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Journal : JURNAL ATOMIK

APLIKASI METODE ELEKTROKOAGULASI TERHADAP PENURUNAN KADAR ION LOGAM Fe DAN Mn, KEKERUHAN SERTA WARNA PADA PENGOLAHAN AIR GAMBUT SECARA BATCH Kurniasih, Ririn Feby; Gunawan, Rahmat; Panggabean, Aman Sentosa
JURNAL ATOMIK Vol 1 No 1 (2016)
Publisher : Jurusan Kimia FMIPA UNMUL

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The research about application of electrocoagulation method regarding the decrease level of metal ion such Fe, Mn, turbidity and color on peat water treatment ini batch method had been done. The research in batch method using alumunium (Al) plat as electrode until obtained higher efficiency elimination on voltages of 12 volt with electrocoagulation process time, 120 minute in batch method. The result on variation of voltages was capable to decrease Fe level with efficiency 99.87% from 3.6899 mg/L become 0.0045 mg/L and followed by Mn 95.90% from 0.0244 mg/L become -0.0008 mg/L, turbidity 98% from 385 NTU become 0,95 NTU and color 97.67% from 338.08 Pt-Co become 7.8646 Pt-Co. Long term variation of contact was capable to decrease fe level with efficiency 99.57% from 3.6899 mg/L to 0.0158 mg/L followed by Mn 93.03% from 0.0244 mg/L become 0.0017 mg/L, turbidity 99.74% from 385 NTU to 0.97 NTU and color 98.73% from 338.08 Pt-Co become 4.2985 Pt-Co. Elimination percent has proving electrocoagulation method was capable to decreasing the level of Fe ion, Mn, turbidity and color on peat water and comply the regulation of healthy minister Indonesia Republic No 416/MENKES/PER/IX/1990 regarding clean water quality Keywords :Peat Water, Electrocoagulation, Fe, Mn, Turbidity, Color Intensity
PEMANFAATAN AIR ASAM TAMBANG BATUBARA SEBAGAI SUMBER ENERGI LISTRIK ALTERNATIF Fatimah Islamunisa; Bohari -; Aman Sentosa Panggabean
JURNAL ATOMIK Vol 3 No 1 (2018)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

The research about utilizing Acid Mine Drainage (AMD) as source of electrical energy has done. The variables of the observations made in the influence of electrode, number of cells and the working time of the cell. The results showed that the electrode, the number of cells and the working time of the cell affect the potential value of cells. The pair of electrodes of the metal cooper (Cu), Zinc (Zn), Carbon (C) have been varied showed the potential value of the most high by using a pair of electrodes C-Zn amounting to 1.68 V. More the number of cells that are used the higher the potential value that is produced, where the use of cells from 1 until 5 consecutive potential values of the cells produced are 1.57 V; 3.28 V; 4.90 V; 6.57 V; 8.20 V. The working time of the cell the longer it is used the more reduced the potential value of what is produced, where from 0 h, 3 h, 6 h, 9 h, 12 h and 15 h respectively the potential value of the cells produced are 1.63 V; 1.61 V; 1.59 V; 1.57 V; 1.56 V.
OPTIMASI KINERJA ANALITIK PADA PENENTUAN SURFAKTAN ANIONIK DALAM SAMPEL AIR ALAM MENGGUNAKAN METODE MBAS (Methyl Blue Active Subtance) Rani Novia Ulya; Bohari Yusuf; Aman Sentosa Panggabean
JURNAL ATOMIK Vol 1 No 1 (2016)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

 Penelitian tentang optimasi kinerja analitik pada penentuan surfaktan analitik pada penentuan surfaktan anionik dalam sampel air alam menggunakan metode MBAS (Methyl Blue Active Subtance) telah dilakukan. Penelitian ini bertujuan mengetahui titik optimum dari surfaktan anionik dengan menggunakan metode MBAS yang telah dioptimasi kinerja analitiknya. Dilakukan metode optimasi pada pengaruh Cloroform dan pH dimana surfaktan anionik bereaksi dengan warna biru metilen dan diukur dengan spektrofotometer UV-Vis dengan panjang gelombang 637 nm. Diperoleh volume Cloroform yang optimal adalah 10 mL dengan pH optimal adalah pH 4. Lalu dilakukan proses kinerja analitik, metode ini sangat baik untuk menganalisis surfaktan ditunjukkan dari pengukuran nilai batas deteksi sebesar 0,3394 ppm, dengan tingkat kebolehulangan yang diyatakan dengan nilai presentase koefisien variasi sebesar 2,33%. Metode ini dapat diaplikasikan untuk analisis surfaktan pada sampel air dari lingkungan dengan nilai perolehan kembali > 95%, menggunakan teknik spike menunjukkan bahwa matriks sampel yang berasal dari sungai Mahakam tidak mempengaruhi hasil pengukuran. Kata Kunci: Kinerja Analitik, Surfaktan, MBAS
Pengembangan Metode Rapid Test Preparation Dalam Penentuan Kadar Inherent Moisture dan Total Sulfur Dengan Menggunakan Metode yang Dipergunakan oleh ISO (International Organization for Standardization)) Lumban Gaol Veronica Destiana; Aman Sentosa Panggabean; Rudi Kartika
JURNAL ATOMIK Vol 2 No 1 (2017)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

