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Contact Name
Resti Nurmala Dewi
Contact Email
restinurmaladewi@gmail.com
Phone
+6281360927917
Journal Mail Official
rkl@che.usk.ac.id
Editorial Address
Jurusan Teknik Kimia Universitas Syiah Kuala, Jl. Tgk. Syech Abdur Rauf No.7, Kopelma Darussalam, Banda Aceh, INDONESIA
Location
Kab. aceh besar,
Aceh
INDONESIA
JURNAL REKAYASA KIMIA & LINGKUNGAN
ISSN : 14125064     EISSN : 23561661     DOI : https://doi.org/10.23955/rkl.v18i2.34018
The Journal of Chemical Engineering and Environment is an open access journal that publishes papers on chemical engineering and environmental engineering. The following topics are included in these sciences: Food and biochemical engineering Catalytic reaction engineering Clean energy technology Environmental and safety technology Fundamentals of chemical engineering and applied industrial engineering Industrial chemical engineering Material science engineering Process and control engineering Polymer and petrochemical technology Membrane technology Agro-industrial technology Separation and purification technology Environmental modelling Environmental and information sciences Water and waste water treatment and management Material flow analysis Mechanisms of clean development
Articles 319 Documents
Organo-Silica Membrane Prepared from TEOS-TEVS Modified with Organic-Acid Catalyst for Brackish Water Desalination Elma, Muthia; Lestari, Aptar Eka; Sumardi, Anna; Assyaifi, Zaini Lambri; Darmawan, Adi; Mujiyanti, Dwi Rasy; Syauqiah, Isna; Rahma, Aulia; Suciwati, Linda; Mawaddah, Yanti
Jurnal Rekayasa Kimia & Lingkungan Vol 16, No 1 (2021): Jurnal Rekayasa Kimia & Lingkungan (June, 2021)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v16i2.18107

Abstract

The sol gel process is one of the processes used in the manufacture of thin films on membranes because it can control the pore size in the resulting silica matrix. In addition, another way to build membrane size can be done by adding catalysts and precursors to be used. In this study, using a combination of tetraethyl ortho silicate (TEOS) and triethoxy vinyl silane (TEVS) precursors and citric acid as a catalyst to produce a silica matrix with mesoporous size so that it is suitable for application in the desalination process. The organo silica membrane was calcined at 350 C for 1 hour using the RTP calcination technique under vacuum, thus preventing the decomposition of carbon in the silica matrix. The membrane was dipcoated 4 times to obtain 4 layers. The FTIR (Fourier-transform Infrared Spectroscopy) test was carried out to see the functional groups on xerogel, namely silanol, siloxane and carbon. In addition, the performance of this membrane is carried out by desalination through pervaporation using 0.3% NaCl feed water with variations in feed air temperature, namely 25, 40and 60. The resulting flux of air value increased with increasing feed water temperature, namely 6.1; 11.2; and 12.1kg.m-2h-1while the resulting salt rejection was 99.72; 99.64 and 99.23%. So that the organo silica membrane is suitable when applied to the desalination process through pervaporation.
Biosorbent Prepared from Calotropis Gigantean Stems for Adsorption of Cu(II) Ions from Aqueous Solution Husna, Asmaul; Abdullah, Faisal; Muslim, Abrar; Suhendrayatna, Suhendrayatna; Meilina, Hesti
Jurnal Rekayasa Kimia & Lingkungan Vol 16, No 1 (2021): Jurnal Rekayasa Kimia & Lingkungan (June, 2021)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v16i2.18677

