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Journal : Journal of Green Science and Technology

Phosphoric Acid-Activated Carbon From Coffee Grounds and Fly Ash For Efficient Laundry Wastewater Adsorption Muhari, Emma Hermawati Muhari; Silalahi, Rafael Leonardo; Puspita, Nina; Maryani, Anisya Sri; Sihombing, Rony Pasonang; Adhitasari, Alfiana; Kurnia, Dianty Rosirda Dewi
Journal of Green Science and Technology Vol 9 No 2 (2025): Journal of Green Science and Technology Vol. 9 No.2 September 2025
Publisher : Faculty of Engineering, Universitas Swadaya Gunung Jati

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33603/jgst.v9i2.10649

Abstract

Laundry waste that is directly discharged into water bodies causes pollution due to its chemical content, such as phosphate. The adsorption method is chosen as an option to reduce the phosphate content in laundry waste due to its simple preparation and low cost. The adsorbent used is a mixture of coffee grounds and fly ash. The use of coffee grounds is based on the increasing waste from coffee shops, thus being utilized as an adsorbent. The aim of this study is to determine the effectiveness of coffee grounds and fly ash with the best combination of composition and contact time using the adsorption method. The stages begin with the preparation of coffee grounds and fly ash through carbonization and activation using H3PO4. The variations performed consisted of variations in the composition of coffee grounds and fly ash with a total of 1 gram in ratios of 1:4; 2:3; 1:1; 3:2; 4:1 and contact time variations of 15 minutes, 30 minutes, 45 minutes, 60 minutes, and 75 minutes. Based on the research results, the highest percentage of removal was found in the composition variation of coffee grounds and fly ash with a ratio of 1:4 for 75 minutes.
Utilization Of Sengon Wood Sawdust Waste as Esterified Cellulose-Based Bioadsorbent for CD(II) Wastewater Purification Fauzan, Rizky; Mujahidah, Nisa Rahmah; Nugraha, Teguh Aditya; Azzahra, Nasya; Paramitha, Tifa; Soeswanto, Bambang; Sihombing, Rony Pasonang
Journal of Green Science and Technology Vol 9 No 3 (2025): Journal of Green Science and Technology Vol. 9 No. 3 December 2025 Special Editio
Publisher : Faculty of Engineering, Universitas Swadaya Gunung Jati

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33603/jgst.v9i3.10650

Abstract

Cadmium (Cd) is a heavy metal with high toxicity that can enter the body through contaminated food chains, so wastewater containing cadmium needs to be treated before being discharged into the environment. This study uses adsorption methods to reduce Cd(II) concentration in artificial wastewater by utilizing modified sengon wood sawdust cellulose as a bioadsorbent. Adsorption tests were conducted in batch mode at room temperature with constant stirring, and the results were analyzed using AAS. The objective of this study was to determine the optimum adsorption conditions using Response Surface Methodology (RSM) and to determine the adsorption capacity of the modified bioadsorbent based on the Freundlich or Langmuir adsorption isotherm models. The variations in bioadsorbent dose in this study were 2, 4, and 6 g/L; adsorption time variations were 30, 60, and 90 minutes; pH variations were 3, 4, and 5. Based on the design expert 13 RSM software, the optimum adsorption conditions for citric acid-modified bioadsorbent are a bioadsorbent dose of 3.957 g/L, time of 31.655 minutes, and pH of 4.968. For the EDTA-modified bioadsorbent, the optimum conditions were a bioadsorbent dose of 3.836 g/L, time of 30 minutes, and pH of 4.708. The results of the adsorption isotherm modeling indicate that the citric acid-modified and EDTA-modified bioadsorbents are more suitable for the Freundlich isotherm model due to their higher determination coefficient (R²). Thus, the adsorption capacities for the citric acid-modified and EDTA-modified bioadsorbents were determined to be 1.7828 mg/g and 1.5776 mg/g, respectively.
Phosphate Reduction in Laundry Wastewater Using Activated Coffee Grounds and Fly Ash as Adsorbents Sihombing, Rony Pasonang; Christianti, Christianti; Ramadhani, Nabila Dwi Nur; Martadinata, Nadya Zafirra; Adhitasari, Alfiana; Kurnia, Dianty Rosirda Dewi
Journal of Green Science and Technology Vol 9 No 3 (2025): Journal of Green Science and Technology Vol. 9 No. 3 December 2025 Special Editio
Publisher : Faculty of Engineering, Universitas Swadaya Gunung Jati

