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Resti Nurmala Dewi
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Jurusan Teknik Kimia Universitas Syiah Kuala, Jl. Tgk. Syech Abdur Rauf No.7, Kopelma Darussalam, Banda Aceh, INDONESIA
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INDONESIA
JURNAL REKAYASA KIMIA & LINGKUNGAN
Published by Universitas Syiah Kuala
ISSN : 14125064     EISSN : 23561661     DOI : https://doi.org/10.23955/rkl.v18i2.34018
Core Subject : Science, Engineering,
Chemical Engineering, Chemistry & Bioengineering Energy Engineering
The Journal of Chemical Engineering and Environment is an open access journal that publishes papers on chemical engineering and environmental engineering. The following topics are included in these sciences: Food and biochemical engineering Catalytic reaction engineering Clean energy technology Environmental and safety technology Fundamentals of chemical engineering and applied industrial engineering Industrial chemical engineering Material science engineering Process and control engineering Polymer and petrochemical technology Membrane technology Agro-industrial technology Separation and purification technology Environmental modelling Environmental and information sciences Water and waste water treatment and management Material flow analysis Mechanisms of clean development
Arjuna Subject : Teknik Kimia (semua kategori) - Bioengineering
Articles 319 Documents
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Optimasi Proses Ekstraksi Oleoresin Jahe (Zingiber officinale Rosc) Menggunakan Ultrasonik Hartuti, Sri; Supardan, Muhammad Dani
Jurnal Rekayasa Kimia & Lingkungan Vol 9, No 1 (2012): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

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Abstract

The study on extraction of oleoresin from ginger by using ultrasonic was carried out in order to obtain the optimum condition of extraction process. The effect of ratio of ginger to solvent (ethanol, X1), extraction temperature (X2), and extraction duration (X3) are studied on the yield of oleoresin. Response surface design method with Central Composite Design (CCD) was used to obtain a mathematical model which describes the relationship between the yield of ginger oleoresin and influencing variables. The experimental results indicate that the optimum condition of extraction which yield of oleoresin of 11.026% was found at ratio of ginger to ethanol (X1) of 1:4.68 gr.ml-1, extraction temperature (X2) of 420 OC, and extraction duration (X3) of 79 minutes.Keywords: extraction, response surface method, ginger oleoresin, ultrasonic
Pengaruh Rasio Aditif Polietilen Glikol Terhadap Selulosa Asetat pada Pembuatan Membran Selulosa Asetat Secara Inversi Fasa Rosnelly, Cut Meurah
Jurnal Rekayasa Kimia & Lingkungan Vol 9, No 1 (2012): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

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Abstract

Preparation of cellulose acetate (CA) membranes with ultrafiltration process had be done by phase inversion using dimethylformamide (DMF) as solvent. Poliethylene glycol (PEG) 1450 Da, as additive, was added with 10, 20, and 30% rasio of celluose acetate. The thin film of polymer solution was immersed on water bath coagulation at room temperature. The analysis of membrane morphology structure by Scanning Electron Microscope (SEM) JSM 5310 LV, Jeol-Japan showed the asymetric of membrane. The addition of PEG can improve the performance of the membrane. In resulting flux is higher than membranes without PEG. Increasing of PEG/CA ratio resulted in the higher flux with lower of rejection. The higher fluxes of water, dextran, and BSA are 146, 114, and 96 L/m2hr with 52,938 and 75,716% rejection for dextran and BSA.Keywords: cellulose acetate membranes, polyethylene glycol, ultrafiltration
Sintesis Membran Poliuretan dari Asam Lemak Bebas Teroksidasi Tolulen Diisosianat Marlina, Marlina
Jurnal Rekayasa Kimia & Lingkungan Vol 9, No 1 (2012): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

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Abstract

Polyurethane (PU) membranes was prepared by reacting the free fatty acids and fatty acids that have been oxidazed from castor oil with a 2,4-toluen di-isocyanate (TDI). He effect of of monomer composition, temperature, and polymerization time was studied on the performances of flat sheet membrane. Experimental results showed that the optimum conditions of the membrane synthesis from free fatty acid by oxidation-methylation was obtained at ratio of 1.2: 0.56 (mol / mol), temperature of 100 C and polymerization time of 5 minutes. The resulting membranes are transparent, elastic, homogeneous, robust and has a glass transition point of 127.4 C and had stensile strength about 41.7 MPa. Infraredspectrum (IR) observation showed that the persistence of the peak CO from -NCO at wavenumber 2272.9 cm-1, whereas the -OH group was disaapear at wave numbers 3100-3300 cm-1. This indicated that the polymerization reaction of PU membrane synthesis from free fatty acids was done successfully.Keyword: Castor oil, free fatty acids, inframerah (IR), 2,4-tolulen di-isocyianat (TDI)
Pengaruh Kondisi Proses Terhadap Yield dan Kadar Lignin Pulp dari Pelepah Sawit dengan Proses Asam Formiat Zulfansyah, Zulfansyah; Fermi, Muhammad Iwan; Amraini, Said Zul; Rionaldo, Hari; Utami, Meilany Sri
Jurnal Rekayasa Kimia & Lingkungan Vol 9, No 1 (2012): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