Abstract

Calotropis gigantea stems (CGS) has the potential to use as biosorbent for adsorption of Cu(II) ions. In this study, the CGS biosorbent (CGSB) was prepared by drying and grounding. The effect of independent variables on adsorption capacity were investigated. As the result, the maximum adsorption capacity of 53.457 mg/g was obtained the optimal condition which was initial Cu(II) ions concentration of 567.47 mg/L, CGSB size of less than 230 mesh, CGSB mass of 1 g, temperature of 27 oC, pH 5, and contact time of 60 min. The CGSB surface morphology was analysed using SEM. The adsorption of Cu(II) ions fitted well with pseudo first-order adsorption kinetic (PFO-AK) model (R2=0.99), and the PFO-AK adsorption capacity and rate constant obtained were 70.194 mg/g and 0.0877 g/mg.min, respectively. The adsorption isotherm of Cu(II) ions was in accordance with Freundlich model (R2=0.99), and the intensity and volume constants attained were 0.876 and 1.017 L/mg, respectively. This result showed that physical adsorption occurred dominantly than chemical adsorption. The application of CGSB on the wastewater of initial Cu(II) ions concentration of 389.31 mg/L from ex-mine pool of acid mine drainage (AMD) in Jantang village, Lhoong District, Aceh Besar, Aceh Province resulted in adsorption capacity of 37.52 mg/g with adsorption efficiency of 66.13%.
Alteration of Biodiesel Properties and Automotive Diesel Engine Performance due to Temperature Variation of the Transesterification Process Widjanarko, Dwi; Kusumaningtyas, Ratna Dewi; Fathoni, Ahmad Afwan
Jurnal Rekayasa Kimia & Lingkungan Vol 15, No 2 (2020): Jurnal Rekayasa Kimia & Lingkungan (December, 2020)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v15i2.16007

Abstract

This study aimed to examine the effects of transesterification reaction temperature on the biodiesel properties and diesel engine performance. Biodiesel properties evaluated in this work included viscosity, density, and methyl ester content. Meanwhile, the diesel engine performance testing comprised the examination of the engines torque and power. The research was conducted in several stages, viz. producing biodiesel from fresh cooking oil with variations in transesterification temperature of 45, 55, and 65; testing the characteristics of biodiesel produced; blending biodiesel with petroleum diesel to result in B30 biodiesel fuel; and testing biodiesel fuel (B30) in diesel-engined vehicles. It was revealed that the higher transesterification temperature led to the lower biodiesel viscosity, the decreasing value of biodiesel density values, and the higher methyl ester content. Furthermore, it was also demonstrated that increase of the transesterification temperature resulted in the higher value of torque and power generated. However, compared to the petroleum diesel fuel (B0), biodiesel fuel (B30) exhibited the lower values of the engines torque and power. The highest average values of torque and power of B30 fueled diesel-engine were 108.11 Nm and 43.51 kW, respectively, provided by the biodiesel produced at the transesterification reaction temperature of 65.of 65.
Adsorption of Mercury Using Different Types of Activated Bentonite: A Study of Sorption, Kinetics, and Isotherm Models Naswir, Muhammad; Jalius, Jalius; Natalia, Desfaur; Arita, Susila; Wibowo, Yudha Gusti
Jurnal Rekayasa Kimia & Lingkungan Vol 15, No 2 (2020): Jurnal Rekayasa Kimia & Lingkungan (December, 2020)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v15i2.17784

Abstract

Mercury is a hazardous element because of its toxicity and harmful effects on human health. Various traditional and low-cost methods have been developed to remove mercury from wastewater. This study used local raw material as an alternative adsorbent to treat mercury-contaminated wastewater. Activated bentonite was prepared using different chemical activators (H3PO4, HCl, and ZnCl2) in various concentrations. Then, it was dried at 200C for an hour. The materials were characterized by SEM-EDS. Its percent removal and isotherm models were analyzed. In this study, the most effective activator was H3PO4 and the experimental data matched the Freundlich model.
Preparation and Characterization of Activated Carbon Made from Robusta Coffee Skin (Coffea Canephora) Raihan, Raudhatul; Setiawan, Adi; Hakim, Lukman; Muhammad, Muhammad; Arif, Muhammad; Hosseiniamoli, Hadi
Jurnal Rekayasa Kimia & Lingkungan Vol 15, No 2 (2020): Jurnal Rekayasa Kimia & Lingkungan (December, 2020)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v15i2.17618