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33603/jgst.v9i3.10651

Abstract

The growth and development of the population have significantly accelerated economic progress within society. Consequently, many new businesses have emerged, including commercial laundry services. One of the substances found in laundry wastewater, phosphate can cause eutrophication, which disrupts the balance of aquatic ecosystems. One method that can be developed to address this issue is adsorption technology. The aim of this research was to lower the phosphat content and to meet the Regulation of the Minister of Environment of the Republic of Indonesia No. 5 of 2014. The increasing number of coffee shops generates coffee grounds that have the potential to be processed into activated carbon. Additionally, fly ash a by-product of coal combustion contains silica and can be used as an adsorbent. The activated carbon is activated using 0.1 N NaOH and combined with fly ash in various compositions: 2:8, 4:6, 5:5, 6:4, and 8:2. Besides the variation in composition, contact time is also varied 30 minutes, 60 minutes, 90 minutes, 120 minutes, and 150 minutes. The observed parameters include pH and phosphate concentration at each contact time. The research results show that the optimal composition is 0.2AC:0.8FA with the highest phosphate removal efficiency of 60.3% at 150 minutes contact time and a pH of 7.1. However, the final phosphate concentration has not yet met the quality standard of 2 mg/L set by the Regulation of the Minister of Environment of the Republic of Indonesia No. 5 of 2014.
Co-Authors -, Alfiana Adhitasari Adi Rizki Nugraha Ageng Priyambudi Ahmad Fauzan Alamsari, Jasinta Putri Alatif, Ikhsan Akmal Alfiana Adhitasari Alisya Nurbaits Althafa Muntaqin Amellia, Yashinta Anindita, Faradila Anisa, Vira Rizki Annisa Nurlatifah Asyari, Restu Adji Alif Azzahra, Nasya Azzahra, Rafila Chika Bambang Soeswanto binti Jamaluddin, Jamarosliza C. Yudha Hidayatulloh Cecep Yudha Hidayatullah Christianti, Christianti Dianty Rosirda Dewi Kurnia Dieni Nurul Fathiyyah Fajriati, Ramadhana Suci Fatah, Khalaida Fania Fatimah Fauzan, Rizky Ferawati, Yohana Fransiska Fitriani, Desti Ghozali, Mukhtar Gunawan, Sinna Chaerunnabila Hariyadi, Tri Hidayatulloh, Irwan Ibrahim, Idham Kholid Indarti, Retno Jayanti, Retno Dwi Keryanti, Keryanti Khalisha, Keira Kharisma, Luthfiana Krista, Gustin Mustika Lingga Permana, Rezza Lutfiah Rahmasari Luviana, Angely Malik, Dava Maulana Marlina, Ari Martadinata, Nadya Zafirra Maryani, Anisya Sri Muhammad Fadly Wiryawan Kautsar, Muhari, Emma Hermawati Muhari, Emma Hermawati Muhari Mujahidah, Nisa Rahmah Mukhtar Gozali Nanda Liant Kumara Ngatin, Agustinus Nidaa’ Rihhadatul ‘Aisya Komara Nidaulhusna, Anisa Ninik Lintang Edi Wahyuni Nugraha, Teguh Aditya Nurbaits, Alisya Nurcahyo Nurcahyo, Nurcahyo Nurhasanah, Santy Nurulgina, Rahma Paramitha, Tifa Permanasari, Ayu Ratna Permatasari, Rahma Puspa Puspita, Nina Putri Utami Dita Cahya Putri, Angelina Rahmawati, Sri Puji Ramadan, Naufal Alip Cahya Ramadhan, Muhammad Zikri Ramadhani, Isma Afifah Ramadhani, Nabila Dwi Nur Renata, Calvin Aditya Restu Adji Alif Asyari Retno Indarti Reynaldi, Randi Rijal Muyasar Fahmi Risnandar, Tiara Devita Rispiandi Rispiandi Robby Sudarman Rusmana, Muchamad Raihan Surya Sajida, Gita Nur Salsabila Nisrina Junaedi Salsabila, Intan Salsabila, Iva Najwa Salsabila, Shafira Salsabilla, Iva Najwa Sari, Hermin Kartika Sari, Radianti Novita Silalahi, Rafael Leonardo Solehuddin Al-Ayubi Solehudin Al-Ayubi Sudrajat Harris Abdulloh Suminar, Dian Ratna Suryadi, Joko Tamba, Alfonsius Perdija Teguh Taufiqurohim Tika Paramitha Tri Hariyadi Unung Leoanggraini Wahyu Wibisono Wahyuni, Ninik Lintang Edi Widya Fitria Nur Fauziah Wina Maulida Yulistiani, Fitria Yunus Tonapa Sarungu Yusmardhany Yusuf Yusmardhany Yusuf Yusuf, Yusmardhany Zafarina, Alizza Asry