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Diferensiasi Sumber Pencemar Sungai Menggunakan Pendekatan Metode Indeks Pencemaran (IP) (Studi Kasus: Hulu DAS Citarum) Dyah Marganingrum; Dwina Roosmini; Pradono Pradono; Arwin Sabar
JURNAL RISET GEOLOGI DAN PERTAMBANGAN Vol 23, No 1 (2013)
Publisher : Indonesian Institute of Sciences

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1533.595 KB) | DOI: 10.14203/risetgeotam2013.v23.68

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ABSTRAK Hingga saat ini pencemaran air masih menjadi persoalan krusial di berbagai negara, khususnya di negara-negara berkembang termasuk Indonesia. Evaluasi tingkat pencemaran air secara berkala merupakan salah satu bentuk upaya dalam sistem pengelolaan sumberdaya air. Metode Indeks Pencemaran (IP) merupakan salah satu metode analisis kualitas air yang diaplikasikan di Indonesia. Metode ini merupakan perhitungan relatif antara hasil pengamatan terhadap baku mutu yang berlaku. Sebagai metode indeks komposit, IP terdiri atas indeks rata-rata dan indeks maksimum. Indeks maksimum dapat memberikan indikator unsur kontaminan utama penyebab penurunan kualitas air. Unsur utama dapat dihubungkan dengan sumber pencemar, apakah dari domestik maupun, non domestik (industri). Studi kasus dilakukan di hulu DAS Citarum (segmen Wangisagara-Nanjung) menggunakan data historikal tahun 2002 s.d. 2010. Hasil penelitian tersebut menunjukkan bahwa fecal coliform, sulfida, dan fenol merupakan tiga unsur utama penurunan kualitas Sungai Citarum. Fecal coliform adalah parameter tipikal dalam limbah domestik. Fenol adalah parameter tipikal dalam limbah industri. Sedangkan sulfida bisa berasal dari domestik maupun industri. Hasil penelitian menunjukkan telah terjadi diferensiasi polutan dari sumber domestik saja menjadi domestik dan non domestik setelah tahun 2005.
Biomarker as an Indicator of River Water Quality Degradation Dwina Roosmini; Indah Rachmatiah; Suharyanto Suharyanto; Agus Soedomo; Fajar Hadisantosa
Journal of Engineering and Technological Sciences Vol. 38 No. 2 (2006)
Publisher : Institute for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/itbj.eng.sci.2006.38.2.3

Abstract

Generally physical and chemical methods are use in river water quality monitoring; currently biomarker is developed as alternative biomonitoring method. The aim of this study is to look at the probability using aquatic species in monitoring river water pollutants exposure. This study was done by using Hyposarcus pardalis as biomarker to analyze river water quality in Upstream Citarum River. Hyposarcus pardalis were taken along the river at five sampling point and look at the Cu and Zn concentration. Results from this study show that there was an indication that river water quality has been degrading along the river from upstream to downstream. Zn concentration in Hyposarcus pardalis were increasing as well as Cu concentration. The increase of Zn concentration in Hyposarcus pardalis indicating that the river was polluted by Zn. Secondary data and observation at sampling location shown that textile was the dominant industry which may contribute the Zn concentration in river as they received the effluent. Cu is use in metal coating process, as well as textile industry metal industries were identified at Majalaya, Bantar Panjang, Dayeuh Kolot and Katapang in Bandung-Indonesia. As a receiving water from many activities along the river, upstream Citarum River water quality become degrading as the increasing of heavy metal Zn and Cu concentration in Hyposarcus pardalis.
Household Water Supply Strategies in Urban Bandung, Indonesia: Findings and Implications for Future Water Access Reporting Barti Setiani Muntalif; Anindrya Nastiti; Dwina Roosmini; Arief Sudradjat; Sander V. Meijerink; Antoine J.M. Smits
Journal of Engineering and Technological Sciences Vol. 49 No. 6 (2017)
Publisher : Institute for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2017.49.6.8

Abstract

Through structured interviews and statistical analyses, this study investigated access to water and strategies of 1227 vulnerable households in Bandung, Indonesia. The use of mixed water sources, household water treatment, and home storage suggest low trust in improved sources, and compromised safety and reliability of water. While official statistics suggest a high level of access to improved water sources, full-time access to such sources is overestimated. Integration of user behavior into the new monitoring approach for the water supply sector in the post-2015 development framework is proposed.
An Investigation of a Conventional Water Treatment Plant in Reducing Dissolved Organic Matter and Trihalomethane Formation Potential from a Tropical River Water Source Mohamad Rangga Sururi; Suprihanto Notodarmojo; Dwina Roosmini; Prama Setia Putra; Yusuf Eka Maulana; Mila Dirgawati
Journal of Engineering and Technological Sciences Vol. 52 No. 2 (2020)
Publisher : Institute for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2020.52.2.10