Abstract

Indonesia is one of the coffee-producing countries where production tends to increase from year to year. Currently, residuals from coffee-fruit processing such as coffee-skin and husks are thrown away without any use and this biomass residual contains several toxic chemicals such as alkaloids, tannins, and polyphenols. One of potential uses of coffee-industry by-product is to make activated carbon (ACs), which is made through a carbonation process and followed by an activation process. In this study, chemical activation was carried out using chemical activators ZnCl2 and NaOH. The purpose of this study is to prepare and investigate the characteristics of chemically activated coffee skin bio-char focusing on the surface properties and iodine adsorption capacity. Prior to carbon activation, a purpose built pilot-scale reactor was fabricated and tested at temperatures of 400 C and 500 C. The difference in carbonation temperature and variations in activator concentration alter the absorption properties. The results showed that the coffee-skin pyrolyzed at 500 C and activated by 2% NaOH solution exhibits the highest absorption value of 720.2 mg/g. Lower absorption values were observed in any ZnCl2 activator samples. SEM-EDS analysis result suggests significant changes in composition of the ACs before and after activation. Most of impurities are gone during activation and washing. The value of C atoms increases and the pores structure of the activated carbon are expanding showing suitable properties for adsorbent.
Effect of Activator Type on Activated Carbon Characters from Teak Wood and The Bleaching Test for Waste Cooking Oil Sriatun, Sriatun; Herawati, Shabrina; Aisyah, Icha
Jurnal Rekayasa Kimia & Lingkungan Vol 15, No 2 (2020): Jurnal Rekayasa Kimia & Lingkungan (December, 2020)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v15i2.14788

Abstract

The starting material for activated carbon was biomass from teak woodcutting, which consists of 47.5% cellulose, 14.4% hemicellulose, and 29.9% lignin. The surface area and iodine number of activated carbons are the factors determining the adsorption ability. This study aims to determine the effect of the activator type on activated carbon characters and test the absorption ability for waste cooking oil. The synthesis stages include carbonization, chemical activation, and then physics activation. The activation process consists of two steps. Firstly, the chemical activation via adding H2SO4, and H3PO4 at room temperature for 24 hours, the second, physical activation by heating at various temperatures of 300, 400, and 500 C for two hours. The characterizations of activated carbon include water content, ash content, iodine number, functional groups, and surface area. Furthermore, the activated carbon was used as an adsorbent for waste cooking oil for 60 minutes at 100 C with a stirring of 500 rpm. The results were analyzed using UV-Vis spectrophotometry at a maximum wavelength of 403 nm. The iodine numbers of activated carbon ranged 481.1-1211.4 mg/g and 494.8-1204 mg/g for H3PO4 and H2SO4, respectively.Activated carbon with H3PO4 of 15% and an activation temperature of 400 C has the highest surface area of 445.30 m2/g. The H2SO4 dan H3PO4 activators can be used to improve the quality of activated carbon in absorbing dyes in waste cooking oil, where the optimum concentration is 10-15% (v/v). The H3PO4 activator tends to produce a higher bleaching percentage than H2SO4.
Soil Fungal Community Responses to the Silver Nanoparticles Contamination as Assessed by Illumina Next Generation Sequencing (NGS) Oktarina, Hartati; Singleton, Ian
Jurnal Rekayasa Kimia & Lingkungan Vol 15, No 2 (2020): Jurnal Rekayasa Kimia & Lingkungan (December, 2020)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v15i2.16025

Abstract

The increasing use of silver nanoparticles (AgNPs) due to its excellent antimicrobial activity in commercial products prompting concerns about their fate in the environment. The toxicity of AgNPs is mainly the result of Ag+ ions. In this study, soil was experimentally contaminated with 100 mg kg-1 of AgNO3 to investigate its effect on fungal soil community. Deoxyribonucleic acid (DNA) from the soil was extracted at the 6th, 12th, and 24th month of observation and assessed by Illumina Next Generation Sequencing (NGS). The results show that, the pollutant change fungal community in soil. After 12 months incubated the number of fungal species in the soil reduced significantly and 40% of the community was dominated by one species.
Preparation of Hydroxyapatite Scaffold using Luffa Cylindrica Sponge as Template Fadli, Ahmad; Widiyanti, Prihartini; Noviana, Deni; Prabowo, Agung; Ismawati, Heni
Jurnal Rekayasa Kimia & Lingkungan Vol 15, No 2 (2020): Jurnal Rekayasa Kimia & Lingkungan (December, 2020)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v15i2.15957

