Garuda - Garba Rujukan Digital

p-Index From 2020 - 2025

2.837

P-Index

This Author published in this journals

All Journal VALENSI JURNAL KIMIA SAINS DAN APLIKASI Jurnal Natur Indonesia Jurnal Sains Materi Indonesia Bulletin of Chemical Reaction Engineering & Catalysis The Journal of Pure and Applied Chemistry Research Jurnal Farmasi Andalas Jurnal Riset Kimia Jurnal Kimia dan Kemasan Elkawnie Jurnal Litbang Industri Lantanida Journal Indonesian Journal of Chemistry Jurnal Ecolab Molekul: Jurnal Ilmiah Kimia Warta Pengabdian Andalas: Jurnal Ilmiah Pengembangan Dan Penerapan Ipteks Hydrogen: Jurnal Kependidikan Kimia REACTOR : Journal of Research On Chemistry And Engineering Jurnal Kimia dan Kemasan Jurnal Litbang Industri Bulletin of Chemical Reaction Engineering & Catalysis al Kimiya : Jurnal Ilmu Kimia dan Terapan

Safni Safni

Department Of Chemistry, Faculty Of Mathematics And Natural Sciences, Andalas University, Kampus Unand Limau Manis Padang, 25163

Author-ID : 368143

Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Computer Science & IT Education Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Medicine & Pharmacology Social Sciences Other

Published : 74 Documents Claim Missing Document

Claim Missing Document

Articles

4 5 6 7 8

Degradasi Zat Warna Direct Red-23 dan Direct Violet Dengan Metode Ozonolisis, Fotolisis Dengan Sinar Uv dan Cahaya Matahari Menggunakan Katalis N-Doped TiO2 Safni Safni; Deby Anggraini; Diana Vanda Wellia; Khoiriah Khoiriah
Jurnal Litbang Industri Vol 5, No 2 (2015)
Publisher : Institution for Industrial Research and Standardization of Industry - Padang

Direct red-23 and Direct violet are non-biodegradable compounds containing azo component and carcinogenic. Direct red-23 and Direct violet had been degraded by ozonolysis, photolysis with UV lamp and solar irradiation methods using N-doped TiO2 catalyst. UV/Vis Spectrophotometer at wavelength 300-800 nm was used to measure the absorption of sample solution. The optimum weight of N-doped TiO2 catalyst was 20 mg. From the three methods obtained that ozonolysis method was the faster degradation process than photolysis with UV and solar irradiation. Direct red-23 and Direct violet was degraded as much as 55 and 50% within 20 minutes by ozonolysis.ABSTRAKZat warna Direct red-23 dan Direct violet merupakan senyawa non-biodegradable yang mengandung senyawa azo dan bersifat karsinogen. Direct red-23 dan Direct violet didegradasi menggunakan metode ozonolisis, fotolisis dengan sinar UV dan dengan penyinaran matahari, tanpa dan dengan katalis N-doped TiO2. Hasil penelitian diukur dengan spektrofotometer UV-Vis pada panjang gelombang 300-800 nm. Berat optimum katalis N-doped TiO2 didapatkan 20 mg. Dari ketiga metode didapatkan bahwa proses degradasi pada metode ozonolisis paling cepat dibandingkan dengan fotolisis sinar UV dan cahaya matahari. Direct red-23 dan Direct violet dapat didegradasi sebanyak 55 dan 50% dalam waktu 20 menit.