Abstract

The characteristics and composition of dissolved organic matter (DOM) and trihalomethane (THM) generation during water treatment are important for producing safe drinking water. However, little information is available on this topic within the context of Indonesia. This study aimed to investigate the efficiency of a conventional drinking water treatment plant (WTP) in removing DOM and chloroform forming potential (CHCl3FP), and evaluate surrogate parameters for CHCl3FP. Samples were taken during the rainy season and the dry season from raw water, after secondary treatment and after the rapid sand filter. DOM was characterized based on the A254, A355, SUVA, dissolved organic carbon (DOC), and fluorescence DOM (FDOM) parameters. The composition of the DOM was identified using the peak picking method. Overall, from raw to finished water, the WTP performed better in the rainy season with 55.96% reduction of DOC and 63.45% reduction of A355 as compared to the dry season with 53.27% reduction of DOC and 24.18% reduction of A355.The overall removal of humic and tryptophan compounds during the rainy season was 33.33% and 37.50%, respectively. In the dry season, humic compounds were reduced by 18.80%, while tryptophan increased threefold. A355 can serve as a surrogate parameter for CHCl3FP in raw water and water after secondary treatment, containing more humic-like compounds than tryptophan-like compounds.
Risk Assessment and Fractionation of Cadmium Contamination in Sediment of Saguling Lake in West Java Indonesia Dwina Roosmini; Eka Wardhani; Suprihanto Notodarmojo
Journal of Engineering and Technological Sciences Vol. 54 No. 2 (2022)
Publisher : Institute for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2022.54.2.3

Abstract

This research focused on the speciation and distribution patterns of cadmium in surface sediment from Saguling Lake, which is located in the Upper Citarum River. Organic compounds and heavy metals from anthropogenic activities in the watershed have contaminated the river. Sample from the upper layer of the sediment from Saguling Lake were taken from 12 locations, representing the dry and the rainy seasons in the period 2015-2018. Sediment cadmium (Cd) classification was conducted through a sequential extraction technique to determine Cd’s bioavailability and its risk to the water environment. During the rainy season, the total Cd concentration in the upper layer of the sediment was higher than during the dry season. The average dry and rainy season concentrations were 11.12 ± 2.16 mg/kg and 14.82 ± 1.48 mg/kgm in the sampling locations, distributed differently with the following order of the largest to the smallest concentration: 10B > 1A > 4 > 3 > 2 > 1B > 10A > 7 > 9 > 5 > 6 > 8 for the dry season, and 4 > 1A > 1B > 2 > 7 > 5 > 9 > 3 > 6 > 10A > 8 > 10B for the rainy season. All sampling locations (>60%) showed Cd in the resistant fraction, indicating no significant anthropogenic input of Cd into the surface sediment but more geological input due to high erosion. The values of RAC, ICF, and GFC indicate that the Cd in the surface sediment can be categorized as low risk.
Rainfall Variability and Landuse Conversion Impacts to Sensitivity of Citarum River Flow Dyah Marganingrum; Arwin Sabar; Dwina Roosmini; P Pradono
Forum Geografi Vol 27, No 1 (2013): July 2013
Publisher : Universitas Muhammadiyah Surakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23917/forgeo.v27i1.5074

