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All Journal Indonesian Journal of Chemistry Widya Teknik
Putro, Jindrayani Nyoo
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Chemical Engineering, Chemistry & Bioengineering Chemistry

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Pseudoternary Phase Diagram and Antibacterial Activity of Microemulsion-Based Citronella Oil Gunarto, Chintya; Go, Alchris Woo; Angkawijaya, Artik Elisa; Lie, Jenni; Soetaredjo, Felycia Edi; Ismadji, Suryadi; Puspitasari, Nathania; Putro, Jindrayani Nyoo; Risdian, Chandra
Indonesian Journal of Chemistry Vol 24, No 3 (2024)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.93250

Abstract

Citronella oil (CTO) is extracted from citronella leaves by maceration or steam distillation process, which has antibacterial and insect-repellent activities. However, the use of CTO is limited and requires modification in other formulations, such as microemulsion (ME), to increase its bioactivities. ME consists of oil, water, surfactant and/or cosurfactant and is commonly applied in food and beverages, cosmetics, and carrier for drug delivery applications. CTO was used as the oil phase for ME with nonionic surfactant and ethanol as a cosurfactant for lowering interfacial tension between oil and water phase. Subsequent observations regarding stability and antibacterial tests were carried out on ME formulations with surfactant/cosurfactant mixture of 2 due to its largest ME area. A hydrodynamic diameter analysis was also carried out to see the stability of the ME within a period of 50 d. ME with 10% CTO, 30% surfactant mixture, and 60% water showed the best formulation observed from the consistent hydrodynamic diameter measurement. In addition, ME with different formulations could inhibit the growth of Escherichia coli and Staphylococcus aureus by more than 90%. From this research, CTO-based ME potentially improve and develop drug carrier applications, especially via topical route.
Optimum and Green Fabrication of MIL-100(Fe) for Crystal Violet Dye Removal from Aqueous Solution Wijaya, Christian Julius; Soetaredjo, Felycia Edi; Yuliana, Maria; Santoso, Shella Permatasari; Hartono, Sandy Budi; Irawaty, Wenny; Lie, Jenni; Putro, Jindrayani Nyoo; Gunarto, Chintya; Puspitasari, Nathania; Ismadji, Suryadi; Gunawan, Setiyo
Indonesian Journal of Chemistry Vol 24, No 5 (2024)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.93323

Abstract

MIL-100(Fe) was prepared and subsequently used to remove crystal violet dye from aqueous solutions simulating dye-containing wastewater in the environment. In the future, it is aimed that MIL-100(Fe) can be used in managing dye-containing wastewater in the environment and reducing the negative impacts it can cause. Here, MIL-100(Fe) fabrication needs to be optimized to obtain optimum process conditions, which are environmentally friendly and can produce MIL-100(Fe) with the best characteristics. This study focused on optimizing the fabrication of MIL-100(Fe), which is a type of MOF with good chemical stability, thermal stability, and flexible structure. In this study, the room-temperature fabrication of MIL-100(Fe) was established using a ligand-to-metal molar ratio of 0.95 and an acetic acid concentration of 5.1 vol% for 6.2 h. The optimum MIL-100(Fe) was tested for crystal violet removal and provided an optimum removal capacity of 182.66 ± 3.81 mg/g. Statistical approaches are used to investigate the independent parameters and their interactions contributing to MIL-100(Fe) formation.
The Effect of Hydrothermal Treatment on the Biological Properties of Anting-Anting (Acalypha indica Linn.) Plant Extract Containing Carbon Dots Setiawaty, Natasya Nadia Poetri; Putro, Jindrayani Nyoo; Santoso, Shella Permatasari
Widya Teknik Vol. 22 No. 1 (2023): May
Publisher : Fakultas Teknik, Universitas Katolik Widya Mandala Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33508/wt.v22i1.4854

Abstract

Anting-anting plant (Acalypha indica Linn.) is shrubs that grow as a weed in most parts of tropical countries. The plant has a record of ethno-pharmacological uses by native Asians, the plant has especially been used widely in the therapeutically practice in India. Owing to its rich biological active compounds content, Acalypha indica is rendered as a wild-plants with excellent antioxidant activities. In this work, hydrothermal extraction was performed to obtained liquid products containing high biological active compounds and carbon dots from Acalypha indica plant powder. The effect of hydrothermal temperature of 100, 110, 120, 130, and 140°C was evaluated on the optical properties and biological activity of the resultant liquid products from A. indica. The results imply that the liquid products obtained at highest investigated hydrothermal temperature of 140°C  had the highest total phenolic and total flavonoid content, specifically the calculated total phenolic content is 5.50 mg GAE/g and total flavonoid content is 0.53 mg QE/g; that is higher than the non-hydrothermally treated extract. Owing to the high biological active compounds, the liquid products also show high radical scavenging activity, that is 78.5% against DPPH and 47.2% against superoxide radicals. The antibacterial assays show that the liquid product obtained from hydrothermal treatment at 140°C has better activity than the extract, with inhibition rate of 61.1 and 97.2% against Escherichia coli and Staphylococcus aureus, respectively.
A Review of the Development and Role of Heterogeneous Catalysts for Biodiesel Production Yuliana, Maria; Ismadji, Suryadi; Wijaya, Christian Julius; Soetaredjo, Felycia Edi; Gunarto, Chintya; Santoso, Shella Permatasari; Putro, Jindrayani Nyoo; Anggorowati, Adriana Anteng; Lourentius, Suratno
Widya Teknik Vol. 23 No. 1 (2024): May
Publisher : Fakultas Teknik, Universitas Katolik Widya Mandala Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33508/wt.v23i1.5453

Abstract

Indonesian regulations regarding the implementation of B30 encourage a significant increase in biodiesel demand. Moreover, this implementation will continue to be increased to B35 in 2025 and is projected to reach B100 in 2045. This high demand for biodiesel needs to be supported by the development of adequate biodiesel production technology where the catalyst is one aspect that plays an important role in biodiesel production. The use of catalysts aims to accelerate biodiesel production so that high biodiesel yields and good quality are achieved. In biodiesel production, the choice of catalyst greatly influences the operating conditions, the products produced, the subsequent purification process, and the environmental impacts. Moreover, the changing trend in biodiesel raw materials from food to non-food ingredients requires the development of catalysts that are more suitable for the raw materials used in biodiesel production. The specific characteristics of each catalyst play an important role in the transesterification reaction to produce biodiesel where this needs to be supported and adapted to optimum operating conditions, especially in terms of alcohol-to-oil molar ratio, catalyst amount, temperature, pressure, and reaction time. This review provides a comprehensive overview of the various heterogeneous catalysts used to assist the transesterification reactions in biodiesel production.
Co-Authors Adriana Anteng Anggorowati Angkawijaya, Artik Elisa Chandra Risdian Felycia Edi Soetaredjo Go, Alchris Woo Gunarto, Chintya Hartono, Sandy Budi Lie, Jenni Lourentius, Suratno Puspitasari, Nathania Santoso, Shella Permatasari Setiawaty, Natasya Nadia Poetri Setiyo Gunawan Suryadi Ismadji Wenny Irawaty Wijaya, Christian Julius Yuliana, Maria