Perlakuan ozon dan sonokimia untuk degradasi residu mankozeb pada cabe hijau (Capsicum annuum L.) Safni Safni; Elma Fadrita Rahman; Deswati Deswati; Salmariza Sy
Jurnal Litbang Industri Vol 11, No 2 (2021)
Publisher : Institution for Industrial Research and Standardization of Industry - Padang

Fungisida, seperti mankozeb, banyak digunakan dalam bidang pertanian berkelanjutan dan akan meninggalkan residu pada bahan pangan. Proses oksidasi lanjutan (AOPs) ozon treatment (ozonolisis dan air ozon), sonokimia (sonolisis) serta kombinasi keduanya (sonozolisis) merupakan salah satu teknik potensial dalam mendegradasi residu mankozeb pada cabe hijau. Perbandingan metode degradasi dilakukan pada kondisi yang sama yakni 50 g cabe hijau, 100 mL air dengan waktu treatment 10 menit mampu mendegradasi residu mankozeb sebesar 69,63±1,60 air ozon; 58,83±2,57 sonozolisis; 56,51±2,29 ozonolisis; dan 23,70±1,60 sonolisis. Penambahan waktu perendaman selama 20 menit air ozon meningkatkan persentase degradasi sebesar 83,80±2,54. Beberapa parameter yang mempengaruhi proses degradasi dipelajari seperti waktu treatment, volume air, dan massa cabe hijau. Proses degradasi dengan waktu treatment 10-15 menit, volume air 100 mL dan 50 g cabe hijau mampu mereduksi residu mankozeb sebesar 25-58%. Data hasil analisis spektrofotometer-HPLC menunjukkan bahwa residu mankozeb pada cabe hijau telah berhasil didegradasi.

Determination of Benzoic Acid, Sodium Saccharin, And Caffeine By High Performance Liquid Chromatography Arief Yandra Putra; Fitri Mairizki; Hamzar Suryani; Safni Safni
Jurnal Litbang Industri Vol 2, No 2 (2012)
Publisher : Institution for Industrial Research and Standardization of Industry - Padang

Concentrations of benzoic acid, sodium saccharin and caffeine in soft drink samples were determined by using Reverse Phase High Performance Liquid Chromatography (HPLC). The optimum analytical conditions of those three samples was methanol-phosphate buffer (1:7) as mobile phases, with pH 4.5 and flow rate 1.0 mL/min, column C18 (150x4.6 mm i.d.) as stationary phases at 400C with UV-Vis Spectrophotometer detection at 220 nm. The concentration level of those compounds observed was not beyond the maximum limit of SNI 01-011101995 for sodium saccharin and benzoic acid and SNI 01-6684-2002 for caffeine. The relative standard deviation based on retention time and peak area, as 0.37% and 0.59% for benzoic acid, 0.16% and 0.21% for sodium saccharin, 0.38% and 0.6% for caffeine. Finally, the recovery for benzoic acid, sodium saccharin and caffeine was 100.82%, 94.92% and 90.32%, respectively. The relative standard deviation and recovery of all samples met AOAC method requirements.ABSTRAKPenelitian tentang penentuan asam benzoat, natrium sakarin dan kafein telah dilakukansecara Kromatografi Cair Kinerja Tinggi (KCKT) Fasa Balik. Kondisi optimum analisis dariketiga senyawa di atas adalah fasa gerak metanol-bufer fosfat (1:7) dengan pH 4,5, laju alir 1 mL/min, kolom C18 (150 x 4,6 mm i.d.) dengan temperatur 40oC dan pendeteksiandengan Spektrofotometer UV/Vis pada panjang gelombang 220 nm. Metoda ini diaplikasikan pada beberapa sampel minuman ringan. Kadar ketiga senyawa ini di dalam sampel tidak melebihi batas maksimum yang diizinkan yaitu berdasarkan SNI 01-0222-1995 untuk natrium sakarin dan asam benzoat serta SNI 01-6684-2002 untuk kafein. Standar Deviasi Relatif ketiga senyawa ini berdasarkan waktu retensi dan luas puncak secara berturut-turut adalah; asam benzoat 0,37% dan 0,59%, natrium sakarin 0,16% dan 0,21%, kafein 0,38% dan 0,60%. Hasil perolehan kembali dari ketiga senyawa ini adalah asam benzoat 100,82%, natrium sakarin 94,92%, kafein 90,32%. Standar Deviasi Relatif dan perolehan kembali ketiga senyawa ini memenuhi persyaratan metoda AOAC.

