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All Journal ASEAN Journal of Systems Engineering Jurnal Rekayasa Proses Jurnal Bahan Alam Terbarukan Seminar Nasional Teknik Kimia Kejuangan Journal of Degraded and Mining Lands Management Jurnal Sains & Teknologi Lingkungan Konversi Journal of the Civil Engineering Forum Communications in Science and Technology Jurnal Chemurgy Jurnal Rekayasa Proses Media Ilmiah Teknik Lingkungan INSIST (International Series on Interdisciplinary Research) Jurnal Inovasi Teknik Kimia Prosiding Conference on Research and Community Services Prosiding Simposium Nasional Rekayasa Aplikasi Perancangan dan Industri Hexagon
Ahmad Tawfiequrrahman Yuliansyah
Departemen Teknik Kimia, Fakultas Teknik, Universitas Gadjah Mada
Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Civil Engineering, Building, Construction & Architecture Computer Science & IT Control & Systems Engineering Economics, Econometrics & Finance Education Electrical & Electronics Engineering Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Mathematics Mechanical Engineering Social Sciences Other

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Journal : Communications in Science and Technology

 1 
Adsorption studies of KOH-modified hydrochar derived from sugarcane bagasse for dye removal: Kinetic, isotherm, and thermodynamic study Lestari, Dwi Indah; Yuliansyah, Ahmad Tawfiequrrahman; Budiman, Arief
Communications in Science and Technology Vol 7 No 1 (2022)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.7.1.2022.669

Abstract

Toxicity of methylene blue (MB) in water bodies has a negative effect on environment and living organisms. The presence of MB in water could last longer in view of the non-biodegradable characteristic. In this study, hydrochar was used as adsorbent to remove MB from aqueous solution. Hydrochar derived from bagasse was successfully prepared by hydrothermal carbonization treatment at temperature of 270oC, and pressure of 10 Bar for 30 minutes. For enhancing the adsorption ability, hydrochar was activated by adding KOH that was able to increase the percent removal by ~11%. The hydrochar was characterized using FTIR before and after adsorption. The results showed that the dominant functional groups of hydrochar included O-H, C=O, -O- and aromatic compounds. Whereas, the functional group of azo groups such as N-H and N=N appeared after adsorption. The maximum adsorption capacity (Qmax) was 5.1204 mg/g, while the adsorption isotherm of MB onto hydrochar followed the Langmuir and Freundlich model. The adsorption mechanism belongs to chemical adsorption, and the rate of diffusion can be neglected because the adsorption kinetics fitted well with pseudo-second order and the value of k2 > kdif > k1. Thermodynamic studies indicated that the adsorption process is classified as endothermic and reversible at room temperature. The results showed that hydrochar could be the alternative adsorbent for removing MB in wastewater. In addition, sugarcane bagasse has a great potential as feedstock of hydrochar.
Co-Authors Achmad Diansyukma Agus Prasetya Ahmad Hanafi Arief Budiman Asep P Zainuddin Aziz Askaputra Bagus Putro Budi Utomo Bratakusuma, Danu Britania Dewi Clarasinta Budi Kamulyan C. Chika Oktalia Putri Cahyono, Rochim Bakti Claudino de Almeida Cabral D Bratakusuma Danu Bratakusuma Dedi Eko Yunanto Dewi Purnama Sari Dewi Purnama Sari Dwi Saputri Dwi Saputri Edia Rahayuningsih Erlina Kurnianingtyas Fajar Marendra Fajar Marendra Fami Amalia Putri Fika Rofiek Mufakir Fika Rofieq Mufakhir Fitriani Fitriani Haidar Ali Handayani, Destias Selly Harimurti Wicaksono Hary Sulistyo Hasanah, Nur Hayati Himawan Tri Bayu Murti Petrus Imam Karfendi Putro Indra P Hakim Kidung Wulan Utami Lestari, Dwi Indah Lisendra Marbelia Mahfudl Sidiq Muhayyat Marendra, Fajar Mufakhir, Fika Rofieq Muhamad Johar Ardany Muhammad A. A. Ramadhan, Muhammad Muhammad Irsan B Muhammad Kurniawan Adiputra mulhidin, mulhidin Pasca Giffari Jusuf Rahmah, Puspa Reno Imam Arthapersada Riski Amalia, Riski Rizka Lestari Rizki Laksono, Rizki RR. Ella Evrita Hestiandari Rukmana Saputri, Dwi Sarto Sarto Septina AVIA Avia Shinta Virdhian shinta virdhian, shinta Sri Puji Saraswati Suprianto Suprianto Suryo Purwono Sutijan Wahyu Wilopo Widi Astuti Widi Astuti Widi Astuti Y Iskandar Yuni Rosita Yusuf Iskandar Zakiah Awalia J S Dahlan