Kata kunci : reactor mikro, pemodelan dan simulasi, shift converter, miniaturisasi

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