Adsorpsi Cu2+ Menggunakan Nanofiber Polisulfon-FeOOH Yang Disintesis Dengan Metode Elektrospinning Dini Hariyati Adam; Hamzar Suyani; Muhamad Nasir; Safni Safni; Willy Cahya Nugraha
Jurnal Litbang Industri Vol 3, No 2 (2013)
Publisher : Institution for Industrial Research and Standardization of Industry - Padang

It had been done a research about adsorption of Cu2+ using polysulfone-FeOOH nanofiber prepared by elektrospinning method. Polysulfone-FeOOH nanofiber was synthesized by dissolving polysulfone pellets in 30 mL dimethylacetamide (DMAc). The effects of process conditions such as concentration, distance between the nozzle and collector, voltage and flow rate on the morphology and diameter of nanofibers were investigated. The optimum conditions of polysulfone nanofiber synthesizing was obtained with concentration 25%, distance 12 cm, voltage 25 kV, and flow rate 0.05 mL/min with average diameters of fibers was 762.927 nm. Polysulfone nanofiber was coated with FeOOH to increase the adsorbtion capacity of Cu2+. The results showed that optimum condition for removal of Cu2+ used polysulfone-FeOOH nanofiber was obtained in 2 hours contact time, pH 6, adsorbent dosage 25 mg, and concentration of Cu2+ 10 mg/L with adsorbstion capacity was 9.79 mg/g, while for polysulfone nanofiber the adsorption capacity was 8.34 mg/g. The adsorbtion pattern of Cu2+ by the both of adsorbent followed the Freundlich isotherm pattern.ABSTRAK Penelitian mengenai pemisahan ion Cu2+menggunakan nanofiber polisulfon-FeOOH yang disintesis dengan metode elektrospinning telah dilakukan. Nanofiber polisulfon P-3500 disintesis dengan cara melarutkan pelet polisulfon ke dalam 30 mL dimethylacetamide (DMAc). Pengaruh kondisi seperti konsentrasi, jarak nozzle dengan kolektor, tegangan dan laju alir terhadap morfologi dan diameter serat dipelajari. Kondisi optimum pembuatan nanofiber polisulfon diperoleh dengan konsentrasi 23 %, jarak 12 cm, tegangan 25 kV, dan laju alir 0,05 mL/min dengan ukuran diameter serat rata-rata 762,927 nm. Nanofiber yang terbentuk dilapisi dengan FeOOH untuk meningkatkan kapasitas penyerapannya terhadap ion Cu2+. Dari hasil penelitian didapatkan kondisi optimum untuk pemisahan ion Cu2+ menggunakan nanofiber polisulfon-FeOOH yaitu waktu kontak 2 jam, pH 6, bobot adsorben 25 mg, dan konsentrasi Cu2+10 mg/L dengan kapasitas penyerapan 9,79 mg/g, sedangkan untuk nanofiber polisulfon kapasitas penyerapan 8,34 mg/g. Pola penyerapan Cu2+ untuk kedua jenis adsorben lebih sesuai dengan pola isoterm Freundlich

Degradasi senyawa fenol secara fotokatalisis dengan menggunakan katalis C-doped TiO2 S Safni; Vepilia Wulanda; K Khoiriah; Diana Vanda Wellia
Jurnal Litbang Industri Vol 9, No 1 (2019)
Publisher : Institution for Industrial Research and Standardization of Industry - Padang