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Abstract

Formic acid pulping of oil palm frond was conducted to study the influence of process variables (formic acid concentration, hydrogen peroxide concentration, and pulping time) on the properties of pulp produced (yield pulp and lignin content). A second order polynomial model consisiting of three independent process variables was found to accurately describe the formic acid pulping of oil palm frond. The propose equations reproduce the experimental results for the dependent variables with erros less than 5% for both yield dan lignin content. The most influential factor on yield pulp was formic acid concentration. Whereas, the cooking time has greater influence on lignin content.Keywords: formic acid, lingocelulose, pulping, pulp organosolv, oil palm fronds
Influence of Water-jet Nozzle Geometry on Cutting Ability of Soft Material Irwansyah, Irwansyah; Ibrahim, Masri; Ferdiansyah, Hendra
Jurnal Rekayasa Kimia & Lingkungan Vol 9, No 1 (2012): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

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Abstract

Hygiene is main reason for food processor to use waterjet cutting system. Traditionally food cutting process is low-quality, unsafe products, procedures and direct contact between product and labor. This paper introduced a low cost waterjet system for cutting soft material as identic food material. The low cost waterjet system has been developed by using a commercial pressure pump for cleaning purposes and modified nozzle. In order to enhance waterjet pressure for cutting products, a modified waterjet nozzle was designed. Paramater design of waterjet system was setup on nozzle orifice diameter 0.5 mm, standoff distance 15 mm, length of nozzle cylindrical tube 2.5 mm. Polycarbonate, polysterene, and polyethelene materials are used as sample product with thickness 2 mm, to represent similar properties with agriculture products. The experimental results indicate good possibilities of waterjet system to cut material in appropriate profile surface. The waterjet also can be used to improve cutting finished surface of food products. Therefore, utilizing a low cost commercial pump and modified nozzle for waterjet system reduces equipment price, operational cost and environmental hazards. It indicates viable technology applied to substitute traditional cutting technology in post harvest agriculture products.Keywords: cutting ability, modified nozzle, polymer material, water-jet system
Adsorpsi Surfaktan Nonionik Alkil Poliglikosida pada Antar muka Fluida-Fluida Adisalamun, Adisalamun; Mangunwidjaja, Djumali; Suryani, Ani; Sunarti, Titi Candra; Arkeman, Yandra
Jurnal Rekayasa Kimia & Lingkungan Vol 9, No 1 (2012): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

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Abstract

Nonionic surfactants have been used extensively in various industrial applications such as cleaning, personal care, crop protection, paint and coating, textile finishing, emulsion stabilization, food and leather processing. In this study, we have studied the adsorption of three nonionic surfactants of alkyl polyglycoside, namely commercial APG from Cognis and APG produced from glucose as well as APG synthesized from sago starch, at fluidfluid interfaces. The variation of surface and interfacial tension with the concentration of surfactant in the bulk was studied, and the data were fitted using a surface equation of state derived from the Langmuir isotherm. The agreement between ?(c) data and Langmuir isotherm model was very good.Keywords: adsorption, air/water interface, interfacial tension, surface tension
Heavy Metal Removal from Wastewater Using Synthesized Silicate-1 Nanocrystal Muhammad, Syaifullah; Syahputra, Edy; Nasrullah, Nasrullah; Suraiya, Suraiya; Wang, Shaobin; Tade, Moses O.
Jurnal Rekayasa Kimia & Lingkungan Vol 8, No 1 (2011): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