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The objective of this study is to determine the sensitivity of Citarum river flow to climate change and land conversion. It will provide the flow information that required in the water resources sustainability. Saguling reservoir is one of the strategic reservoirs, which 75% water is coming from the inflow of Upper Citarum measured at Nanjung station. Climate variability was identified as rainfall variability. Sensitivity was calculated as the elasticity value of discharge using three-variate model of statistical approach. The landuse conversion was calculated used GIS at 1994 and 2004. The results showed that elasticity at the Nanjung station and Saguling station decreased from 1.59 and 1.02 to 0.68 and 0.62 respectively. The decreasing occurred in the before the dam was built period (1950-1980) to the after reservoirs operated period (1986-2008). This value indicates that: 1) Citarum river flow is more sensitive to rainfall variability that recorded at Nanjung station than Saguling station, 2) rainfall character is more difficult to predict. The landuse analysis shows that forest area decrease to ± 27% and built up area increased to ± 26%. Those implied a minimum rainfall reduction to± 8% and minimum flow to ± 46%. Those were caused by land conversion and describing that the vegetation have function to maintain the base flow for sustainable water resource infrastructure.
Studi Penurunan Kandungan Besi Organik dalam Air Tanah dengan Oksidasi H2O2-UV Rohmatun Rohmatun; Dwina Roosmini; Suprihanto Notodarmojo
Journal of Mathematical and Fundamental Sciences Vol. 39 No. 1-2 (2007)
Publisher : Institute for Research and Community Services (LPPM) ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Fe(II) terlarut dapat bergabung dengan zat organik dan membentuk senyawa kompleks yang sulit untuk dihilangkan dengan aerasi biasa. Salah satu teknologi alternatif untuk menghilangkan besi tersebut adalah dengan Advanced Oxidation Processes (AOPs) yang dapat menghasilkan radikal hidroksil (OH"¢). OH radikal yang terbentuk mempunyai potensial oksidasi yang tinggi sehingga diharapkan mampu mengoksidasi senyawa besi kompleks zat organik. Penelitian ini bertujuan untuk mengetahui efisiensi penurunan besi menggunakan H2O2-UV, kinetika reaksi yang terjadi, dan melihat pengaruh masing-masing faktor serta interaksi setiap faktor terhadap reaksi oksidasi besi melalui uji statistik. Penelitian ini dilakukan secara batch dengan variasi konsentrasi besi total awal: 3, 5, dan 10 mg/l; Fe:H2O2 = 1:5, 1:8, dan 1:10 (mol/mol); dengan perlakuan menggunakan UV 3x10 watt dan tanpa UV. Hasil penelitian menunjukkan bahwa kombinasi H2O2-UV 3x10 watt memberikan efisiensi penurunan besi yang paling baik pada dosis Fe:H2O2 = 1:5, yaitu 99% dan H2O2 menghasilkan efisiensi paling baik pada dosis Fe:H2O2 = 1: 8, yaitu 84%. Semakin besar konsentrasi besi total awal semakin kecil persen penurunan besi. Tetapi tidak selamanya penambahan dosis H2O2 akan meningkatkan efisiensi. Sedangkan sinar UV memberikan pengaruh yang lebih besar terhadap oksidasi besi apabila dikombinasikan dengan H2O2. Reaksi oksidasi besi ini menghasilkan orde pertama-semu untuk penurunan besi kompleks zat organik dan konstanta laju reaksi semakin besar apabila oksidasi menggunakan H2O2-UV 3 x10 watt. Proses oksidasi dengan H2O2-UV 3x10 watt ini akan menghasilkan persen penurunan Fe-R sebesar 67% setelah diujikan pada air sumur di daerah Bandung.
PENYISIHAN SENYAWA KLOROLIGNIN OLEH Phanerochaete chrysosporium DALAM BIOREAKTOR UNGGUN TERFLUIDISASI Dwina Roosmini; Wisjnuprapto Wisjnuprapto; Reski Dian Diniari; Junianti Roslinda
JURNAL SELULOSA Vol 42, No 02 (2007): BERITA SELULOSA
Publisher : Center for Pulp and Paper

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (227.55 KB) | DOI: 10.25269/jsel.v42i2.188