Fenol merupakan senyawa kimia yang banyak digunakan dalam proses industri. Akan tetapi fenol dalam konsentrasi berlebihan dapat menimbulkan efek buruk terhadap kehidupan manusia dan lingkungan pada umumnya. Pada penelitian ini, fenol didegradasi secara fotolisis tanpa dan dengan menggunakan katalis TiO2/C di bawah sinar UV (10 Watt, λ= 365 nm) dan sinar tampak (lampu philips LED 13 watt 1400 lux, λ= 465-640 nm). Larutan fenol yang telah didegradasi diukur dengan Spektrofotometer UV-Vis pada panjang gelombang 200-400 nm. Hasil karakterisasi XRD dan DRS UV-Vis memperlihatkan bahwa katalis modifikasi titania menggunakan unsur karbon berpotensi aktif pada sinar tampak. Aplikasi katalis TiO2/C mampu meningkatkan efisiensi dari degradasi fenol pada sistem fotolisis. Larutan fenol 8 mg/L terdegradasi sebanyak 38,98% dan 35,59% tanpa katalis dan meningkat menjadi 51,69% dan 66,10% dengan penambahan 5 mg katalis TiO2/C masing-masing di bawah sinar UV dan sinar tampak.ABSTRACTPhenol is a chemical compound that is widely used in industrial processes. However, phenol in excessive concentration can endanger human life and the environment. In this study, phenol was degraded without and using TiO2/C catalyst under UV-light (10 Watts, λ = 365 nm) and visible-light (13 watt Philips, lux= 1400, λ = 465-640 nm) photolysis. The degraded of phenol solution was measured by a UV-Vis spectrophotometer at a wavelength 200-400 nm. The results of XRD and DRS UV-Vis characterization show that the modified of titania catalyst using carbon potentially actives in visible-light. Application of TiO2/C catalyst can improve the efficiency of phenol degradation in photolysis system. Phenol solution with concentration 8 mg/L was degraded by 38.98% and 35.59% without catalyst and increased to be 51.69% and 66.10% in presence of 5 mg TiO2/C catalyst under UV-light and visible-light, respectively.

Degradation of Paraquat in Gramoxone Pesticide with Addition of ZnO Febrina Arfi; Safni Safni; Zaimi Abdullah
Molekul Vol 12, No 2 (2017)
Publisher : Universitas Jenderal Soedirman

Paraquat is the most toxic herbicide, the main agricultural crops and plantations that use them are cloves, cocoa, oil palm, rubber, coffee, and pepper. Therefore, it is necessary to study to degrade paraquat compounds by photolysis method with using ZnO. Photolysis is a process of UV irradiation with a wavelength of 200-400 nm. In this study Photolysis method used UV light with λ = 365 nm. Degradation of paraquat compound was done with the influence of variation of time without the addition ZnO, the influence of ZnO additional variations, and the effect of combination between variations of time and optimization of ZnO addition. The result of the study shows that photolysis degradation product without the addition of ZnO for 120 minutes has been degraded by 12.56%. While the optimum addition of 0.1 grams ZnO increased the percentage of degradation which is about 57.64%. This is proved that the addition of ZnO with photolysis method can degrade more paraquat compounds.

Degradation of Imidacloprid Residues on Unripe Tomatoes (Solanum lycopersicum) by AOPs and Its Analysis using Spectrophotometer and HPLC Trisna Olinovela; Hazanita Jumiaty; Safni Safni; Syukri Syukri
Jurnal Kimia Sains dan Aplikasi Vol 24, No 7 (2021): Volume 24 Issue 7 Year 2021
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Imidacloprid is an insecticide-active ingredient used by farmers to kill and control insects. Imidacloprid residue can be found in unripe tomatoes. Consuming unripe tomatoes contaminated with imidacloprid can cause human health problems such as cancer, chronic kidney disease, neurological disorders, and reproductive issues. In this study, imidacloprid pesticide residues on unripe tomatoes were degraded by the Advanced Oxidation Processes (AOPs) method, namely ozonolysis, sonolysis, and sonozolysis at various processing times (5, 10, 15, 20, and 25 minutes) in 50 g sample mass and 100 mL water volume. The changes in imidacloprid concentration before and after degradation were measured using a UV-Vis spectrophotometer and HPLC. The results of imidacloprid residue degradation by sonolysis was 66.99%, ozonolysis was 74.87%, and sonozolysis was 66.00%. The degradation kinetics of the imidacloprid residue was then studied. Kinetic study of all AOPs methods found that imidacloprid degradation followed a first-order kinetic model. The kinetics data showed that ozonolysis degradation is faster than sonolysis and sonozolysis, with a half-life (t1/2) of 16.90 minutes.