The research about the development of rapid test method in determination of inherent moisture concentration and total sulfur which used by the ISO (International Organization for Standardization) has been diving. This research aims to determine is the rapid test method could be used to analyze inherent moisture and total sulfur to determine the analytical performance of the rapid test. Parameters of the validation used in this research are accuracy which described in percent of recovery as the percent of the recovery of inherent moisture are 99,98 % and total sulfur value are 98,57 %, precision described in coefficient of the variant which gained in inherent moisture are 0,49% and total sulfur value is 4,1%. Robustness of method is described in the variation of drying time, which accuracy and precision do not affect by time variation in preparation. The results show that rapid test method can be used for an alternative method which used by the ISO.
PERBANDINGAN KINERJA ANALITIK HASIL PENENTUAN ION LOGAM Pb DENGAN MENGGUNAKAN SPEKTROFOTOMETER SERAPAN ATOM DI BERBAGAI LABORATORIUM SAMARINDA arifin syam syam; bohari Yusuf; Aman Sentosa Panggabean
JURNAL ATOMIK Vol 6 No 2 (2021)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

The study about the comparison of analytical performance of the determination of Pb metal ions using Atomic Absorption Spectrophotometer in various laboratories in samarinda has been conducted. The validated methods are linearity, detection limits, quantity and precision limits. The results showed, a standardized regression test obtained by laboratory A, a value of R2 ≥ 0.4103, laboratory B a value of R2 ≥ 0.983 and laboratory C, a value of R2 ≥ 0.000. The detection limit found at laboratory A was 0.6728 µg/L, laboratory B was 0.1989 µg/L and laboratory C was 0.0001 µg/L. The quantization limit obtained by laboratory A was 0.6817 µg/L, laboratory B was 0.6063 µg/L and laboratory C was 0.0001 µg/L. The precision test of laboratory A was 7.2208, laboratory B was 5.4557 and laboratory C was 0,000. The result of determining Pb of gas station soil samples in laboratory A is 0.737 µg/L and laboratory B is 0.391 µg/L, so that means they have exceeded the quality standards set by the Indonesian National Standard (INS).
ELEKTRODELOKALISASI ZAT WARNA LIMBAH CAIR SARUNG TENUN SAMARINDA MENGGUNAKAN ELEKTRODA PbO2/Cu Menono, Fera Friskaneke; Wirawan, Teguh; Panggabean, Aman Sentosa
JURNAL ATOMIK Vol 9 No 1 (2024)
Publisher : Jurusan Kimia FMIPA UNMUL

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30872/ja.v9i1.1361

Abstract

Electrodecolorization of Sarung Tenun Samarinda liquid waste dyestuff using PbO2/Cu electrode has been conducted. This study aims to reduce the level of dyes in Sarung Tenun Samarinda liquid waste samples by electrodecolorization method using lead dioxide (PbO2) electrode as anode and Copper (Cu) as cathode. Electrodecolorization was carried out by varying the working potential, Na2SO4 electrolyte concentration, time, and dye concentration in order to obtain optimum conditions for dye decolorization by electrolysis process. The concentration of the dye was determined by calculating the absorbance data obtained from measurements using a UV-Vis spectrophotometer. The results showed that the optimum conditions of electrodecolorization on orange dyes using PbO2/Cu electrodes were a working potential of 10.5 volts, 0.2 M Na2SO4 electrolyte concentration and a time of 20 minutes. In green dyes, the optimum conditions are working potential of 10.5 volts, electrolyte concentration of Na2SO4 0.1 M and time for 15 minutes. The percentage of decolorization of the orange Sarung Tenun Samarinda liquid waste sample using the PbO2/Cu electrode was 100% and in the green Sarung Tenun Samarinda liquid waste sample was 100%.
VERIFIKASI PARAMETER PENGUJIAN SURFAKTAN ANIONIK DALAM AIR LIMBAH DENGAN METODE MBAS MENGGUNAKAN SPEKTROFOTOMETER UV-VIS Victoria, Stefanie; Sitorus, Saibun; Panggabean, Aman Sentosa
JURNAL ATOMIK Vol 7 No 2 (2022)
Publisher : Jurusan Kimia FMIPA UNMUL