Abstract

Chlorolignin compound in pulp and paper wastewater are toxic and mutagenic. The pulp and paper wastewater consisting chlorolignin are harmful if discharged to the receiving water without treatment. Biological treatment is an alternative to treat the chlorolignin. White rot fungi Phanerochaete chrysosporium with extra cellular enzyme are able to degrade chlorolignin. This study is conducted by using fluidized bed reactor to treat chlorolignin by using immobilized Phanerochaete chrysosporium. This study are intended to find the ability of  Phanerochaete chrysosporium in degrading chlorolignin in the range of concentration (0.05g/L; 0.1g/L; 0.2g/L; 0.3 g/L and 0.4 g/L). The molecular distribution of chlorolignin before and after treatment is measured by using High Performance Liquid Chromatography. This study showed that Phanerochaete chrysosporium are able to depolymerization high molecular chlorolignin to low molecular. INTISARISenyawa klorolignin, yang terdapat pada air buangan industri pulp dan kertas, merupakan senyawa lignin yang terklorinasi. Senyawa ini bersifat toksik dan mutagenik dan akan sangat berbahaya bila langsung dibuang ke perairan tanpa mengalami pengolahan terlebih dahulu. Pengolahan secara biologis merupakan alternatif yang tepat untuk mengolah klorolignin. Jamur Phanerochaete chrysosporium diketahui memiliki enzim ekstraseluler yang mampu mendegradasi senyawa aromatik tersebut. Pada penelitian ini digunakan bioreaktor unggun terfluidisasi sebagai tempat terjadinya reaksi. Pada penelitian dilakukan variasi konsentrasi klorolignin 0,05 g/L; 0,1 g/L; 0,2 g/L; 0,3 g/L; dan 0,4 g/L. Konsentrasi glukosa yang dipakai ialah konsentrasi dimana efisiensi penyisihan optimum, yaitu penyisihan lignin 62,02% dan warna 75,05%. Perubahan distribusi berat molekul klorolignin sebelum dan sesudah pengolahan diperiksa dengan menggunakan metoda kromatografi cair kinerja tinggi. Hasil yang diperoleh menunjukkan bahwa jamur Phanerochaete chrysosporium mampu melakukan depolimerisasi senyawa klorolignin berat molekul tinggi menjadi senyawa-senyawa dengan berat molekul yang lebih rendah.
ANALISIS KANDUNGAN SENYAWA ORGANIK TERKLORINASI (AOX) PADA PERAIRAN DI SEKITAR INDUSTRI PULP DAN KERTAS Yasmidi .; Dwina Roosmini
JURNAL SELULOSA Vol 43, No 01 (2008): BERITA SELULOSA
Publisher : Center for Pulp and Paper

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (4415.416 KB) | DOI: 10.25269/jsel.v43i01.165

Abstract

In the period 1996 to 2006, Indonesian pulp and paper production increased rapidly from 5.5 million tones to 16.5 million tones. One of pollutant from a pulp and paper mills is chlorinated organic compounds (Adsorbable Organic Halide, AOX), that produced from using chlorine (Cl2) when the bleaching process. The AOX characteristics are toxic, bio-aumulative, carcinogen, and persistent. This research objectives are analysis the AOX concentration in aquatic around pulp and paper mills, and identification impact of pulp and paper mills existence on the AOX concentration. Selected location are A River and B River in Indonesia that receive effluents from 2 the big pulp and paper mills, PT. X and PT. Y. The results of AOX analyzing shown that AOX concentration of PT. X effluent are 2.330 ppm (0.0982 kg/ADT) in the morning (subside) and 3.200 ppm (0.1349 kg/ADT) in the afternoon (tide), while for PT. Y are 0.1511 ppm (0.0071 kg/ADT) in the morning (subside), and 0.5236 ppm (0.0245 kg/ADT) in the afternoon (tide). Both of mills are comply with Sweden AOX Standard (0.2 kg/ADT). In both of the rivers, decreasing of AOX concentration accordance with decreasing of pH value untul less than 5, DO value until 3 mg/L (B River) and 2 mg/L (A River). At 16 km distance from effluent, AOX value decreased until 95.58% (morning/subside) and 99.74% (afternoon/tide) in A River, and until 100% (morning/subside) and 98.01% (afternoon/subside) in B River. It still needed to develop this research to all of the pulp and paper mills effluent in Indonesia to get representatives data for AOX included identification of compounds in AOX from bleach effluent. Then we hope it useful for determining the national AOX standards.Keywords: AOX, bleaching, chlorine, effluent, pulp and paperINTISARISelama tahun 1996-2006 terjadi peningkatan pesat produksi pulp dan kertas di Indonesia dari 5,5 juta ton menjadi 16,5 juta ton. Salah satu polutan dari sebuah pabrik pulp dan kertas adalah senyawa organik terklorinasi (Adsorbable Organic Halide, AOX), yang dihasilkan sebagai konsekuensi penggunaan bahan kimia klorin (Cl2) dalam proses pemutihan pulp. AOX memiliki karakteristik beracun bioakumulatif, karsinogen, dan persisten. Penelitian ini bertujuan untuk melakukan analisis kandungan senyawa AOX pada perairan di sekitar industri pulp dan kertas, serta pengaruh keberadaan industri pulp dan kertas terhadap kandungan senyawa AOX  perairan. Lokasi yang dipilih adalah sungai A dan sungai B di Indonesia, yang menerima air limbah dari 2 pabrik pulp dan kertas besar yakni PT. X dan PT. Y. Hasil pengujian menunjukkan kandungan AOX dari air limbah PT. X sebesar 2,330 ppm (0,0982 kg/ADT) pada pagi hari (pasang) dan 3,200 ppm (0,1349 kg/ADT) pada sore hari (pasang), sedangkan untuk PT. Y adalah 0,1511 ppm (0,0071 kg/ADT) pada pagi hari (surut) dan 0,5236 ppm (0,0245 kg/ADT) pada sore hari (surut). Kedua industri telah memenuhi baku mutu AOX yang berlaku di Swedia (0,2 kg/ADT). Pada kedua sungai yang diamati, penurunan konsentrasi AOX seiring dengan penurunan pH sampai kurang  dari 5 serta nilai DO sampai 3 mg/L pada sungai B dan 2 mg/L pada sungai A. Hingga jarak 16 km aliran sungai dari air limbah, nilai AOX mengalami penurunan sampai dengan 98,58% (pagi/surut) dan 99,74% (sore/pasang) pada sungai A serta sampai dengan 100% (pagi/surut) dan 98,01% (sore/surut) pada sungai B. Diperlukan penelitian lebih lanjut pada air limbah setiap industri pulp dan kertas di Indonesia agar diperoleh data konsentrasi AOX yang lebih representatif termasuk identifikasi senyawa-senyawa yang terukur dalam AOX yang berasal dari air limbah proses pemutihan pulp, sehingga diharapkan dapat bermanfaat bagi penetapan baku mutu AOX secara nasionalKata kunci: AOX, proses pemutihan, klorin, air limbah, pulp dan kertas
PENYISIHAN SENYAWA KLOROLIGNIN oleh Phanerochaete Chrysosporium dengan PENAMBAHAN JERAMI SEBAGAI CO-SUBSTRAT Dwina Roosmini; Sri Harjati Suharti; Kevin Triadi; Junianti Roslinda
JURNAL SELULOSA Vol 42, No 01 (2007): BERITA SELULOSA
Publisher : Center for Pulp and Paper