Pelatihan Praktikum Kimia Sederhana di SMAN 16 Padang Imelda Imelda; Refinel Refinel; Refilda Refilda; Yefrida Yefrida; Hermansyah Aziz; Yulizar Yusuf; Suryati Suryati; Zulkarnain Chaidir; Sumaryati Syukur; Rahmiana Zein; Novesar Jamarun; Safni Safni; Zilfa Zilfa; Yetria Rilda; Norman Ferdinal; Tommi Hermansyah; Fivi Mona Bareno
Warta Pengabdian Andalas Vol 30 No 3 (2023)
Publisher : Lembaga Penelitian dan Pengabdian kepada Masyarakat (LPPM) Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jwa.30.3.562-568.2023

Chemistry is one of the subjects taught in State Senior High Schools (SMAN), especially in Natural Sciences (IPA). The problem with chemistry subjects is that it is difficult to practice in the laboratory because laboratory facilities such as space, equipment and chemicals are expensive. As a result, chemical laboratory practices were only sometimes carried out. Several lecturers and students from the Department of Chemistry, FMIPA Unand Kimia Unand, carried out service activities at SMAN 16 Padang through laboratory practice using materials and equipment that were cheap and readily available in the surrounding environment. This community service aims to train teachers and students to carry out chemistry practicums using simple materials and equipment available around them. The training was given to chemistry subject teachers and students in the science laboratory at SMAN 16 on 17 and 21 November 2022. The material was practised in oxidation and reduction (redox) and electrolysis reactions. The activity went smoothly; the students enthusiastically carried out the practicum. Through the results of this simple chemistry practicum, students can design and carry out chemical experiments using simple tools and materials, conduct direct observations of chemical processes, practice scientific thinking, attitude and work skills and analyze and solve various scientific processes using scientific methods. SMAN 16 hopes that this activity will continue with different topics.

Synthesis of Porous N-doped TiO2 by Using Peroxo Sol-Gel Method for Photocatalytic Reduction of Cd(II) Diana Vanda Wellia; Dina Nofebriani; Nurul Pratiwi; Safni Safni
Bulletin of Chemical Reaction Engineering & Catalysis 2022: BCREC Volume 17 Issue 1 Year 2022 (March 2022)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.17.1.12347.103-112

Porous N-doped TiO2 photocatalyst was successfully synthesized by an environmentally friendly peroxo sol-gel method using polyethylene glycol (PEG) as a templating agent. Here, the effect of PEG addition to the aqueous peroxotitanium solutions on the structure, pore properties and photocatalytic activity of the obtained photocatalysts was systematically studied. The prepared photocatalysts were characterized by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), and Brunauer-Emmett-Teller (BET). It was found that the doping of nitrogen narrows the band gap of TiO2 leading to enhance its visible-light response. The BET analysis shows that the prepared photocatalysts have a typical mesoporous structure with pore sizes of 3–6 nm. The photocatalytic activity of the prepared photocatalysts was evaluated by photocatalytic reduction of Cd(II) in an aqueous solution under visible light irradiation. The results show that porous N-doped TiO2 with the optimal PEG addition had the highest Cd(II) reduction of 85.1% after 2.5 h irradiation in neutral aqueous solution. This significant improvement in photocatalytic activity of the prepared photocatalysts was mainly attributed to the synergistic combination of N doping and porous structure, which could actively increase the catalytic active site of this photocatalysts. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Degradation of Phenol Using Sonolysis and Photolysis by TiO2/RHAC Catalyst and Analysis with Spectrophotometer UV-VIS and HPLC Safni - Safni; Eno Okta Patricia; Trisna Ollinovela; Yulizar Yusuf
al Kimiya: Jurnal Ilmu Kimia dan Terapan Vol 10, No 1 (2023): al Kimiya: Jurnal Ilmu Kimia dan Terapan
Publisher : Department of Chemistry, Faculty of Science and Technology, UIN Sunan Gunung Djati Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15575/ak.v10i1.24775