Abstract

Hydroxyapatite (HA) scaffold has been widely applied in the biomedical field especially for bone implants. The purpose of this research is to determine the influence of dispersant addition and stirring time on HA scaffold which formed using gambas sponges as a template. HA slurry was made by mixing 10 grams of HA, 12 grams of aquadest, 0,2; 0,25; 0,3 grams of Darvan 821A and 1 gram of sago. The slurry was impregnated into Luffa cylindrica sponges. The sample then dried at 110oC for 3 hours. The green bodies were burned at 600oC for 1 hour and followed by sintering at 1250oC for 1 hour. The results showed that the addition of dispersant and increasing of stirring time lead to smaller porosity and shrinkage. In addition 0,2; 0,25; and 0,3 grams dispersant, the resulting porosity in the range of 63,85-70,78%; 58,74-70,35%; and 53,42-69,66%. Shrinkage 39,43-53,71%; 27,75-50,68%; and 13,61-41,25%. Compressive strength 0,61-1,05 MPa; 2,88-3,81MPa; and 0,52-2,96 MPa. The macroporous and microporous average pore sized was 50 m dan 5 m.
Electroanalytical Performance of Graphene Paste Electrode Modified Al(III)-TiO2 Nanocomposites in Fipronil Solution Nurdin, Muhammad; Arham, Zul; Rahayu, Sri; Agus Salim, La Ode; Maulidiyah, Maulidiyah
Jurnal Rekayasa Kimia & Lingkungan Vol 15, No 2 (2020): Jurnal Rekayasa Kimia & Lingkungan (December, 2020)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v15i2.16947

Abstract

The new composite material Al(III)-TiO2 has been synthesized and applied as a modifier of graphene paste electrode for the determination of fipronil pesticide by cyclic voltammetry. The methods were to synthesis of Aluminum-Titanium dioxide (AT), preparation of graphene paste electrode with mass varied Al(III)-TiO2 (GAT) (0.05 g, 0.1 g, 0.2 g), and fipronil electroanalytic respons. Addition of Al(III)-TiO2 to the graphene paste electrode shows redox properties which are well characterized by a fast electron transfer process. Based on the results of measurements in a solution containing fipronil, it is known that fipronil is oxidized at a potential value of 0.26 V. Furthermore, the fipronil oxidation process on the GAT surface is influenced by diffusion control, this is powered by R2 value 0.91 when plotted between peak oxidation currents (Ipa) vs. root scan rate. Other results show that measurement linearity is in the range 0.01 to 0.09 g/L with a limit of detection (LOD) value of 0.0164 g/L. Moreover, GAT shows good stability in the determination of fipronil with% RSD equal to 5%.
Characterization of Activated Coconut Shell Charcoal as a Zinc Absorbent for Used Oil Lubricant Erawati, Emi; Haryanto, Haryanto; Astuti, Neysa Wirantika; Prasetyanti, Annida Mitha
Jurnal Rekayasa Kimia & Lingkungan Vol 15, No 2 (2020): Jurnal Rekayasa Kimia & Lingkungan (December, 2020)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v15i2.13589

Abstract

Lubricating oil is classified as B3 waste (hazardous and toxic waste). In the lubricating oil consists of zinc waste which is very dangeraous for healt and environment. So that to handle lubricating oil is used the adsorption method using coconut shell as adsorbent. This study aims to determine the efficiency of zinc adsorption on lubricating oil with stirring speed, percent solvent, mesh size, and mass of adsorbent variation; to learn the equibilium equation of adsorpsion of Zn metal ion on the activated carbon of coconut shell charcoal using Freundlich and Langmuir equilibirium; and to calculate adsorbtion kinetic constanta using the pseudo first model or pseudo second order kinetics approach. Coconut shells was heated at a temperature of 300C for 1 hour for the driving process . Furthermore, charcoal was soaked in 25% HCl for 18 hours. After being neutralized to pH 7, the charcoal was activated for 3 hours at a temperature of 500C and stored in a closed place. Coconut shell adsorbent and H2SO4 solvent were put into a beaker glass containing 400 ml of lubricating oil and stirred for 2 hours, every 30 minutes intervals were taken 50 ml to destruction for 2 hours with 68% HNO3. The zinc concentration before and after adsorption were measured using AAS. This study uses the Langmuir isotherm and Freundlich Isotherm models. The greatest efficiency of zinc adsorption with solvent percent variation 0.5% is 95.0567% and 99.9375% in adsorbent mass variation of 10 gram.

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