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (184.835 KB) | DOI: 10.25269/jsel.v42i1.181

Abstract

White rot fungi Phanerochaete chrysosporium strain BKM-F-1767 are known to have extra cellular enzyme that able to degrade chlorolignin. Previous study showed that high delignification ability of the fungi is not supported by dehalogenase processes. This study is done by using rice straw as carbon source for chloroklorolignin degradation. The study is conducted in batch culture with straw concentration of 3.2 g/L and 0.3 g/L for chloroklorolignin.  The straws are varies in form of powder and chips. The enzymes activity are identified in liquid, solid and SDS-PAGE.  By using SDS-PAGE the enzymes identified are molecular weight 42 kD and 29 kD which is indicating the occurrence of Klorolignin peroxidase (LiP) and active endoglucanse in 11th day.  Positive result from solid media showed that Phanerochaete chrysosporium has an ability to degrade high molecular chloroklorolignin through enzymatic mechanism resulting from secondary metabolism reaction in generating H2O2.INTISARIJamur Phanerochaete chrysosporium strain BKM-F-1767 diketahui memiliki enzim ekstraseluler yang mampu untuk mendegradasi senyawa khloroklorolignin. Studi terdahulu  menunjukkan bahwa kemampuan delignifikasi yang tinggi oleh jamur ini tidak selalu didukung oleh proses dehalogenase. Selain itu, jamur sangat tergantung pada keberadaan glukosa sebagai co-substrat utama untuk pertumbuhan. Dengan penambahan jerami diharapkan konsentrasi glukosa dapat dikurangi karena keberadaan senyawa selulosa yang dapat dijadikan sumber karbon bagi jamur. Pada penelitian ini digunakan sistem kultur batch  dengan variabel tetap yaitu jumlah jerami sebesar 3,2 g/L dan substrat yang digunakan yaitu klorolignin dengan konsentrasi 0,3 g/L. Variabel bebas yang digunakan adalah konsentrasi co-substrat glukosa dan tipe perlakuan jerami yang berbeda yaitu potongan (chips) dan serbuk. Aktivitas-aktivitas enzim ekstraseluler diuji melalui media padat, cair, dan SDS- PAGE.  Percobaan dengan SDS-PAGE diperoleh enzim dengan berat molekul 42 kD dan 29 kD yang mengindikasikan adanya enzim LiP dan endoglucanase yang masih aktif hingga akhir hari ke-11. Hasil positif  yang diperoleh pada media padat menunjukkan bahwa jamur Phanerochaete chrysosporium memiliki kemampuan untuk mendegradasi senyawa klorolignin berat molekul tinggi melalui mekanisme sistem enzimatik yang dihasilkan oleh reaksi metabolisme sekunder dalam sistem generasi H2O2.