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Determination of the parameters verification of anionic surfactants in waste water samples based on the MBAS (Methylene Blue Active Substances) method using a UV-Vis spectrophotometer has been done. Verification of the measurement parameters refer to SNI 06-6989.51- 2005. The measurement results of several verification parameters is good showed that the linearity of the measurement indicated by the correlation coefficient value of 0.9909. The detection limit and quantitation limit values ​​obtained were 0.3622 mg/L and 1.2072 mg/L respectively. The precision value with %RSD was 2.5415%, and the %RPD value was 3.0686%. It is stated that this method can be used for the analysis of anionik surfactants in laundry wastewater and can be applied as a routine test at PT. Global Environment Laboratory.
THE MANUFACTURING OF SILICA GEL FROM BAMBOO LEAF ASH (Dendrocalamus asper (Schult. f) Backer ex Heyne) AND THE APPLICATION FOR ADSORPTION Cd (II) ION -, Yasrin; -, Alimuddin; Panggabean, Aman Sentosa
JURNAL ATOMIK Vol 5 No 2 (2020)
Publisher : Jurusan Kimia FMIPA UNMUL

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The research about silica gel manufacturing from bamboo leaf ash (Dendrocalamus asper (Schult.) Backer ex Heyne) and the application for Cd (II) ion adsorption has been done. The adsorption of Cd (II) ion done by some varieties, such as pH, concentration, and contact time. The result of the research showed the optimum pH was 8, the optimum concentration was 4 ppm and the contact time was 60 minutes. The adsorption capacity was 0.388 mg/g and the percentage of recovery was 93.44%.
SINTESIS DAN KARAKTERISASI NANOPARTIKEL PERAK TERMODIFIKASI KITOSAN MENGGUNAKAN REDUKTOR NaBH4 Az Zahra, Upi Fathimah; Hindryawati, Noor; Panggabean, Aman Sentosa
JURNAL ATOMIK Vol 9 No 2 (2024)
Publisher : Jurusan Kimia FMIPA UNMUL

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30872/ja.v9i2.1406

Abstract

The research about synthesis of chitosan-modified silver nanoparticles using NaBH4 reducing agents has been carried out. This research aims to determine the optimum AgNO3 concentration, optimum pH and optimum stirring time. The chitosan-modified silver nanoparticles obtained were then characterized using a UV Vis Spectrophotometer, Particle Size Analyzer and Transmission Electron Microscopy instruments. The results of measurements using a UV-Vis Spectrophotometer, the synthesis of chitosan-modified silver nanoparticles was obtained was obtained at the optimum condition of AgNO3 concentration of 3x10-3 M, pH 4 and the optimum stirring time was 2 hours. The formation of AgNPs is characterized by the presence of typical absorption peaks at maximum wavelengths of 402 nm-434 nm. Keywords: Silver Nanoparticles, Chitosan, NaBH4
PEMANFAATAN LIMBAH NON B3 FLY ASH DAN BOTTOM ASH DARI KEGIATAN PLTU SEBAGAI SUBTITUSI BAHAN BAKU PEMBUATAN PAVING BLOCK DAN BATAKO Erzha, Nutfahryza; Sitorus, Saibun; Panggabean, Aman Sentosa
JURNAL ATOMIK Vol 9 No 2 (2024)
Publisher : Jurusan Kimia FMIPA UNMUL