This study focuses on the degradation of phenol in aqueous solutions using photolysis and sonolysis methods. It investigates the impact of catalyst mass, types of light (UV-A, UV-C, and visible light), types of catalyst (RHAC, TiO2, and TiO2/RHAC), and processing time on phenol degradation. The phenol solutions are analyzed before and after degradation using Spectrophotometer UV-Vis and HPLC. The research aims to understand the factors influencing phenol degradation and provide a basis for further studies to enhance the efficiency of phenol removal. Results show significant improvements in degradation percentages of phenol by using TiO2/RHAC as the catalyst. Sonolysis achieves a degradation of 20.82% with a catalyst, which increases to 50.57% with the catalyst. Photolysis achieves a degradation of 29.06%, which rises to 91.99% with the catalyst. The highest degradation percentage is achieved using UV-A light for 5 hours with a catalyst mass of 30 mg of TiO2/RHAC catalyst. HPLC analysis confirms a decreased phenol concentration and the presence of intermediate compounds. The TiO2/RHAC catalyst demonstrates the promising potential for efficient phenol degradation in aqueous solutions.

Co-Authors -, Maizatisna -, Roswita -, Zulfarman Abinul Hakim Adlis Santoni Admi Admi Aldini, Tasya Amelia, Fitrah Anggraini, Deby Anna Fadhilla Arief Yandra Putra Bhayu Gita Bhernama BUSTANUL ARIFIN Chris Deviarny Deby Anggraini Deliza - Deliza, Deliza Desmiati - Deswati Deswati Dheasy Gustira Dina Nofebriani Dini Hariyati Adam Dytta Fitria Elma Fadrita Rahman Emriadi - Eno Okta Patricia Era, Yuni Fadhilla, Anna Fardila Sari Febi Rahmi Febrina Arfi Fitra Febrianti Fitrah Amelia Fitrah Amelia fitri mairizki Fitri Mairizki, Fitri Fivi Mona Bareno Gustiana, Mega Hakim, Abinul Hamzar Suryani Hamzar Suyani Harza Dipajana Umardi Hazanita Jumiaty Hazanita Jumiaty Henny Lucida Hermansyah Aziz Hermansyah Aziz Hilfi Pardi Ibnu Irawan Imelda Imelda Jarnuzi Gunlazuardi Jihanul Khaira K Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah Khoiriah, Khoiriah Liansari, Oktanora Mai Efdi Mai Efdi Maizatisna - Maizatisna Maizatisna Marniati Salim Matlal Fajri Alif Mechy Rezita Wahyuni Mega Gustiana Muhamad Nasir Muhamad Nasir, Muhamad Neila Yenni Norman Ferdinal Novesar Jamarun Novesar Jamarun Nurul Pratiwi Oktanora Liansari Olly Norita Tetra Putri Arwanda Putri Perdana Roza Putri, Reza Audina Rahmi, Febi Rahmiana Zein Refilda Refilda Refinel - Reza Audina Putri Reza Audina Putri Roswita - Roza, Putri Perdana Sakai, T. Sakai, Tadao Salmariza Sy Sumaryati Syukur Suryati Suryati Syukri - Syukri Arief Syukri Syukri Syukri Syukri Syukri Syukri T. Sakai Tadao Sakai Tommi Hermansyah Trisna Olinovela Trisna Ollinovela Umiati Loekman Umiati Loekman Umiati Loekman Upita Septiani Vanny Yulia Safitri Vepilia Wulanda Wellia, Diana Vanda Willy Cahya Nugraha Willy Cahya Nugraha, Willy Cahya Yefrida - Yefrida Yefrida Yetria Rilda Yuli Okta Fitriyani Yulizar Yusuf Yulizar Yusuf Yuni Era Zaimi Abdullah Zaimi Abdullah Zilfa Zilfa Zulfarman - Zulfarman Zulfarman Zulkarnain Chaidir

Title

Found 74 Documents
Search

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Title Search

Found 74 Documents Search

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Abstract

Title

Found 74 Documents
Search