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Abstract

Particle size reduction of zeolite to the nanometer scale leads to substantial changes in the properties of zeolite which make them promising materials for many applications including adsorption. Zeolite silicate-1 Nanocrystal was synthesized at temperatures of 800C, 1200C and 1500C by adding tetrapropylammonium hydroxide (TPAOH) into silica sources. The synthesis mixtures are 2TPAOH: 0.15Na2O: 4.5Si: 382H2O: 51EtOH (TEOS as silica source) and 2TPAOH: 0.15Na2O: 6SiO2: 532H2O: 51EtOH (Ludox LS as silica source). X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) were used to characterize the synthesised products. The nanosilicate-1 particle size were obtained in range of 119 nm 1678 nm. This research also confirmed that TEOS can make smaller particle size up to 36.43 % than Ludox LS due to an average hydrodynamic diameter of 4 nm of TEOS smaller than Ludox LS of 15-19 nm. In the heavy metal adsorption study, it was found that the adsorption capacity indicated by Qmax (Langmuir) and KF (Freundlic) shows higher Pb2+ adsorption than Cr3+. The maximum adsorption capacities of Pb and Cr at 300C are 131.58 mg/g and 129.87 mg/g, respectively. Further, it can also be seen that the KL values in the Langmuir isotherm indicate the higher selectivity of Pb on silicate-1 zeolite than Cr.Keywords :Adsorption capacity, Heavy metal, Isotherm, Silicate-1 nanocrystal
Produksi Aluminium Sulfat dari Kaolin dan Asam Sulfat Dalam Reaktor Berpengaduk Menggunakan Proses Kering Ismayanda, Muhammad Husin
Jurnal Rekayasa Kimia & Lingkungan Vol 8, No 1 (2011): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

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Abstract

Aluminium sulphate is form by reacting alumina which contains in kaolin with sulphuric acid solution in a stirred reactor. Reaction occurs in variance of different time and temperature. The result of reaction is paste aluminium which will be extracted about 3 times using hot aquadest and consentration of aluminum analized by titrimetric methode. Time, temperature and ratio of sulphuric acid and kaolin in reaction have a lot effect to conversion value result, while sulphuric acid concentration and speed of agitation are not too effected. Process condition which is about to be good is temperature 180 oC, reaction time 90 minutes, ratio of sulphuric acid and kaolin is 3:1, sulphuric acid concentration 65% and speed of agitation 350 rpm. Converted aluminum can reach 82%.Keywords: Aluminum sulphate, Dry process, Kaolin, Sulphuric acid, Stirred reactor
Penentuan Nilai Penyerapan Suara Pada Panel Dinding Beton Busa Sebagai Panel Alternatif Yang Ramah Lingkungan Zulfian, Zulfian; Abdullah, Abdullah; Fahridhal, Fahridhal
Jurnal Rekayasa Kimia & Lingkungan Vol 8, No 1 (2011): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

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Abstract

Panel of foam concrete wall is a type of membrane panel which has maximum sound absorption and can create quite and environmentally friendly room. The purpose of this study was to determine the magnitudeof the sound absorption value using the Sabine formula in Reverberation Chamber at Syiah Kuala University acoustic laboratory. The result of this study show that peak value curve sound absorption of 0.67 accurs at the frequency of 250 Hz, and painting of the panel surface can increase the value of sound absorption to be 0.76 at the frequency of 250 Hz,but the slope of sound absorption value sharply decreased to be 0.07at the frequency of 1000 Hz. Treatment on the panel surface can increase or decrease the value of sound absorption especially at the low frequency regions.Keywords: Panel of foam concrete wall, Sabine formula, The value of sound absorption
Efek Adsorpsi Dye ke dalam Lapisan TiO2 dengan Metode Elektroforesis : DSSC Berbasis Lapisan TiO2 Terbuat dengan Metode Slip Casting dan Metode Elektroforesis Nuryadi, Ratno
Jurnal Rekayasa Kimia & Lingkungan Vol 8, No 1 (2011): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

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Abstract

This research aims to investigate the effect of dye adsorption into TiO2 layer in dye sensitized solar cell (DSSC), which the TiO2 layer is formed by slip casting and electrophoresis methods. Adsorption process of the dye into the cavities of the TiO2 layer was conducted by electrophoresis technique. As results, two DSSCs prepared by the slip casting and electrophoresis methods were successfully realized and tested. In case of DSSC based on electrophoresis method, XRD results show the appearance of MgO on TiO2 layer, which is probably caused by the addition of salt Mg(NO3)2 in the electrophoresis solution. Therefore, electrophoresis condition without the addition of salt needs to be investigated in the next research. It is found that the electrophoresis method can be used in the process of dye adsorption into the TiO2 layer. The electrophoresis with larger voltage results in the larger DSSC output. It is also seen that open circuit voltage for the slip casting-based DSSC is found to be greater than that for the electrophoresis-based one. This may be due to the larger size of the pores in TiO2 layer for the slip casting process compared to that for the electrophoresis process. For larger size of the pores, the dye can easily fit into the pores with the help of electrophoresis.Keywords: Dye-sensitized solar cell, Dye adsorption, Electrophoresis, Slip casting

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