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30872/ja.v9i2.1416

Abstract

The use of coal in power plant activities will produce solid waste in the form of fly ash and bottom ash. Alternative management to reduce the volume of ash waste is through utilization. Therefore, this study aims to determine the toxic characteristics of bottom ash fly ash waste, determine the physical properties of the compressive strength of paving blocks and bricks from the substitution of fly ash and bottom ash, as well as the most optimal proportion of substitution of the product based on the compressive strength parameter. Compatibility of Toxic Waste Characteristics is carried out through the Toxicity Characteristic Leaching Procedure (TCLP) test. Variation of optimal substitution for compressive strength is known through variations of fly ash and bottom ash substitution, for brick products which are 5%, 10%, 15%, and 20%, and for paving blocks which are 10%, 20%, 30%, and 40%. Through the TCLP test, it is known that the waste is below the TCLP A and TCLP B quality standards so it can be categorized as non toxic and hazardous waste. The results of using fly ash and bottom ash in brick products meet the requirements for compressive strength according to SNI 03-0349-1989. The results of using fly ash and bottom ash in paving block products meet the requirements for compressive strength according to SNI 03-0691-1996. The optimal variation of fly ash substitution for bricks is with 5% fly ash substitution that produces a compressive strength value of 201.42 kg/cm2 and paving blocks with 10% fly ash substitution that produces a compressive strength value of 225.01 kg/cm2. The optimal variation of bottom ash substitution for brick is with 5% bottom ash substitution that produces a compressive strength value of 226.30 kg/cm2 and for paving block is with 10% bottom ash substitution that produces a compressive strength value of 308.22 kg/cm2.
Co-Authors -, Yasrin Adha, Laila Sufina Adhi Surya Pranata Surya Pranata Adhi Surya Pranata Surya Pranata, Adhi Surya Pranata Surya Adhitya Rinaldi Akhmad Rifani Akkas, Erwin Ali Murtopo Alimuddin Alimuddin - Alimuddin Alimuddin Alimuddin Alimuddin Alimuddin Alimuddin Alimuddin Alimuddin Alya Yuni Maulana Amrina Rosyada Anggun Ridha Avitri Ani Trisnawati Anwar, Adliah Arif, Moh. Syaiful Arifin Syam Surya arifin syam syam Az Zahra, Upi Fathimah Bagus Muliawan Bayu Iskandar Bohari - Bohari Bohari Bohari Bohari Bohari Yusuf Bohari Yusuf Buchari Buchari Buchari Buchari Budiono, May Cahaya, Tentriati Chairul Saleh Darmin - Darwin, Chepy Dirgarini Julia Nurlianta Subagyono Eka Apriska S Kusuma Erwin - Erwin Erwin Erwin Erwin Erwin Erwin Erwin Erwin Erzha, Nutfahryza Fadilah Ramadhani Farida Kristiana Farlianti, Resma Lita Fatimah Islamunisa Filus, Tio Fitriana, Mila Friscylia Friscylia Gaanty Pragas Maniam, Gaanty Pragas Hariati, Hariati Hariati, Hariati Harum Widyastuti Hening Ayu Marinda Hutagalung, Sandi Christopher Idris Mandang, Idris Irviansyah, Alfian Iskandar, Bayu Joni Rahman Josephine Josephine, Josephine Juntia Kirana Pratiwi Khasanah, Manja’a Kumalasari, Anisa Kurniasih, Ririn Feby Kusmiaty, Prilianda Leonardus Lewo Hayon Lianasari, Ika Yekti Lossi Hotmaida Simanjuntak Lumban Gaol Veronica Destiana M. Bachri Amran Manja’a Khasanah Margaretta D. R. N. S Marvin Horale Pasaribu May Budiono Mayang, Julia Agustin Menono, Fera Friskaneke Mila Fitriana Moh Syaiful Arif Muhammad Asfian Nur Muhammad Bachri Amran Muhammad Rizky Muhammad Robiansyah Nanang Tri Widodo Nanang Tri Widodo Nauval Dwi Fadillah Nazaratun Thaiyibah Noor Hindryawati Noor Hindryawati, Noor Nur, Nana Septiana Nurhasanah Nurhasanah Oktavia, Dwina Putri Oktaviani, Reka pakasi, Resy Prayuda, Adif Putri, Amelia Putri, Rinda Anisyah RAHMAT GUNAWAN Rahmat Gunawan Rani Novia Ulya Rida Awliyani Rientha Septiana Rika anggraini Rina Rina Ristia Asri Fidayana Rita Hairani Rudi Kartika, Rudi Rumengan, Nur Khamillah Sadijah Achmad Saepudin Suwarsa Saibun Sitorus Saibun Sitorus Sandi Christopher Hutagalung Sari, Ermalia Lintang Sari, Ika Yekti Liana Sari, Rahma Juwita Septiana, Rientha Shintia Alifah R Soerja Koesnarpadi Soerja Koesnarpadi Subagyono, Dirgarini Julia Nurlianti Subur P Pasaribu Sujito Sujito Teguh Wirawan Teguh Wirawan, Teguh Tentriati Cahaya Tika Widyastuti Tio Filus Trisnawati, Ani Victoria, Stefanie Willem Hendrik G Wirdhaningsih Wirdhaningsih Yasser Arafat Yulianti Kartika Yulieta, Afifah Nur Yusuf, Irfan Maulana